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Search Results (4,203)

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Keywords = impact strength test

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28 pages, 2475 KiB  
Article
Optimal Scheduling of a Hydropower–Wind–Solar Multi-Objective System Based on an Improved Strength Pareto Algorithm
by Haodong Huang, Qin Shen, Wan Liu, Ying Peng, Shuli Zhu, Rungang Bao and Li Mo
Sustainability 2025, 17(15), 7140; https://doi.org/10.3390/su17157140 - 6 Aug 2025
Abstract
Under the current context of the large-scale integration of wind and solar power, the coupling of hydropower with wind and solar energy brings significant impacts on grid stability. To fully leverage the regulatory capacity of hydropower, this paper develops a multi-objective optimization scheduling [...] Read more.
Under the current context of the large-scale integration of wind and solar power, the coupling of hydropower with wind and solar energy brings significant impacts on grid stability. To fully leverage the regulatory capacity of hydropower, this paper develops a multi-objective optimization scheduling model for hydropower, wind, and solar that balances generation-side power generation benefit and grid-side peak-regulation requirements, with the latter quantified by the mean square error of the residual load. To efficiently solve this model, Latin hypercube initialization, hybrid distance framework, and adaptive mutation mechanism are introduced into the Strength Pareto Evolutionary Algorithm II (SPEAII), yielding an improved algorithm named LHS-Mutate Strength Pareto Evolutionary Algorithm II (LMSPEAII). Its efficiency is validated on benchmark test functions and a reservoir model. Typical extreme scenarios—months with strong wind and solar in the dry season and months with weak wind and solar in the flood season—are selected to derive scheduling strategies and to further verify the effectiveness of the proposed model and algorithm. Finally, K-medoids clustering is applied to the Pareto front solutions; from the perspective of representative solutions, this reveals the evolutionary trends of different objective trade-off schemes and overall distribution characteristics, providing deeper insight into the solution set’s distribution features. Full article
19 pages, 8559 KiB  
Article
Flexural Behavior of Concrete Beam and Slab with Novel Demountable Connectors
by Wei Li, Wei Chen, Huaming Jiang and Hongzhi Su
Buildings 2025, 15(15), 2776; https://doi.org/10.3390/buildings15152776 - 6 Aug 2025
Abstract
In this study, a new type of novel demountable connector is proposed to enable complete dry connections between concrete beams and slabs, facilitating the full demountable design of these components. To analyze and evaluate the flexural performance of the concrete beams with the [...] Read more.
In this study, a new type of novel demountable connector is proposed to enable complete dry connections between concrete beams and slabs, facilitating the full demountable design of these components. To analyze and evaluate the flexural performance of the concrete beams with the novel demountable connectors, a finite element model was developed, which was then validated by previous tests. The results indicate that bolt diameter, bolt strength, channel spacing, and concrete slab thickness have a significant impact on peak load, while concrete beam strength, concrete slab strength, and flange width have minimal influence. Similarly, flexural stiffness is strongly affected by bolt diameter, channel spacing, concrete slab strength, slab thickness, and flange width, whereas bolt strength and concrete beam strength play a lesser role. Notably, the finite element analysis confirms the absence of plastic deformation in most bolts and end plates, ensuring that the flexural components are designed for effective disassembly. A theoretical model for calculating the ultimate flexural moment of demountable concrete beams under different conditions is also proposed, and it agrees with the ultimate flexural moment from numerical analysis. Full article
(This article belongs to the Section Building Structures)
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15 pages, 2417 KiB  
Article
Mechanical Behavior of Sustainable Concrete with Alkali-Activated Pumice as Cement Replacement for Walkway Slabs in Humid Tropical Climates
by Oscar Moreno-Vázquez, Pablo Julián López-González, Sergio Aurelio Zamora-Castro, Brenda Suemy Trujillo-García and Joaquín Sangabriel-Lomelí
Eng 2025, 6(8), 191; https://doi.org/10.3390/eng6080191 - 6 Aug 2025
Abstract
Portland cement production is a major source of global CO2 emissions due to its high energy consumption and calcination processes. This study proposes a sustainable alternative through the partial replacement of cement with alkali-activated pumice, a naturally occurring aluminosilicate material with high [...] Read more.
Portland cement production is a major source of global CO2 emissions due to its high energy consumption and calcination processes. This study proposes a sustainable alternative through the partial replacement of cement with alkali-activated pumice, a naturally occurring aluminosilicate material with high regional availability. Mixes with 0%, 10%, 20%, and 30% cement replacement were designed for pedestrian slabs exposed to humid tropical conditions. Compressive strength was evaluated using non-destructive testing over a period of 364 days, and carbonation was analyzed at different ages. The results show that mixes with up to 30% pumice maintain adequate strength levels for light-duty applications, although with a more gradual strength development. A significant reduction in carbonation depth was also observed, especially in the mix with the highest replacement level, suggesting greater durability in aggressive environments. These findings support the use of pumice as a viable and sustainable supplementary cementitious material in tropical regions, promoting low-impact construction practices. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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21 pages, 4070 KiB  
Article
Effects of Aggregate Size and Nozzle Diameter on Printability and Mechanical Properties of 3D Printed Ferronickel Slag–GGBFS Concrete
by Suguo Wang, Xing Wang, Xueyuan Yan and Shanghong Chen
Materials 2025, 18(15), 3681; https://doi.org/10.3390/ma18153681 - 5 Aug 2025
Abstract
Ferronickel slag and ground granulated blast-furnace slag (GGBFS) are solid waste by-products from the metallurgical industry. When incorporated into concrete, they help promote resource utilization, reduce hydration heat, and lower both solid waste emissions and the carbon footprint. To facilitate the application of [...] Read more.
Ferronickel slag and ground granulated blast-furnace slag (GGBFS) are solid waste by-products from the metallurgical industry. When incorporated into concrete, they help promote resource utilization, reduce hydration heat, and lower both solid waste emissions and the carbon footprint. To facilitate the application of ferronickel slag–GGBFS concrete in 3D printing, this study examines how aggregate size and nozzle diameter affect its performance. The investigation involves in situ printing, rheological characterization, mechanical testing, and scanning electron microscopy (SEM) analysis. Results indicate that excessively large average aggregate size negatively impacts the smooth extrusion of concrete strips, resulting in a cross-sectional width that exceeds the preset dimension. Excessively small average aggregate size results in insufficient yield stress, leading to a narrow cross-section of the extruded strip that fails to meet printing specifications. The extrusion performance is closely related to both the average aggregate size and nozzle diameter, which can significantly influence the normal extrusion stability and print quality of 3D printed concrete strips. The thixotropic performance improves with an increase in the aggregate size. Both compressive and flexural strengths improve with increasing aggregate size but decrease with an increase in the printing nozzle size. Anisotropy in mechanical behavior decreases progressively as both parameters mentioned increase. By examining the cracks and pores at the interlayer interface, this study elucidates the influence mechanism of aggregate size as well as printing nozzle parameters on the mechanical properties of 3D printed ferronickel slag–GGBFS concrete. This study also recommends the following ranges. When the maximum aggregate size exceeds 50% of the nozzle diameter, smooth extrusion is not achievable. If it falls between 30% and 50%, extrusion is possible but shaping remains unstable. When it is below 30%, both stable extrusion and good shaping can be achieved. Full article
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25 pages, 4475 KiB  
Article
Physical, Mechanical, and Durability Behavior of Sustainable Mortars with Construction and Demolition Waste as Supplementary Cementitious Material
by Sandra Cunha, Kubilay Kaptan, Erwan Hardy and José Aguiar
Buildings 2025, 15(15), 2757; https://doi.org/10.3390/buildings15152757 - 5 Aug 2025
Abstract
The construction industry plays a major role in the consumption of natural resources and the generation of waste. Construction and demolition waste (CDW) is produced in substantial volumes globally and is widely available. Its accumulation poses serious challenges related to storage and disposal, [...] Read more.
The construction industry plays a major role in the consumption of natural resources and the generation of waste. Construction and demolition waste (CDW) is produced in substantial volumes globally and is widely available. Its accumulation poses serious challenges related to storage and disposal, highlighting the need for effective strategies to mitigate the associated environmental impacts of the sector. This investigation intends to evaluate the influence of mixed CDW on the physical, mechanical, and durability properties of mortars with CDW partially replacing Portland cement, and allow performance comparisons with mortars produced with fly ash, a commonly used supplementary binder in cement-based materials. Thus, three mortar formulations were developed (reference mortar, mortar with 25% CDW, and mortars with 25% fly ash) and several characterization tests were carried out on the CDW powder and the developed mortars. The work’s principal findings revealed that through mechanical grinding processes, it was possible to obtain a CDW powder suitable for cement replacement and with good indicators of pozzolanic activity. The physical properties of the mortars revealed a decrease of about 10% in water absorption by immersion, which resulted in improved performance regarding durability, especially with regard to the lower carbonation depth (−1.1 mm), and a decrease of 51% in the chloride diffusion coefficient, even compared to mortars incorporating fly ash. However, the mechanical performance of the mortars incorporating CDW was reduced (25% in terms of flexural strength and 58% in terms of compressive strength), but their practical applicability was never compromised and their mechanical performance proved to be superior to that of mortars incorporating fly ash. Full article
(This article belongs to the Special Issue Research on Sustainable Materials in Building and Construction)
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22 pages, 10739 KiB  
Article
Effects of Natural Seashell Presence on the Engineering Performance of Sea Sand Concrete
by Anuradha Koswaththa, Pasindu Abeyaratne, Samith Buddika, Hiran Yapa and Satheeskumar Navaratnam
Buildings 2025, 15(15), 2751; https://doi.org/10.3390/buildings15152751 - 4 Aug 2025
Abstract
Processed sea sand has emerged as a viable alternative to traditional fine aggregates in the Sri Lankan construction industry. Despite its economic and environmental advantages, concerns over residual seashell content have limited its widespread adoption by local contractors. Residual seashell content, typically ranging [...] Read more.
Processed sea sand has emerged as a viable alternative to traditional fine aggregates in the Sri Lankan construction industry. Despite its economic and environmental advantages, concerns over residual seashell content have limited its widespread adoption by local contractors. Residual seashell content, typically ranging from 1% to 3% after processing, has raised concerns about its impact on the performance of concrete. This study systematically investigates the influence of seashell fragments, with a content of up to 5%, on the fresh, mechanical, and durability properties of sea sand concrete and mortar. Experimental results indicate that workability remains stable, with minor variations across the tested range of shell content. Compressive strength remains relatively consistent from 0% to 5% seashells, indicating that seashell content does not significantly impact the strength within this range. Durability tests reveal minimal effects of shell content on concrete performance within the tested shell range, as indicated by results for water absorption, rapid chloride penetration, and acid exposure testing. Accelerated corrosion indicates that the typical shell content does not increase corrosion risk; however, high shell content (>3%) can compromise corrosion durability. Overall, these findings demonstrate that the mechanical and durability performance of sea sand concrete remains uncompromised at typical seashell content levels (1–3%), supporting the use of processed sea sand as a sustainable and viable alternative to traditional fine aggregates in Sri Lankan construction. Full article
(This article belongs to the Collection Advanced Concrete Materials in Construction)
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28 pages, 6413 KiB  
Article
Scaling the Dynamic Buckling Behavior of a Box Girder Based on the Finite Similitude Approach
by Chongxi Xu, Zhuo Wang, Xiangshao Kong, Hu Zhou, Cheng Zheng and Weiguo Wu
J. Mar. Sci. Eng. 2025, 13(8), 1496; https://doi.org/10.3390/jmse13081496 - 4 Aug 2025
Viewed by 64
Abstract
In the design of small-scale test models for hull structures, the directional dimensional analysis method is commonly employed. However, conventional dimensional analysis based on elasticity theory may be insufficient to capture the nonlinear behaviors of structural materials under dynamic loading, which restricts its [...] Read more.
In the design of small-scale test models for hull structures, the directional dimensional analysis method is commonly employed. However, conventional dimensional analysis based on elasticity theory may be insufficient to capture the nonlinear behaviors of structural materials under dynamic loading, which restricts its applicability in ultimate strength tests for small-scale hull structure models. This paper presents a scaling method grounded in the theory of finite similitude. Based on the finite similitude theory, this paper deduces similarity scaling criteria applicable to the static and dynamic responses of box girders and designs a series of trial models of box girders. The scaling criteria are verified and analyzed through numerical tests conducted under static and dynamic loads. On the basis of the numerical test results of dynamic responses, the dynamic response similarity criteria considering the similarity relationship of material constitutive parameters are modified and verified. By applying the static response scaling criteria in this paper to select appropriate materials, the prediction deviation of the box girder trial models under static loads is less than 2%. With the modified dynamic response scaling criteria proposed in this paper, the prediction deviations of each trial model under dynamic loads are less than 2% and 7%. A comprehensive analysis of material parameters was conducted to examine their impact on the nonlinear similarities observed in the processes. To validate the ultimate strength and nonlinear response scaling criterion based on the finite similitude approach, numerical experiments were performed to assess the ultimate strength and dynamic buckling response characteristics of the box girder across various scaling ratios and material parameters. The analysis demonstrated that the ultimate strength scaling criterion and the nonlinear response scaling criterion derived from the finite similitude approach effectively captured material nonlinearity. The results from the small-scale model provided accurate predictions of the ultimate strength of the full-scale model. Full article
(This article belongs to the Special Issue Safety and Reliability of Ship and Ocean Engineering Structures)
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25 pages, 4247 KiB  
Article
Mechanical Behavior of Self-Compacting Concrete Incorporating Rubber and Recycled Aggregates for Non-Structural Applications: Optimization Using Response Surface Methodology
by Yaqoob Saif, Jihen Mallek, Bilel Hadrich and Atef Daoud
Buildings 2025, 15(15), 2736; https://doi.org/10.3390/buildings15152736 - 3 Aug 2025
Viewed by 208
Abstract
The accumulation of end-of-life tires and the rapid increase in demolition activities pose significant environmental and waste-management challenges. The redevelopment of construction materials incorporating this waste is a potentially promising strategy for minimizing environmental impact while promoting the principles of a circular economy. [...] Read more.
The accumulation of end-of-life tires and the rapid increase in demolition activities pose significant environmental and waste-management challenges. The redevelopment of construction materials incorporating this waste is a potentially promising strategy for minimizing environmental impact while promoting the principles of a circular economy. This study investigates the performance of self-compacting concrete (SCC) incorporating up to 20% rubber aggregates (sand and gravel) and 40% recycled concrete aggregate (RCA) for non-structural applications. A series of tests was conducted to assess fresh and hardened properties, including flowability, compressive strength, tensile strength, flexural strength, water absorption, and density. The results indicated that increasing RCA content reduced density and compressive strength, while tensile and flexural strengths were only moderately affected. Response surface methodology (RSM), utilizing a Box–Behnken design, was employed to optimize compressive, tensile, and flexural strength responses. Statistical analysis was used to identify the optimal mix proportions, which balance the mechanical performance and sustainability of SCC with recycled components. Mixtures incorporating moderate rubber content—specifically, 5–5.5% sand rubber and 0–6% coarse rubber—and 40% recycled-concrete aggregate (RCA) achieved the highest predicted performance, with compressive strength ranging from 20.00 to 28.26 MPa, tensile strength from 2.16 to 2.85 MPa, and flexural strength reaching 5.81 MPa, making them suitable for sidewalks and walkways. Conversely, mixtures containing higher rubber proportions (5.5–20% sand rubber and 20% coarse rubber) combined with the same RCA level (40%) showed the lowest mechanical performance, with compressive strength between 5.2 and 10.08 MPa, tensile strength of 1.05–1.41 MPa, and flexural strength from 2.18 to 3.54 MPa. These findings underscore the broad performance range achievable through targeted optimization. They confirm the viability of recycled materials for producing environmentally friendly SCC in non-structural applications. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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16 pages, 1053 KiB  
Article
The Relationship Between Parental Phubbing and Preschoolers’ Behavioral Problems: The Mediation Role of Mindful Attention Awareness
by Antonio Puligheddu, Annamaria Porru, Andrea Spano, Stefania Cataudella, Maria Lidia Mascia, Dolores Rollo, Cristina Cabras, Maria Pietronilla Penna and Daniela Lucangeli
Children 2025, 12(8), 1022; https://doi.org/10.3390/children12081022 - 2 Aug 2025
Viewed by 385
Abstract
Phubbing, a relatively new phenomenon in the field of digital risks, refers to the act of ignoring someone in favor of focusing on a smartphone during face-to-face interactions. Parental phubbing, a specific form of this behavior, is a prevalent negative parenting practice that [...] Read more.
Phubbing, a relatively new phenomenon in the field of digital risks, refers to the act of ignoring someone in favor of focusing on a smartphone during face-to-face interactions. Parental phubbing, a specific form of this behavior, is a prevalent negative parenting practice that can affect parent–child relationships and child development. However, the impact of parental phubbing on the emotional and behavioral development of preschool children remains unclear. This study aims to explore the relationship between parental phubbing and preschoolers’ behavioral problems, as well as test whether parents’ mindful attention awareness (MAA) acts as a mediator between them. Method: A questionnaire was administered to 138 Italian parents (mean age = 38.5, SD = 6.2) of 138 kindergarten preschoolers (mean age = 3.9, SD = 1.03). Questionnaires included the Generic Scale of Phubbing (GSP), the Mindful Attention Awareness Scale (MAAS), and the Strengths and Difficulties Questionnaire (SDQ). Results: Analyses revealed a significant negative correlation between the MAAS and SDQ total scores, a positive correlation between the GSP total score and the SDQ total score, and a negative correlation between the GSP total score and the MAAS total score. The mediation analysis did not show a direct effect of GSP on SDQ, suggesting that parental phubbing did not directly predict children’s behavioral difficulties. Nevertheless, the indirect effect measured by bootstrapping was significant, indicating that parental MAA fully mediated the relationship between parental phubbing and preschoolers’ problematic behaviors. Conclusions: Although further research is needed, parental mindfulness may influence phubbing behaviors in parents providing valuable insights for early interventions aimed at reducing problem behaviors in young children. Full article
(This article belongs to the Section Pediatric Mental Health)
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21 pages, 20135 KiB  
Article
Strain-Rate Effects on the Mechanical Behavior of Basalt-Fiber-Reinforced Polymer Composites: Experimental Investigation and Numerical Validation
by Yuezhao Pang, Chuanlong Wang, Yue Zhao, Houqi Yao and Xianzheng Wang
Materials 2025, 18(15), 3637; https://doi.org/10.3390/ma18153637 - 1 Aug 2025
Viewed by 241
Abstract
Basalt-fiber-reinforced polymer (BFRP) composites, utilizing a natural high-performance inorganic fiber, exhibit excellent weathering resistance, including tolerance to high and low temperatures, salt fog, and acid/alkali corrosion. They also possess superior mechanical properties such as high strength and modulus, making them widely applicable in [...] Read more.
Basalt-fiber-reinforced polymer (BFRP) composites, utilizing a natural high-performance inorganic fiber, exhibit excellent weathering resistance, including tolerance to high and low temperatures, salt fog, and acid/alkali corrosion. They also possess superior mechanical properties such as high strength and modulus, making them widely applicable in aerospace and shipbuilding. This study experimentally investigated the mechanical properties of BFRP plates under various strain rates (10−4 s−1 to 103 s−1) and directions using an electronic universal testing machine and a split Hopkinson pressure bar (SHPB).The results demonstrate significant strain rate dependency and pronounced anisotropy. Based on experimental data, relationships linking the strength of BFRP composites in different directions to strain rate were established. These relationships effectively predict mechanical properties within the tested strain rate range, providing reliable data for numerical simulations and valuable support for structural design and engineering applications. The developed strain rate relationships were successfully validated through finite element simulations of low-velocity impact. Full article
(This article belongs to the Special Issue Mechanical Properties of Advanced Metamaterials)
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28 pages, 9076 KiB  
Article
Performance Evaluation of Waste Toner and Recycled LDPE-Modified Asphalt Pavement: A Mechanical and Carbon Assessment-Based Optimization Approach Towards Sustainability
by Muhammad Usman Siddiq, Muhammad Kashif Anwar, Faris H. Almansour, Jahanzeb Javed and Muhammad Ahmed Qurashi
Sustainability 2025, 17(15), 7003; https://doi.org/10.3390/su17157003 - 1 Aug 2025
Viewed by 251
Abstract
Due to the increasing environmental concerns and the growing generation of electronic waste and plastic, sustainable waste management solutions are essential for the construction industry. This study explores the potential of using electronic waste toner powder (WTP) and recycled low-density polyethylene (LDPE), either [...] Read more.
Due to the increasing environmental concerns and the growing generation of electronic waste and plastic, sustainable waste management solutions are essential for the construction industry. This study explores the potential of using electronic waste toner powder (WTP) and recycled low-density polyethylene (LDPE), either individually or in combination as modifiers for asphalt binder to enhance pavement performance and reduce environmental impact. The analysis focused on three key components: (1) binder development and testing; (2) performance evaluation through Marshall stability, indirect tensile strength, and Dynamic Shear Rheometer (DSR) testing for rutting resistance; and (3) sustainability assessment in terms of carbon footprint reduction. The results revealed that the formulation of 25% WTP and 8% LDPE processed at 160 °C achieved the best mechanical performance and lowest carbon index, enhancing Marshall stability by 32% and rutting resistance by 41%. Additionally, this formulation reduced the carbon footprint by 27% compared to conventional asphalt. The study demonstrated that the combination of WTP and LDPE significantly improves the sustainability and performance of asphalt pavements, offering mechanical, environmental, and economic benefits. By providing a quantitative assessment of waste-modified asphalt, this study uniquely demonstrates the combined use of WTP and LDPE in asphalt, offering a novel dual-waste valorization approach that enhances pavement performance while promoting circular economy practices. Full article
(This article belongs to the Special Issue Sustainable Development of Asphalt Materials and Pavement Engineering)
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17 pages, 588 KiB  
Article
The Effect of Methacrylate-POSS in Nanosilica Dispersion Addition on Selected Mechanical Properties of Photo-Cured Dental Resins and Nanocomposites
by Norbert Sobon, Michal Krasowski, Karolina Kopacz, Barbara Lapinska, Izabela Barszczewska-Rybarek, Patrycja Kula and Kinga Bociong
J. Compos. Sci. 2025, 9(8), 403; https://doi.org/10.3390/jcs9080403 - 1 Aug 2025
Viewed by 153
Abstract
Background: This study aimed to assess the impact of methacrylate-functionalized polyhedral oligomeric silsesquioxanes dispersed in nanosilica (MA/Ns-POSS) on the mechanical properties of light-curable dental resins and composites. The primary goal was to evaluate how different concentrations of MA/Ns-POSS (0.5–20 wt.%) affect the hardness, [...] Read more.
Background: This study aimed to assess the impact of methacrylate-functionalized polyhedral oligomeric silsesquioxanes dispersed in nanosilica (MA/Ns-POSS) on the mechanical properties of light-curable dental resins and composites. The primary goal was to evaluate how different concentrations of MA/Ns-POSS (0.5–20 wt.%) affect the hardness, flexural strength, modulus, diametral tensile strength, polymerization shrinkage stress, and degree of conversion of these materials. Methods: A mixture of Bis-GMA, UDMA, TEGDMA, HEMA, and camphorquinone, with a tertiary amine as the photoinitiator, was used to create resin and composite samples, incorporating 45 wt.% silanized silica for the composites. Hardness (Vickers method, HV), flexural strength (FS), and flexural modulus (Ef) were assessed using three-point bending tests, while diametral tensile strength (DTS) polymerization shrinkage stresses (PSS), and degree of conversion (DC) analysis were analyzed for the composites. Results: The results showed that resins with 10 wt.% MA/Ns-POSS exhibited the highest Ef and FS values. Composite hardness peaked at 20 wt.% MA/Ns-POSS, while DTS increased up to 2.5 wt.% MA/Ns-POSS but declined at higher concentrations. PSS values decreased with increasing MA/Ns-POSS concentration, with the lowest values recorded at 15–20 wt.%. DC analysis also showed substantial improvement for 15–20 wt.% Conclusion: Incorporating MA/Ns-POSS improves the mechanical properties of both resins and composites, with 20 wt.% showing the best results. Further studies are needed to explore the influence of higher additive concentrations. Full article
(This article belongs to the Special Issue Innovations of Composite Materials in Prosthetic Dentistry)
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21 pages, 2332 KiB  
Article
Evaluation of Spent Catalyst from Fluid Catalytic Cracking in Fly Ash and Blast Furnace Slag Based Alkali Activated Materials
by Yolanda Luna-Galiano, Domigo Cabrera-Gallardo, Mónica Rodríguez-Galán, Rui M. Novais, João A. Labrincha and Carlos Leiva Fernández
Recycling 2025, 10(4), 149; https://doi.org/10.3390/recycling10040149 - 1 Aug 2025
Viewed by 208
Abstract
The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a [...] Read more.
The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a AAM matrix offers several advantages: valorization of the material, reducing its disposal in landfills and the landfill cost, and minimizing the environmental impact. Mineralogical, physical and mechanical characterization were carried out. The durability of the specimens was studied by performing acid attack and thermal stability tests. Mass variation, compressive strength and porosity parameters were determined to assess the durability. BFS- and FA-based AAMs have a different chemical composition, which contribute to variations in microstructure and physical and mechanical properties. Acid neutralization capacity was also determined to analyse the acid attack results. Porosity, including the pore size distribution, and the acid neutralization capacity are crucial in explaining the resistance of the AAMs to sulfuric acid attack and thermal degradation. Herein, a novel route was explored, the use of SCFCC to enhance the durability of AAMs under harsh operating conditions since results show that the compositions containing SCFCC showed lower strength decay due to the lower macroporosity proportions in these compositions. Full article
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25 pages, 5156 KiB  
Article
Enhancing the Mechanical Properties of Sulfur-Modified Fly Ash/Metakaolin Geopolymers with Polypropylene Fibers
by Sergey A. Stel’makh, Evgenii M. Shcherban’, Alexey N. Beskopylny, Levon R. Mailyan, Alexandr A. Shilov, Irina Razveeva, Samson Oganesyan, Anastasia Pogrebnyak, Andrei Chernil’nik and Diana Elshaeva
Polymers 2025, 17(15), 2119; https://doi.org/10.3390/polym17152119 - 31 Jul 2025
Viewed by 305
Abstract
High demand for sustainable solutions in the construction industry determines the significant relevance of developing new eco-friendly composites with a reduced carbon impact on the environment. The main aim of this study is to investigate the possibility and efficiency of using technical sulfur [...] Read more.
High demand for sustainable solutions in the construction industry determines the significant relevance of developing new eco-friendly composites with a reduced carbon impact on the environment. The main aim of this study is to investigate the possibility and efficiency of using technical sulfur (TS) as a modifying additive for geopolymer composites and to select the optimal content of polypropylene fiber (PF). To assess the potential of TS, experimental samples of geopolymer solutions based on metakaolin and fly ash were prepared. The TS content varied from 0% to 9% by weight of binder in 3% increments. In the first stage, the density, compressive and flexural strength, capillary water absorption and microstructure of hardened geopolymer composites were tested. The TS additive in an amount of 3% was the most effective and provided an increase in compressive strength by 12.6%, flexural strength by 12.8% and a decrease in capillary water absorption by 18.2%. At the second stage, the optimal PF content was selected, which was 0.75%. The maximum increases in strength properties were recorded for the composition with 3% TS and 0.75% PF: 8% for compression and 32.6% for bending. Capillary water absorption decreased by 12.9%. The geopolymer composition developed in this work, modified with TP and PF, has sufficient mechanical and physical properties and can be considered for further study in order to determine its competitiveness with cement composites in real construction practice. Full article
(This article belongs to the Special Issue Challenges and Trends in Polymer Composites—2nd Edition)
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16 pages, 4426 KiB  
Article
Analysis of Dynamic Properties and Johnson–Cook Constitutive Relationship Concerning Polytetrafluoroethylene/Aluminum Granular Composite
by Fengyue Xu, Jiabo Li, Denghong Yang and Shaomin Luo
Materials 2025, 18(15), 3615; https://doi.org/10.3390/ma18153615 - 31 Jul 2025
Viewed by 189
Abstract
The polytetrafluoroethylene/aluminum (PTFE/Al) granular composite, a common formulation in impact-initiated energetic materials, undergoes mechanochemical coupling reactions under sufficiently strong dynamic loading. This investigation discusses the dynamic properties and the constitutive relationship of the PTFE/Al granular composite to provide a preliminary guide for the [...] Read more.
The polytetrafluoroethylene/aluminum (PTFE/Al) granular composite, a common formulation in impact-initiated energetic materials, undergoes mechanochemical coupling reactions under sufficiently strong dynamic loading. This investigation discusses the dynamic properties and the constitutive relationship of the PTFE/Al granular composite to provide a preliminary guide for the research on mechanical properties of a series of composite materials based on PTFE/Al as the matrix. Firstly, the 26.5Al-73.5PTFE (wt.%) composite specimens are prepared by preprocessing, mixing, molding, high-temperature sintering, and cooling. Then, the quasi-static compression and Hopkinson bar tests are performed to explore the mechanical properties of the PTFE/Al composite. Influences of the strain rate of loading on the yield stress, the ultimate strength, and the limited strain are also analyzed. Lastly, based on the experimental results, the material parameters in the Johnson–Cook constitutive model are obtained by the method of piecewise fitting to describe the stress–strain relation of the PTFE/Al composite. Combining the experimental details and the obtained material parameters, the numerical simulation of the dynamic compression of the PTFE/Al composite specimen is carried out by using the ANSYS/LS-DYNA platform. The results show that the computed stress–strain curves present a reasonable agreement with the experimental data. It should be declared that this research does not involve the energy release behavior of the 26.5Al-73.5PTFE (wt.%) reactive material because the material is not initiated within the strain rate range of the dynamic test in this paper. Full article
(This article belongs to the Section Advanced Composites)
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