4.1. Time–Evaporation–Strength Model
The previous results based on SHAP analysis and multivariate regression indicate that the printing interval time, together with environmental parameters such as temperature, humidity, and wind speed, controls the evolution of interlayer splitting tensile strength. Among these, time is the dominant factor, and humidity is the most important environmental factor. However, such data-driven models primarily reflect empirical correlations. The contribution of each variable to strength is expressed as a statistical “weight,” which makes it difficult to directly reveal the unified underlying physical processes, especially the intrinsic relationship between moisture changes and interfacial strength development. Therefore, it is necessary to further construct a strength model in the Discussion Section based on hydration and water content. This model aims to integrate evaporation loss, effective hydration water, and interfacial bonding capacity under different environmental conditions into a unified framework, thereby interpreting and extending the experimental phenomena and regression results from a mechanistic level.
Since 3DPC is a typical layered casting material, assuming a reasonable mix design, all water in the initial mix proportion can be considered effective water for the hydration reaction process, and the development of interlayer strength mainly stems from the cementation produced by the hydration reaction.
As shown in
Figure 6, based on the state of 3DPC at different stages, its hydration process can be divided into the following three phases:
(1) The first phase is the moment immediately after printing is completed, at which time the initial water content of the concrete is .
(2) The second phase is the moment just before being covered by the upper layer of concrete. At this point, the water in the concrete can be divided into three parts: evaporated water
, chemically bound water consumed by reaction
, and remaining water
. At this stage, the degree of hydration
of the 3DPC matrix can be expressed as:
(3) The third phase is the moment when the hydration reaction is basically completed. At this time, the water has only transformed into two parts: evaporated water
and chemically bound water consumed by reaction
. It should be noted that after the second layer of concrete is printed, the surface of the lower layer is covered, and evaporation stops, meaning
. At this point, the degree of hydration
can be expressed as:
Regarding the strength of the reaction zone, existing studies [
30,
31,
32] have shown that the relationship between strength
F and the degree of hydration
α is as follows:
where
is the maximum strength achievable by the concrete under the original mix proportion when hydration is complete, which corresponds to the matrix strength in 3DPC;
is the critical degree of hydration when the concrete just begins to develop strength, which is a constant value for a determined material mix; and
is an exponential coefficient.
Figure 6.
Schematic diagram of moisture change in 3DPC.
Figure 6.
Schematic diagram of moisture change in 3DPC.
Regarding the interlayer bond strength, before the second layer of concrete is printed, the surface of the first layer has not yet formed effective strength, meaning the initial interlayer strength is zero. However, after the second layer is printed and enters the curing stage, it can be assumed that the growth rate of the interlayer strength is consistent with that of the bulk strength of the lower layer concrete.
Therefore, the total increment of interlayer bond strength
can be defined as the strength development from the moment of the second layer casting (corresponding to hydration degree
) to the moment of hydration completion (corresponding to hydration degree
), that is:
Substituting Equations (5) and (6) into Equation (7), the expression for interlayer strength can be derived.
Equation (8) establishes a quantitative relationship between interlayer strength, evaporated water (
), and remaining water (
). Among them, the cumulative evaporated water
has been determined through experiments, while the remaining water
, as an internal state variable not directly observed, needs to be based on the law of conservation of water mass. The value of
depends on the competition between physical evaporative water loss and chemical hydration water consumption. However, for a given mix proportion, the chemically bound water
is mainly determined by hydration kinetics and can be regarded as a function of time, while
is driven by environmental conditions. To simplify the model, assuming that within the printing interval time, the surface physical evaporation process and the internal chemical hydration reaction are kinetically approximately decoupled (i.e., proceed independently without mutual interference), the remaining water can be further expressed as the residual value of the initial water after deducting evaporation and hydration consumption, expressed in terms of time and evaporated water:
Analysis of the experimental results indicates that among the factors affecting interlayer strength, time (
) is the primary factor, and environmental evaporation (
) is the secondary factor. Based on the physicochemical characteristics of cement hydration reactions, the reaction rate is highest in the initial stages and then gradually slows down, exhibiting a trend of nonlinear decay. Therefore, employing a linear term to describe the effect of printing interval time on interlayer strength is inappropriate. Compared to a linear term, a quadratic function can better capture this nonlinear characteristic, which involves an initial rapid decrease followed by a gradual leveling off. While cubic or other higher-order terms might mathematically offer finer fitting, introducing too many parameters would not only significantly increase model complexity, leading to a higher risk of overfitting, but also provide limited improvement in accuracy given our current data scale. Consequently, a quadratic function offers the optimal balance between physical reasonableness and model simplicity in describing the temporal effect. Thus, the time function can be set as a quadratic function, and the evaporation function as a linear function. By setting
in the simplified model [
33,
34], the following can be obtained:
where
are coefficients to be fitted, which can be determined through experiments. Based on this, this paper proposes a prediction model for the interlayer strength of 3DPC with printing interval time and evaporation amount as independent variables.
4.2. Model Validation
Based on the established theoretical model for interlayer strength, the experimentally measured interlayer splitting tensile strength, printing interval time, and cumulative evaporation under corresponding conditions (input as negative values to represent moisture loss) were substituted into the equation. Multivariate non-linear regression analysis was performed using the least squares method. The fitted response surface and the specific regression equation are shown in
Figure 7a. The regression results show that the interlayer splitting tensile strength (
) satisfies the following relationship with the printing interval time (
) and evaporated water (
):
The coefficient of determination (
) of the model reaches 0.9360, indicating that this semi-empirical and semi-mechanistic model possesses a high goodness of fit. Analyzing the physical significance of the regression coefficients, the linear coefficient of the time term is −1.086 while the quadratic coefficient is 0.282. This parabolic form opening upwards accurately characterizes the non-linear feature where interlayer strength monotonically decays with time but at a gradually decreasing rate. This is consistent with the experimental phenomenon observed in
Figure 7, where strength drops rapidly with time and then tends to plateau. For the evaporation term, the coefficient is 0.036. Since the evaporation amount
in the input data is a negative value, this positive coefficient implies that as the absolute value of water evaporation increases, the calculated strength decreases. This quantitatively verifies from a mechanistic perspective the observed law that high-evaporation working conditions (such as T8) lead to more severe strength loss, confirming the physical hypothesis that environmental factors weaken interlayer bonding capacity by aggravating water evaporation.
Figure 7b further displays the error statistical characteristics of the model. The high agreement between the predicted normalized strength and the measured values near the 45° line demonstrates the good generalization ability of the model. The statistical results show that the mean residual approaches 0, and the root mean square error (RMSE) and standard deviation (STD) are 0.0604 and 0.0607, respectively. Furthermore, the vast majority of residuals fall within the ±2σ standard deviation interval and are randomly distributed, with no obvious heteroscedasticity or systematic bias observed. This result confirms that introducing evaporation amount to represent environmental influence into the physical model not only makes it more interpretable in terms of mechanism but also provides sufficient statistical accuracy to reliably predict interlayer bond performance under complex working conditions.
The aforementioned evaporation-based model has clarified the evolution mechanism of interlayer strength from the perspective of water mass conservation. To further verify this law from the perspective of material physical state and explore portable detection methods suitable for on-site applications, this paper attempts to introduce the dielectric constant as another key state variable to construct a prediction model. The dielectric constant is highly sensitive to the internal free water content of the material and can non-destructively reflect the real-time wetting state of the concrete surface, serving as an effective supplement and cross-verification for evaporation data.
Substituting the experimentally measured dielectric constant
into the model instead of the evaporation amount for non-linear regression, the results are shown in
Figure 8a. The interlayer splitting tensile strength (
) satisfies the following relationship with the printing interval time (
) and dielectric constant (
):
Its coefficient of determination (
) is as high as 0.9331, which is comparable to the precision of the evaporation model. Specifically, the coefficient of the dielectric constant term is 0.101, indicating that at the same time interval, a higher dielectric constant corresponds to more sufficient surface free water, which is conducive to interlayer hydration cementation. The error analysis in
Figure 8b further shows that the root mean square error (RMSE) of this model is only 0.0676, and the residuals are uniformly distributed without systematic bias. This indicates that the dielectric constant and evaporation amount have good consistency in characterizing the interlayer moisture state. The model based on dielectric properties not only corroborates the correctness of the hydration-evaporation theory but also provides a highly potential non-destructive testing alternative for evaluating interlayer strength in engineering scenarios where direct weighing is difficult.
4.3. Model Optimization
Although the aforementioned model employing a linear term for evaporation has successfully revealed the evolution law of interlayer strength, the non-linear characteristics of the experimental data become increasingly significant when dealing with high-evaporation working conditions (such as T8). Consequently, the linear assumption might introduce specific prediction deviations under extreme conditions. To further enhance the prediction accuracy and applicable scope of the model, this paper attempts to incorporate a quadratic term for evaporation into the original physical model, constructing an optimized model with a higher degree of nonlinearity.
By substituting the experimental data into the modified quadratic polynomial for regression analysis, the fitted surface and residual distribution of the optimized model were obtained, as presented in
Figure 9. The optimized regression equation is given by:
Compared to the pre-optimization model, after introducing the quadratic term for evaporation, the coefficient of determination () of the model improved from 0.9360 to 0.9571, demonstrating a further enhancement in the model’s capability to capture and characterize the experimental data. From a physical perspective, although the coefficient of the quadratic evaporation term is small (0.003), it is non-negligible. It corrects the non-linear rate of strength decay during stages of severe moisture loss, enabling the model to perform more smoothly and accurately across different environments.
The error statistical results in
Figure 9b further confirm the effectiveness of the optimization. Compared with the original model, the root mean square error (RMSE) of the optimized model was reduced from 0.0604 to 0.0554, and the standard deviation (STD) was synchronously reduced to 0.0556. The residual distribution plot reveals that the data points converge more tightly around the zero line, and the degree of dispersion across the entire strength prediction range is significantly improved. This indicates that by introducing the non-linear correction for evaporation, the model not only maintains the original physical mechanism framework but also significantly enhances the robustness and precision of interlayer strength prediction under complex environmental working conditions. This provides more reliable theoretical support for the refined construction control of 3DPC.
4.4. Construction of General Model
Although the aforementioned model incorporating the quadratic term significantly improves prediction accuracy, the evaporation (absolute mass) and strength (MPa) parameters in the model still depend on specific specimen dimensions and mix designs, limiting the direct application of the model in different engineering scenarios. To eliminate the influence of differences in specimen geometry and material composition, and to further improve the universality and broad applicability of the model, this paper introduces dimensionless parameters to normalize the model and establish a general model. The Strength Index (
) is defined as:
where
is the predicted strength at any given time, and
is the average reference strength of the mix proportion under standard curing.
The amount of evaporated water is changed to the evaporation water index
, while the printing interval time
remains unchanged. The general prediction model constructed based on the normalized data is shown in
Figure 10. The general equation obtained from non-linear regression is:
As shown in
Figure 10a, the coefficient of determination (
) of this general model reaches 0.9565, indicating that after removing the influence of physical dimensions, the model can still excellently capture the intrinsic evolution law among “time–moisture–strength.” From the error analysis in
Figure 10b, the root mean square error (RMSE) of the residuals between the predicted strength index and the measured values is only 0.0556, and the residuals exhibit good random distribution characteristics near the zero line.
In the general model, by converting the absolute evaporation amount into the relative evaporation index, the model successfully links the environmental influence factors with the initial water content (deduced from mix proportion) of the material itself. This means that the prediction model is no longer limited to specific printed specimen sizes or specific concrete formulations, but provides a generalized evaluation standard based on the degree of water loss. For 3D-printed components of different sizes or mix proportions, as long as their initial water content and reference strength are known, and after basic calibration of the equation parameters, this equation can be used to make rapid and reliable estimations of the interlayer bond performance under complex evaporation environments.
4.5. Engineering Implementation Scheme
In the actual engineering practice of 3DPC, the construction site environment is complex and variable. Factors such as low humidity, high wind speed, and high temperature directly affect the surface moisture evaporation of the printed filaments, leading to fluctuations in interlayer bond strength. Traditional destructive testing methods are lagging and difficult to reflect the real-time quality of the overall structure. Therefore, it is particularly important to construct a non-destructive monitoring system capable of sensing the environment in real-time and predicting structural performance. Based on the established prediction model for interlayer splitting tensile strength of 3DPC, this study proposes an engineering application scheme integrating environmental monitoring, data acquisition and calculation, and digital twin visualization, aiming to solve quality control problems during the printing process.
As shown in
Figure 11, the implementation system of this scheme mainly consists of three core parts working in synergy: (1) process data acquisition of environment; (2) printing time, evaporated water amount, and strength prediction calculation; (3) visualization feedback. As illustrated, while printing the main structure, a portable weather station is deployed at the construction site to monitor real-time microclimate data. When significant changes occur in meteorological data, the printing of small companion specimens is triggered. These small companion specimens are printed synchronously alongside the main structure, and the evaporation index (
) is obtained through real-time weighing. This design ingeniously solves the problem of acquiring real evaporation data without interfering with the main printing process. In addition, the digital system automatically records the printing timestamp of each layer, accurately obtaining the printing interval time (
) at any position by calculating the time difference between adjacent layers. Before the printing task begins, only one standard interlayer splitting test is required to determine the reference splitting strength without interval time (
), providing basic data for predicting the actual splitting tensile strength.
In actual use, the system follows data-driven operation logic. The system substitutes the real-time collected evaporation index and printing interval time into the bivariate regression model proposed in this study () to calculate the strength index of each interlayer. Then, combining with the reference strength, the predicted tensile strength () of the current interface is calculated. Finally, these calculation results are mapped back to the digital twin model in real-time, rendering the printing path through color-coding technology—different colored layers intuitively characterize the distribution differences in predicted strength (e.g., red represents high-strength areas, and blue represents potential weak zones). This visualization method allows engineers to instantly identify structural weak links caused by sudden environmental changes or excessive long intervals, thereby achieving a transformation from post-event inspection to process early warning, and enhancing the safety and reliability of 3DPC engineering.
4.6. Limitation
In terms of experimental methodology, despite the rapid operations and standardized procedures adopted during specimen printing and transfer, even brief exposure during the highly sensitive early-age hydration of concrete may cause transient disturbances to the surface moisture state and temperature of the specimens. Specifically, splitting tensile specimens, after the first layer is printed, need to be removed from the environmental chamber, repositioned on the printing platform for the second layer, and then returned to the environmental chamber, thus undergoing an additional disturbance compared to specimens for continuous monitoring. However, considering that the printing and transfer times are relatively short compared to the overall time interval, and all operations are consistent, this study believes that such transient disturbances have a limited and controllable overall impact on the long-term evaporation, dielectric constant evolution, and final interlayer bond strength. Future research could further eliminate such potential disturbances by optimizing experimental equipment, such as directly setting up the 3D printing equipment in a controlled environmental chamber, to obtain more precise experimental data.
Regarding the experimental environmental conditions, although the environmental parameters selected in this study are relevant to actual construction, the experimental conditions necessitated the use of small-scale environmental chambers for staged environmental exposure. This approach could not fully replicate the continuous and highly variable environmental conditions found on actual construction sites. It is important to note that numerous complex environmental factors exist on real construction sites, such as wind speed, solar radiation intensity, and spatial variability of microclimates. These factors can significantly influence the concrete’s moisture evaporation rate, internal hydration kinetics, and ultimately, the interlayer bonding performance. For instance, high wind speeds accelerate moisture loss, and solar radiation causes localized temperature increases, accelerating reaction rates. Both can lead to premature drying of the printed layer interfaces, thereby weakening bond strength. Furthermore, microclimate differences across various areas of a construction site can also lead to non-uniformity in interlayer bonding performance. Therefore, when directly extending the experimental results and prediction models obtained under laboratory conditions in this study to the complex and variable on-site construction environment, their limitations must be carefully considered. Although the model developed in this study exhibits good predictive capabilities on laboratory data, in practical applications, the aforementioned unconsidered environmental factors and constantly changing environmental conditions may affect the model’s prediction accuracy. Future research should consider incorporating more environmental parameters, such as wind speed and solar radiation, into the experimental design. Moreover, developing more comprehensive on-site environmental monitoring techniques, combined with digital twin platforms, could enable real-time, accurate prediction and control of 3D-printed concrete interlayer bonding performance under complex field conditions, thereby further enhancing the model’s generalization ability and practical engineering guidance value.
Regarding the influence of printing parameters, all experiments in this study were based on a single concrete mix proportion, one 3D printer, and fixed layer geometry. Although we proposed a dimensionless model to describe the interlayer bonding performance, its fitted relationships and coefficients have not been fully validated for their generality and extrapolation to other materials, printing systems, or different layer geometries. The sensitivity of the research results may manifest in several aspects: different mix proportion components (e.g., type of cementing material, aggregate gradation, or water-cement ratio) significantly affect the rheological properties, hydration rate, and drying shrinkage of concrete, thereby altering interlayer moisture transport and interfacial bond strength; rheological parameters such as thixotropy and yield stress directly influence the quality of layer deposition and the effectiveness of interlayer contact, thus affecting interlayer bonding; furthermore, changes in nozzle size and printing speed can alter the geometric accuracy, surface roughness, and interlayer contact area of the printed layers. Therefore, the model proposed in this study has certain limitations when applied to materials, printing parameters, or geometries with significant differences. Future work will focus on expanding the experimental scope by introducing various mix proportions, printing equipment, and geometric parameters for validation, and thoroughly investigating the sensitivity of different factors to interlayer bonding performance, with the aim of developing a more universal and robust prediction model.
Regarding the influence of printing paths, this study primarily employed simplified, linear printing paths when evaluating interlayer bond strength. However, actual 3D-printed concrete paths often involve complex geometric features such as curves, directional changes, start-stop events, and overlaps. These complexities can significantly affect extrusion stability, local compaction, surface roughness, and the effective interlayer contact area. For instance, research by Daneshvar et al. [
35] showed that curved trajectories are more prone to geometric errors and more sensitive to printing speed compared to straight trajectories. Li et al. [
36] also pointed out that printing instability on non-planar surfaces primarily arises from inaccurate fiber deposition, and nozzle height and the decomposition of material self-weight along inclined surfaces are crucial for print quality. These complex paths and the resulting local time delays can cause spatial heterogeneity in interlayer bonding performance under the same environmental conditions, and interact more complexly with the moisture evaporation and hydration kinetics considered in this study. Therefore, the model proposed in this study is primarily based on the decay mechanism of interlayer performance under simplified paths, and its direct applicability to more complex printing trajectories is limited. Future work will consider expanding the scope of research to experimentally investigate the effects of different complex printing paths (e.g., curves, start-stop events, and overlaps) on extrusion quality, interface morphology, and interlayer bonding performance, and strive to develop a more comprehensive model that can incorporate path geometric complexity and the spatial heterogeneity it introduces. This is equally important for improving the reliability of 3D-printed concrete in practical engineering applications.
Regarding model setup, the mechanistic model in this study assumes that moisture evaporation and hydration reactions are decoupled when analyzing interlayer bonding performance during printing intervals. The rationale behind this simplifying assumption is that, under normal environmental conditions and within shorter printing intervals, the internal moisture of the printed body is relatively abundant, and evaporation primarily removes free water with limited overall impact on the cement hydration reaction process. Under this assumption, the model can effectively focus on the critical roles of moisture migration and hydration in interface formation. However, we recognize the potential limitations of this assumption. Particularly under extreme environmental conditions such as high temperature, low humidity, or strong wind, the rate of moisture evaporation significantly accelerates. In such cases, rapid evaporation not only removes surface free water but also accelerates the migration of internal moisture to the surface, leading to insufficient water supply for cement hydration, and even inducing self-desiccation, thereby directly affecting the progress and extent of the hydration reaction. In this scenario, moisture evaporation and hydration reactions are no longer simply decoupled processes but exhibit strong coupling, where evaporation directly limits the progress of hydration reactions. Therefore, this model may have predictive biases under these extreme environments. Since the model does not fully consider the inhibitory effect of rapid moisture loss on the hydration rate, it might overestimate the degree of hydration at printed layer interfaces and the resulting bond strength under high temperature or low humidity conditions. Future research will consider a more comprehensive model of coupled evaporation and hydration, especially under extreme environmental conditions, by incorporating dynamic moisture balance and hydration kinetics equations to improve the model’s universality and predictive accuracy.