Search Results (923)

The design of ladle furnace (LF) refining pathways for weathering steels requires precise control of multi-component steel/slag reactions governed simultaneously by thermodynamics and interfacial mass transfer kinetics. An EERZ-based kinetic modeling strategy was employed using the Thermo-Calc^® (version 2022a) Process Metallurgy Module and the CALPHAD TCOX11 database to develop LF refining schedules capable of upgrading conventional S355J2R steel to weathering steel grades: S355J2W and S355J2WP. First, the sensitivity of predicted compositions to key kinetic inputs was quantified. The validated model was then used to simulate deoxidation and desulfurization sequences, predicting the evolution of liquid–steel and slag compositions, slag basicity, and FeO activity throughout the LF cycle. Subsequently, Cr- and P-ferroalloys were introduced to design tap-to-tap schedules that meet the EN 10025-5 chemical specifications for S355J2W and S355J2WP. To correlate simulation outcomes with material performance, plates produced following the modeled schedules were evaluated through a 1000 h accelerated salt spray test. Steel density and steel phase mass transfer coefficients were found to produce the highest prediction sensitivity (up to 7.5 wt.% variation in C and S), whereas slag phase parameters exhibited a lower impact. The predicted steel compositions showed strong agreement with industrial values obtained during plant trials. SEM-EDS analyses confirmed the development of a Cr-enriched protective patina and validated model-based alloying strategies. Full article

The heat transfer and flow characteristics of TiO₂/R123 nano-organic working fluid are investigated and compared with that of R123. A three-dimensional numerical model of the smooth circular tube with a diameter of 10 mm and a length of 1 m is established, and the thermodynamic properties of the nano-organic working fluids are rectified with the volume of fluid model. The grid independence validation is conducted, and the simulation results from three models (the k-ε model, the realizable k-ε model, and the Reynolds Stress Model) are evaluated against experimental data. When using the TiO₂/R123 nano-organic working fluid, the error between the simulation and experimental results is 6.1%. The flow field distribution is examined, and the effect of mass flux on heat transfer coefficient and pressure drop is discussed. Results demonstrated that the inclusion of TiO₂ nanoparticles significantly enhances heat transfer performance. At a 0.1 wt% nanoparticle concentration, the heat transfer coefficient increases by 23.2%, reaching a range of 1430.11 to 2647.25 W/(m²·K), compared to pure R123. However, this improvement in heat transfer performance is accompanied by an increase in flow resistance, with the flow resistance coefficient rising from 0.0353 to 0.0571. Additionally, pressure drops increase by up to 18.7%. Full article

In Proton Exchange Membrane Water Electrolysis (PEMWE), the two-phase flow distribution in the anode field significantly affects overall electrolysis performance. Based on visualized experimental data, in this paper, the reaction kinetics equations were theoretically revised, and a three-dimensional, two-phase, non-isothermal, multi-physics coupled model of the electrolysis was developed and experimentally validated. Four different configurations of rectangular turbulence promoters were designed within the anode serpentine flow field and compared with a conventional serpentine flow field (SFF) in terms of their multi-physics distribution characteristics. The results showed that, in the double-row rectangular block serpentine flow field (DRB SFF), the uniformity of liquid water saturation, temperature, and current density improved by 16.6%, 0.49% and 40.8%, respectively. The normal mass transfer coefficient increased by a factor of 6.3, and polarization performance improved by 6.98%. A cross-arranged turbulence promoter structure was further proposed. This design maintains effective turbulence while reducing flow resistance and pressure drop, thereby enhancing mass transfer efficiency and overall electrolysis performance through improved bubble fragmentation. Full article

This work focuses on testing and validating a prototype device for measuring mass transfer phenomena in biomass drying processes, patented by the Universitat Politècnica de València (UPV) and Escuela Politécnica del Litoral (ESPOL), WO2025/109237 A1. The first step involved evaluating and calibrating the sensors of the measuring device to ensure accurate and consistent measurements. Subsequently, extensive tests were conducted to validate the prototype’s functionality for obtaining mass diffusivity and the mass transfer coefficient by convection at the solid-air interface. Finally, the results obtained were compared with those provided by existing predictive theoretical models in the literature. Areas for improvement in the theoretical models were identified, and adjustments were made to optimize prediction. The study highlights that the theoretical Sherwood method for estimating the mass transfer coefficient shows discrepancies with experimental data, mainly due to the assumption that the transfer coefficient remains constant during drying, whereas it actually varies with the material’s moisture content. This leads to inaccuracies that affect the efficiency of industrial drying systems. The prototype proved effective in measuring both diffusivity and mass transfer coefficient, validating the method. Full article

Adsorption chillers can produce chilled and desalinated water using low-grade heat, but their performance is limited by low coefficient of performance (COP) and large system mass. Enhancing heat and mass transfer in the sorbent bed is key to improving efficiency. This work introduces and systematically evaluates binder-stabilized silica gel composites as a structural and thermal enhancement strategy for adsorption chillers. Silica gel composites bonded with epoxy resin and polyvinyl alcohol (PVA) were evaluated for adsorption chiller applications. Thermal stability, conductivity, microstructure, equilibrium sorption, and sorption hysteresis were assessed. The results indicate that PVA-based composites were thermally unstable and discarded, whereas epoxy-bonded silica gel showed high thermal stability and mechanically robust granules with preserved pore connectivity. The epoxy composite exhibited 109% higher thermal conductivity than loose silica gel, improving internal heat transfer. This improvement is accompanied by a reduction in sorption capacity of approximately 58%, attributable to the inert resin fraction. Notably, the composite exhibits a reduced and locally negative sorption hysteresis, indicating facilitated desorption and lowered internal diffusion resistance. The epoxy-bonded silica gel therefore provides a promising combination of thermal stability, improved heat transfer, and enhanced sorption–desorption behaviour, supporting its potential to increase the efficiency of next-generation adsorption chillers. Full article

Tannery wastewater from textile-related industries poses treatment challenges due to its high load of recalcitrant pollutants. Various advanced hybrid treatments, such as electro-oxidation (EO), have been proposed but mainly focus on electrode material development. Several studies on EO using multiple electrode pairs with large electroactive surface areas exist, however, none have reported on mass transfer characterization. This study addresses these gaps by investigating the electro-degradation performance of active (mixed-metal oxide, MMO) and non-active (boron-doped diamond, BDD) anodes paired with carbonaceous (graphite) and non-carbonaceous (stainless steel, SS) cathodes under applied current densities of 2 to 6 mA/cm². A 2 L volume of simulated tannery wastewater containing recalcitrant tannic acid was treated using three electrode pairs with a total surface area of 500 cm². Results showed optimal condition was identified at 4 mA/cm² across all electrode combinations and better degradation using BDD anodes and SS cathodes, with total organic carbon (TOC) removed up to 500 mg/L (98% removal). Adopting the 3-electrode configuration, mass transfer coefficients ranged from 4.15 to 5.18 × 10⁻⁶ m/s. Energy consumption evaluation suggested MMO as a more cost-effective option, while BDD remained preferable for highly recalcitrant waste. Higher currents show diminishing returns due to mass transfer and parasitic reactions. Full article

Lead–bismuth eutectic (LBE), while advantageous for advanced nuclear reactors due to its thermophysical properties, faces oxidation and corrosion challenges during operation. This study aims to optimize gas-phase oxygen control by computationally analyzing oxygen transport dynamics in an LBE loop. High-fidelity simulations were performed using ANSYS Fluent and STAR-CCM+ based on the CORRIDA loop geometry, employing detailed meshing for convergence. Steady-state analyses revealed localized oxygen enrichment near the gas–liquid interface (peaking at ∼$3\times {10}^{-6}$ wt%), decreasing to ∼$5.0-6.8\times {10}^{-8}$ wt% at the outlet. Transient simulations from an oxygen-deficient state ($1\times {10}^{-8}$ wt%) demonstrated distribution stabilization within 150 s, driven by convection-enhanced diffusion. Parametric studies identified a non-monotonic relationship between inlet velocity and oxygen uptake, with optimal performance at 0.7–0.9 m/s, while increasing temperature from 573 K to 823 K monotonically enhanced the outlet concentration by >$200\%$ due to improved diffusivity/solubility. The average mass transfer coefficient (0.6–0.7) aligned with literature values ($\pm 20\%$ deviation), validating the model’s treatment of interface thermodynamics and turbulence. These findings the advance mechanistic understanding of oxygen transport in LBE and directly inform the design of oxygenation systems and corrosion mitigation strategies for liquid metal-cooled reactors. Full article

Ammonia (NH₃) recovery from animal manure offers both environmental and economic benefits by reducing nitrogen emissions and producing valuable fertilisers. Hollow fibre membrane contactors (HFMCs) are a promising technology for this purpose, yet their performance is strongly influenced by the complex composition of manure. In this study, the effects of solids concentration and organic foulants concentration on the mass transfer coefficients governing NH₃ recovery were systematically investigated. Total suspended solids (TSS) were reduced through graded filtration, and protein concentrations in the ammonium solutions were quantified to assess their role in limiting mass transfer. Results showed that TSS concentration primarily affected the shell-side film resistance. After extensive filtration, residual proteins attached to the membrane surface induced partial wetting, thereby reducing the effective membrane mass transfer coefficient. Using a penalty function approach, it was possible to separately describe TSS- and protein-related resistances, enabling improved prediction of effective model coefficients under real world conditions. These findings highlight the dual importance of solid–liquid separation and protein management in optimising HFMC operation for NH₃ recovery and provide a framework for up-scaling the technology in agricultural nutrient management systems. Full article

Industrial heat exchangers are widely used in industries such as petrochemicals, energy and power, and food processing, making them one of the most important pieces of heat and mass transfer equipment in industry. During operation, a layer of fouling often adheres to the heat transfer surfaces, which reduces the heat transfer coefficient of the equipment and increases the thermal resistance of the surfaces. Additionally, fouling can corrode the material of the heat transfer surfaces, compromise their integrity, and even lead to perforations and leaks, severely impacting equipment operation and safety while increasing energy consumption and costs for enterprises. The application of anti-fouling coatings on surfaces is a key technology to address fouling on heat transfer surfaces. This paper focuses on introducing major types of anti-fouling coatings, including polymer-based coatings, “metal material + X”-type coatings, “inorganic material + X”-type coatings, carbon-based material coatings, and other varieties. It analyzes and discusses the current research status and hotspots for these coatings, elaborates on their future development directions, and proposes ideas for developing new coating systems. On the other hand, this paper summarizes the current research on the main factors—surface roughness, surface free energy, surface wettability, and coating corrosion resistance—that affect the anti-fouling performance of coatings. It outlines the research hotspots and challenges in understanding the influence of these three factors and suggests that future research should consider the synergistic effects of multiple factors, providing valuable insights for further studies in the field of anti-fouling coatings. Full article

Fixed-bed adsorption is widely employed in the scaling-up of liquid-phase adsorption processes because it offers significant operational advantages over batch systems. However, conventional approaches for scaling up adsorption columns are subject to important limitations. In this regard, the Axial Dispersion Model (ADM) coupled with the Pore Volume and Surface Diffusion Model (PVSDM) provides a framework capable of overcoming these constraints. In this study, ADM–PVSDM was applied predictively using equilibrium relationships and diffusion coefficients obtained from batch experiments. Model validity was assessed against nine experimental breakthrough curves, yielding an average deviation of 7.6% in breakthrough time. Furthermore, the model successfully predicted system behavior across a feed-flux range of 18–174 g h⁻¹m⁻². The integration of ADM–PVSDM was supported by the characterization of the Mass Transfer Zone (MTZ), which underpins the scaling approach proposed herein. The predicted breakthrough curves were also used to estimate MTZ length and velocity, which ranged from 0.97 to 8.7 cm and from 0.56 × 10⁻³ to 20 × 10⁻³ cm min⁻¹, respectively, with mean percentage deviations of 6.4% and 7.3%. These predictions enabled the development of a methodology which is capable of scaling adsorption columns over a wide operational range while requiring substantially fewer experiments compared to conventional scaling methods. Finally, it was demonstrated that commonly used empirical models, such as the Bohart–Adams model, failed to predict breakthrough curves with sufficient accuracy, thus rendering them unsuitable for developing this scaling methodology. Full article

Binary mixtures of HFE-73DE and ethyl acetate are investigated as dielectric working fluids for laminar minichannel cooling. Thermophysical properties of the pure components and four mixtures (10/90, 25/75, 50/50 and 75/25 mass % HFE-73DE/ethyl acetate) were measured over the relevant temperature range. Single-phase convective heat transfer tests were then carried out in a heated 1 × 4 × 180 mm minichannel test section under constant heat-flux conditions for pure HFE-73DE. A three-dimensional conjugate CFD model with temperature-dependent liquid properties was developed in Simcenter STAR-CCM+ and validated against these measurements; the average relative temperature difference between CFD and experiment remained below 0.5%, while a grid-convergence study based on the Grid Convergence Index (GCI) confirmed that the numerical uncertainty is comparable to the experimental one. The validated model was subsequently used to predict the axial evolution of wall temperature, fluid-core temperature, velocity and heat transfer coefficient for the four mixtures under identical conditions. The mean Nusselt numbers obtained from CFD were further compared with the classical Shah and London fully developed laminar solution for rectangular ducts, revealing that the present configuration yields values about 35–42% higher than the theoretical prediction owing to asymmetric heating and conjugate heat transfer. The results show that increasing the HFE-73DE mass fraction strengthens convective heat transfer and reduces fluid-temperature rise, while intermediate compositions (50/50 and 75/25) provide a favourable compromise between enhanced heat transfer performance and moderate pressure drop. The study provides guidance for composition selection and the design of dielectric minichannel heat exchangers operating with HFE-73DE/ethyl acetate mixtures. Full article

Background: Paralympic athletes represent a highly heterogeneous athletic population, which poses unique challenges for body composition assessment. This study evaluated the accuracy of Bioelectrical Impedance Analysis (BIA), Air Displacement Plethysmography (ADP), and a set of skinfold equations in estimating relative fat mass (%FM) in Paralympians, using Dual-Energy X-Ray Absorptiometry (DXA) as reference method. Methods: Sixty-six male and sixty-seven female Paralympians underwent body composition assessments on the same day. The %FM estimated using BIA, ADP, and six existing skinfold equations was compared with %FM measured by DXA (%FM_DXA). Accuracy and agreement between the methods were evaluated using two-tailed paired-sample t-tests, concordance correlation coefficients, reduced major axis regression, and Bland–Altman analysis. Linear regression analyses with the %FM_DXA as dependent variable and anthropometric measurements as independent variable were also carried out. Results: BIA, ADP, and skinfold equations exhibited poor agreement with DXA and significantly underestimated %FM_DXA, with systematic biases ranging from −1.8% to −10.7% in both men and women. In both groups, skinfold sums showed strong correlations with %FM_DXA (r > 0.7), with the nine-skinfold model providing the best prediction (adjusted R² approximately 0.8). Conclusions: The results of this study indicate a lack of transferability of available methods for assessing body composition (skinfold equations, BIA, and ADP) in estimating %FM_DXA in both male and female Paralympians, as these methods proved inaccurate. Future research is needed to further investigate the accuracy of methods for assessing body composition in this population, taking into account the specific impairment and health condition of the athletes. Full article

Mixed amine/sulfolane (TMS) biphasic solutions have gained attention for their adjustable structure–activity relationships and lower regeneration energy. In this study, monoethanolamine (MEA) is employed as the main absorbent and polyamine as the co-absorbent, which are subsequently mixed with the phase separation promoter sulfolane (TMS) to form ternary biphasic solvent systems. Polyamine co-absorbents include 3-Dimethylaminopropylamine (DMAPA), 3-Diethylaminopropylamine (DEAPA), and Diethylenetriamine (DETA). Phase separation, absorption, and desorption performances were systematically studied. Reaction and phase separation mechanisms were elucidated through ¹³C nuclear magnetic resonance (NMR) spectroscopy. The overall mass transfer coefficients (K_G) were measured using a wetted wall column (WWC). Variations in the amine-to-sulfolane concentration ratio showed minimal impact on phase volume, while temperature and solvent composition significantly influenced phase separation behavior. All three solvents exhibited superior CO₂ capture performance, with CO₂ loadings in the rich phases ranging from 4.09 to 4.71 mol/L and over 96.82% of CO₂ concentrated in them, cyclic capacities reached or exceeded 3 mol/L, and regeneration energy consumption was 29.63–55.51% lower than 5 M MEA. ¹³C NMR analysis indicated that multiple N atoms in polyamines promoted the formation of additional ionic species during CO₂ absorption, thereby enhancing phase separation completeness. Furthermore, K_G values for the ternary systems exceeded that of conventional MEA, with the MEA/DEAPA/TMS system exhibiting a 1.7-fold increase. These findings demonstrated the industrial potential of MEA/polyamine/TMS biphasic solvents for efficient CO₂ capture. Full article

This study aimed to enhance the extraction efficiency and elucidate the mechanism of ultrasound-assisted extraction (UAE) of taxanes from Taxus chinensis by natural deep eutectic solvents (NADES). The processes of kinetics and thermodynamics were systematically investigated. These extractions adhered to a pseudo-second-order kinetic model (R² > 0.972), with intraparticle diffusion identified as the dominant mechanism. Key parameters such as temperature, ultrasonic power, and solid/liquid ratio significantly improved the effective diffusion coefficient (D_e) and mass transfer coefficient (K_T), reaching values of 6.21 × 10⁻⁹ m²/s and 4.14 × 10⁻³ m/s, respectively. A high Biot number (B_i > 59.21) confirmed that internal diffusion is the rate-determining step. Thermodynamic analysis indicated that the process is endothermic (ΔH > 0), irreversible (ΔS > 0), and spontaneous (ΔG < 0). These results elucidate the underlying mechanisms of UAE and establish a foundational framework for its industrial-scale implementation. Full article

Enhancing the evaporator configuration of plate heat exchangers is essential for improving the overall efficiency of organic Rankine cycle (ORC) systems. To investigate the evaporator’s heat transfer characteristics, an experimental ORC test rig was developed. The experiments were conducted at saturation temperatures of 62.8–86.2 °C, mass fluxes of 5.0–16.6 kg/(m²·s), and heat fluxes of 3.1–9.2 kW/m², spanning subcooled boiling, saturated two-phase, and superheating regions. The heat flux showed minimal variation with heat source temperature, whereas higher mass fluxes resulted in substantial increases in generator power and thermal efficiency due to enhanced convection and vaporization. The overall and refrigerant heat transfer coefficients rise with heat source temperature and mass flux, peaking under moderate conditions and declining as the superheating region becomes constrained. Comparison with existing correlations reveals pronounced deviations, indicating their limited applicability under the present operating conditions. A nondimensional correlation was established using dimensional analysis and multivariate regression to predict heat transfer across the subcooled boiling, saturated two-phase, and superheating regions. The proposed correlation yielded a mean absolute percentage error of 15.9%, demonstrating good predictive accuracy and providing a reliable theoretical basis for performance evaluation and design optimization of plate evaporators in ORC systems. Full article