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Search Results (201)

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Keywords = natural gas combined cycle

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23 pages, 2593 KiB  
Article
Preliminary Comparison of Ammonia- and Natural Gas-Fueled Micro-Gas Turbine Systems in Heat-Driven CHP for a Small Residential Community
by Mateusz Proniewicz, Karolina Petela, Christine Mounaïm-Rousselle, Mirko R. Bothien, Andrea Gruber, Yong Fan, Minhyeok Lee and Andrzej Szlęk
Energies 2025, 18(15), 4103; https://doi.org/10.3390/en18154103 - 1 Aug 2025
Viewed by 252
Abstract
This research considers a preliminary comparative technical evaluation of two micro-gas turbine (MGT) systems in combined heat and power (CHP) mode (100 kWe), aimed at supplying heat to a residential community of 15 average-sized buildings located in Central Europe over a year. Two [...] Read more.
This research considers a preliminary comparative technical evaluation of two micro-gas turbine (MGT) systems in combined heat and power (CHP) mode (100 kWe), aimed at supplying heat to a residential community of 15 average-sized buildings located in Central Europe over a year. Two systems were modelled in Ebsilon 15 software: a natural gas case (benchmark) and an ammonia-fueled case, both based on the same on-design parameters. Off-design simulations evaluated performance over variable ambient temperatures and loads. Idealized, unrecuperated cycles were adopted to isolate the thermodynamic impact of the fuel switch under complete combustion assumption. Under these assumptions, the study shows that the ammonia system produces more electrical energy and less excess heat, yielding marginally higher electrical efficiency and EUF (26.05% and 77.63%) than the natural gas system (24.59% and 77.55%), highlighting ammonia’s utilization potential in such a context. Future research should target validating ammonia combustion and emission profiles across the turbine load range, and updating the thermodynamic model with a recuperator and SCR accounting for realistic pressure losses. Full article
(This article belongs to the Special Issue Clean and Efficient Use of Energy: 3rd Edition)
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17 pages, 3524 KiB  
Article
Experimental Study on Microseismic Monitoring of Depleted Reservoir-Type Underground Gas Storage Facility in the Jidong Oilfield, North China
by Yuanjian Zhou, Cong Li, Hao Zhang, Guangliang Gao, Dongsheng Sun, Bangchen Wu, Chaofeng Li, Nan Li, Yu Yang and Lei Li
Energies 2025, 18(14), 3762; https://doi.org/10.3390/en18143762 - 16 Jul 2025
Viewed by 329
Abstract
The Jidong Oilfield No. 2 Underground Gas Storage (UGS), located in an active fault zone in Northern China, is a key facility for ensuring natural gas supply and peak regulation in the Beijing–Tianjin–Hebei region. To evaluate the effectiveness of a combined surface and [...] Read more.
The Jidong Oilfield No. 2 Underground Gas Storage (UGS), located in an active fault zone in Northern China, is a key facility for ensuring natural gas supply and peak regulation in the Beijing–Tianjin–Hebei region. To evaluate the effectiveness of a combined surface and shallow borehole monitoring system under deep reservoir conditions, a 90-day microseismic monitoring trial was conducted over a full injection cycle using 16 surface stations and 1 shallow borehole station. A total of 35 low-magnitude microseismic events were identified and located using beamforming techniques. Results show that event frequency correlates positively with wellhead pressure variations instead of the injection volume, suggesting that stress perturbations predominantly control microseismic triggering. Events were mainly concentrated near the bottom of injection wells, with an average location error of approximately 87.5 m and generally shallow focal depths, revealing limitations in vertical resolution. To enhance long-term monitoring performance, this study recommends deploying geophones closer to the reservoir, constructing a 3D velocity model, applying AI-based phase picking, expanding array coverage, and developing a microseismic-injection coupling early warning system. These findings provide technical guidance for the design and deployment of long-term monitoring systems for deep reservoir conversions into UGS facilities. Full article
(This article belongs to the Section H2: Geothermal)
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17 pages, 3203 KiB  
Article
Performance Assessment of CCGT Integrated with PTSA-Based CO2 Capture: Effect of Sorbent Type and Operating Conditions
by Karol Sztekler, Agata Mlonka-Mędrala, Piotr Boruta, Tomasz Bujok, Ewelina Radomska and Łukasz Mika
Energies 2025, 18(13), 3289; https://doi.org/10.3390/en18133289 - 23 Jun 2025
Viewed by 261
Abstract
Recognizing the growing importance of natural gas as a transition fuel in Poland’s energy mix and the necessity of reducing CO2 emissions, this article aims to assess the use of carbon capture and storage (CCS) technology to effectively reduce CO2 emissions [...] Read more.
Recognizing the growing importance of natural gas as a transition fuel in Poland’s energy mix and the necessity of reducing CO2 emissions, this article aims to assess the use of carbon capture and storage (CCS) technology to effectively reduce CO2 emissions from combined cycle gas turbine (CCGT). The research employs the pressure–temperature swing adsorption (PTSA) to capture CO2 from flue gases. Computer simulations, using IPSEpro (SimTech), are used to calculate the heat and mass balances for CCGT and PTSA units and assess their performance. In the first part of the research, the effect of sorbent type (Na-A and 5A) and flue gas share directed to the PTSA unit on the performance of the CCGT was investigated. Secondly, the parametric analysis regarding the adsorption and desorption pressures in the PTSA was carried out. The results showed that CO2 emissions from CCGT can be reduced by 1.1 Mt (megatons) per year, but the use of PTSA was associated with a reduction in net electrical power and efficiency of the CCGT by up to 14.7% for Na-A and 11.1% for 5A sorbent. It was also found that the heat and electricity demand of the PTSA depends on the adsorption and desorption pressures. Full article
(This article belongs to the Section B3: Carbon Emission and Utilization)
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21 pages, 1037 KiB  
Systematic Review
Evaluating the Sustainability of the Natural Gas-Based Methanol-to-Gasoline Industry: A Global Systematic Review
by Hussein Al-Yafei, Saleh Aseel and Ali Ansaruddin Kunju
Sustainability 2025, 17(12), 5355; https://doi.org/10.3390/su17125355 - 10 Jun 2025
Viewed by 932
Abstract
The sustainability of the natural gas-to-methanol (NGTM) and methanol-to-gasoline (MTG) processes are assessed in this systematic review as a potential substitute in the global energy transition. Methanol offers itself as a versatile and less carbon-intensive substitute for conventional gasoline in light of growing [...] Read more.
The sustainability of the natural gas-to-methanol (NGTM) and methanol-to-gasoline (MTG) processes are assessed in this systematic review as a potential substitute in the global energy transition. Methanol offers itself as a versatile and less carbon-intensive substitute for conventional gasoline in light of growing environmental concerns and the demand for cleaner fuels. This review’s rationale is to assess MTG’s ability to lessen environmental impact while preserving compatibility with current fuel infrastructure. The goal is to examine methanol and gasoline’s effects on the environment, society, and economy throughout their life cycles. This review used a two-phase systematic literature review methodology, filtering and evaluating studies that were indexed by Scopus using bibliometric and thematic analysis. A total of 25 documents were reviewed, in which 22 documents analyzed part of this study, and 68% employed LCA or techno-economic analysis, with the U.S. contributing 35% of the overall publications. A comparative analysis of the reviewed literature indicates that methanol-based fuels offer significantly lower greenhouse gas (GHG) emissions and life cycle environmental impacts than gasoline, particularly when combined with carbon capture and renewable feedstocks. This review also highlights benefits, such as improved safety and energy security, while acknowledging challenges, including high production costs, infrastructure adaptation, and toxicity concerns. Several drawbacks are high manufacturing costs, the necessity to adjust infrastructure, and toxicity issues. The report suggests investing in renewable methanol production, AI-driven process optimization, and robust legislative frameworks for integrating green fuels. The life cycle sustainability assessment (LCSA) of NGTM and MTG systems should be investigated in future studies, particularly in light of different feedstock and regional circumstances. The findings emphasize NGTM and MTG’s strategic role in aligning with several UN Sustainable Development Goals (SDGs) and add to the worldwide conversation on sustainable fuels. A strong transition necessitates multi-stakeholder cooperation, innovation, and supporting policies to fully realize the sustainability promise of cleaner fuels like methanol. Full article
(This article belongs to the Section Energy Sustainability)
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23 pages, 1984 KiB  
Article
Economic Methods for the Selection of Renewable Energy Sources: A Case Study
by James DiLellio, George Aggidis, David Vandercruyssen and David Howard
Sustainability 2025, 17(11), 4857; https://doi.org/10.3390/su17114857 - 26 May 2025
Cited by 1 | Viewed by 664
Abstract
Governments need to evaluate technologies generating electricity from different sources; levelised cost of energy (LCOE) is a widely used metric. However, LCOE is weak at comparing disparate technologies, especially where they have different operational lifespans. The discrepancy is demonstrated using UK government data [...] Read more.
Governments need to evaluate technologies generating electricity from different sources; levelised cost of energy (LCOE) is a widely used metric. However, LCOE is weak at comparing disparate technologies, especially where they have different operational lifespans. The discrepancy is demonstrated using UK government data to examine a range of technologies, namely combined cycle generation (natural gas and hydrogen), sustainable renewable technologies along with independent data describing nuclear power and tidal range schemes. Three methods of analysis were used: LCOE, the internal rate of return (IRR), and a novel analysis. A new metric, the sustained cost of energy (SCOE), negates some of the LCOE shortcomings such as the application of discounting. SCOE examines a fixed period of continuous generation, using the lowest common length of operating life of the technologies analysed. It appears to be a useful metric, especially when interpreted with IRR. The analyses produce broadly similar ordering of technologies, but the longer-lasting systems with high initial costings perform better in SCOE. Subsidies, carbon tax, or credit schemes are essential government incentives if net zero emissions targets are to be met without overly burdening consumers with rapidly growing electricity rates. Full article
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27 pages, 3894 KiB  
Article
The Effects of Increasing Ambient Temperature and Sea Surface Temperature Due to Global Warming on Combined Cycle Power Plant
by Asiye Aslan and Ali Osman Büyükköse
Sustainability 2025, 17(10), 4605; https://doi.org/10.3390/su17104605 - 17 May 2025
Viewed by 1846
Abstract
The critical consequence of climate change resulting from global warming is the increase in temperature. In combined cycle power plants (CCPPs), the Electric Power Output (PE) is affected by changes in both Ambient Temperature (AT) and Sea Surface Temperature (SST), particularly in plants [...] Read more.
The critical consequence of climate change resulting from global warming is the increase in temperature. In combined cycle power plants (CCPPs), the Electric Power Output (PE) is affected by changes in both Ambient Temperature (AT) and Sea Surface Temperature (SST), particularly in plants utilizing seawater cooling systems. As AT increases, air density decreases, leading to a reduction in the mass of air absorbed by the gas turbine. This change alters the fuel–air mixture in the combustion chamber, resulting in decreased turbine power. Similarly, as SST increases, cooling efficiency declines, causing a loss of vacuum in the condenser. A lower vacuum reduces the steam expansion ratio, thereby decreasing the Steam Turbine Power Output. In this study, the effects of increases in these two parameters (AT and SST) due to global warming on the PE of CCPPs are investigated using various regression analysis techniques, Artificial Neural Networks (ANNs) and a hybrid model. The target variables are condenser vacuum (V), Steam Turbine Power Output (ST Power Output), and PE. The relationship of V with three input variables—SST, AT, and ST Power Output—was examined. ST Power Output was analyzed with four input variables: V, SST, AT, and relative humidity (RH). PE was analyzed with five input variables: V, SST, AT, RH, and atmospheric pressure (AP) using regression methods on an hourly basis. These models were compared based on the Coefficient of Determination (R2), Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), Mean Square Error (MSE), and Root Mean Square Error (RMSE). The best results for V, ST Power Output, and PE were obtained using the hybrid (LightGBM + DNN) model, with MAE values of 0.00051, 1.0490, and 2.1942, respectively. As a result, a 1 °C increase in AT leads to a decrease of 4.04681 MWh in the total electricity production of the plant. Furthermore, it was determined that a 1 °C increase in SST leads to a vacuum loss of up to 0.001836 bara. Due to this vacuum loss, the steam turbine experiences a power loss of 0.6426 MWh. Considering other associated losses (such as generator efficiency loss due to cooling), the decreases in ST Power Output and PE are calculated as 0.7269 MWh and 0.7642 MWh, respectively. Consequently, the combined effect of a 1 °C increase in both AT and SST results in a 4.8110 MWh production loss in the CCPP. As a result of a 1 °C increase in both AT and SST due to global warming, if the lost energy is to be compensated by an average-efficiency natural gas power plant, an imported coal power plant, or a lignite power plant, then an additional 610 tCO2e, 11,184 tCO2e, and 19,913 tCO2e of greenhouse gases, respectively, would be released into the atmosphere. Full article
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28 pages, 13795 KiB  
Article
Research on Seepage and Phase Change Characteristics During Multi-Cycle Injection–Production in Oil Reservoir-Based Underground Gas Storage
by Yong Tang, Zhitao Tang, Jiazheng Qin, Youwei He, Yulong Luo, Minmao Cheng and Ziyan Wang
Energies 2025, 18(10), 2550; https://doi.org/10.3390/en18102550 - 14 May 2025
Cited by 1 | Viewed by 351
Abstract
China’s natural gas demand is growing under the “dual carbon” goal. However, the peaking capacity of gas storage remains insufficient. Oil reservoir-based underground gas storage (UGS) has, thus, emerged as a critical research focus due to its potential for efficient capacity expansion. The [...] Read more.
China’s natural gas demand is growing under the “dual carbon” goal. However, the peaking capacity of gas storage remains insufficient. Oil reservoir-based underground gas storage (UGS) has, thus, emerged as a critical research focus due to its potential for efficient capacity expansion. The complexity of seepage and phase change characteristics during the multi-cycle injection–production process has not been systematically elucidated. This study combines experimental and numerical simulations to examine the seepage and phase change characteristics. This study innovatively reveals the synergistic mechanism of permeability, pressure, and cycle. The control law of multi-factor coupling on the dynamic peaking capacity of UGS is first expounded. Oil–water mutual drive reduced oil displacement efficiency by 2.5–4.7%. Conversely, oil–gas mutual drive improved oil displacement efficiency by 3.0–4.5% and storage capacity by 4.7–6.5%. The fifth-cycle oil–gas mutual displacement in high-permeability cores (74 mD) under high pressure (22 MPa) exhibited reductions in irreducible water saturation (7.06 percentage points) and residual oil saturation (6.38 percentage points) compared with the first-cycle displacement in low-permeability cores (8.36 mD) under low pressure (16 MPa). Meanwhile, the gas storage capacity increased by 13.44 percentage points, and the displacement efficiency improved by 10.62 percentage points. Multi-cycle huff-and-puff experiments and numerical simulations revealed that post-depletion multi-cycle huff-and-puff operations can enhance the oil recovery factor by 2.74–4.22 percentage points compared to depletion. After five-cycle huff-and-puff, methane content in the produced gas increased from 80.2% to 87.3%, heavy components (C8+) in the remaining oil rose by 2.7%, and the viscosity of the remaining oil increased from 2.0 to 4.6 mPa·s. The deterioration of the physical properties of the remaining oil leads to a reduction in the recovery factor in the cycle stage. This study elucidates seepage mechanisms and phase evolution during multi-cycle injection–production, demonstrating the synergistic optimization of high-permeability reservoirs and high-pressure injection techniques for enhanced gas storage design and efficiency. Full article
(This article belongs to the Section B: Energy and Environment)
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23 pages, 6098 KiB  
Article
Simulation and Environmental Sustainability Assessment of an Integrated LNG-Power Cycle-Electrolyzer-Methanol Process for Clean Energy Generation
by Asmae Abousalmia, Laalea Al-Remaihi, Shouq Al-Kaabi, Fatima Jassim and Seckin Karagoz
Processes 2025, 13(5), 1476; https://doi.org/10.3390/pr13051476 - 12 May 2025
Viewed by 573
Abstract
The growing demand for clean energy and sustainable industrial processes has driven interest in integrated energy systems that optimize resource utilization while minimizing environmental impacts. This study presents the simulation and environmental sustainability assessment of an integrated process combining liquefied natural gas (LNG), [...] Read more.
The growing demand for clean energy and sustainable industrial processes has driven interest in integrated energy systems that optimize resource utilization while minimizing environmental impacts. This study presents the simulation and environmental sustainability assessment of an integrated process combining liquefied natural gas (LNG), Allam–Fetvedt cycle, solid oxide electrolysis’ system, and methanol synthesis to produce clean energy. The proposed system enhances overall efficiency and sustainability by utilizing the Allam–Fetvedt cycle to generate power while capturing CO2, which is then used in the manufacture of syngas and hydrogen by the electrolysis of water and CO2. Syngas is subsequently transformed into methanol, a viable alternative fuel characterized by lowcarbon emissions. A comprehensive process simulation is conducted to evaluate energy efficiency, material flows, and system performance. The sustainability assessment focuses on environmental impact indicators, including carbon footprint reduction, energy efficiency improvements, and resource optimization. The results demonstrate that the integrated system significantly reduces CO2 emissions while maximizing energy recovery, making it a promising approach for decarbonized energy production. In this study, the integrated process including the ASU, power cycle, electrolyzers, methanol production units, and LNG unit results in carbon emissions of 0.29 kg CO2 per kg of LNG produced, which is very close to the literature-reported lower limit, even though it also has methanol production. On the other hand, when the identical process is assessed solely for methanol production (without the LNG unit), it attains net-zero carbon emissions. Despite the incorporation of high-energy electrolyzer systems, the overall energy demand of the proposed integrated process remains comparable to that of existing conventional technologies with high emission outputs. Full article
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26 pages, 4688 KiB  
Article
How Best to Use Forest Wood for Energy: Perspectives from Energy Efficiency and Environmental Considerations
by John J. Fitzpatrick, Jack Carroll, Strahinja Macura and Neil Murphy
Eng 2025, 6(5), 95; https://doi.org/10.3390/eng6050095 - 8 May 2025
Viewed by 666
Abstract
This paper examines how best to use forest wood for energy application, considering that it is a limited natural resource. Eight systems are considered, including wood stoves, steam systems (boiler, power plant, and combined heat and power (CHP)), and gasification combined systems (gas [...] Read more.
This paper examines how best to use forest wood for energy application, considering that it is a limited natural resource. Eight systems are considered, including wood stoves, steam systems (boiler, power plant, and combined heat and power (CHP)), and gasification combined systems (gas turbine and combined cycle power plant, CHP, and Fischer–Tropsch). The methodology uses energy analysis and modelling and environmental/sustainability considerations to compare the energy systems. In terms of energy conversion efficiency, steam boilers and high-efficiency wood stoves for heating applications provide the highest efficiencies (~80 to 90%) and should be considered. Steam CHP systems provide lower overall energy conversion efficiencies (~75 to 80%) but do provide some electrical energy, and thus should be considered. The use of wood for the production of electricity on its own should not be considered due to low efficiencies (~20 to 30%). Particulate emissions hinder the application of high-efficiency stoves, especially in urban areas, whereas for industrial-scale steam boilers and CHP systems, particle separators can negate this problem. Gasification/Fischer–Tropsch systems have a lower energy efficiency (~30 to 50%); however, a sustainability argument could be made for liquid fuels that have few sustainable alternatives. Full article
(This article belongs to the Special Issue Interdisciplinary Insights in Engineering Research)
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25 pages, 6699 KiB  
Article
Optimization of ORC-Based Micro-CHP Systems: An Experimental and Control-Oriented Study
by Márcio Santos, Jorge André, Ricardo Mendes and José B. Ribeiro
Processes 2025, 13(4), 1104; https://doi.org/10.3390/pr13041104 - 7 Apr 2025
Cited by 1 | Viewed by 916
Abstract
This study presents an experimental and numerical investigation into the performance and control optimization of an Organic Rankine Cycle (ORC)-based micro-combined heat and power (micro-CHP) system. A steady-state, off-design, charge-sensitive model is developed to design a control strategy for an ORC micro-CHP combi-boiler, [...] Read more.
This study presents an experimental and numerical investigation into the performance and control optimization of an Organic Rankine Cycle (ORC)-based micro-combined heat and power (micro-CHP) system. A steady-state, off-design, charge-sensitive model is developed to design a control strategy for an ORC micro-CHP combi-boiler, aiming to efficiently meet real-time domestic hot water demands (up to 40 °C and 35 kW) while generating up to 2 kW of electricity. The system utilizes a natural gas burner to evaporate the working fluid (R245fa), with combustion heat power, volumetric pump speed, and expander speed as control variables. Experimental and numerical evaluations generate steady-state control maps to identify optimal operating regions. A PID-based dynamic control strategy is then developed to stabilize operation during start-ups and user demand variations. The results confirm that the strategy delivers hot water within 1.5 min in simple boiler mode and 3 min in cogeneration mode while improving electricity generation stability and outperforming manual control. The findings demonstrate that integrating steady-state modeling with optimized control enhances the performance, responsiveness, and efficiency of ORC-based micro-CHP systems, making them a viable alternative for residential energy solutions. Full article
(This article belongs to the Special Issue Modeling, Simulation and Control of Industrial Processes)
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30 pages, 6184 KiB  
Article
A New Hybrid Deep Sequence Model for Decomposing, Interpreting, and Predicting Sulfur Dioxide Decline in Coastal Cities of Northern China
by Guoju Wang, Rongjie Zhu, Xiang Gong, Xiaoling Li, Yuanzheng Gao, Wenming Yin, Renzheng Wang, Huan Li, Huiwang Gao and Tao Zou
Sustainability 2025, 17(6), 2546; https://doi.org/10.3390/su17062546 - 14 Mar 2025
Viewed by 701
Abstract
The recent success of emission reduction policies in China has significantly lowered sulfur dioxide (SO2) levels. However, accurately forecasting these concentrations remains challenging due to their inherent non-stationary tendency. This study introduces an innovative hybrid deep learning model, RF-VMD-Seq2Seq, combining the [...] Read more.
The recent success of emission reduction policies in China has significantly lowered sulfur dioxide (SO2) levels. However, accurately forecasting these concentrations remains challenging due to their inherent non-stationary tendency. This study introduces an innovative hybrid deep learning model, RF-VMD-Seq2Seq, combining the Random Forest (RF) algorithm, Variational Mode Decomposition (VMD), and the Sequence-to-Sequence (Seq2Seq) framework to improve SO2 concentration forecasting in five coastal cities of northern China. Our results show that the predicted SO2 concentrations closely align with observed values, effectively capturing fluctuations, outliers, and extreme events—such as sharp declines the Novel Coronavirus Pneumonia (COVID-19) pandemic in 2020—along with the upper 5% of SO2 levels. The model achieved high coefficients of determination (>0.91) and Pearson’s correlation (>0.96), with low prediction errors (RMSE < 1.35 μg/m3, MAE < 0.94 μg/m3, MAPE < 15%). The low-frequency band decomposing from VMD showed a notable long-term decrease in SO2 concentrations from 2013 to 2020, with a sharp decline since 2018 during heating seasons, probably due to the ‘Coal-to-Natural Gas’ policy in northern China. The input sequence length of seven steps was recommended for the prediction model, based on high-frequency periodicities extracted through VMD, which significantly improved our model performance. This highlights the critical role of weekly-cycle variations in SO2 levels, driven by anthropogenic activities, in enhancing the accuracy of one-day-ahead SO2 predictions across northern China’s coastal regions. The results of the RF model further reveal that CO and NO2, sharing common anthropogenic sources with SO2, contribute over 50% to predicting SO2 concentrations, while meteorological factors—relative humidity (RH) and air temperature—contribute less than 20%. Additionally, the integration of VMD outperformed both the standard Seq2Seq and Ensemble Empirical Mode Decomposition (EEMD)-enhanced Seq2Seq models, showcasing the advantages of VMD in predicting SO2 decline. This research highlights the potential of the RF-VMD-Seq2Seq model for non-stationary SO2 prediction and its relevance for environmental protection and public health management. Full article
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25 pages, 6133 KiB  
Article
Chemical Looping CH4 Reforming Through Isothermal Two-Step Redox Cycling of SrFeO3 Oxygen Carrier in a Tubular Solar Reactor
by Stéphane Abanades, Xinhe Wang and Srirat Chuayboon
Molecules 2025, 30(5), 1076; https://doi.org/10.3390/molecules30051076 - 26 Feb 2025
Viewed by 668
Abstract
The chemical looping reforming of methane using an SrFeO3 oxygen carrier to produce synthesis gas from solar energy was experimentally investigated and validated. High-temperature solar heat was used to provide the reaction enthalpy, and therefore the methane feedstock was entirely dedicated to [...] Read more.
The chemical looping reforming of methane using an SrFeO3 oxygen carrier to produce synthesis gas from solar energy was experimentally investigated and validated. High-temperature solar heat was used to provide the reaction enthalpy, and therefore the methane feedstock was entirely dedicated to producing syngas. The two-step isothermal process encompassed partial perovskite reduction with methane (partial oxidation of CH4) and exothermic oxidation of SrFeO3-δ with CO2 or H2O splitting under the same operating temperature. The oxygen carrier material was shaped in the form of a reticulated porous foam structure for enhancing heat and mass transfer, and it was cycled in a solar-heated tubular reactor under different operating parameters (temperature: 950–1050 °C, methane mole fraction: 5–30%, and type of oxidant gas: H2O vs. CO2). This study aimed to assess the fuel production capacity of the two-step process and to demonstrate the potential of using strontium ferrite perovskite during solar cycling for the first time. The maximum H2 and CO production rates during CH4-induced reduction were 70 and 25 mL/min at 1000 °C and 15% CH4 mole fraction. The increase in both the cycle temperature and the methane mole fraction promoted the reduction step, thereby enhancing syngas yields up to 569 mL/g during reduction at 1000 °C under 30% CH4 (778 mL/g including both cycle steps), and thus outperforming the performance of the benchmark ceria material. In contrast, the oxidation step was not significantly affected by the experimental conditions and the material’s redox performance was weakly dependent on the nature of the oxidizing gas. The syngas yield remained above 200 mL/g during the oxidation step either with H2O or CO2. Twelve successive redox cycles with stable patterns in the syngas production yields validated material stability. Combining concentrated solar energy and chemical looping reforming was shown to be a promising and sustainable pathway toward carbon-neutral solar fuels. Full article
(This article belongs to the Special Issue 10th Anniversary of Green Chemistry Section)
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26 pages, 5237 KiB  
Article
Modular DC-DC Converter with Adaptable Fast Controller for Supercapacitor Energy Storage Integration into DC Microgrid
by Kaspars Kroičs, Kristiāns Gaspersons and Mariusz Zdanowski
Electronics 2025, 14(4), 700; https://doi.org/10.3390/electronics14040700 - 11 Feb 2025
Viewed by 751
Abstract
Supercapacitors are well suited for braking energy recovery in electrical drive applications and for voltage sag compensation. For voltage-sensitive devices, only a small voltage deviation can be acceptable, and therefore the voltage controller should be fast. This paper analyzes the design of such [...] Read more.
Supercapacitors are well suited for braking energy recovery in electrical drive applications and for voltage sag compensation. For voltage-sensitive devices, only a small voltage deviation can be acceptable, and therefore the voltage controller should be fast. This paper analyzes the design of such a controller for DC bus voltage stabilization considering a GaN transistor-based converter with a 400 kHz switching frequency. Inner and outer loop controller design considering delays caused by the digital nature of the controllers has been analyzed in the paper. This paper proposes to use adaptable controller for the outer voltage loop, thus increasing the stability and reducing the calculation time. The 2p2z controller has been developed for the current loop, achieving a 20 kHz bandwidth and a response time of less than 0.2 ms. A 2p2z controller with adaptable coefficients has been developed for the outer voltage loop, achieving a 2 kHz bandwidth and a response time of 2 ms. Voltage controller digital implementation is split into two switching cycles, thus decreasing the required time for current and voltage control loops implementation from 2.1 µs to 1.5 µs. This allows calculating three current control loops for three-phase interleaved converter control. By combining such three-phase converters in parallel, it is possible to develop modular six-, nine-, or even more-phase interleaved DC-DC converters for high-current applications. Full article
(This article belongs to the Special Issue DC–DC Power Converter Technologies for Energy Storage Integration)
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18 pages, 5617 KiB  
Article
Base-Load Nuclear Reactors for Fully Dispatchable Electricity: Nuclear Air-Brayton Combined Cycles, Firebrick Heat Storage, Hydrogen Storage, and Hydrocarbon Biofuels
by Charles Forsberg
Energies 2025, 18(4), 821; https://doi.org/10.3390/en18040821 - 10 Feb 2025
Viewed by 1027
Abstract
Three partly coupled integrated nuclear energy systems are described. These enable base-load nuclear reactors to provide fully dispatchable electricity without greenhouse-gas emissions, thus replacing gas turbines burning natural gas and batteries storing electricity. These hybrid systems link the industrial sector to the electricity [...] Read more.
Three partly coupled integrated nuclear energy systems are described. These enable base-load nuclear reactors to provide fully dispatchable electricity without greenhouse-gas emissions, thus replacing gas turbines burning natural gas and batteries storing electricity. These hybrid systems link the industrial sector to the electricity sector. Firstly, electricity-to-high-temperature (1800 °C) gigawatt-hour firebrick heat storage converts low-price electricity to high-temperature stored heat to provide dispatchable heat for industry and power generation. Secondly, Nuclear Air-Brayton Combined Cycles (NACC) with thermodynamic topping cycles using high-temperature stored heat or combustible fuel to provide dispatchable electricity. Peak power output can be two to five times the base-load electricity production. The heat-to-electricity efficiency of the thermodynamic topping cycles exceeds 70%. Thirdly, nuclear hydrogen production for industrial markets enables the production of dispatchable electricity where hydrogen is used for energy storage but not to produce heat and electricity. Base-load nuclear reactors send electricity to the grid and/or electrolyzers for hydrogen production depending upon electricity prices. Low-cost hydrogen storage enables us to meet steady-state industrial hydrogen demands, even though hydrogen and grid electricity production is varied. Hydrogen production for industrial uses (ammonia fertilizer, direct reduction of iron ore to iron replacing coke, cellulosic liquid hydrocarbon biofuels replacing crude oil) may exceed 20% of total energy demand and may be a massive source of dispatchable electricity. The biofuels provide storable energy when heat storage is depleted. Full article
(This article belongs to the Special Issue Advances in Nuclear Power for Integrated Energy Systems)
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30 pages, 7440 KiB  
Article
Performance Evaluation of a Combined Heat and Power Generation System with Borehole Thermal Energy Storage: A Feasibility Study of a Combined Heat Pump and Organic Rankine Cycle System
by Roshaan Mudasar and Wey H. Leong
Energies 2025, 18(4), 818; https://doi.org/10.3390/en18040818 - 10 Feb 2025
Cited by 1 | Viewed by 617
Abstract
The current research is focused on the introduction of a heat pump (HP)-assisted organic Rankine cycle (ORC), which runs on the heat extracted from a high-temperature borehole thermal energy storage (BTES). By varying different source temperatures from 40 °C to 60 °C, the [...] Read more.
The current research is focused on the introduction of a heat pump (HP)-assisted organic Rankine cycle (ORC), which runs on the heat extracted from a high-temperature borehole thermal energy storage (BTES). By varying different source temperatures from 40 °C to 60 °C, the HP cycle works to upgrade the heat to run the ORC. Different combinations of environmentally friendly fluids are studied in comparison to match the top and bottom cycles and to make the overall system a combined heat and power (CHP) system. A power sufficiency condition is defined to compare and identify the best working fluid combination for the HP cycle and ORC. Based on the analysis, ammonia for the HP and R1234zee for the ORC emerged to be a suitable combination among all the studied combinations. As an example, for a BTES heat source of 237 kW at the source temperature of 60 °C, the BTES–HP–ORC–district heating system with the ammonia–R1234zee pair has resulted in the HP compressor work input of 21.9 kW with the coefficient of performance (COP) of 10.9 for the HP cycle and the ORC net work output and district heating supply of 10.4 kW and 209 kW, respectively, with the thermal efficiency (η) of 4.3% for the ORC at the evaporation temperature of 65 °C. A study in terms of the greenhouse gas (GHG) emissions reveals the feasibility of the system depending on the regional GHG intensity and emission factor of electricity and natural gas. Full article
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