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14 Results Found

  • Article
  • Open Access
39 Citations
5,643 Views
20 Pages

Synthesis and Characterization of In-Situ-Prepared Nanocomposites Based on Poly(Propylene 2,5-Furan Dicarboxylate) and Aluminosilicate Clays

  • Lazaros Papadopoulos,
  • Zoi Terzopoulou,
  • Dimitrios N. Bikiaris,
  • Dimitra Patsiaoura,
  • Kostantinos Chrissafis,
  • Dimitrios G. Papageorgiou and
  • George Z. Papageorgiou

23 August 2018

Poly(propylene 2,5-furan dicarboxylate) (PPF), or poly(trimethylene 2,5-furan dicarboxylate) (PTF), is a biobased alipharomatic polyester that is expected to replace its fossil-based terephthalate (PPT) and naphthate (PPN) homologues. PPF possesses e...

  • Article
  • Open Access
29 Citations
4,471 Views
19 Pages

Calorimetric and Dielectric Study of Renewable Poly(hexylene 2,5-furan-dicarboxylate)-Based Nanocomposites In Situ Filled with Small Amounts of Graphene Platelets and Silica Nanoparticles

  • Olawale Monsur Sanusi,
  • Lazaros Papadopoulos,
  • Panagiotis A. Klonos,
  • Zoi Terzopoulou,
  • Nourredine Aït Hocine,
  • Abdelkibir Benelfellah,
  • George Z. Papageorgiou,
  • Apostolos Kyritsis and
  • Dimitrios N. Bikiaris

29 May 2020

Poly(hexylene 2,5 furan-dicarboxylate) (PHF) is a relatively new biobased polyester prepared from renewable resources, which is targeted for use in food packaging applications, owing to its great mechanical and gas barrier performance. Since both pro...

  • Article
  • Open Access
1 Citations
2,112 Views
17 Pages

Melting Behaviors of Bio-Based Poly(propylene 2,5-furan dicarboxylate)-b-poly(ethylene glycol) Co Polymers Related to Their Crystal Morphology

  • Ouyang Shi,
  • Peng Li,
  • Chao Yang,
  • Haitian Jiang,
  • Liyue Qin,
  • Wentao Liu,
  • Xiaolin Li and
  • Zhenming Chen

28 December 2023

In this experiment, a series of poly(propylene 2,5-furan dicarboxylate)-b-poly(ethylene glycol) (PPFEG) copolymers with different ratios were synthesized using melt polycondensation of dimethylfuran-2,5-dicarboxylate (DMFD), 1,3-propanediol (PDO) and...

  • Article
  • Open Access
2 Citations
2,342 Views
18 Pages

Study on Impact of Monomers Towards High Molecular Weight Bio-Based Poly(ethylene Furanoate) via Solid State Polymerization Technique

  • Johan Stanley,
  • Eleftheria Xanthopoulou,
  • Margaritis Kostoglou,
  • Lidija Fras Zemljič,
  • Dimitra A. Lambropoulou and
  • Dimitrios N. Bikiaris

26 November 2024

In recent years, bio-based poly(ethylene furanoate) has gained the attention of packaging industries owing to its remarkable properties as a promising alternative to fossil-based polymers. It is necessary to synthesize high-molecular-weight polymers...

  • Article
  • Open Access
11 Citations
3,014 Views
23 Pages

Blending PLA with Polyesters Based on 2,5-Furan Dicarboxylic Acid: Evaluation of Physicochemical and Nanomechanical Properties

  • Zoi Terzopoulou,
  • Alexandra Zamboulis,
  • Lazaros Papadopoulos,
  • Maria-Eirini Grigora,
  • Konstantinos Tsongas,
  • Dimitrios Tzetzis,
  • Dimitrios N. Bikiaris and
  • George Z. Papageorgiou

4 November 2022

Poly(lactic acid) (PLA) is a readily available, compostable biobased polyester with high strength and toughness, and it is excellent for 3D printing applications. Polymer blending is an economic and easy way to improve its properties, such as its slo...

  • Feature Paper
  • Article
  • Open Access
21 Citations
4,373 Views
16 Pages

Towards High Molecular Weight Furan-Based Polyesters: Solid State Polymerization Study of Bio-Based Poly(Propylene Furanoate) and Poly(Butylene Furanoate)

  • Lazaros Papadopoulos,
  • Eleftheria Xanthopoulou,
  • George N. Nikolaidis,
  • Alexandra Zamboulis,
  • Dimitris S. Achilias,
  • George Z. Papageorgiou and
  • Dimitrios N. Bikiaris

30 October 2020

In the era of polymers from renewable resources, polyesters derived from 2,5 furan dicarboxylic acid (FDCA) have received increasing attention due to their outstanding features. To commercialize them, it is necessary to synthesize high molecular weig...

  • Article
  • Open Access
25 Citations
6,102 Views
17 Pages

Thermal Decomposition Kinetics and Mechanism of In-Situ Prepared Bio-Based Poly(propylene 2,5-furan dicarboxylate)/Graphene Nanocomposites

  • Zoi Terzopoulou,
  • Evangelia Tarani,
  • Nejib Kasmi,
  • Lazaros Papadopoulos,
  • Konstantinos Chrissafis,
  • Dimitrios G. Papageorgiou,
  • George Z. Papageorgiou and
  • Dimitrios N. Bikiaris

Bio-based polyesters are a new class of materials that are expected to replace their fossil-based homologues in the near future. In this work, poly(propylene 2,5-furandicarboxylate) (PPF) nanocomposites with graphene nanoplatelets were prepared via t...

  • Article
  • Open Access
69 Citations
7,521 Views
9 Pages

Structural Investigation of Poly(ethylene furanoate) Polymorphs

  • Lucia Maini,
  • Matteo Gigli,
  • Massimo Gazzano,
  • Nadia Lotti,
  • Dimitrios N. Bikiaris and
  • George Z. Papageorgiou

9 March 2018

α and β crystalline phases of poly(ethylene furanoate) (PEF) were determined using X-ray powder diffraction by structure resolution in direct space and Rietveld refinement. Moreover, the α’ structure of a PEF sample was refined from data previously r...

  • Article
  • Open Access
21 Citations
8,681 Views
18 Pages

Polyol Structure and Ionic Moieties Influence the Hydrolytic Stability and Enzymatic Hydrolysis of Bio-Based 2,5-Furandicarboxylic Acid (FDCA) Copolyesters

  • Karolina Haernvall,
  • Sabine Zitzenbacher,
  • Motonori Yamamoto,
  • Michael Bernhard Schick,
  • Doris Ribitsch and
  • Georg M. Guebitz

30 August 2017

A series of copolyesters based on furanic acid and sulfonated isophthalic acid with various polyols were synthetized and their susceptibility to enzymatic hydrolysis by cutinase 1 from Thermobifida cellulosilytica (Thc_Cut1) investigated. All copolye...

  • Article
  • Open Access
21 Citations
6,107 Views
26 Pages

Effect of Monomer Type on the Synthesis and Properties of Poly(Ethylene Furanoate)

  • Johan Stanley,
  • Zoi Terzopoulou,
  • Panagiotis A. Klonos,
  • Alexandra Zamboulis,
  • Eleftheria Xanthopoulou,
  • Savvas Koltsakidis,
  • Dimitrios Tzetzis,
  • Lidija Fras Zemljič,
  • Dimitra A. Lambropoulou and
  • Dimitrios N. Bikiaris
  • + 2 authors

16 June 2023

This work aimed to produce bio-based poly(ethylene furanoate) (PEF) with a high molecular weight using 2,5-furan dicarboxylic acid (FDCA) or its derivative dimethyl 2,5-furan dicarboxylate (DMFD), targeting food packaging applications. The effect of...

  • Article
  • Open Access
7 Citations
3,010 Views
12 Pages

5 June 2022

A series of poly(ester amide)s based on dimethyl furan 2,5-dicarboxylate (DMFDC), 1,3-propanediol (PDO), 1,6-hexylene glycol (HDO), and 1,3-diaminopropane (DAP) were synthesized via two-step melt polycondensation. The phase transition temperatures an...

  • Article
  • Open Access
41 Citations
6,672 Views
17 Pages

12 June 2020

Environmentally friendly polymer blends between post-consumer PET-G and bio-based poly(ethylene 2,5 furanoate) (PEF) have been prepared. The PET-G granules were obtained from the post-consumer glycol-modified poly(ethylene terephthalate) PET-G foils...

  • Article
  • Open Access
1 Citations
954 Views
25 Pages

Ecofriendly PEF- and PBF-Based Blends with Epoxidized Natural Rubber: Unraveling the Structure–Property Relationship

  • Sandra Paszkiewicz,
  • Konrad Walkowiak,
  • Izabela Irska,
  • Jakub Śmigielski,
  • Elżbieta Piesowicz,
  • Aleksander Hejna,
  • Beata Dudziec and
  • Mateusz Barczewski

28 August 2025

Two series of environmentally friendly polymer blends of bio-based poly(ethylene 2,5 furanoate) (PEF) and poly(butylene 2,5 furanoate) (PBF) with epoxidized natural rubber (epNR) have been prepared. Both bio-based polyesters were synthesized from dim...

  • Article
  • Open Access
33 Citations
5,009 Views
14 Pages

An Eco-Friendly Method to Get a Bio-Based Dicarboxylic Acid Monomer 2,5-Furandicarboxylic Acid and Its Application in the Synthesis of Poly(hexylene 2,5-furandicarboxylate) (PHF)

  • Junhua Zhang,
  • Qidi Liang,
  • Wenxing Xie,
  • Lincai Peng,
  • Liang He,
  • Zhibin He,
  • Susmita Paul Chowdhury,
  • Ryan Christensen and
  • Yonghao Ni

23 January 2019

Recently, we have developed an eco-friendly method for the preparation of a renewable dicarboxylic acid 2,5-furandicarboxylic acid (FDCA) from biomass-based 5-hydroxymethylfrufural (HMF). In the present work, we optimized our reported method, which u...