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21 pages, 1946 KiB  
Article
Three-Dimensional Modelling for Interfacial Behavior of a Thin Penny-Shaped Piezo-Thermo-Diffusive Actuator
by Hui Zhang, Lan Zhang and Hua-Yang Dang
Modelling 2025, 6(3), 78; https://doi.org/10.3390/modelling6030078 - 5 Aug 2025
Abstract
This paper presents a theoretical model of a thin, penny-shaped piezoelectric actuator bonded to an isotropic thermo-elastic substrate under coupled electrical-thermal-diffusive loading. The problem is assumed to be axisymmetric, and the peeling stress of the film is neglected in accordance with membrane theory, [...] Read more.
This paper presents a theoretical model of a thin, penny-shaped piezoelectric actuator bonded to an isotropic thermo-elastic substrate under coupled electrical-thermal-diffusive loading. The problem is assumed to be axisymmetric, and the peeling stress of the film is neglected in accordance with membrane theory, yielding a simplified equilibrium equation for the piezoelectric film. By employing potential theory and the Hankel transform technique, the surface strain of the substrate is analytically derived. Under the assumption of perfect bonding, a governing integral equation is established in terms of interfacial shear stress. The solution to this integral equation is obtained numerically using orthotropic Chebyshev polynomials. The derived results include the interfacial shear stress, stress intensity factors, as well as the radial and hoop stresses within the system. Finite element analysis is conducted to validate the theoretical predictions. Furthermore, parametric studies elucidate the influence of material mismatch and actuator geometry on the mechanical response. The findings demonstrate that, the performance of the piezoelectric actuator can be optimized through judicious control of the applied electrical-thermal-diffusive loads and careful selection of material and geometric parameters. This work provides valuable insights for the design and optimization of piezoelectric actuator structures in practical engineering applications. Full article
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13 pages, 1623 KiB  
Article
Effect of Absolute Ethanol and Thermal Treatment on Shrinkage and Mechanical Properties of TPU Electrospun Nanofiber Membranes
by Lei Wang, Ming Kong, Shengchun Wang, Chunsheng Li and Min Yang
Coatings 2025, 15(8), 897; https://doi.org/10.3390/coatings15080897 (registering DOI) - 1 Aug 2025
Viewed by 166
Abstract
Thermoplastic polyurethane (TPU) electrospun fiber membranes possess unique micro-nano structures and excellent properties. Adjusting their wettability enables the directional transportation of lubricants. A conventional method for adjusting porosity and wettability involves inducing membrane shrinkage using absolute ethanol and heat treatment. However, the shrinkage [...] Read more.
Thermoplastic polyurethane (TPU) electrospun fiber membranes possess unique micro-nano structures and excellent properties. Adjusting their wettability enables the directional transportation of lubricants. A conventional method for adjusting porosity and wettability involves inducing membrane shrinkage using absolute ethanol and heat treatment. However, the shrinkage response and the corresponding changes in the tensile properties of TPU fiber membranes after induction remain unclear, limiting their applications. Thus, in this study, after being peeled off, the samples were first left to stand at room temperature (RT) for 24 h to release residual stress and stabilize their dimensions, and then treated with dehydrated ethanol at RT and high temperature, respectively, with their shrinkage behaviors observed and recorded. The results showed that TPU nanofiber membranes shrank significantly in absolute ethanol, and the degree of shrinkage was temperature-dependent. The shrinkage rates were 2% and 4% in dehydrated ethanol at room temperature and high temperature, respectively, and heating increased the shrinkage effect by 200%. These findings prove that absolute ethanol causes TPU fibers to shrink, and high temperatures further promote shrinkage. However, although the strong synergistic effect of heat and solvent accelerates shrinkage, it may induce internal structural defects, resulting in the deterioration of mechanical properties. The contraction response induced by anhydrous ethanol stimulation can be used to directionally adjust the local density and modulus of TPU nanofiber membranes, thereby changing the wettability. This approach provides new opportunities for applications in areas such as medium transportation and interface friction reduction in lubrication systems. Full article
(This article belongs to the Section Surface Characterization, Deposition and Modification)
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21 pages, 3814 KiB  
Article
Features of the Structure of Layered Epoxy Composite Coatings Formed on a Metal-Ceramic-Coated Aluminum Base
by Volodymyr Korzhyk, Volodymyr Kopei, Petro Stukhliak, Olena Berdnikova, Olga Kushnarova, Oleg Kolisnichenko, Oleg Totosko, Danylo Stukhliak and Liubomyr Ropyak
Materials 2025, 18(15), 3620; https://doi.org/10.3390/ma18153620 - 1 Aug 2025
Viewed by 246
Abstract
Difficult, extreme operating conditions of parabolic antennas under precipitation and sub-zero temperatures require the creation of effective heating systems. The purpose of the research is to develop a multilayer coating containing two metal-ceramic layers, epoxy composite layers, carbon fabric, and an outer layer [...] Read more.
Difficult, extreme operating conditions of parabolic antennas under precipitation and sub-zero temperatures require the creation of effective heating systems. The purpose of the research is to develop a multilayer coating containing two metal-ceramic layers, epoxy composite layers, carbon fabric, and an outer layer of basalt fabric, which allows for effective heating of the antenna, and to study the properties of this coating. The multilayer coating was formed on an aluminum base that was subjected to abrasive jet processing. The first and second metal-ceramic layers, Al2O3 + 5% Al, which were applied by high-speed multi-chamber cumulative detonation spraying (CDS), respectively, provide maximum adhesion strength to the aluminum base and high adhesion strength to the third layer of the epoxy composite containing Al2O3. On this not-yet-polymerized layer of epoxy composite containing Al2O3, a layer of carbon fabric (impregnated with epoxy resin) was formed, which serves as a resistive heating element. On top of this carbon fabric, a layer of epoxy composite containing Cr2O3 and SiO2 was applied. Next, basalt fabric was applied to this still-not-yet-polymerized layer. Then, the resulting layered coating was compacted and dried. To study this multilayer coating, X-ray analysis, light and raster scanning microscopy, and transmission electron microscopy were used. The thickness of the coating layers and microhardness were measured on transverse microsections. The adhesion strength of the metal-ceramic coating layers to the aluminum base was determined by both bending testing and peeling using the adhesive method. It was established that CDS provides the formation of metal-ceramic layers with a maximum fraction of lamellae and a microhardness of 7900–10,520 MPa. In these metal-ceramic layers, a dispersed subgrain structure, a uniform distribution of nanoparticles, and a gradient-free level of dislocation density are observed. Such a structure prevents the formation of local concentrators of internal stresses, thereby increasing the level of dispersion and substructural strengthening of the metal-ceramic layers’ material. The formation of materials with a nanostructure increases their strength and crack resistance. The effectiveness of using aluminum, chromium, and silicon oxides as nanofillers in epoxy composite layers was demonstrated. The presence of structures near the surface of these nanofillers, which differ from the properties of the epoxy matrix in the coating, was established. Such zones, specifically the outer surface layers (OSL), significantly affect the properties of the epoxy composite. The results of industrial tests showed the high performance of the multilayer coating during antenna heating. Full article
(This article belongs to the Section Metals and Alloys)
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18 pages, 9314 KiB  
Article
Damage Mechanism and Modeling of CFRP Laminates Impacted by Single Waterjets: Effect of the Impact Direction
by Naidan Hou, Yulong Li and Ping Liu
Materials 2025, 18(15), 3495; https://doi.org/10.3390/ma18153495 - 25 Jul 2025
Viewed by 253
Abstract
In engineering practice, liquid droplet impingement typically occurs at an oblique angle relative to the target surface, yet the influence of impact orientation on damage outcomes remains contentious and exhibits target-material dependency. In this paper, a typical single-waterjet-generating technique is applied to liquid [...] Read more.
In engineering practice, liquid droplet impingement typically occurs at an oblique angle relative to the target surface, yet the influence of impact orientation on damage outcomes remains contentious and exhibits target-material dependency. In this paper, a typical single-waterjet-generating technique is applied to liquid impact tests on a unidirectional carbon fiber-reinforced polymer (CFRP) laminate, with special focus on the effects of the impingement angle and the fiber orientation. Finite-element simulation is employed to help reveal the failure mechanism of oblique impacts. The results show that, in most cases, the damage caused by a 15° oblique impact is slightly larger than that of a normal impact, while the increase amplitude varies with different impact speeds. Resin removal is more prone to occur when the projection of the waterjet velocity on the impact surface is perpendicular (marked as the fiber orientation PE) rather than parallel (marked as the fiber orientation PA) to the fiber direction of the top layer. A PE fiber orientation can lead to mass material peeling in comparison with PA, and the damage range is even much larger than for a normal impact. The underlying mechanism can be attributed to the increased lateral jet-particle velocity and resultant shear stress along the impact projection direction. The distinct damage modes observed on the CFRP laminate with the different fiber orientations PE and PA originate from the asymmetric tensile properties in the longitudinal/transverse directions of laminates coupled with dissimilar fiber–matrix interfacial characteristics. A theoretical model for the surface damage area under a single-jet impact was established through experimental data fitting based on a modified water-hammer pressure contact-radius formulation. The model quantitatively characterizes the influence of critical parameters, including the jet velocity, diameter, and impact angle, on the central area of the surface failure ring. Full article
(This article belongs to the Section Mechanics of Materials)
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18 pages, 7058 KiB  
Article
Failure Analysis and Optimized Simulation Design of Silicon Micromechanical Resonant Accelerometers
by Jingchen Wang, Heng Liu and Zhi Li
Sensors 2025, 25(15), 4583; https://doi.org/10.3390/s25154583 - 24 Jul 2025
Viewed by 203
Abstract
To develop solutions to the frequency instability and failure of silicon micromechanical resonant accelerometers, the state characteristics of micromechanical resonant accelerometers are investigated under temperature and vibration stresses. Through theoretical analysis and finite element simulation, the following is found: the Young’s modulus of [...] Read more.
To develop solutions to the frequency instability and failure of silicon micromechanical resonant accelerometers, the state characteristics of micromechanical resonant accelerometers are investigated under temperature and vibration stresses. Through theoretical analysis and finite element simulation, the following is found: the Young’s modulus of silicon varies with temperature, causing a resonance frequency shift of −1.364 Hz/°C; the residual stress of temperature change affects the resonance frequency shift of the microstructure, causing it to be 5.43 Hz/MPa (tensile stress) and −5.25 Hz/MPa (compressive stress); thermal expansion triggers the failure of the bonding wire, and, in the range of 10 °C to 150 °C, the peak stress of the electrode/lead bond area increases from 83.2/85.6 MPa to 1.08/1.28 GPa. The failure mode under vibration stress is resonance structure fracture and interlayer peeling. An isolation frame design is proposed for the sensitive part of the microstructure, which reduces the frequency effects by 34% (tensile stress) and 15% (compressive stress) under temperature-variable residual stresses and the maximum value of the structural root mean square stresses by 69.7% (X-direction), 63.6% (Y-direction), and 71.3% (Z-direction) under vibrational stresses. Full article
(This article belongs to the Section Physical Sensors)
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19 pages, 3112 KiB  
Article
Durable Superhydrophobic Composite Coating Based on Hydrangea-like SiO2 Nanoparticles with Excellent Performance in Anticorrosion, Drag Reduction, and Antifouling
by Yuhao Xue, Yamei Zhao, Xiaoqi Gu, Mengdan Huo, Kunde Yang, Mingyu Liu, Sixian Fan and Maoyong Zhi
Materials 2025, 18(15), 3443; https://doi.org/10.3390/ma18153443 - 23 Jul 2025
Viewed by 273
Abstract
Superhydrophobic coatings possess distinct wettability characteristics and hold significant potential in metal corrosion protection and underwater drag reduction. However, their practical application is often hindered by poor durability arising from the fragility of their micro/nanostructured surface roughness. In this study, a durable superhydrophobic [...] Read more.
Superhydrophobic coatings possess distinct wettability characteristics and hold significant potential in metal corrosion protection and underwater drag reduction. However, their practical application is often hindered by poor durability arising from the fragility of their micro/nanostructured surface roughness. In this study, a durable superhydrophobic coating featuring a hierarchical, hydrangea-like micro/nanostructure was successfully fabricated on an aluminum alloy substrate via a simple one-step cold-spraying technique. The coating consisted of hydrangea-shaped SiO2 nanoparticles modified with 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (PFDT) to produce multiscale roughness, while epoxy resin (EP) served as the binding matrix to enhance mechanical integrity. The hydrangea-like SiO2 nanostructures were characterized by solid cores and wrinkled, petal-like outgrowths. This unique morphology not only increased the surface roughness but also provided more active sites for air entrapment, thereby enhancing the coating’s overall performance. The h-SiO2@PFDT-EP composite coating exhibited excellent superhydrophobicity, with a WCA of 170.1° ± 0.8° and a SA of 2.7° ± 0.5°. Durability was evaluated through sandpaper abrasion, tape peeling, acid and alkali immersion, artificial weathering, and salt spray tests. The results demonstrated that the coating retained stable superhydrophobic performance under various environmental stresses. Compared with bare 6061 aluminum and EP coatings, its corrosion current density was reduced by four and three orders of magnitude, respectively. Furthermore, the coating achieved a maximum drag-reduction rate of 31.01% within a velocity range of 1.31–7.86 m/s. The coating also displayed excellent self-cleaning properties. Owing to its outstanding durability, corrosion resistance, and drag-reducing capability, this one-step fabricated superhydrophobic coating showed great promise for applications in marine engineering and defense. Full article
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16 pages, 614 KiB  
Article
Bioactive Properties of Persea americana Peel Extract and Their Role in Hypercholesterolemia Management and Cardiovascular Health
by Laura M. Teixeira, Catarina P. Reis and Rita Pacheco
Foods 2025, 14(14), 2482; https://doi.org/10.3390/foods14142482 - 16 Jul 2025
Viewed by 237
Abstract
Cardiovascular diseases remain the leading cause of death worldwide, with hypercholesterolemia being a major contributing risk factor. Although cholesterol-lowering drugs are widely available, concerns about several adverse side effects have increased the demand for natural alternatives, with the most common approaches involving the [...] Read more.
Cardiovascular diseases remain the leading cause of death worldwide, with hypercholesterolemia being a major contributing risk factor. Although cholesterol-lowering drugs are widely available, concerns about several adverse side effects have increased the demand for natural alternatives, with the most common approaches involving the incorporation of foods rich in bioactive compounds into the diet. To explore this growing interest in food-based strategies for cardiovascular health, this study formulated and evaluated an aqueous peel extract of Persea americana to assess its potential role as a complementary approach to managing hypercholesterolemia. The extract was characterized, revealing the presence of various bioactive compounds, including pyridoxine-O-Hex, which was identified for the first time in a P. americana extract component. The safety profile of the extract was confirmed through in vivo assessment. Furthermore, the extract demonstrated protective effects against oxidative stress in HepG2 cells. Additionally, permeability studies using Caco-2 cells, as a model of the gastrointestinal barrier, indicated that the extract effectively reduced cholesterol’s permeation. In summary, these findings suggest that P. americana peel extract may serve as a promising natural product for functional foods for cardiovascular health and hypercholesterolemia management. Full article
(This article belongs to the Special Issue Advances in Biological Activities of Functional Food (3rd Edition))
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28 pages, 7820 KiB  
Review
Mechanisms and Performance of Composite Joints Through Adhesive and Interlocking Means—A Review
by Khishigdorj Davaasambuu, Yu Dong, Alokesh Pramanik and Animesh Kumar Basak
J. Compos. Sci. 2025, 9(7), 359; https://doi.org/10.3390/jcs9070359 - 10 Jul 2025
Viewed by 864
Abstract
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their [...] Read more.
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their geometries and mechanical properties of bonded materials. As such, joint geometry and material properties play a critical role in determining the capability of the joints to withstand high loads, resist fatigue, and absorb energy under impact loading. This paper investigates the effects of geometry and material dissimilarity on the performance of both conventional bonded and interlocking joints under tensile loading based on the information available in the literature. In addition, bonding and load transfer mechanisms were analysed in detail. It was found that stress concentration often occurs at free edges of the adhesive layer due to geometric discontinuities, while most of the load is carried by these regions rather than its centre. Sharp corners further intensify resulting stresses, thereby increasing the risk of joint failure. Adhesives typically resist shear loads better than peel loads, and stiffness mismatches between adherents induce an asymmetric stress distribution. Nonetheless, similar materials promote symmetric load sharing. Among conventional joints, scarf joints provide the most uniform load distribution. In interlocking joints such as dovetail, T-slot, gooseneck, and elliptical types, the outward bending of the female component under tension can lead to mechanical failure. Full article
(This article belongs to the Special Issue Mechanical Properties of Composite Materials and Joints)
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31 pages, 8652 KiB  
Article
Study on Road Performance and Ice-Breaking Effect of Rubber Polyurethane Gel Mixture
by Yuanzhao Chen, Zhenxia Li, Tengteng Guo, Chenze Fang, Jingyu Yang, Peng Guo, Chaohui Wang, Bing Bai, Weiguang Zhang, Deqing Tang and Jiajie Feng
Gels 2025, 11(7), 505; https://doi.org/10.3390/gels11070505 - 29 Jun 2025
Viewed by 371
Abstract
Aiming at the problems of serious pavement temperature diseases, low efficiency and high loss of ice-breaking methods, high occupancy rate of waste tires and the low utilization rate and insufficient durability of rubber particles, this paper aims to improve the service level of [...] Read more.
Aiming at the problems of serious pavement temperature diseases, low efficiency and high loss of ice-breaking methods, high occupancy rate of waste tires and the low utilization rate and insufficient durability of rubber particles, this paper aims to improve the service level of roads and ensure the safety of winter pavements. A pavement material with high efficiency, low carbon and environmental friendliness for active snow melting and ice breaking is developed. Firstly, NaOH, NaClO and KH550 were used to optimize the treatment of rubber particles. The hydrophilic properties, surface morphology and phase composition of rubber particles before and after optimization were studied, and the optimal treatment method of rubber particles was determined. Then, the optimized rubber particles were used to replace the natural aggregate in the polyurethane gel mixture by the volume substitution method, and the optimum polyurethane gel dosages and molding and curing processes were determined. Finally, the influence law of the road performance of RPGM was compared and analyzed by means of an indoor test, and the ice-breaking effect of RPGM was explored. The results showed that the contact angles of rubber particles treated with three solutions were reduced by 22.5%, 30.2% and 36.7%, respectively. The surface energy was improved, the element types on the surface of rubber particles were reduced and the surface impurities were effectively removed. Among them, the improvement effect of the KH550 solution was the most significant. With the increase in rubber particle content from 0% to 15%, the dynamic stability of the mixture gradually increases, with a maximum increase of 23.5%. The maximum bending strain increases with the increase in its content. The residual stability increases first and then decreases with the increase in rubber particle content, and the increase ranges are 1.4%, 3.3% and 0.5%, respectively. The anti-scattering performance increases with the increase in rubber content, and an excessive amount will lead to an increase in the scattering loss rate, but it can still be maintained below 5%. The fatigue life of polyurethane gel mixtures with 0%, 5%, 10% and 15% rubber particles is 2.9 times, 3.8 times, 4.3 times and 4.0 times higher than that of the AC-13 asphalt mixture, respectively, showing excellent anti-fatigue performance. The friction coefficient of the mixture increases with an increase in the rubber particle content, which can be increased by 22.3% compared with the ordinary asphalt mixture. RPGM shows better de-icing performance than traditional asphalt mixtures, and with an increase in rubber particle content, the ice-breaking ability is effectively improved. When the thickness of the ice layer exceeds 9 mm, the ice-breaking ability of the mixture is significantly weakened. Mainly through the synergistic effect of stress coupling, thermal effect and interface failure, the bonding performance of the ice–pavement interface is weakened under the action of driving load cycle, and the ice layer is loosened, broken and peeled off, achieving efficient de-icing. Full article
(This article belongs to the Special Issue Synthesis, Properties, and Applications of Novel Polymer-Based Gels)
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19 pages, 3400 KiB  
Article
Garlic Peel-Derived Phytochemicals Using GC-MS: Antioxidant, Anti-Inflammatory, and Anti-Apoptotic Effects in Ulcerative Colitis Rat Model
by Duaa A. Althumairy, Rasha Abu-Khudir, Afnan I. Alandanoosi and Gehan M. Badr
Pharmaceuticals 2025, 18(7), 969; https://doi.org/10.3390/ph18070969 - 27 Jun 2025
Viewed by 600
Abstract
Background/Objectives: Ulcerative colitis (UC) is a chronic, relapsing inflammatory bowel disease (IBD) that poses a significant gastroenterological challenge. Methods: This study investigates the protective effects of garlic peel extract (GPE) in a rat model of acetic acid (AA)-induced colitis. Rats received [...] Read more.
Background/Objectives: Ulcerative colitis (UC) is a chronic, relapsing inflammatory bowel disease (IBD) that poses a significant gastroenterological challenge. Methods: This study investigates the protective effects of garlic peel extract (GPE) in a rat model of acetic acid (AA)-induced colitis. Rats received oral GPE (100 mg/kg) for 14 days prior to AA administration, and this continued for 14 days post-induction. Results: GC-MS analysis of GPE identified several key phytochemicals, primarily methyl esters of fatty acids (62.47%), fatty acids (10.36%), fatty acid derivatives (6.75%), and vitamins (4.86%) as the major constituents. Other notable compounds included steroids, natural alcohols, organosulfur compounds, fatty aldehydes, carotenoids, sugars, and glucosinolates. GPE treatment significantly improved body weight and colon length. Biochemical analysis showed that GPE downregulated the levels of the pro-inflammatory cytokines interleukin-1 (IL-1), IL-6, IL-17, tumor necrosis factor-alpha (TNF-α), and nuclear factor-kappa B (NF-κB), compared to the colitis (AA) group. Additionally, GPE reduced the oxidative stress (OS) biomarkers, including myeloperoxidase (MPO) and malondialdehyde (MDA), as well as caspase-3, a marker for apoptosis. Furthermore, GPE treatment resulted in enhanced activities of the enzymatic antioxidants catalase (CAT) and superoxide dismutase (SOD), along with increased levels of the anti-inflammatory cytokine IL-10. These findings were supported by histological evidence. Conclusions: Collectively, GPE holds promise as a therapeutic strategy for UC, owing to its natural bioactive compounds and their potential synergistic anti-inflammatory, antioxidant, and anti-apoptotic effects. Full article
(This article belongs to the Section Natural Products)
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19 pages, 1032 KiB  
Article
Red Beetroot Skin Powder Addition as a Multifunctional Ingredient in Nougat
by Oana Emilia Constantin, Silvia Lazăr (Mistrianu), Florina Stoica, Roxana Nicoleta Rațu, Doina Georgeta Andronoiu, Nicoleta Stănciuc, Marija Banožić, Nada Ćujić Nikolić, Zorana Mutavski and Gabriela Râpeanu
Antioxidants 2025, 14(6), 676; https://doi.org/10.3390/antiox14060676 - 1 Jun 2025
Viewed by 956
Abstract
Beetroot (Beta vulgaris L.) is a plant grown for its roots, which are used to obtain sugar, feed animals, and for human use. Beetroot skin, a by-product of food processing, is a significant source of bioactive compounds, including dietary fiber and antioxidants. [...] Read more.
Beetroot (Beta vulgaris L.) is a plant grown for its roots, which are used to obtain sugar, feed animals, and for human use. Beetroot skin, a by-product of food processing, is a significant source of bioactive compounds, including dietary fiber and antioxidants. The primary objective of this work was to utilize beetroot skin powder to produce value-added nougat. Analytical methods, like antioxidant activity tests, proximate analysis, and sensory assessments, are used to determine the impact of beetroot skin powder on the final product. The beetroot skin powder extract had a remarkable content of phytochemicals and antioxidant activity. The inhibitory effect of the extract was tested on enzymes linked to metabolic syndrome, oxidative stress, and inflammation. The beetroot skin powder extract inhibited α-glucosidase, α-amylase, lipase, and lipoxygenase enzymes. The characterization of value-added nougat illustrates the multifunctionality of beetroot peel powder within its composition, serving as a significant source of natural compounds with antioxidant, coloring, and flavoring properties. This enhances sensory attributes, including color, aroma, and texture, augmenting product diversity and consumer appeal. This is evidenced by the increase in the total content of betalains (3.77 ± 0.09 mg/g DW.) and polyphenols (69.48 ± 2.88 mg GAE/100 g DW.), which lead to high antioxidant activity (73.89 ± 3.65 mM Trolox/100 g DW.) for the nougat sample with 6% added beetroot powder. Thus, beetroot skin powder replaced chemically synthesized additives with antioxidants and natural pigments, improving life quality and implicitly capitalizing on beetroot processing by-products, supporting circular economy principles at the global level. Full article
(This article belongs to the Special Issue Valorization of the Antioxidant Power of Natural Compounds)
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19 pages, 1424 KiB  
Article
Jasmonates in the Ethylene-Induced Resistance of Detached Citrus Fruits to Peel Damage
by María T. Lafuente, Raúl Sampedro and Paco Romero
Int. J. Mol. Sci. 2025, 26(10), 4805; https://doi.org/10.3390/ijms26104805 - 17 May 2025
Viewed by 388
Abstract
It is known that nutrient deprivation following detachment can cause non-chilling peel pitting (NCPP) in citrus fruits when stored under a non-stressful environment and that this damage is reduced by pretreating the fruit with ethylene (ETH) (4 d, 10 µL L−1). [...] Read more.
It is known that nutrient deprivation following detachment can cause non-chilling peel pitting (NCPP) in citrus fruits when stored under a non-stressful environment and that this damage is reduced by pretreating the fruit with ethylene (ETH) (4 d, 10 µL L−1). The present work investigates the effect of this pretreatment on jasmonate (JA) accumulation and transcriptional regulation in mature Navelate oranges (Citrus sinensis L. Osbeck) stored under non-stressful conditions. ETH increased the expression of abundant genes participating in the synthesis of cis-(+)-12-oxo-phytodienoic acid (OPDA), jasmonic acid (JA), and methyl jasmonate (MeJA). ETH also upregulated genes involved in jasmonoyl–isoleucine (JAIle) synthesis (CsJAR1) and decrease (CsCYP94B3 and CYP94C1), and CsSTA2, related to JA sulfation. The levels of these JA metabolites increased during fruit holding in ETH and after shifting them to air, with MeJA accumulation being especially remarkable. Overall, the beneficial effect of ETH on reducing NCPP appears to be related not only to this redirection of OPDA and JA metabolism towards the formation of JA derivatives but also to the regulation of JA signalling. Indeed, the repression of the receptor CsCOI1 and upregulation of various CsJAZs repressors caused by nutrient deprivation, together with the ETH-mediated induction of CsCOI1, CsTOPLESS, and abundant CsJAZs during long-term storage, suggests the occurrence of an ETH-enhanced negative transcriptional regulatory feedback loop in JA metabolism and signalling, by which the susceptibility of detached Navelate oranges to NCPP might be reduced. Full article
(This article belongs to the Special Issue Phytohormones: From Physiological Response to Application)
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15 pages, 4612 KiB  
Article
Regulation of MdANR in Anti-Burning Process of Apple Peel
by Yifeng Feng, Wenya Tian, Junjiao Guo, Jianghong Fu, Jiangbo Wang, Yan Wang and Zhengyang Zhao
Int. J. Mol. Sci. 2025, 26(10), 4656; https://doi.org/10.3390/ijms26104656 - 13 May 2025
Viewed by 489
Abstract
Sunburn in apple peel significantly affects fruit appearance and reduces its commercial value. Previous research has shown that apple peel reduces sunburn by increasing the accumulation of proanthocyanidins (PAs) and other protective compounds. However, the precise molecular regulatory mechanism remains unclear. In this [...] Read more.
Sunburn in apple peel significantly affects fruit appearance and reduces its commercial value. Previous research has shown that apple peel reduces sunburn by increasing the accumulation of proanthocyanidins (PAs) and other protective compounds. However, the precise molecular regulatory mechanism remains unclear. In this study, we systematically investigated MdANR, a key gene involved in PAs biosynthesis. We found that MdANR expression in apple peel is responsive to temperature and light fluctuations, with higher expression levels observed under increased temperature and light exposure. Functional analysis revealed that MdANR overexpression in apple peel and callus enhanced resistance to high-temperature and -light-intensity stress, accompanied by a corresponding increase in PAs and chlorogenic acid contents. In addition, we demonstrated that MdMYBR9 can activate MdANR promoter activity and promote its expression through yeast one-hybrid, dual-luciferase, and electrophoretic mobility transfer experiments. The results indicated that MdMYBR9 was an upstream regulator of MdANR. Based on these findings, this study proposes the MdMYBR9-MdANR-PAs regulatory model for apple sunburn resistance, providing a molecular framework for enhancing sunburn tolerance in apple breeding programs. Full article
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14 pages, 6163 KiB  
Article
Analysis of Bruising Characteristics of Large-Stone Fruits upon Impact Using Finite Element Method—A Case Study of Postharvest Loquats
by Chunxiang Liu, Baiqiu Li and Changsu Xu
Horticulturae 2025, 11(4), 440; https://doi.org/10.3390/horticulturae11040440 - 20 Apr 2025
Cited by 1 | Viewed by 575
Abstract
The bruising of fruits occurs at various stages, including picking, transportation, and sale. For fruits with large kernels that occupy a significant portion of their overall volume, considering the impact of the kernel is crucial in elucidating the mechanisms of bruising and controlling [...] Read more.
The bruising of fruits occurs at various stages, including picking, transportation, and sale. For fruits with large kernels that occupy a significant portion of their overall volume, considering the impact of the kernel is crucial in elucidating the mechanisms of bruising and controlling bruise formation. This study employs reverse engineering to develop a composite finite element model of loquat peel, flesh, and kernels. Bruise formation during collisions is analyzed from the perspectives of contact force, equivalent stress, energy, bruise volume, and bruise susceptibility, aiming to reveal the significant role of the fruit core in the bruise formation process. In this paper, we propose the use of 3D printing technology to accurately quantify bruise measurement for fruits with large kernels. The results showed that the maximum contact force, equivalent stress, and internal energy between loquat and steel/wood were essentially consistent, but all exceeded those observed when using rubber. Due to the blocking of stress transmission by the kernel, the susceptibility of loquats to bruising increases with height before decreasing. This study elucidates the mechanism of bruise formation in fruits with large kernels and provides methods and ideas for the research and precise measurement of complex fruit bruising characteristics. Full article
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33 pages, 15037 KiB  
Article
Persea americana Peel: A Promising Source of Nutraceutical for the Mitigation of Cardiovascular Risk in Arthritic Rats Through the Gut–Joint Axis
by Doha A. Mohamed, Asmaa A. Ramadan, Hoda B. Mabrok, Gamil E. Ibrahim and Shaimaa E. Mohammed
Biomolecules 2025, 15(4), 590; https://doi.org/10.3390/biom15040590 - 16 Apr 2025
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Abstract
Rheumatoid arthritis (RA) is a chronic autoimmune inflammatory disease characterized by the inflammation of synovial fluid. The incidence of cardiovascular diseases (CVDs) is increasing in RA patients. This research is the first report to investigate the anti-arthritic effect of avocado peel nutraceutical (APN) [...] Read more.
Rheumatoid arthritis (RA) is a chronic autoimmune inflammatory disease characterized by the inflammation of synovial fluid. The incidence of cardiovascular diseases (CVDs) is increasing in RA patients. This research is the first report to investigate the anti-arthritic effect of avocado peel nutraceutical (APN) and its potential in mitigating the cardiovascular risk associated with RA. The antioxidant activity and phytochemical composition of APN were assessed. The potential interaction of APN’s active compounds with protein tyrosine phosphatase non-receptor type 22 (PTPN22) was studied using molecular docking. The impact of APN on the plasma lipid profile, oxidative and inflammatory markers, and the indices of coronary risk and atherogenicity as CVD markers were evaluated. The gene expression of COX-2, IL-6, IL-1β, IL-10, and TNF-α in liver and spleen tissues were measured. The rat gut microbiota profile was investigated using 16S rRNA amplicon sequencing. APN exhibited high antioxidant activity, low atherogenicity and thrombogenicity indices, and a high ratio of hypocholesterolemic to hypercholesterolemic fatty acids indicating its cardioprotective potential. The administration of APN led to a reduction in oxidative stress markers, inflammatory markers, dyslipidemia, and CVD markers. APN administration downregulated the expression of COX-2, IL-6, IL-1β, and TNF-α genes, while the IL-10 gene was significantly upregulated in the liver and spleen. Treatment with APN was favorable in restoring eubiosis in the gut by modulating RA-associated bacterial taxa linked to impaired immune function and cardiometabolic diseases. In molecular docking, β-amyrin and ellagic acid showed the highest binding affinity for PTPN22. APN may represent a promising approach to ameliorating the cardiovascular risk of RA. The present results will be offering a foundation for future in-depth research in nutraceuticals from agriculture by-products. Additionally, they will be supporting the public health policies aimed at preventing and controlling rheumatoid arthritis. Full article
(This article belongs to the Section Molecular Medicine)
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