Search Results (294)

Hydrogen energy is vital for a clean, low-carbon society, and proton exchange membrane fuel cells (PEMFCs) represent a core technology for the conversion of hydrogen chemical energy into electrical energy. When PEMFC single cells are stacked under assembly force for high power output, their porous electrodes (gas diffusion layers, GDLs; catalyst layers, CLs) undergo compressive deformation, altering internal transport processes and affecting cell performance. However, existing microscale studies on PEMFC porous electrodes insufficiently consider compression (especially in CLs) and have limitations in obtaining compressed microstructures. This study proposes a combined framework from a microstructure perspective. It integrates the finite element method (FEM) with computational fluid dynamics (CFD). It reconstructs microstructures of GDL, CL, and GDL-bipolar plate (BP) interface. FEM simulates elastic compressive deformation, and CFD calculates transport properties (solid zone: heat/charge conduction via Laplace equation; fluid zone: gas diffusion/liquid permeation via Fick’s/Darcy’s law). Validation shows simulated stress–strain curves and transport coefficients match experimental data. Under 2.5 MPa, GDL’s gas diffusivity drops 16.5%, permeability 58.8%, while conductivity rises 2.9-fold; CL compaction increases gas resistance but facilitates electron/proton conduction. This framework effectively investigates compression-induced transport property changes in PEMFC porous electrodes. Full article

Optimizing the MEA structure is crucial for enhancing the performance of open-cathode PEMFCs under water shortage conditions. By investigating the impact of gradient ambient temperature on performance, it is highlighted that cathode catalyst layer hydration deeply affects proton conduction in the membrane and three-phase boundary formation. These issues consequently increase ohmic resistance and cathode activation resistance as seen via polarization curve comparison and the electrochemical impedance spectroscopy analysis method, ultimately degrading overall stack voltage output under the same current density. Under indoor temperature and humidity conditions, an orthogonal experiment was designed to validate the sensitivity analysis on the cathode I/C ratio (0.74–0.9) and catalyst layer thickness (8, 12 μm) by controlling the catalyst-coated membrane manufacture process; GDL thickness (185–324 μm) and pore structure were also investigated, combining parameter characterization techniques like MIP and BET. It is shown that with an I/C ratio of 0.86, a medium GDL pore structure and a higher catalyst layer thickness of 12 μm bring better performance output, especially when the OC PEMFC is 700 mA/cm² @ 0.62 V. Full article

Nanoporous Pt/C electrodes fabricated via aerosol coating offer excellent reactant delivery and electrochemical activity owing to their high porosity. However, the practical application prospects of such electrodes are limited by their poor mechanical properties. Herein, we quantitatively analyze the effects of thermal annealing (at 110, 150, 190, and 230 °C) on the mechanical stability and electrical properties of aerosol-based Pt/C electrodes. Post-annealing at an optimal temperature of 190 °C improved the tensile strength by 65.3%, increased their elongation from 0.82% to 1.78%, and decreased the electrical resistance while maintaining the secondary pore structure. Analyses of the electrode’s surface roughness, pore structure, and contact angle indicate that thermal reconstruction of the ionomer is crucial for stabilizing the electrode structure and controlling its surface properties. Finite element simulations using experimentally measured single-electrode properties enabled accurate prediction of the mechanical behavior of the membrane electrode assembly. These results provide design guidelines for balancing the process efficiency with the mechanical stability of aerosol-based Pt/C electrodes and can be used to improve their application prospects in aerosol-based fuel cell catalyst layers. Full article

In recent years, the development of stretchable electronic devices with mechanical properties similar to those of human tissues has attracted increasing research interest in biomedical engineering, wearables, and other fields. These devices have demonstrated, and some other researchers have already shown, promising advancements towards applications that span from measurements of the disruption of model barrier tissues to wearable or implantable devices, soft robotics, and the development of flexible and stretchable batteries. For example, models of barrier tissues, consisting of two compartments separated by a porous membrane, have been used to measure their integrity as well as to investigate the passage of drugs, toxins, and cancer cells through these tissues. Some of these models include an elastomeric membrane which can be stretched to model processes such as breathing and gut peristalsis, while others include electrodes for real-time measurement of barrier tissue integrity. However, to date, microelectrodes have not been fabricated directly on a porous elastomeric membrane. Here, we present lithographically patterned gold electrodes on porous PDMS membranes that enable electronic sensing capabilities in addition to mechanical manipulation. These membranes are incorporated into vacuum-actuated devices which impart cyclic mechanical strain, and their suitability for electrical impedance measurements, even after 1000 stretching cycles under fluids similar to cell culture media, is demonstrated. In the future, we expect to use these electrodes to measure the disruption in model cell barriers as well as to dielectrophoretically trap cells in a region of interest for more rapid assembly of a model tissue. Other areas like wearables, robotics, and power sources will greatly benefit from the further development of this technology. Full article

Green hydrogen production using membrane electrode assembly (MEA) has attracted significant attention due to its remarkable energy conversion efficiency. To further enhance its sustainability, MEA-based water electrolysis can be integrated with renewable solar energy by adopting a photocatalytic MEA (P-MEA) system, incorporating light-transmitting windows into MEA stacks, and employing suitable photocatalytic electrode materials. A critical challenge lies in developing cost-effective and high-performance photocatalytic electrode materials by replacing conventional noble material systems with earth-abundant photocatalytic electrode materials. This review discusses recent advances in P-MEA concepts and fabrication strategies for photoelectrodes tailored to MEA operation. Particular emphasis is placed on elucidating the mechanisms of light-induced charge dynamics that govern the P-MEA-based water electrolysis process. Overall, this review highlights the synergistic potential of integrating photocatalysis with MEA-based water electrolysis to advance sustainable green hydrogen production. Full article

The high efficiency, light weight, and reliability of hydrogen energy electrochemical equipment are among the future development directions. Membrane electrode assemblies (MEAs) and electrolyzers, as key components, have structures and strengths that determine the efficiency of their power generation and the hydrogen production efficiency of electrolyzers. This article summarizes the evolution of membrane electrode and electrolyzer structures, and their power and efficiency in recent years, highlighting the significant role of integrated structures in promoting proton transport and enhancing performance. Finally, it proposes the development direction of integrating electrolyte and electrode manufacturing using phase-change methods. Full article

Bacterial cellulose (BC) is a high-purity biopolymer with excellent physicochemical and mechanical properties, including high crystallinity, water absorption, biocompatibility, and structural tunability. However, its large-scale production is hindered by high substrate costs and limited sustainability. In this study, spent black tea waste was utilized as a low-cost and eco-friendly carbon source for BC synthesis by Komagataeibacter xylinus ATCC 53524 under varying initial pH conditions (4–9). Six different BC membranes were produced and systematically characterized in terms of mechanical strength, water absorption capacity, electrical conductivity, antimicrobial performance, and polyvinyl alcohol (PVA) attachment efficiency. Morphological and chemical analyses were conducted using SEM and FTIR techniques to investigate pH-induced structural variations. The results revealed that the BC6 sample (pH 6) exhibited the highest tensile strength (2.4 MPa), elongation (13%), PVA incorporation (12%), and electrical conductivity, confirming the positive impact of near-neutral conditions on nanofiber assembly and functional integration. In contrast, the BC4 sample (pH 4) demonstrated strong antimicrobial activity (log reduction = 3.5) against E. coli, suggesting that acidic pH conditions enhance bioactivity. SEM images confirmed the most cohesive and uniform fiber morphology at pH 6, while FTIR spectra indicated the preservation of characteristic cellulose functional groups across all samples. Overall, this study presents a sustainable and efficient strategy for BC production using food waste and demonstrates that synthesis pH is a key parameter in tuning its functional performance. The optimized BC membranes show potential for biomedical, flexible electronic, and antibacterial material applications, particularly in wearable electrode technologies. Full article

Fuel cells have become a fundamental technology in the development of clean energy systems, playing a vital role in the global shift toward a low-carbon future. With the growing need for sustainable hydrogen production, perfluoro sulfonic acid (PFSA) ionomer membranes play a critical role in optimizing green hydrogen technologies and fuel cells. This study aims to investigate the effects of different environmental and solvent treatments on the chemical and physical properties of Nafion N−115 membranes to evaluate their suitability for both hydrogen production in proton exchange membrane (PEM) electrolyzers and hydrogen utilization in fuel cells, supporting integrated applications in the local and global green hydrogen economy. To achieve this, Nafion N−115 membranes were partially dissolved in various solvent mixtures, including ethanol/isopropanol (EI), isopropanol/water (IW), dimethylformamide/N-methyl-2-pyrrolidone (DN), and ethanol/methanol/isopropanol (EMI), evaluated under water immersion and thermal stress, and characterized for chemical stability, mechanical strength, water uptake, and proton conductivity using advanced electrochemical and spectroscopic techniques. The results demonstrated that the EMI-treated membrane showed the highest proton conductivity and maintained its structural integrity, making it the most promising for hydrogen electrolysis applications. Conversely, the DN-treated membrane exhibited reduced stability and lower conductivity due to solvent-induced degradation. This study highlights the potential of EMI as an optimal solvent mixture for enhancing PFSA membranes performance in green hydrogen production, contributing to the advancement of sustainable energy solutions. Full article

This study examines the effects of several commercial surfactants on the dispersion of catalyst inks for proton exchange membrane fuel cells (PEMFCs). Catalyst inks containing Pt/C were spray-coated and assembled into membrane electrode assemblies (MEAs) by hot pressing. The structural and electrochemical properties of the resulting catalyst layers were characterized through particle size analysis, zeta potential measurements, contact angle determinations, and single-cell performance tests. Among the formulations evaluated, the ink with non-ionic surfactant Triton X-100 (TX) delivered the best performance, achieving a current density of 1134 mA/cm² at 0.3 V—substantially higher than that of the surfactant-free control. These findings provide practical guidance for selecting appropriate surfactants to optimize catalyst-ink preparation and enhance PEMFC performance. Full article

The advancement of catalytic materials is critical to improving the performance, reducing the cost and enhancing the sustainability of Proton Exchange Membrane (PEM) fuel cells and electrolyzers. Although Platinum Group Metal (PGM)-based electrocatalysts exhibit high electrochemical activity, their limited availability and the environmentally intensive extraction pose significant challenges. This study aims to demonstrate the direct reuse of recycled impure platinum (Pt) precursors for the synthesis of effective Pt/C electrocatalysts as a viable step toward circular hydrogen economy implementation. A low-cost and eco-friendly chlorine-based hydrometallurgical method was successfully employed to recycle over 99% of Pt from End-of-Life (EoL) Membrane Electrode Assemblies (MEAs), with an industrial perspective. Recycled metal precursor was used without purification to synthesize Pt/C electrocatalyst via a scalable and sustainable method. The catalyst was structurally and chemically characterized, and their electrochemical performance towards the Oxygen Reduction Reaction (ORR) was conducted under conditions simulating real operating environments. The recycled-metal-derived catalyst demonstrated comparable activity toward ORR (170 A/gPt) relative to a commercial catalyst, indicating its potential as viable alternative to conventional PGM-based catalysts. By integrating energy-efficient recycling with advanced material design, this work supports the development of cost-effective and green solutions for clean energy technologies aligned with a circular hydrogen economy model. Full article

The optimum degree of sulfonation (DS) for sulfonated poly(ether ether ketone) (SPEEK) membranes is determined by comprehensive characterization results, including proton conductivity, swelling ratio, water uptake, chemical stability, thermal stability, mechanical indicators, and proton exchange membrane fuel cell (PEMFC) performance. The PEMFC with a membrane electrode assembly containing a SPEEK-62 (DS = 62%) membrane realizes the power density of 482.08 mW/cm², surpassing that of commercial Nafion-212 under identical conditions. In the crucial Fenton test for durability, the SPEEK-51 membrane demonstrated outstanding dimensional and chemical stability, with a decomposition time of up to 137 min, far surpassing the durability of SPEEK-62 or other membranes with a higher DS. The results indicate that in comparison to the SPEEK-67 membrane as reported in the literature, SPEEK membranes with a DS = 51~62% hold great potential for future applications in PEMFC, and further modifications of these membranes can be a promising approach to enhance the conductivity while maintaining good chemical stability. Full article

Metal–Organic Frameworks (MOFs) have emerged as advanced porous crystalline materials due to their highly ordered structures, ultra-high surface areas, fine-tunable pore sizes, and massive chemical diversity. These features, arising from the coordination between an almost unlimited number of metal ions/clusters and organic linkers, have resulted in significant interest in MOFs for applications in gas storage, catalysis, sensing, energy, and biomedicine. Beyond their stand-alone properties and applications, recent research has increasingly explored the integration of MOFs with other substrates, particularly electrodes, polymeric thin films, and glass surfaces, to create synergistic effects that enhance material performance and broaden application potential. Coating MOFs onto these substrates can yield significant benefits, including, but not limited to, improved sensitivity and selectivity in electrochemical sensors, enhanced mechanical and separation properties in membranes, and multifunctional coatings for optical and environmental applications. This review provides a comprehensive and up-to-date summary of recent advances (primarily from the past 3–5 years) in MOF coating techniques, including layer-by-layer assembly, in situ growth, and electrochemical deposition. This is followed by a discussion of the representative applications arising from MOF-substrate coating and an outline of key challenges and future directions in this rapidly evolving field. This article aims to serve as a focused reference point for researchers interested in both fundamental strategies and applied developments in MOF surface coatings. Full article

Fuel cells, as one of the most promising alternatives to lithium-ion batteries for portable power systems, still face significant challenges. A critical issue is their substantial performance degradation under low-humidity conditions. To address this, researchers commonly add silica to components. This study employs a control variable method to systematically investigate the impact of four parameters—gas stoichiometry, temperature, humidity, and silica content—on fuel cell performance. Initially, the effects of gas stoichiometry, temperature, and humidity on performance were examined. Subsequently, hydrophilic silica was incorporated into the membrane electrode assembly (MEA) to assess its potential for improving performance in low-humidity environments. Experimental results reveal that under 100% humidification, silica addition had a minimal impact on performance, particularly at high temperatures where performance improved by only 2.5%. This is attributed to increased water production at elevated temperatures, which—when combined with silica’s water retention properties—exacerbates flooding. However, when humidity was reduced to 50%, silica incorporation significantly enhanced performance. At high temperatures, silica addition resulted in a 126.2% performance improvement, demonstrating its efficacy as a rational strategy under low-humidity conditions. Full article

Green hydrogen production from water electrolysis (WE) is one of the most promising technologies to realize a decarbonized future and efficiently utilize intermittent renewable energy. Among the various WE technologies, the emerging anion exchange membrane (AEMWE) technology shows the greatest potential for producing green hydrogen at a competitive price. To achieve this goal, simple methods for the large-scale synthesis of efficient and low-cost electrocatalysts are needed. This paper proposes a very simple and scalable process for the synthesis of nanostructured NiCo- and NiFe-based electrode materials for a zero-gap AEMWE full cell. For the preparation of the cell anode, oxides with different Ni molar fractions (0.50 or 0.85) are synthesized by the sol–gel method, followed by calcination in air at different temperatures (400 or 800 °C). To fabricate the cell cathode, the oxides are reduced in a H₂/Ar atmosphere. Electrochemical testing reveals that phase purity and average crystal size significantly influence cell performance. Highly pure and finely grained electrocatalysts yield higher current densities at lower overpotentials. The best performing membrane electrode assembly exhibits a current density of 1 A cm⁻² at 2.15 V during a steady-state 150 h long stability test with 1 M KOH recirculating through the cell, the lowest series resistance at any cell potential (1.8 or 2.0 V), and the highest current density at the cut-off voltage (2.2 V) both at the beginning (1 A cm⁻²) and end of tests (1.78 A cm⁻²). The presented results pave the way to obtain, via simple and scalable techniques, cost-effective catalysts for the production of green hydrogen aimed at a wider market penetration by AEMWE. Full article

Nanostructured bimetallic IrSn composites deposited on the natural aluminosilicate montmorillonite were synthesized and evaluated as anode electrocatalysts for polymer electrolyte membrane electrolysis cells (PEMECs). The test series prepared via the sol–gel method consisted of samples with 30 wt. % total metal content and varying Ir:Sn ratio. The performed X-ray diffraction analysis and high-resolution transmission electron icroscopy registered very fine nanostructure of the composites with metal particles size of 2–3 nm homogeneously dispersed on the support surface and also intercalated in the basal space of its layered structure. The electrochemical behavior was investigated by cyclic voltammetry and steady-state polarization techniques. The initial screening was performed in 0.5 M H₂SO₄. Then, the catalysts were integrated as anodes in membrane electrode assemblies (MEAs) and tested in a custom-made PEMEC. The electrochemical tests revealed that the catalysts with Ir:Sn ratio 15:15 and 18:12 wt. % demonstrated high efficiency toward the oxygen evolution reaction during repetitive potential cycling and sustainable performance with current density in the range 140–120 mA cm⁻² at 1.6 V vs. RHE during long-term stability tests. The results obtained give credence to the studied IrSn/MMT nanocomposites to be considered promising, cost-efficient catalysts for the oxygen evolution reaction (OER). Full article