Search Results (13,664)

This paper is dedicated to investigating how short-term indoor temperature drift influences occupants’ thermal sensation in residential nZEB buildings and how this affects the applicability of steady-state comfort prediction. Residential buildings frequently operate under transient conditions, where the classical PMV approach may deviate from reported sensation. The objective of this paper is to evaluate the agreement between steady-state PMV and occupants’ thermal sensation votes under winter conditions to test a regression-based correction index A_eff and an adjusted indicator PMV_adj while preserving the PMV concept. The study uses high-resolution measurements of indoor air temperature and mean radiant temperature synchronised with TSV responses, followed by statistical evaluation using error metrics and correlation analysis. The results show that baseline PMV correlates well with TSV but exhibits a consistent magnitude mismatch under transient conditions. The proposed PMV_adj reduces this mismatch, decreasing NRMSE from 17.61% to 14.00% and slightly improving agreement with Pearson r = 82.18%, R² = 67.54%. Regression analysis shows that A_eff is strongly associated with the indoor air temperature drift rate ΔT_in/Δt with R² = 0.6805, but has a weaker relationship with ΔT_MRT/Δt, R² = 0.1851. The research provides a practical basis for improving PMV-based comfort assessment during winter operation in residential nZEB. Full article

The Jiangsu Provincial Judicial Commissioner’s Office, a significant official yamen and regional judicial-administrative center during the Ming and Qing dynasties, exemplifies one of the rare remaining instances of official architecture in Suzhou. Notwithstanding its historical continuity, the thermal and hygrothermal performance of its high and large historical building areas is unable to meet modern thermal comfort standards. Due to the concept of heritage conservation, “restoring the original state”, changing the thermal properties of the building envelope is difficult. Therefore, this study adopts a combined simulation method using DesignBuilder and Fluent to explore the potential to improve the indoor thermal climate by optimizing the HVAC air supply system. Various situations with differing supply air angles, velocities, and outlet configurations are assessed, utilizing temperature fields, velocity fields, and PMV-PPD indices as the primary evaluation criteria. The study’s findings demonstrate that air supply configurations have a substantial impact on the distribution of comfortable zones. The judicious selection of supply angles, velocities, and outlet arrangements can effectively mitigate vertical temperature stratification and enhance thermal comfort in the primary activity areas. The results offer technical guidance for optimizing HVAC operations in high and large historical buildings while preserving their original architectural characteristics. Full article

The study establishes key patterns in the influence of pre-applied impact-oscillatory loading (IOL) of varying intensity—realizing dynamic non-equilibrium processes (DNP)—in liquid nitrogen on the mechanical properties and structural state of stainless steel X10CrNi18-8. Static tensile deformation was investigated at room temperature following impulsive strain levels of ε_imp = 0.06–2.69%. A wave-like mechanical response of the steel to DNP was observed within this ε_imp range, most pronounced at ε_imp = 0.11% and ε_imp = 2.69%. After DNP at ε_imp = 0.11%, despite a maximum increase in ultimate strength by 5.25%, the relative elongation of the specimen increased to 10.3%. The scatter in ultimate tensile strength specimens across all loading regimes was within 6.38%, while the variation in ductility reached up to 21.25%. In contrast, after ε_imp = 2.69%, the stress–strain diagram resembled that of the steel in its initial state. Metallophysical investigations and X-ray diffraction analysis were conducted to explain the observed effects. At ε_imp > 2.7%, the high-strength but low-ductility X10CrNi18-8 steel undergoes brittle failure under impulsive loading. At the same time, the total fraction of the more brittle martensitic phase in the steel microstructure reaches approximately 22%. Full article

The continuous tightening of emission regulations and the escalating costs of palladium (Pd) and rhodium (Rh) have renewed interest in platinum (Pt)-based three-way catalysts (TWCs) as cost-effective alternatives for gasoline aftertreatment. However, despite extensive studies on Pt/CeO₂ and Pt/Ba-based formulations, the cooperative roles of Ba and Ce and, in particular, the fundamental influence of the Ba/Ce ratio on oxygen mobility, NO_x storage behavior, and Pt–support interactions remain poorly understood. In this work, we address this gap by systematically tuning the Ba/Ce molar ratio in a series of Pt–Ba–Ce/Al₂O₃ catalysts prepared from Ba(CH₃COO)₂ and CeO₂ precursors, and evaluating their structure–function relationships in both fresh and hydrothermally aged states. Through comprehensive characterization (N₂ physisorption, XRD, XPS, H₂-TPR, NO_x-TPD, SEM, CO pulse adsorption, and dynamic light-off testing), we establish previously unrecognized correlations between Ba/Ce ratio–dependent structural evolution and TWC performance. The results reveal that the Ba/Ce ratio exerts a decisive control over catalyst textural properties, Pt dispersion, and interfacial Pt–CeO₂ oxygen species. Low Ba/Ce ratios uniquely promote Pt–Ce interfacial oxygen and O₂ spillover—providing a new mechanistic basis for enhanced low-temperature oxidation and reduction reactions—while higher Ba loading selectively drives BaCO₃ formation and boosts NO_x storage capacity. A clear volcano-type dependence of NO_x storage on the Ba/Ce ratio is demonstrated for the first time. Hydrothermal aging at 850 °C induces PtO_x decomposition, BaCO₃–Al₂O₃ solid-state reactions forming inactive BaAl₂O₄, and Pt sintering, collectively suppressing Pt–Ce interactions and reducing TWC activity. Importantly, an optimized Ba/Ce ratio is shown to mitigate these degradation pathways, offering a new design principle for thermally durable Pt-based TWCs. Overall, this study provides new mechanistic insight into Ba–Ce cooperative effects, establishes the Ba/Ce ratio as a critical and previously overlooked parameter governing Pt–support interactions and NO_x storage, and presents a rational strategy for designing cost-effective, hydrothermally robust Pt-based alternatives to Pd/Rh commercial TWCs. Full article

While organolithium reactions hold great promise in synthetic chemistry, their high reactivity, strong exothermicity, and the instability of intermediates often limit their application, making the effective control of reaction processes difficult in traditional batch reactors. This review systematically summarizes the latest advances in utilizing flow chemistry technology to address process challenges related to organolithium reactions from 2014 to 2025. From a process perspective, we systematically discuss the literature cases regarding three key themes: the synthesis of organic compounds applied in the pharmaceutical field, the development of novel methods centered on effective process control (reaction temperature, residence time, phase state, multi-step reaction sequence, and safety), and fundamental process research on continuous flow organolithium reactions. Analysis shows that continuous flow systems provide a powerful platform for fully realizing the potential of organolithium chemistry by enhancing heat/mass transfer and precisely controlling reaction parameters. This review emphasizes how flow chemistry technology not only improves process safety and efficiency but also enables transformations and process scaling that are difficult or impossible in batch modes, thus providing a novel process intensification method for modern synthetic chemistry. Full article

Supercritical CO₂ pipeline transportation is a crucial link in Carbon Capture, Utilization, and Storage (CCUS). Compared with traditional oil and gas pipelines, if a supercritical CO₂ pipeline is shut down for an excessively long time, the phase state of CO₂ may transform into a gas–liquid two-phase state. It is urgently necessary to conduct research on the phase change mechanism and safety control during the restart process of gas–liquid two-phase CO₂ pipelines. Based on a certain planned supercritical carbon dioxide pipeline demonstration project, this paper proposes a new pipeline safety restart scheme that actively seeks the liquefaction of gaseous CO₂ inside the pipeline by injecting liquid-phase CO₂ at the initial station. Through numerical simulation and experimental methods, the co-variation laws of parameters such as temperature, pressure, density, and phase state during the pipeline restart process were revealed. It was found that the pipeline shutdown and restart process could be subdivided into four stages: shutdown stage, liquefaction stage, pressurization stage, and displacement stage. The phase transition line would form a closed curve that is approximately trapezoidal. It is suggested to optimize the restart scheme from aspects such as reducing the restart time, controlling the pressure rise rate, and saving CO₂ consumption. It is proposed that the liquid holdup of CO₂ fluid in the pipe at the initial moment of restart and the mass flow rate of CO₂ injected at the initial station during the restart process are the main controlling factors affecting the evolution of the phase path of pipeline restart. For the demonstration project, the specific critical threshold values are given. The research results can provide a certain theoretical guidance and reference basis for the safe restart method of supercritical CO₂ pipelines. Full article

The accurate assessment of the aging state of epoxy resin insulation is critical for the safe operation of cast resin dry-type transformers. This study investigates the evolution of activation energy during thermal aging and its correlation with insulation degradation. Accelerated aging experiments at 150 °C, 170 °C, and 200 °C were conducted, followed by frequency-domain dielectric spectroscopy and Havriliak–Negami (HN) model analysis. An improved method for calculating activation energy, incorporating temperature correction via an HN-based model, is proposed. The evolution of key HN parameters—relaxation strength (Δε), relaxation time (τ), and shape parameters (α, β)—serves as the criterion for identifying the dominant aging mechanism: crosslinking at 150 °C, competition between crosslinking and degradation at 170 °C, and degradation-dominated chain scission at 200 °C. Using 150 °C data as a baseline, the initial activation energy is determined to be 90.03 kJ/mol, increasing to 166.83 kJ/mol at the end of service life. A practical, graded insulation condition indicator based on the rate of change in activation energy (ΔEa) is established, providing clear guidance for maintenance decisions—from routine monitoring (ΔEa ≤ 20%) to prioritized inspection or replacement (ΔEa > 60%). The proposed method offers a non-destructive tool for insulation diagnosis, residual life prediction, and condition-based maintenance of dry-type transformers. Full article

Recently, the kinetic improvement of the nitrogenation reaction of lithium hydride (LiH) to form lithium imide (Li₂NH) by adding a scaffold was reported. The scaffold prevents agglomeration of Li₂NH and maintains the activity of LiH, achieving a reduction in reaction temperature and an increase in reaction rate. In this work, a Li–Si alloy, Li₂₂Si₅, was used as a starting material to form nano-sized LiH dispersed in a Li alloy matrix. Lithium nitride (Li₃N) is generated by the reaction between Li₂₂Si₅ and N₂ to form Li₇Si₃, and then Li₃N is converted to LiH with ammonia (NH₃) generation during heat treatment under H₂ flow conditions. Since Li₃N is formed at the nano-scale on the surface of alloy particles, LiH generated from the above nano-Li₃N is also nano-scale. The differential scanning calorimetry results indicate that direct nitrogenation of LiH in the alloy matrix occurred from around 280 °C, which is much lower than that of the LiH powder itself. Such a highly active state might be achieved due to the nano-crystalline LiH confined by the Li alloy as a self-transformed scaffold. From the above experimental results, the nano-confined LiH in the alloy matrix was recognized as a potential NH₃ synthesis technique based on the LiH-Li₂NH type chemical looping process. Full article

In this research, we investigate the interaction between the redox mediator ferrocene carboxylic acid (Fc-COOH) and glucose oxidase (GOD) in order to determine the thermodynamics parameters K_int, ΔG_int, ΔH_int, and ΔS_int using simple UV–visible experiments at different temperatures. Positive values of ΔH_int, ΔS_int, together with a negative value of ΔG_int indicate an entropy-driven hydrophobic interaction typical of spontaneous association processes. The homogeneous electron transfer rate constants between the oxidized organometallic mediator and the reduced enzyme (k_s), along with their activation parameters (ΔG_ET^≠, ΔH_ET^≠ and ΔS_ET^≠), were calculated using data obtained from foot of the wave analysis (FOWA) of cyclic voltammetry experiments performed at variable temperature. According to transition state theory, the obtained parameters indicate a low activation enthalpy that reflects minimal energetic requirements for electron transfer, while the large negative activation entropy suggests the formation of an ordered transition state. The positive activation free energy falls within the expected range for biological electron transfer processes. Variable temperature cyclic voltammetry experiments of ferrocene carboxylic acid (Fc-COOH) were also performed. The obtained ΔG°, ΔH°, and ΔS° parameters indicate strong stabilization of the redox pair, consistent with a small difference in solvation energy. Circular dichroism, UV–vis spectroscopy, and combined CD and UV–Vis Spectroelectrochemistry measurements performed during redox mediation demonstrate that no significant structural alterations occur in either the enzyme or the redox mediator before or during the electron transfer processes. Full article

The rapid growth of new energy vehicles necessitates accurate battery state of health (SOH) assessment to ensure safety and reliability. However, real-world SOH estimation is challenging because users rarely perform full charge–discharge cycles, leaving only fragmented charging segments that obscure true battery capacity. To address this, we propose a data-driven method that reconstructs a virtual full-charge cycle. By clustering charging segments based on temperature and current, the approach creatively splices multiple incomplete curves from similar mileages and conditions into a complete charging profile. This enables robust full-capacity estimation on a large-scale real-world vehicle dataset, achieving estimation errors below 2% when compared with offline validation tests. The method offers a practical and scalable solution for SOH monitoring and fleet management using field data. Full article

We propose a Hybrid Parallel Temporal–Spatial CNN-LSTM (HPTS-CL) architecture for optimized indoor environment modeling in sports halls, addressing the computational and scalability challenges of high-resolution spatiotemporal data processing. The sports hall is partitioned into distinct zones, each processed by dedicated CNN branches to extract localized spatial features, while hierarchical LSTMs capture both short-term zone-specific dynamics and long-term inter-zone dependencies. The system integrates model and data parallelism to distribute workloads across specialized hardware, dynamically balanced to minimize computational bottlenecks. A gated fusion mechanism combines spatial and temporal features adaptively, enabling robust predictions of environmental parameters such as temperature and humidity. The proposed method replaces monolithic CNN-LSTM pipelines with a distributed framework, significantly improving efficiency without sacrificing accuracy. Furthermore, the architecture interfaces seamlessly with existing sensor networks and control systems, prioritizing critical zones through a latency-aware scheduler. Implemented on NVIDIA Jetson AGX Orin edge devices and Google Cloud TPU v4 pods, HPTS-CL demonstrates superior performance in real-time scenarios, leveraging lightweight EfficientNetV2-S for CNNs and IndRNN cells for LSTMs to mitigate gradient vanishing. Experimental results validate the system’s ability to handle large-scale, high-frequency sensor data while maintaining low inference latency, making it a practical solution for intelligent indoor environment optimization. The novelty lies in the hybrid parallelism strategy and hierarchical temporal modeling, which collectively advance the state of the art in distributed spatiotemporal deep learning. Full article

Traditional colloid SERS substrates are mostly based on metal nanoparticles (MNPs), which have complex and time-consuming fabrication processes, poor structural control, and are susceptible to oxidation. As a result, solid-state SERS substrates have emerged as an effective alternative. Here, we propose using two-step mild and hard anodization to fabricate ordered anodic aluminum oxide (AAO) substrates with high total pore circumference for SERS detection. Hybrid pulse anodization (HPA) enables the fabrication of AAO at room temperature using 40 V in the first step and 40, 110, and 120 V in the second step of anodization. The different voltages applied in the second step effectively control the pore diameter, thereby achieving various nanostructures. The enhancement mechanism primarily originates from the high total pore circumference of nanostructures, which generates abundant hot spots around the pore peripherals, thereby significantly amplifying the SERS signal. Sorbic acid is a common preservative widely used in food products and employed as a test substance on high regularity AAO substrates at concentrations of 1000 ppm to 10 ppb. The resulting SERS spectra exhibited distinct characteristic peaks at 1640–1645 cm⁻¹. The analytical enhancement factor is calculated as 1.02 × 10⁵ at the AAO substrate prepared by 110 V with the Si substrate as the reference. By appropriately tuning the process parameters, a limit of detection (LOD) as low as 10 ppb of sorbic acid was achieved. Full article

Accurate knowledge of phase behavior in polyolefin–solvent mixtures is critical for ensuring stable operation and safe scale-up of industrial solution polymerization processes. The binary (n-hexane + ethylene/1-octene copolymer, POE96k-10) and ternary (α-olefin + n-hexane + POE96k-10) phase behaviors were investigated via a visual high-pressure cell (POE96k-10: M_w = 96 kg·mol^–1, M_w/M_n = 3.87, 1-octene mole fraction = 10.31 mol%) at temperatures of 380~480 K and pressures as high as 14 MPa. To systematically analyze the effects of α-olefin mass fraction and type on phase transition, four industrially relevant α-olefins (ethylene, 1-butene, 1-hexene, and 1-octene) were investigated. The results show that the phase transition temperature and pressure for liquid–liquid and liquid–vapor transitions show an approximately linear dependence on α-olefin mass fraction. Ethylene, 1-butene, and 1-hexene lower the phase transition temperature, whereas 1-octene increases it. Ethylene exhibits a strong anti-solvent effect, significantly lowering the transition temperature while increasing the phase transition pressure. The modified Sanchez-Lacombe equation of state (MSL EOS) effectively correlates and reproduces the phase equilibrium data of the α-olefin + n-hexane + POE96k-10 ternary systems, though its accuracy decreases with increasing α-olefin chain length. Full article

In this study, a new experimental method is proposed to evaluate the interaction between psychological state and behavioral changes under fire conditions. The ISO 5660-1 and the OFM (Open Field Maze) were employed to measure combustion characteristics and behavioral responses, respectively. Additional structure components were designed to establish appropriate inhalation environments with controlled temperature and uniform gas concentration within the OFM. A numerical simulation was then conducted to optimize these structural components for each inhalation method. The results confirmed that the proposed structures effectively provided proper thermal conditions and consistent gas concentrations inside the OFM. Therefore, the proposed experimental method improves the practicality and reliability of inhalation toxicology experiments. However, further research is required to enhance gas dispersion and to reduce excessive thermal effects under different inhalation conditions. Full article

Alkaline treatment in 0.2 and 0.4 M NaOH solutions successfully generated controlled mesoporosity into ZSM-5 (Zeolite Socony Mobil-5) zeolite, resulting in average mesopore diameters of approximately 15 and 25 nm, respectively, while preserving the crystalline structure of the zeolite framework. Parent ZSM-5 and its mesoporous derivatives obtained by desilication were used to prepare (Fe species)@(zeolite matrix) composites. The synthesis was carried out by co-precipitating Fe²⁺/Fe³⁺ ions onto both parent and desilicated ZSM-5 matrices under oxygen-free conditions. Comprehensive characterization by X-ray diffraction, scanning electron microscopy, N₂ adsorption, vibrating-sample magnetometry, ⁵⁷Fe Mössbauer spectroscopy, and diffuse reflectance UV–Vis spectroscopy revealed that the degree of introduced mesoporosity dramatically influences the size, dispersion, phase composition, and oxidation state of the iron-containing nanospecies. On purely microporous ZSM-5, relatively large (~15 nm) partially oxidized magnetite nanoparticles are formed predominantly on the external surface, exhibiting superparamagnetism at room temperature (Mₛ = 11 emu/g) and a band gap of 2.12 eV. Increasing mesoporosity leads to progressively smaller and more highly dispersed iron(III) oxo/hydroxo clusters with significantly lower blocking temperatures and reduced magnetization (down to 0.7 emu/g for Fe@ZSM-5_0.4). All composites display strong visible-light absorption confirming their potential as magnetically separable visible-light-driven photocatalysts for environmental remediation. Full article