Search Results (41)

Hydrogen internal combustion engines are a promising propulsion technology due to their zero-carbon emission potential and high efficiency. However, achieving stable mixture formation during direct hydrogen injection remains a key challenge affecting ignition stability and NO_x emissions. Although numerous studies address the combustion characteristics of hydrogen, only a limited number have examined the transient behavior of hydrogen/air mixing during the intake stroke, particularly its interaction with in-cylinder flow structures prior to ignition. This lack of detailed insight into early mixture stratification and jet-driven turbulence represents a significant research gap that currently limits further optimization of DI-H₂ICE systems. This study therefore deals with the numerical analysis of the process of mixing hydrogen with air in the combustion chamber of a direct hydrogen injection engine (DI-H₂ICE). A 3D CFD model of a hydrogen direct-injection engine was used to evaluate in-cylinder mixing during the intake and early compression strokes. Unlike most existing publications that focus primarily on combustion or emission formation, this work examines the mixing process from the beginning of the intake stroke and provides a new evaluation of the evolution of the hydrogen jet and its interaction with the piston-induced swirl as the crankshaft angle changes. The simulation covers the section from the exhaust top dead center (TDC) to the early compression phase, during which hydrogen is injected at a high pressure. The results show that the shape of the combustion chamber and the interaction of the hydrogen jet with the piston significantly affect the distribution of the equivalent ratio and the intensity of the swirl. Quantitative evaluation showed that the mixture remained lean overall throughout the cycle: typical hydrogen mass fractions in the cylinder ranged from 0.01 to 0.05, corresponding to equivalence ratios of φ = 0.35–1.81 (λ = 2.85–0.55). Only the core of the jet reached an instantaneous local mass fraction of 0.96, representing undiluted hydrogen and not a combustible mixture. No persistent zones with φ > 1 were detected, confirming that the chosen injection strategy prevents the formation of locally rich pockets. This study confirmed that a suitably selected injection configuration and combustion chamber geometry can significantly contribute to a uniform mixture distribution, a more stable combustion process, and lower NO_x production. The presented findings provide a methodological basis for improving mixture formation strategies in hydrogen engines and may support the development of efficient, zero-carbon powertrains in future mobility systems. Full article

Ground-penetrating radar (GPR) is widely used for thickness or compaction degree detection of asphalt pavement layers, where the dielectric properties of asphalt mixtures serve as a key parameter influencing detection accuracy. These properties are closely related to the composition of the mixture and are susceptible to environmental factors such as water or ice. To clarify the influence of various factors on the dielectric behavior of asphalt mixtures, an experimental study was conducted under controlled environmental conditions. Asphalt mixture specimens with different air void contents (5.49~10.29%) were prepared, and variables such as void fraction, moisture, and ice presence were systematically controlled. Air-coupled GPR was employed to measure the specimens, and the relative permittivity was calculated using both the reflection coefficient method (RCM) and the thickness inversion algorithm (TIA). Discrepancies between the two methods were compared and analyzed. Results indicate that the RCM is significantly influenced by surface water or ice and is only suitable for dielectric characterization under dry pavement conditions. In contrast, the TIA yields more reliable results across varying surface environments. A unified model (the optimized shape factor u = −4.5 and interaction coefficient v = 5.1) was established to describe the relationship between the dielectric properties of asphalt mixtures and their volumetric parameters (bulk specific density, air void content, voids in mineral aggregate, and voids filled with asphalt). This study enables quantitative analysis of the effects of water, ice, and mixture composition on the dielectric properties of asphalt mixtures, providing a scientific basis for non-destructive and accurate GPR-based evaluation of asphalt pavements. Full article

Nitrated monoaromatic hydrocarbons (NMAHs) are emerging air pollutants commonly found in biomass burning (BB) and anthropogenic aerosols (AA). Despite their frequent deposition into aquatic systems, their ecotoxicity is still poorly understood. This study evaluates the toxicity of BB and AA aerosol extracts and their main NMAH constituents (nitrocatechols, nitrophenols, and nitrosalicylic acids) using in vitro (cellular uptake, cytotoxicity) and in vivo (algal growth inhibition, zebrafish embryo development) bioassays. Polar aerosol extracts showed higher toxicity than nonpolar ones, with stronger interaction via zebrafish organic anion Oatp1d1 than organic cation Oct1 transporter, indicating selective uptake. NMAHs and their relevant mixtures showed similar toxicity patterns as BB water extract, so NMAHs were identified as contributors to aerosol toxicity. Nitrocatechols stand out for their toxicity, showing the highest chronic toxicity in algae (IC₅₀: 0.6–1.1 mg/L) and acute cytotoxicity in fish cells (IC₅₀: 2.0–4.1 mg/L), possibly because they dominated the NMAHs composition of aerosols (BB: 80.6%; AA: 79.8%). Sublethal NMAH concentrations caused developmental disorders and altered lipid homeostasis in zebrafish embryos, indicating early physiological stress on higher organisms. These findings reveal NMAHs as significant ecotoxic components of BB and AA emissions which may pose an increasing threat to aquatic ecosystems following atmospheric deposition. Full article

In this study, the thermal effectiveness of thermally conductive concrete pavements (TCPs) using silicon carbide (SiC) as a fine aggregate replacement was investigated, compared with that of ordinary Portland cement pavements (OPCPs). The most important purpose of this study is to improve the thermal performance of concrete pavement. Additionally, this study utilized improved thermal properties to enhance the efficiency of pavement heating to prevent icing and snow stacking. Both mixtures met the Korean standards for air content (4.5–6%) and slump (80–150 mm), demonstrating adequate workability. TCP exhibited a higher mechanical performance, with average compressive and flexural strengths of 42.88 MPa and 7.35 MPa, respectively, exceeding the required targets of a 30 MPa compressive strength and a 4.5 MPa flexural strength. The improved strength was mainly attributed to the filler effect and partly due to the van der Waals interactions of the SiC particles. Thermal conductivity tests showed a significant improvement in the TCP (3.20 W/mK), which was approximately twice that of OPCP (1.59 W/mK), indicating an enhanced heat transfer efficiency. In winter field tests, TCP effectively maintained high surface temperatures, overcoming heat loss and outperforming the OPCP. In the site experiment, thermal efficiency was clearly shown in the temperature at the center of the TCP, which was 3.5 °C higher than at the center of the OPCP at the coldest time. These improvements suggest that SiC-reinforced concrete pavements can be practically utilized for effective snow removal and ice mitigation in road systems. Full article

The activity of the present work is part of a research project aimed at proposing a solution for off-grid charging stations relying on the adoption of a reciprocating engine fuelled with alternative renewable fuels. This technology has as its main advantage the zero-carbon emissions impact of biofuels with small modifications to current ICE technology and refuelling infrastructure. This research is founded on preliminary experimental tests carried out on a six-cylinder spark-ignition engine adapted to pure ethanol fuelling with a single-point injection system. The experimental results obtained at different engine loads have been useful to build and validate a CFD model by testing several kinetic mechanisms and for the proper calibration of a flame speed model. Nevertheless, due to the chemical and physical properties of alcohols such as ethanol, this type of fuelling system leads to a significant non-uniformity of the mixture among the cylinders, and in some cases, to rich air-to-fuel ratio; numerical simulations are performed to address such an issue, and to evaluate performance and exhaust emissions, in terms of CO, CO₂, and NO_x. Finally, a study on spark timing variation is presented as well, to study its effect on performance and pollutants. Full article

The process of formation of composite systems based on nanosilica A-300 and biologically active substances (BAS), namely gallic acid (GA), glycyrrhizic acid (GLA), and its salts, was studied using a set of physicochemical methods. It was shown that when BAS are immobilized on the silica surface by the method of joint grinding in a porcelain mortar, they pass into a nanosized X-ray amorphous state. Water adsorbed on the surface of such composite systems is also in a clustered state, and the radius of adsorbed water clusters is in the range of 0.4–50 nm. The chloroform environment has a complex effect on the size of water clusters. In general, there is a tendency for the radius of water clusters to increase when air is replaced by a chloroform environment. However, this does not always lead to a decrease in the interfacial energy. The possibility of the existence of metastable ice in the temperature range up to 287 K, stabilized by the surface of composite systems, was discovered. The amount of such ice can reach 20% of the total water content in the sample. The possibility of using complex viscosity measurements for hydrated silica powders and silica containing immobilized biologically active substances was shown. These measurements allow recording changes in the phase state of complex mixtures during the formation of compact composite forms under the influence of periodic mechanical loading. Full article

Traditional photovoltaic-powered forced air-cooling systems face significant challenges in balancing energy efficiency and thermal comfort due to temperature sensitivity, mechanical ventilation energy consumption, and spatial constraints. This study aims to enhance building energy efficiency by integrating a radiant cooling ceiling (RCC) with a phase change material (PCM) thermal storage system, addressing the limitations of traditional photovoltaic-powered cooling systems through optimized material design and dynamic energy management. A ternary PCM mixture (glycerol–alcohol–water) was optimized using differential scanning calorimetry (DSC), demonstrating superior latent heat storage (361.66 J/g) and phase transition temperature (1.91 °C) in the selected “Slushy Ice” formulation. A 3D transient thermal model and experimental validation revealed that the RCC system achieved 57% energy savings under quasi-steady operation, with radiative heat transfer contributing 55% of total cooling capacity. The system dynamically stores cold energy during peak photovoltaic generation and releases it via RCC during low-power periods, resolving the “cooling energy consumption paradox”. Key challenges, including PCM cycling stability and thermal response time mismatches, were identified, with future research directions emphasizing multi-scale simulations and intelligent encapsulation. This work provides a viable pathway for improving building energy efficiency while maintaining thermal comfort and for improving building energy efficiency in temperate zones, with future extensions to arid and tropical climates requiring targeted material and system optimizations. Full article

Transportation infrastructure such as concrete pavements, parapets, barriers, and bridge decks in cold regions are usually exposed to a heavy amount of deicing chemicals during the winter for ice and snow control. Various deicer salts can physically and chemically react with concrete and result in damage and deterioration. Currently, Idaho uses four different types of deicers during the winter: salt brine, mag bud converse, freeze guard plus, and mag chloride. The most often utilized substance is salt brine, which is created by dissolving rock salt at a concentration of 23.3%. Eight concrete mixtures for paving and structural purposes were made and put through a battery of durability tests. Following batching, measurements were made of the unit weight, entrained air, slump, and super air meter (SAM) fresh characteristics. Rapid freeze–thaw (F-T) cycle experiments, deicing scaling tests, and surface electrical resistivity testing were used to test and assess all mixes. Tests with mag bud converse, freeze guard plus mag chloride, and acid-soluble chloride were conducted following an extended period of soaking in salt brine. Two different structural mixtures were suggested as a result of the severe scaling observed in the structural mixtures lacking supplemental cementitious materials (SCMs) and the moderate scaling observed in the other combinations. The correlated values of the SAM number with the spacing factor have been shown that mixture with no SCMs has a spacing factor of 0.24, which is higher than the recommended value of 0.2 and concentrations of acid soluble chloride over the threshold limit were discernible. In addition, the highest weight of calcium hydroxide using the TGA test was observed. For all examined mixes, the residual elastic moduli after 300 cycles varied between 76.0 and 83.3 percent of the initial moduli. Mixture M5 displayed the lowest percentage of initial E (76.0 percent), while mixtures M1 and M2 showed the highest percentage of residual E (83.3 and 80.0 percent, respectively) among the evaluated combinations. There were no significant variations in the percentage of maintained stiffness between the combinations. As a result, it was difficult to identify distinct patterns about how the air content or SAM number affected the mixture’s durability. Class C coal fly ash and silica fume were present in the suggested mixtures, which were assessed using the same testing matrix as the original mixtures. Because of their exceptional durability against large concentrations of chemical deicers, the main findings suggest altering the concrete compositions to incorporate SCMs in a ternary form. Full article

IC Engines have played a vital role in past years and will in future years too. The only way that engines are made popular is the power they produce, which is useful in the transportation sector, with which humans’ daily lives become easier concerning time and effort. The only issues with these engines are the depletion of fossil fuels and harmful emissions. To regulate these threats, in the current study an SI engine is modified to duel fuel mode in such a way that the engine runs with hydrogen gas at different flow rates along with air. Engine speed is varied from 1800 to 3400 rpm under constant load by letting an ethanol, methanol, and gasoline mixture enter into the cylinder. Performance parameters like brake thermal efficiency, HC emissions, and vibrations produced from the engine are in agreement with the blended fuels used in this study. Full article

Freezing time stands out as the most critical parameter in ice cream production, significantly influencing the final product’s quality and production efficiency. Therefore, it is essential to accurately estimate the freezing time based on ice cream recipes. This research paper focuses on determining the thermal properties of ice cream samples by leveraging insights from previous studies. Moreover, a new specific heat correlation is proposed to account for the latent heat effect of water during the freezing process. The results demonstrated that the new specific heat correlation aligns well with established formulas from previous research as well as experimental results with maximum 2.5% deviation. To validate the accuracy of the proposed numerical model, experimental studies were compared with numerical results for the first time in the context of ice cream freezing inside a mold. Additionally, a parametric analysis was conducted using numerical modelling to discern the relative importance of various production process parameters. Notably, the glycol–water mixture temperature emerged as the most influential parameter affecting freezing time, while the amount of air inside the ice cream was identified as the least significant factor. Full article

The growing interest in the use of building materials with a reduced carbon footprint was the aim of this research assessing the impact of four different types of low-emission cements on the properties of cement concretes used for the construction of local roads. This research work attempted to verify the strength characteristics and assess the durability of such solutions, which used the commonly used CEM I 42.5 R pure clinker cement and three multi-component cements: CEM II/A-V 42.5 R, CEM III/A 42.5 N-LH/HSR/NA, and CEM V/A S-V 42.5 N-LH/HSR/NA. Cement was used in a constant amount of 360 kg/m³, sand of 0/2 mm, and granite aggregate fractions of 2/8 and 8/16 mm. This research was carried out in two areas: the first concerned strength tests and the second focused on the area of assessing the durability of concrete in terms of frost resistance F150, resistance to de-icing agents, water penetration under pressure, and an analysis of the air entrainment structure in concrete according to the PN EN 480-11 standard. Analyzing the obtained test results, it can be concluded that the highest compressive strength of more than 70 MPa was obtained for CEM III concrete, 68 MPa for CEM V concrete, and the lowest for CEM I cement after 90 days. After the durability tests, it was found that the smallest decrease in compressive strength after 150 freezing and thawing cycles was obtained for CEM III (−0.9%) and CEM V (−1.4%) concretes. The high durability of concrete is confirmed by water penetration tests under pressure, because for newly designed recipes using CEM II, CEM III, and CEM V, water penetration from 17 mm to 18 mm was achieved, which proves the very high tightness of the concrete. The assessment of the durability of low-emission cements was confirmed by tests of resistance to de-icing agents and the aeration structure performed under a microscope in accordance with the requirements of the PN-EN 480-11 standard. The obtained analysis results indicate the correct structure and minimal spacing of air bubbles in the concrete, which confirms and guarantees the durability of concrete intended for road construction. Concretes designed using CEM V cement are characterized by a carbon footprint reduction of 36%, and for the mixture based on CEM III, we even observed a decrease of 39% compared to traditional concrete. Concrete using CEM II, CEM III, and CEM V cements can be successfully used for the construction of local roads. Therefore, it is necessary to consider changing the requirements of the technical specifications recommended for roads in Poland. Full article

Technologies used in the transport sector have a substantial impact on air pollution and global warming. Due to the immense impact of air pollution on Earth, it is crucial to investigate novel ways to reduce emissions. One way to reduce pollution from ICE is to use alternative fuels. However, blends of alternative fuels in different proportions are known to improve some emissions’ parameters, while others remain unchanged or even worsen. It is therefore necessary to find ways of reducing all the main pollutants. For SI engines, mixtures of hydrogen and natural gas can be used as alternative fuels. The use of such fuel mixtures makes it possible to reduce CO, HC, and CO₂ emissions from the engine, but the unique properties of hydrogen tend to increase NO_x emissions. One way to address this challenge is to use port water injection (PWI). This paper describes studies carried out under laboratory conditions on an SI engine fuelled with CNG and CNG + H₂ mixtures (H₂ = 5, 10, 15% by volume) and injected with 60 and 120 mL/min of water into the engine. The tests showed that the additional water injection reduced CO and NO_x emissions by about 20% and 4–5 times, respectively. But, the results also show that water injection at the rate of 120 mL/min increases fuel consumption by between 2.5% and 7% in all cases. Full article

This paper presents the extension of the monolayer snow model of a semi-distributed hydrological model (HYDROTEL) to a multilayer model that considers snow to be a combination of ice and air, while accounting for freezing rain. For two stations in Yukon and one station in northern Quebec, Canada, the multilayer model achieves high performances during calibration periods yet similar to the those of the monolayer model, with KGEs of up to 0.9. However, it increases the KGE values by up to 0.2 during the validation periods. The multilayer model provides more accurate estimations of maximum SWE and total spring snowmelt dates. This is due to its increased sensitivity to thermal atmospheric conditions. Although the multilayer model improves the estimation of snow heights overall, it exhibits excessive snow densities during spring snowmelt. Future research should aim to refine the representation of snow densities to enhance the accuracy of the multilayer model. Nevertheless, this model has the potential to improve the simulation of spring snowmelt, addressing a common limitation of the monolayer model. Full article

One of the key factors of the current energy transition is the use of hydrogen (H₂) as fuel in energy transformation technologies. This fuel has the advantage of being produced from the most primary forms of energy and has the potential to reduce carbon dioxide (CO₂) emissions. In recent years, hydrogen or hydrogen-rich mixtures in internal combustion engines (ICEs) have gained popularity, with numerous reports documenting their use in spark ignition (SI) and compression ignition (CI) engines. Homogeneous charge compression ignition (HCCI) engines have the potential for substantial reductions in nitrogen oxides (NOx) and particulate matter (PM) emissions, and the use of hydrogen along with this kind of combustion could substantially reduce CO₂ emissions. However, there have been few reports using hydrogen in HCCI engines, with most studies limited to evaluating technical feasibility, combustion characteristics, engine performance, and emissions in laboratory settings at sea level. This paper presents a study of HCCI combustion using hydrogen in a stationary air-cooled Lombardini 25 LD 425-2 modified diesel engine located at 1495 m above sea level. An experimental phase was conducted to determine the intake temperature requirements and equivalence ratios for stable HCCI combustion. These results were compared with previous research carried out at sea level. To the best knowledge of the authors, this is the first report on the combustion and operational limits for an HCCI engine fueled with hydrogen under the mentioned specific conditions. Equivalence ratios between 0.21 and 0.28 and intake temperatures between 188 °C and 235 °C effectively achieved the HCCI combustion. These temperature values were, on average, 100 °C higher than those reported in previous studies. The maximum value for the indicated mean effective pressure (IMEPn) was 1.75 bar, and the maximum thermal efficiency (ITEn) was 34.5%. The achieved results are important for the design and implementation of HCCI engines running solely on hydrogen in developing countries located at high altitudes above sea level. Full article

Exhaust gas recirculation (EGR) has been an efficient emission treatment strategy employed in internal combustion engines (ICEs) to cope with NO_x emission limits since the introduction of Euro 4 regulations for heavy-duty commercial vehicles. A portion of the exhaust gas is fed back into the intake port, replacing O₂ in the fresh air with inert CO₂ from the exhaust gas, resulting in a reduction in the combustion temperature and, hence, a reduction in NO_x emissions. Considering the high exhaust temperature, this process increases the charge mixture temperature and degrades the volumetric efficiency of the engine. EGR coolers have been introduced as vital parts of EGR exhaust treatment systems with the aim of reducing the intake port temperature to increase volumetric efficiency and further reduce combustion temperatures. EGR coolers are heat exchangers (HXs) that generally employ engine coolant to reduce the EGR temperature with effectiveness values around 0.7~0.85 and downgrade with engine usage owing to soot deposition. Increasing the effectiveness of the EGR cooler has a positive effect on engine volumetric efficiency and reduces NO_x, particulate matter (PM), and fuel consumption. The current study involved the design of a microchannel HX for a 500 PS heavy-duty Euro 6 diesel engine EGR cooler. The mechanical and thermal-hydraulic design calculations of the proposed HX were performed using Mathematica software. The optimum HX dimensions for the required boundary conditions were determined, and the performance of the EGR cooler was analyzed for the current and proposed options. Furthermore, Diesel-RK software was used to model the engine performance with NO_x, PM, CO₂ emissions, and fuel consumption predictions. The results show that the newly proposed microchannel HX design improves NO_x, PM, and specific fuel consumption by 6.75%, 11.30%, and 0.65%, respectively. Full article