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Keywords = interlayer interval time

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25 pages, 53027 KB  
Article
Failure Mechanism of Sudden Rock Landslide Under the Coupling Effect of Hydrological and Geological Conditions: A Case Study of the Wanshuitian Landslide, China
by Pengmin Su, Maolin Deng, Long Chen, Biao Wang, Qingjun Zuo, Shuqiang Lu, Yuzhou Li and Xinya Zhang
Water 2026, 18(9), 1001; https://doi.org/10.3390/w18091001 - 23 Apr 2026
Viewed by 476
Abstract
At around 8:40 a.m. on 17 July 2024, the Wanshuitian landslide in the Three Gorges Reservoir Area (TGRA) experienced a deformation failure characterized by thrust load-caused deformations and high-speed sliding. Using geological surveys and unmanned aerial vehicle (UAV) photography, this study divided the [...] Read more.
At around 8:40 a.m. on 17 July 2024, the Wanshuitian landslide in the Three Gorges Reservoir Area (TGRA) experienced a deformation failure characterized by thrust load-caused deformations and high-speed sliding. Using geological surveys and unmanned aerial vehicle (UAV) photography, this study divided the Wanshuitian landslide area into five zones: sliding initiation (A1), secondary disintegration (A2), main accumulation (B1), right falling (B2), and left falling (B3) zones. Through monitoring data analysis and GeoStudio-based numerical simulations, this study revealed the mechanisms behind the landslide failure mode characterized by slope sliding approximately along the strike of the rock formation under the coupling effect of hydrological and geological conditions. The results indicate that factors inducing the landslide failure include the geomorphic feature of alternating grooves and ridges, the lithologic assemblage characterized by interbeds of soft and hard rocks, the slope structure with well-developed joints, and the sustained heavy rains in the preceding period. In the Wanshuitian landslide area, mudstone valleys are prone to accumulate rainwater, which can infiltrate directly into the weak interlayers of rock masses and soften the rock masses. Multi-peak rain events with a short time interval serve as a critical factor in groundwater recharge. Within 17 days preceding its failure, the Wanshuitian landslide experienced a superimposed process of heavy and secondary rain events with a short interval (four days). Rainwater from the first heavy rain event failed to completely discharge during the short interval, while the secondary rain event also caused rainwater accumulation. These led to a continuous rise in the groundwater table, a constant decrease in the shear strength of the slope, and ultimately the landslide instability. Since the landslide sliding in the dip direction of the rock formation was impeded, the main sliding direction of the landslide formed an angle of 88° with this direction. This led to a unique failure mode characterized by slope sliding approximately along the strike of the rock formation. Based on these findings, this study proposed characteristics for the early identification of the failure of similar landslides, aiming to provide a robust scientific basis for the monitoring, early warning, and prevention and control of the failure of similar landslides. Full article
(This article belongs to the Special Issue Water-Related Landslide Hazard Process and Its Triggering Events)
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29 pages, 9816 KB  
Article
A Prediction Model of Interlayer Bond Strength for 3D-Printed Concrete Considering Printing Interval and Environmental Effects
by Wenbin Xu, Zihao Xu, Tao Liu, Jun Ouyang, Juan Wang, Hailong Wang and Wenqiang Xu
Materials 2026, 19(7), 1377; https://doi.org/10.3390/ma19071377 - 30 Mar 2026
Viewed by 531
Abstract
Interlayer bond strength is critical for ensuring the safety and durability of 3D-printed concrete (3DPC) structures. However, there remains a lack of real-time prediction methods addressing interlayer performance under the combined effects of interval time and environmental factors during the in situ printing [...] Read more.
Interlayer bond strength is critical for ensuring the safety and durability of 3D-printed concrete (3DPC) structures. However, there remains a lack of real-time prediction methods addressing interlayer performance under the combined effects of interval time and environmental factors during the in situ printing process. To address this issue, this study conducted experiments considering various printing interval times and environmental conditions, incorporating monitoring of dielectric constant and water evaporation, alongside interlayer splitting tensile tests. By integrating the SHAP interpretability algorithm with nonlinear regression analysis, the results indicate that the printing interval time is the dominant factor inducing interlayer strength decay (with a contribution rate of 68.6%), while relative humidity emerges as the primary environmental variable (with a contribution rate of 21.3%). Mechanism analysis reveals that prolonged printing intervals intensify the hydration of the lower deposited layer, leading to reduced interfacial moisture content and loss of plasticity. Furthermore, environmental evaporation significantly regulates this process, with high-humidity environments notably mitigating the moisture loss and strength reduction caused by time delays. Based on the correlation mechanism between moisture and strength, a dimensionless general prediction model for 3DPC interlayer strength was established, incorporating printing interval time and an evaporation index (goodness of fit, R2 = 0.96). Consequently, a digital twin quality inversion scheme based on companion specimen monitoring and printing timestamps was proposed. This study quantifies the intrinsic relationships among printing interval time, environmental conditions, and interlayer strength, offering a novel approach for determining the construction window and achieving non-destructive quality prediction for 3DPC in complex environments. Full article
(This article belongs to the Special Issue Additive Manufacturing of Structural Materials and Their Composites)
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21 pages, 13465 KB  
Article
Microscopic Characteristics and Development Model of Phosphatic Bioclastic Laminae in the Jurassic Lianggaoshan Formation Shale, Eastern Sichuan Basin
by Cong Zhang, Weikun Chen, Yuan Zhang, Tenger Borjigin, Boran Wang, Daojun Wang, Miaomiao Liu, Wenren Zeng, Haohan Li, Ronghui Fang and Zi Wang
Minerals 2026, 16(3), 295; https://doi.org/10.3390/min16030295 - 11 Mar 2026
Viewed by 410
Abstract
Phosphatic bioclastic laminae distributed along bedding planes have been recently discovered within the Jurassic Lianggaoshan Formation shale in the eastern Sichuan Basin. However, their characteristics and potential as shale oil and gas reservoirs remain unclear. To reveal their microscopic pore structure characteristics and [...] Read more.
Phosphatic bioclastic laminae distributed along bedding planes have been recently discovered within the Jurassic Lianggaoshan Formation shale in the eastern Sichuan Basin. However, their characteristics and potential as shale oil and gas reservoirs remain unclear. To reveal their microscopic pore structure characteristics and development model, this study focuses on samples of phosphatic bioclastic laminae obtained from drilling cores in the Fuxing area of eastern Sichuan. A multi-scale analytical approach was employed, integrating micro-X-ray fluorescence spectroscopy (μ-XRF), field emission scanning electron microscopy (FE-SEM), nitrogen adsorption, nuclear magnetic resonance (NMR), and geochemical analyses. The results indicate that the phosphatic bioclastic laminae are primarily composed of apatite and calcite and formed in a low-energy, anoxic, semi-deep to deep lacustrine environment. They exhibit an average total porosity of 4.84% and an average TOC of 1.99 mg/g. It is 14.7% and 17.8% higher than the clay laminae, and 255.9% and 109.57% higher than the calcareous bioclastic laminae. The pore system is dominated by mesopores and macropores, encompassing multiple pore types including dissolution pores, interparticle pores, interlayer pores, organic matter-hosted pores, and micro-fractures. Notably, a well-connected nanometer-scale pore network developed within fish bone fragments contributes substantially to the storage space. These intervals integrate high organic matter richness with superior reservoir properties, demonstrating typical “source-reservoir integration” characteristics. Their pore structure is synergistically regulated by sedimentary–diagenetic processes, with a core mechanism of primary biogenic pore foundation–late diagenetic dissolution enhancement–micro-fracture connectivity. This study systematically elucidates, for the first time, the reservoir formation mechanism of the phosphatic bioclast-rich laminae in the Lianggaoshan Formation. It confirms their potential as “geological-engineering” dual sweet spots for shale oil and gas exploration, providing a new basis for sweet spot prediction and exploration deployment targeting similar phosphatic bioclastic laminae in the Sichuan Basin and analogous regions. Full article
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22 pages, 40292 KB  
Article
Maritime Applications as Motivation for Analytical Calculation of Thermal History in Low-Carbon Mild Steel WAAM Cylinders
by Eleftherios Lampros and Anna D. Zervaki
Metals 2026, 16(2), 192; https://doi.org/10.3390/met16020192 - 5 Feb 2026
Cited by 2 | Viewed by 853
Abstract
This study reviews the application of wire arc additive manufacturing (WAAM) technology in maritime engineering and investigates an experimentally driven analytical approach for prediction of thermal distributions based on the Rosenthal solution. Two ER70S-6 low-carbon steel WAAM cylinders were fabricated using gas metal [...] Read more.
This study reviews the application of wire arc additive manufacturing (WAAM) technology in maritime engineering and investigates an experimentally driven analytical approach for prediction of thermal distributions based on the Rosenthal solution. Two ER70S-6 low-carbon steel WAAM cylinders were fabricated using gas metal arc welding (GMAW) and plasma arc welding (PAW) processes, with interlayer temperatures of 453 °C and 250 °C, respectively. Accurately measuring the temperature field to tailor the microstructure has long been a challenge. The results indicated a significant deviation between the analytical predictions and the experimental data. To address this discrepancy, a hybrid approach combining analytical and experimental results was implemented. Time intervals between layers, extracted from the experimental data, were incorporated into the Rosenthal equation to improve the accuracy of temperature field predictions. The microstructure at the bottom, middle, and top regions of the WAAM components was examined using optical microscopy. Tensile testing and Vickers microhardness measurements were conducted to evaluate mechanical properties. Scanning electron microscopy (SEM) was used to analyze fracture surfaces and identify fracture modes. The results were consistent with those reported for other ER70S-6 cylindrical WAAM components. This work highlights limitations of the Rosenthal solution and emphasizes the need for thermal models in WAAM applications. Full article
(This article belongs to the Special Issue Advanced Additive Manufacturing of Metallic Materials)
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25 pages, 7740 KB  
Article
Anisotropy of Mechanical Properties of 3D-Printed Materials—Influence of Application Time of Subsequent Layers
by Marcin Maroszek, Izabela Hager, Katarzyna Mróz, Mateusz Sitarz and Marek Hebda
Materials 2025, 18(16), 3845; https://doi.org/10.3390/ma18163845 - 15 Aug 2025
Cited by 13 | Viewed by 4763
Abstract
Three-dimensional concrete printing (3DCP) is an emerging additive manufacturing technology with increasing application potential in the construction industry, offering advantages such as reduced labor requirements, shortened construction time, and material efficiency. However, structural integrity remains a challenge, particularly due to weak interlayer bonding [...] Read more.
Three-dimensional concrete printing (3DCP) is an emerging additive manufacturing technology with increasing application potential in the construction industry, offering advantages such as reduced labor requirements, shortened construction time, and material efficiency. However, structural integrity remains a challenge, particularly due to weak interlayer bonding resulting from the layered manufacturing process. This study investigates the mechanical performance and anisotropy of 3D-printed mineral-based composites with respect to the time interval between successive layers. Specimens were printed with varying interlayer intervals (0, 25, and 50 min) and tested in different loading directions. Flexural, compressive, and tensile strengths (direct and splitting methods) were measured both parallel and perpendicular to the layer orientation. Results showed a clear degradation in mechanical properties with increasing interlayer time, particularly in the direction perpendicular to the layers. Flexural strength decreased by over 25% and direct tensile strength by up to 40% with a 25 min interval. Compressive strength also declined, though less dramatically. Compared to cast specimens, printed elements showed 3–4 times lower compressive strength, highlighting the significant impact of interlayer cohesion. This study confirms that both the time between layers and the loading direction strongly influence mechanical behavior, underlining the anisotropic nature of 3DCP elements and the need for process optimization to ensure structural reliability. Full article
(This article belongs to the Special Issue 3D Printing Materials in Civil Engineering)
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24 pages, 11697 KB  
Article
Layered Production Allocation Method for Dual-Gas Co-Production Wells
by Guangai Wu, Zhun Li, Yanfeng Cao, Jifei Yu, Guoqing Han and Zhisheng Xing
Energies 2025, 18(15), 4039; https://doi.org/10.3390/en18154039 - 29 Jul 2025
Cited by 3 | Viewed by 948
Abstract
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones [...] Read more.
The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones in their pore structure, permeability, water saturation, and pressure sensitivity, significant variations exist in their flow capacities and fluid production behaviors. To address the challenges of production allocation and main reservoir identification in the co-development of CBM and tight gas within deep gas-bearing basins, this study employs the transient multiphase flow simulation software OLGA to construct a representative dual-gas co-production well model. The regulatory mechanisms of the gas–liquid distribution, deliquification efficiency, and interlayer interference under two typical vertical stacking relationships—“coal over sand” and “sand over coal”—are systematically analyzed with respect to different tubing setting depths. A high-precision dynamic production allocation method is proposed, which couples the wellbore structure with real-time monitoring parameters. The results demonstrate that positioning the tubing near the bottom of both reservoirs significantly enhances the deliquification efficiency and bottomhole pressure differential, reduces the liquid holdup in the wellbore, and improves the synergistic productivity of the dual-reservoirs, achieving optimal drainage and production performance. Building upon this, a physically constrained model integrating real-time monitoring data—such as the gas and liquid production from tubing and casing, wellhead pressures, and other parameters—is established. Specifically, the model is built upon fundamental physical constraints, including mass conservation and the pressure equilibrium, to logically model the flow paths and phase distribution behaviors of the gas–liquid two-phase flow. This enables the accurate derivation of the respective contributions of each reservoir interval and dynamic production allocation without the need for downhole logging. Validation results show that the proposed method reliably reconstructs reservoir contribution rates under various operational conditions and wellbore configurations. Through a comparison of calculated and simulated results, the maximum relative error occurs during abrupt changes in the production capacity, approximately 6.37%, while for most time periods, the error remains within 1%, with an average error of 0.49% throughout the process. These results substantially improve the timeliness and accuracy of the reservoir identification. This study offers a novel approach for the co-optimization of complex multi-reservoir gas fields, enriching the theoretical framework of dual-gas co-production and providing technically adaptive solutions and engineering guidance for multilayer unconventional gas exploitation. Full article
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18 pages, 9755 KB  
Article
Numerical Simulation Analysis of the Influence of Interlayer Quantity on the Long-Term Stable Operation of Gas Storage Facilities
by Lilong Li, Xin Jiang, Jiafeng Tan, Rong Liu, Xiaolinag Quan, Jinyang Fan, Cheng Qian and Jinjie Suo
Appl. Sci. 2024, 14(21), 9760; https://doi.org/10.3390/app14219760 - 25 Oct 2024
Cited by 4 | Viewed by 1452
Abstract
Salt rock is considered as an ideal energy storage medium, and compressed air energy storage by a salt cavern can improve the utilisation efficiency of renewable energy. Salt rock in China mostly contains different interlayers, among which mudstone interlayers are the most common. [...] Read more.
Salt rock is considered as an ideal energy storage medium, and compressed air energy storage by a salt cavern can improve the utilisation efficiency of renewable energy. Salt rock in China mostly contains different interlayers, among which mudstone interlayers are the most common. At present, there are relatively few studies on the influence of mudstone interlayers on the long-term stable operation of gas storage. FLAC3D software was used to simulate the long-term operation of salt rock gas storage with different numbers of interlayers in the Yexian area of Pingdingshan. The results show that with the passage of time, the vertical displacement of the surrounding rock of the vertical single-cavity gas storage tank increases gradually. The maximum settlement value at the top of the surrounding rock is always greater than the maximum uplift value at the bottom. The horizontal displacement shows obvious symmetry with the vertical displacement at the top and bottom of the surrounding rock. The effect of the cyclic pressure interval on horizontal displacement is the same as that of vertical displacement. With the increase in the number of interlayers, the volume of the plastic zone gradually increases with the increase in the running time, and the increasing speed shows a growing trend. Full article
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21 pages, 8030 KB  
Article
Numerical Modeling and Analysis of Transient and Three-Dimensional Heat Transfer in 3D Printing via Fused-Deposition Modeling (FDM)
by Büryan Apaçoğlu-Turan, Kadir Kırkköprü and Murat Çakan
Computation 2024, 12(2), 27; https://doi.org/10.3390/computation12020027 - 5 Feb 2024
Cited by 13 | Viewed by 5132
Abstract
Fused-Deposition Modeling (FDM) is a commonly used 3D printing method for rapid prototyping and the fabrication of plastic components. The history of temperature variation during the FDM process plays a crucial role in the degree of bonding between layers. This study presents research [...] Read more.
Fused-Deposition Modeling (FDM) is a commonly used 3D printing method for rapid prototyping and the fabrication of plastic components. The history of temperature variation during the FDM process plays a crucial role in the degree of bonding between layers. This study presents research on the thermal analysis of the 3D printing process using a developed simulation code. The code employs numerical discretization methods with an implicit scheme and an effective heat transfer coefficient for cooling. The computational model is validated by comparing the results with analytical solutions, demonstrating an agreement of more than 99%. The code is then utilized to perform thermal analyses for the 3D printing process. Interlayer and intralayer reheating effects, sensitivity to printing parameters, and realistic printing patterns are investigated. It is shown that concentric and zigzag paths yield similar peaks at different time intervals. Nodal temperatures can fall below the glass transition temperature (Tg) during the printing process, especially at the outer nodes of the domain and under conditions where the cooling period is longer and the printed volume per unit time is smaller. The article suggests future work to calculate welding time at different conditions and locations for the estimation of the degree of bonding. Full article
(This article belongs to the Special Issue 10th Anniversary of Computation—Computational Engineering)
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15 pages, 2838 KB  
Article
Determining the Effects of Inter-Layer Time Interval in Powder-Fed Laser-Directed Energy Deposition on the Microstructure of Inconel 718 via In Situ Thermal Monitoring
by Evan Handler, Aref Yadollahi, Yucheng Liu and Scott M. Thompson
Materials 2024, 17(3), 538; https://doi.org/10.3390/ma17030538 - 23 Jan 2024
Cited by 7 | Viewed by 3053
Abstract
Cylindrical Inconel 718 specimens were fabricated via a blown-powder, laser-directed energy deposition (DED-L) additive manufacturing (AM) process equipped with a dual thermal monitoring system to learn key process–structure relationships. Thermographic inspection of the heat affected zone (HAZ) and melt pool was performed with [...] Read more.
Cylindrical Inconel 718 specimens were fabricated via a blown-powder, laser-directed energy deposition (DED-L) additive manufacturing (AM) process equipped with a dual thermal monitoring system to learn key process–structure relationships. Thermographic inspection of the heat affected zone (HAZ) and melt pool was performed with different layer-to-layer time intervals of ~0 s, 5 s, and 10 s, using an infrared camera and dual-wavelength pyrometer, respectively. Maximum melt pool temperatures were found to increase with layer number within a substrate affected zone (SAZ), and then asymptotically decrease. As the layer-to-layer time interval increased the HAZ temperature responses became more repetitive, indicating a desirable approach for achieving a more homogeneous microstructure along the height of a part. Microstructural variations in grain size and the coexistence of specific precipitate phases and Laves phases persisted among the investigated samples despite the employed standard heat treatment. This indicates that the effectiveness of any post DED-L heat treatment depends significantly on the initial, as-printed microstructure. Overall, this study demonstrates the importance of part size, part number per build, and time intervals on DED-L process parameter selection and post-process heat treatments for achieving better quality control. Full article
(This article belongs to the Collection Additive Manufacturing: Alloy Design and Process Innovations)
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21 pages, 5769 KB  
Article
SiamHSFT: A Siamese Network-Based Tracker with Hierarchical Sparse Fusion and Transformer for UAV Tracking
by Xiuhua Hu, Jing Zhao, Yan Hui, Shuang Li and Shijie You
Sensors 2023, 23(21), 8666; https://doi.org/10.3390/s23218666 - 24 Oct 2023
Cited by 2 | Viewed by 2695
Abstract
Due to high maneuverability as well as hardware limitations of Unmanned Aerial Vehicle (UAV) platforms, tracking targets in UAV views often encounter challenges such as low resolution, fast motion, and background interference, which make it difficult to strike a compatibility between performance and [...] Read more.
Due to high maneuverability as well as hardware limitations of Unmanned Aerial Vehicle (UAV) platforms, tracking targets in UAV views often encounter challenges such as low resolution, fast motion, and background interference, which make it difficult to strike a compatibility between performance and efficiency. Based on the Siamese network framework, this paper proposes a novel UAV tracking algorithm, SiamHSFT, aiming to achieve a balance between tracking robustness and real-time computation. Firstly, by combining CBAM attention and downward information interaction in the feature enhancement module, the provided method merges high-level and low-level feature maps to prevent the loss of information when dealing with small targets. Secondly, it focuses on both long and short spatial intervals within the affinity in the interlaced sparse attention module, thereby enhancing the utilization of global context and prioritizing crucial information in feature extraction. Lastly, the Transformer’s encoder is optimized with a modulation enhancement layer, which integrates triplet attention to enhance inter-layer dependencies and improve target discrimination. Experimental results demonstrate SiamHSFT’s excellent performance across diverse datasets, including UAV123, UAV20L, UAV123@10fps, and DTB70. Notably, it performs better in fast motion and dynamic blurring scenarios. Meanwhile, it maintains an average tracking speed of 126.7 fps across all datasets, meeting real-time tracking requirements. Full article
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11 pages, 4290 KB  
Article
Influence of Pre-Tinning Process on Coating Morphology and Interface Structure of Low Carbon Steel Dipped in Molten 6061 Al Alloy
by Naglaa Fathy, Khaled Saad Abdel Halim, K. M. Hafez, Mohamed Ramadan, Badreddine Ayadi, Abdulaziz S. Alghamdi and Khaled M. Ibrahim
Coatings 2022, 12(10), 1499; https://doi.org/10.3390/coatings12101499 - 8 Oct 2022
Viewed by 2402
Abstract
Pre-treated low carbon steel specimens with flux or flux + tin mixture were coated by hot-dip aluminizing process. Al alloy (6061) was melted and hold at 750 °C. Fluxed and pre-tinned low carbon steel samples were dipped in a molten bath for time [...] Read more.
Pre-treated low carbon steel specimens with flux or flux + tin mixture were coated by hot-dip aluminizing process. Al alloy (6061) was melted and hold at 750 °C. Fluxed and pre-tinned low carbon steel samples were dipped in a molten bath for time intervals of 0.5, 1, 2.5 and 3.5 min. Applying double coating processes via tinning-aluminizing techniques facilitated the formation of Fe-Al intermetallic interface and increasing the thickness of homogenous coating layer over the substrate material. The presence of Sn facilitates to great extent the formation of a better interlayer-free bond of residual flux and/or oxides. The fluxed–dipped steel substrates have inhomogeneous distribution of Al alloy coating as well as an interface with residual flux and oxides for dipping time up to 2.5 min. A homogenous distribution with good thickness morphology of the Al alloy coating and homogeneous thin intermetallic interface was achieved for tinned steel substrate at all applied dipping times. The comparison between the pre-tinning and pre-fluxing processes on steel substrates showed a significant effect of tinning over fluxing treatment acting on the thickness layer of Al-coating and interface using a short time dipping. For dipping time up to 2.5 min, the hardness of pre-tinning substrates is greater than that of fluxed ones due to the presence of residual flux and void interface in fluxed steel. Full article
(This article belongs to the Special Issue Surface Function Enhancement Film and Coating Technology)
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19 pages, 7343 KB  
Article
Low-Cycle Fatigue Behavior of 3D-Printed PLA Reinforced with Natural Filler
by Miroslav Müller, Vladimír Šleger, Viktor Kolář, Monika Hromasová, Dominik Piš and Rajesh Kumar Mishra
Polymers 2022, 14(7), 1301; https://doi.org/10.3390/polym14071301 - 23 Mar 2022
Cited by 60 | Viewed by 5064
Abstract
Additive production is currently perceived as an advanced technology, where intensive research is carried out in two basic directions—modifications of existing printing materials and the evaluation of mechanical properties depending on individual production parameters and the technology used. The current research is focused [...] Read more.
Additive production is currently perceived as an advanced technology, where intensive research is carried out in two basic directions—modifications of existing printing materials and the evaluation of mechanical properties depending on individual production parameters and the technology used. The current research is focused on the evaluation of the fatigue behavior of 3D-printed test specimens made of pure PLA and PLA reinforced with filler based on pinewood, bamboo, and cork using FDM (fused deposition modeling) technology. This research was carried out in response to the growing demand for filaments from biodegradable materials. This article describes the results of tensile fatigue tests and image analysis of the fracture surface determined by the SEM method. Biodegradable PLA-based materials have their limitations that influence their applicability in practice. One of these limitations is fatigue life, which is the cyclic load interval exceeding 50% of the tensile strength determined in a static test. Comparison of the cyclic fatigue test results for pure PLA and PLA reinforced with natural reinforcement, e.g., pinewood, bamboo, and cork, showed that, under the same loading conditions, the fatigue life of the 3D-printed specimens was similar, i.e., the filler did not reduce the material’s ability to respond to low-cycle fatigue. Cyclic testing did not have a significant effect on the change in tensile strength and associated durability during this loading interval for PLA-based materials reinforced with biological filler. Under cyclic loading, the visco-elastic behavior of the tested materials was found to increase with increasing values of cyclic loading of 30%, 50% and 70%, and the permanent deformation of the tested materials, i.e., viscoelastic behavior (creep), also increased. SEM analysis showed the presence of porosity, interlayer disturbances, and at the same time good interfacial compatibility of PLA with the biological filler. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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19 pages, 11403 KB  
Article
Comparison of Properties of 3D-Printed Mortar in Air vs. Underwater
by Seong-Jin Woo, Jun-Mo Yang, Hojae Lee and Hong-Kyu Kwon
Materials 2021, 14(19), 5888; https://doi.org/10.3390/ma14195888 - 8 Oct 2021
Cited by 21 | Viewed by 4510
Abstract
Research and technological advancements in 3D concrete printing (3DCP) have led to the idea of applying it to offshore construction. The effect of gravity is reduced underwater, which can have a positive effect on 3DCP. For basic verification of this idea, this study [...] Read more.
Research and technological advancements in 3D concrete printing (3DCP) have led to the idea of applying it to offshore construction. The effect of gravity is reduced underwater, which can have a positive effect on 3DCP. For basic verification of this idea, this study printed and additively manufactured specimens with the same mortar mixture in air and underwater and evaluated properties in the fresh state and the hardened state. The mechanical properties were evaluated using the specimens produced by direct casting to the mold and specimens produced by extracting from the additive part through coring and cutting. The results of the experiment show that underwater 3D printing required a greater amount of printing output than in-air 3D printing for a good print quality, and buildability was improved underwater compared to that in air. In the case of the specimen layered underwater, the density and compressive strength decreased compared to the specimen layered in air. Because there are almost no effects of moisture evaporation and bleeding in water, the interlayer bond strength of the specimen printed underwater was somewhat larger than that printed in air, while there was no effect of the deposition time interval underwater. Full article
(This article belongs to the Special Issue Concrete 3D Printing and Digitally-Aided Fabrication (Second Volume))
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14 pages, 4741 KB  
Article
Structure, Corrosion Resistance, Mechanical and Tribological Properties of ZrB2 and Zr-B-N Coatings
by Philipp Kiryukhantsev-Korneev, Alina Sytchenko, Yuriy Kaplanskii, Alexander Sheveyko, Stepan Vorotilo and Evgeny Levashov
Metals 2021, 11(8), 1194; https://doi.org/10.3390/met11081194 - 27 Jul 2021
Cited by 16 | Viewed by 3582
Abstract
The coatings ZrB2 and Zr-B-N were deposited by magnetron sputtering of ZrB2 target in Ar and Ar–15%N2 atmospheres. The structure and properties of the coatings were investigated via scanning and transmission electron microscopy, energy dispersion analysis, optical profilometry, glowing discharge [...] Read more.
The coatings ZrB2 and Zr-B-N were deposited by magnetron sputtering of ZrB2 target in Ar and Ar–15%N2 atmospheres. The structure and properties of the coatings were investigated via scanning and transmission electron microscopy, energy dispersion analysis, optical profilometry, glowing discharge optical emission spectroscopy and X-ray diffraction analysis. Mechanical and tribological properties of the coatings were investigated using nanoindentation, “pin-on-disc” tribological testing and “ball-on-plate” impact testing. Free corrosion potential and corrosion current density were measured by electrochemical testing in 1 N H2SO4 and 3.5%NaCl solutions. The oxidation resistance of the coatings was investigated in the 600–800 °C temperature interval. The coatings deposited in Ar contained 4–11 nm grains of the h-ZrB2 phase along with free boron. Nitrogen-containing coatings consisted of finer crystals (1–4 nm) of h-ZrB2, separated by interlayers of amorphous a-BN. Both types of coatings featured hardness of 22–23 GPa; however, the introduction of nitrogen decreased the coating’s elastic modulus from 342 to 266 GPa and increased the elastic recovery from 62 to 72%, which enhanced the wear resistance of the coatings. N-doped coatings demonstrated a relatively low friction coefficient of 0.4 and a specific wear rate of ~1.3 × 10−6 mm3N−1m−1. Electrochemical investigations revealed that the introduction of nitrogen into the coatings resulted in the decrease of corrosion current density in 3.5% NaCl and 1 N H2SO4 solution up to 3.5 and 5 times, correspondingly. The superior corrosion resistance of Zr-B-N coatings was related to the finer grains size and increased volume of the BN phase. The samples ZrB2 and Zr-B-N resisted oxidation at 600 °C. N-free coatings resisted oxidation (up to 800 °C) and the diffusion of metallic elements from the substrate better. In contrast, Zr-B-N coatings experienced total oxidation and formed loose oxide layers, which could be easily removed from the substrate. Full article
(This article belongs to the Special Issue Corrosion without Limit: From Past to Future)
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14 pages, 1736 KB  
Article
Adsorption/Desorption Capability of Potassium-Type Zeolite Prepared from Coal Fly Ash for Removing of Hg2+
by Yuhei Kobayashi, Fumihiko Ogata, Chalermpong Saenjum, Takehiro Nakamura and Naohito Kawasaki
Sustainability 2021, 13(8), 4269; https://doi.org/10.3390/su13084269 - 12 Apr 2021
Cited by 23 | Viewed by 3273
Abstract
The feasibility of using potassium-type zeolite (K-type zeolite) prepared from coal fly ash (CFA) for the removal of Hg2+ from aqueous media and the adsorption/desorption capabilities of various potassium-type zeolites were assessed in this study. Potassium-type zeolite samples were synthesized by hydrothermal [...] Read more.
The feasibility of using potassium-type zeolite (K-type zeolite) prepared from coal fly ash (CFA) for the removal of Hg2+ from aqueous media and the adsorption/desorption capabilities of various potassium-type zeolites were assessed in this study. Potassium-type zeolite samples were synthesized by hydrothermal treatment of CFA at different intervals (designated CFA, FA1, FA3, FA6, FA12, FA24, and FA48, based on the hours of treatment) using potassium hydroxide solution, and their physicochemical characteristics were evaluated. Additionally, the quantity of Hg2+ adsorbed was in the order CFA, FA1 < FA3 < FA6 < FA12 < FA24 < FA48, in the current experimental design. Therefore, the hydrothermal treatment time is important to enhance the adsorption capability of K-type zeolite. Moreover, the effects of pH, temperature, contact time, and coexistence on the adsorption of Hg2+ were elucidated. In addition, Hg2+ adsorption mechanism using FA48 was demonstrated. Our results indicated that Hg2+ was exchanged with K+ in the interlayer of FA48 (correlation coefficient = 0.946). Finally, adsorbed Hg2+ onto FA48 could be desorbed using a sodium hydroxide solution (desorption percentage was approximately 70%). Our results revealed that FA48 could be a potential adsorbent for the removal of Hg2+ from aqueous media. Full article
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