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Keywords = heat load condition

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18 pages, 2664 KiB  
Article
Analysis of Heat Exchange Efficiency and Influencing Factors of Energy Tunnels: A Case Study of the Torino Metro in Italy
by Mei Yin, Pengcheng Liu and Zhenhuang Wu
Buildings 2025, 15(15), 2704; https://doi.org/10.3390/buildings15152704 (registering DOI) - 31 Jul 2025
Abstract
Both ground source heat pumps (GSHPs) and energy underground structures are engineered systems that utilize shallow geothermal energy. However, due to the construction complexity and associated costs of energy tunnels, their heat exchange efficiency relative to GSHPs remains a topic worthy of in-depth [...] Read more.
Both ground source heat pumps (GSHPs) and energy underground structures are engineered systems that utilize shallow geothermal energy. However, due to the construction complexity and associated costs of energy tunnels, their heat exchange efficiency relative to GSHPs remains a topic worthy of in-depth investigation. In this study, a thermal–hydraulic (TH) coupled finite element model was developed based on a section of the Torino Metro Line in Italy to analyze the differences in and influencing factors of heat transfer performance between energy tunnels and GSHPs. The model was validated by comparing the outlet temperature curves under both winter and summer loading conditions. Based on this validated model, a parametric analysis was conducted to examine the effects of the tunnel air velocity, heat carrier fluid velocity, and fluid type. The results indicate that, under identical environmental conditions, energy tunnels exhibit higher heat exchange efficiency than conventional GSHP systems and are less sensitive to external factors such as fluid velocity. Furthermore, a comparison of different heat carrier fluids, including alcohol-based fluids, refrigerants, and water, revealed that the fluid type significantly affects thermal performance, with the refrigerant R-134a outperforming ethylene glycol and water in both heating and cooling efficiency. Full article
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26 pages, 9475 KiB  
Article
Microalgae-Derived Vesicles: Natural Nanocarriers of Exogenous and Endogenous Proteins
by Luiza Garaeva, Eugene Tolstyko, Elena Putevich, Yury Kil, Anastasiia Spitsyna, Svetlana Emelianova, Anastasia Solianik, Eugeny Yastremsky, Yuri Garmay, Elena Komarova, Elena Varfolomeeva, Anton Ershov, Irina Sizova, Evgeny Pichkur, Ilya A. Vinnikov, Varvara Kvanchiani, Alina Kilasoniya Marfina, Andrey L. Konevega and Tatiana Shtam
Plants 2025, 14(15), 2354; https://doi.org/10.3390/plants14152354 (registering DOI) - 31 Jul 2025
Abstract
Extracellular vesicles (EVs), nanoscale membrane-enclosed particles, are natural carriers of proteins and nucleic acids. Microalgae are widely used as a source of bioactive substances in the food and cosmetic industries and definitely have a potential to be used as the producers of EVs [...] Read more.
Extracellular vesicles (EVs), nanoscale membrane-enclosed particles, are natural carriers of proteins and nucleic acids. Microalgae are widely used as a source of bioactive substances in the food and cosmetic industries and definitely have a potential to be used as the producers of EVs for biomedical applications. In this study, the extracellular vesicles isolated from the culture medium of two unicellular microalgae, Chlamydomonas reinhardtii (Chlamy-EVs) and Parachlorella kessleri (Chlore-EVs), were characterized by atomic force microscopy (AFM), cryo-electronic microscopy (cryo-EM), and nanoparticle tracking analysis (NTA). The biocompatibility with human cells in vitro (HEK-293T, DF-2 and A172) and biodistribution in mouse organs and tissues in vivo were tested for both microalgal EVs. An exogenous therapeutic protein, human heat shock protein 70 (HSP70), was successfully loaded to Chlamy- and Chlore-EVs, and its efficient delivery to human glioma and colon carcinoma cell lines has been confirmed. Additionally, in order to search for potential therapeutic biomolecules within the EVs, their proteomes have been characterized. A total of 105 proteins were identified for Chlamy-EVs and 33 for Chlore-EVs. The presence of superoxide dismutase and catalase in the Chlamy-EV constituents allows for considering them as antioxidant agents. The effective delivery of exogenous cargo to human cells and the possibility of the particle yield optimization by varying the microalgae growth conditions make them favorable producers of EVs for biotechnology and biomedical application. Full article
(This article belongs to the Section Plant Cell Biology)
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21 pages, 6163 KiB  
Article
Residual Stress and Corrosion Performance in L-PBF Ti6Al4V: Unveiling the Optimum Stress Relieving Temperature via Microcapillary Electrochemical Characterisation
by Lorenzo D’Ambrosi, Katya Brunelli, Francesco Cammelli, Reynier I. Revilla and Arshad Yazdanpanah
Metals 2025, 15(8), 855; https://doi.org/10.3390/met15080855 - 30 Jul 2025
Viewed by 21
Abstract
This study aims to determine the optimal low-temperature stress relieving heat treatment that minimizes residual stresses while preserving corrosion resistance in Laser Powder Bed Fusion (L-PBF) processed Ti6Al4V alloy. Specifically, it investigates the effects of stress relieving at 400 °C, 600 °C, and [...] Read more.
This study aims to determine the optimal low-temperature stress relieving heat treatment that minimizes residual stresses while preserving corrosion resistance in Laser Powder Bed Fusion (L-PBF) processed Ti6Al4V alloy. Specifically, it investigates the effects of stress relieving at 400 °C, 600 °C, and 800 °C on microstructure, residual stress, and electrochemical performance. Specimens were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical techniques. A novel microcapillary electrochemical method was employed to precisely assess passive layer stability and corrosion behaviour under simulated oral conditions, including fluoride contamination and tensile loading. Results show that heat treatments up to 600 °C effectively reduce residual stress with minimal impact on corrosion resistance. However, 800 °C treatment leads to a phase transformation from α′ martensite to a dual-phase α + β structure, significantly compromising passive film integrity. The findings establish 600 °C as the optimal stress-relieving temperature for balancing mechanical stability and electrochemical performance in biomedical and aerospace components. Full article
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21 pages, 2695 KiB  
Article
Thermographic Investigation of Elastocaloric Behavior in Ni-Ti Sheet Elements Under Cyclic Bending
by Saeed Danaee Barforooshi, Gianmarco Bizzarri, Girolamo Costanza, Stefano Paoloni, Ilaria Porroni and Maria Elisa Tata
Materials 2025, 18(15), 3546; https://doi.org/10.3390/ma18153546 - 29 Jul 2025
Viewed by 186
Abstract
Growing environmental concerns have driven increased interest in solid-state thermal technologies based on the elastocaloric properties of shape memory alloys (SMA). This work examines the elastocaloric effect (eCE) in Ni-Ti SMA sheets subjected to cyclic bending, providing quantitative thermal characterization of their behavior [...] Read more.
Growing environmental concerns have driven increased interest in solid-state thermal technologies based on the elastocaloric properties of shape memory alloys (SMA). This work examines the elastocaloric effect (eCE) in Ni-Ti SMA sheets subjected to cyclic bending, providing quantitative thermal characterization of their behavior under controlled loading conditions. The experimental investigation employed passive thermography to analyze the thermal response of Ni-Ti sheets under two deflection configurations at 1800 rpm loading. Testing revealed consistent adiabatic temperature variations (ΔTad) of 4.14 °C and 4.26 °C for the respective deflections during heating cycles, while cooling phases demonstrated efficient thermal homogenization with temperature gradients decreasing from 4.13 °C to 0.13 °C and 4.43 °C to 0.68 °C over 60 s. These findings provide systematic thermal documentation of elastocaloric behavior in bending-loaded Ni-Ti sheet elements and quantitative data on the relationship between mechanical loading parameters and thermal gradients, enhancing the experimental understanding of elastocaloric phenomena in this configuration. Full article
(This article belongs to the Special Issue Technology and Applications of Shape Memory Materials)
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35 pages, 3995 KiB  
Review
Recent Advancements in Latent Thermal Energy Storage and Their Applications for HVAC Systems in Commercial and Residential Buildings in Europe—Analysis of Different EU Countries’ Scenarios
by Belayneh Semahegn Ayalew and Rafał Andrzejczyk
Energies 2025, 18(15), 4000; https://doi.org/10.3390/en18154000 - 27 Jul 2025
Viewed by 459
Abstract
Heating, ventilation, and air-conditioning (HVAC) systems account for the largest share of energy consumption in European Union (EU) buildings, representing approximately 40% of the final energy use and contributing significantly to carbon emissions. Latent thermal energy storage (LTES) using phase change materials (PCMs) [...] Read more.
Heating, ventilation, and air-conditioning (HVAC) systems account for the largest share of energy consumption in European Union (EU) buildings, representing approximately 40% of the final energy use and contributing significantly to carbon emissions. Latent thermal energy storage (LTES) using phase change materials (PCMs) has emerged as a promising strategy to enhance HVAC efficiency. This review systematically examines the role of latent thermal energy storage using phase change materials (PCMs) in optimizing HVAC performance to align with EU climate targets, including the Energy Performance of Buildings Directive (EPBD) and the Energy Efficiency Directive (EED). By analyzing advancements in PCM-enhanced HVAC systems across residential and commercial sectors, this study identifies critical pathways for reducing energy demand, enhancing grid flexibility, and accelerating the transition to nearly zero-energy buildings (NZEBs). The review categorizes PCM technologies into organic, inorganic, and eutectic systems, evaluating their integration into thermal storage tanks, airside free cooling units, heat pumps, and building envelopes. Empirical data from case studies demonstrate consistent energy savings of 10–30% and peak load reductions of 20–50%, with Mediterranean climates achieving superior cooling load management through paraffin-based PCMs (melting range: 18–28 °C) compared to continental regions. Policy-driven initiatives, such as Germany’s renewable integration mandates for public buildings, are shown to amplify PCM adoption rates by 40% compared to regions lacking regulatory incentives. Despite these benefits, barriers persist, including fragmented EU standards, life cycle cost uncertainties, and insufficient training. This work bridges critical gaps between PCM research and EU policy implementation, offering a roadmap for scalable deployment. By contextualizing technical improvement within regulatory and economic landscapes, the review provides strategic recommendations to achieve the EU’s 2030 emissions reduction targets and 2050 climate neutrality goals. Full article
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30 pages, 8885 KiB  
Article
Seasonally Adaptive VMD-SSA-LSTM: A Hybrid Deep Learning Framework for High-Accuracy District Heating Load Forecasting
by Yu Zhang, Keyong Hu, Lei Lu, Qingqing Yang and Min Fang
Mathematics 2025, 13(15), 2406; https://doi.org/10.3390/math13152406 - 26 Jul 2025
Viewed by 169
Abstract
To improve the accuracy of heating load forecasting and effectively address the energy waste caused by supply–demand imbalances and uneven thermal distribution, this study innovatively proposes a hybrid prediction model incorporating seasonal adjustment strategies. The model establishes a dynamically adaptive forecasting framework through [...] Read more.
To improve the accuracy of heating load forecasting and effectively address the energy waste caused by supply–demand imbalances and uneven thermal distribution, this study innovatively proposes a hybrid prediction model incorporating seasonal adjustment strategies. The model establishes a dynamically adaptive forecasting framework through synergistic integration of the Sparrow Search Algorithm (SSA), Variational Mode Decomposition (VMD), and Long Short-Term Memory (LSTM) network. Specifically, VMD is first employed to decompose the historical heating load data from Arizona State University’s Tempe campus into multiple stationary modal components, aiming to reduce data complexity and suppress noise interference. Subsequently, the SSA is utilized to optimize the hyperparameters of the LSTM network, with targeted adjustments made according to the seasonal characteristics of the heating load, enabling the identification of optimal configurations for each season. Comprehensive experimental evaluations demonstrate that the proposed model achieves the lowest values across three key performance metrics—Mean Absolute Percentage Error (MAPE), Mean Absolute Error (MAE), and Root Mean Square Error (RMSE)—under various seasonal conditions. Notably, the MAPE values are reduced to 1.3824%, 0.9549%, 6.4018%, and 1.3272%, with average error reductions of 9.4873%, 3.8451%, 6.6545%, and 6.5712% compared to alternative models. These results strongly confirm the superior predictive accuracy and fitting capability of the proposed model, highlighting its potential to support energy allocation optimization in district heating systems. Full article
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17 pages, 1742 KiB  
Article
Assessment of Aerodynamic Properties of the Ventilated Cavity in Curtain Wall Systems Under Varying Climatic and Design Conditions
by Nurlan Zhangabay, Aizhan Zhangabay, Kenzhebek Akmalaiuly, Akmaral Utelbayeva and Bolat Duissenbekov
Buildings 2025, 15(15), 2637; https://doi.org/10.3390/buildings15152637 - 25 Jul 2025
Viewed by 272
Abstract
Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to [...] Read more.
Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to ensure healthy and favorable conditions for human life but also to the need for the rational use of energy resources. This area is becoming particularly relevant in the context of global challenges related to climate change, rising energy costs and increased environmental requirements. Practice shows that any technical solutions to ensure comfortable temperature, humidity and air exchange in rooms should be closely linked to the concept of energy efficiency. This allows one not only to reduce operating costs but also to significantly reduce greenhouse gas emissions, thereby contributing to sustainable development and environmental safety. In this connection, this study presents a parametric assessment of the influence of climatic and geometric factors on the aerodynamic characteristics of the air cavity, which affect the heat exchange process in the ventilated layer of curtain wall systems. The assessment was carried out using a combined analytical calculation method that provides averaged thermophysical parameters, such as mean air velocity (Vs), average internal surface temperature (tin.sav), and convective heat transfer coefficient (αs) within the air cavity. This study resulted in empirical average values, demonstrating that the air velocity within the cavity significantly depends on atmospheric pressure and façade height difference. For instance, a 10-fold increase in façade height leads to a 4.4-fold increase in air velocity. Furthermore, a three-fold variation in local resistance coefficients results in up to a two-fold change in airflow velocity. The cavity thickness, depending on atmospheric pressure, was also found to affect airflow velocity by up to 25%. Similar patterns were observed under ambient temperatures of +20 °C, +30 °C, and +40 °C. The analysis confirmed that airflow velocity is directly affected by cavity height, while the impact of solar radiation is negligible. However, based on the outcomes of the analytical model, it was concluded that the method does not adequately account for the effects of solar radiation and vertical temperature gradients on airflow within ventilated façades. This highlights the need for further full-scale experimental investigations under hot climate conditions in South Kazakhstan. The findings are expected to be applicable internationally to regions with comparable climatic characteristics. Ultimately, a correct understanding of thermophysical processes in such structures will support the advancement of trends such as Lightweight Design, Functionally Graded Design, and Value Engineering in the development of curtain wall systems, through the optimized selection of façade configurations, accounting for temperature loads under specific climatic and design conditions. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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25 pages, 4237 KiB  
Article
Cost-Effective Thermal Mass Walls for Solar Greenhouses in Gobi Desert Regions
by Xiaodan Zhang, Jianming Xie, Ning Ma, Youlin Chang, Jing Zhang and Jing Li
Agriculture 2025, 15(15), 1618; https://doi.org/10.3390/agriculture15151618 - 25 Jul 2025
Viewed by 212
Abstract
Gobi solar greenhouses (GSGs) enhance energy, food, and financial security in Gobi Desert regions through passive solar utilization. Thermal mass walls are critical for plant thermal comfort in GSGs but can lead to resource waste if poorly designed. This study pioneers the integration [...] Read more.
Gobi solar greenhouses (GSGs) enhance energy, food, and financial security in Gobi Desert regions through passive solar utilization. Thermal mass walls are critical for plant thermal comfort in GSGs but can lead to resource waste if poorly designed. This study pioneers the integration of payback period constrains into thermal mass wall optimization, establishing a new performance–cost trade-off approach for GSG wall design, balancing thermal performance and economic feasibility. We quantified energy-conserving benefits against wall-construction costs to derive the optimal inner-layer thicknesses under <25% GSG lifespan payback criteria. Three GSG thermal mass walls in China’s Hexi Corridor were optimized. For the concrete-layered, stone-layered, and pebble-soil walls, the optimum inner-layer thicknesses were 0.47, 0.65, and 1.24 m, respectively, with extra costs of 620.75, 767.60, and 194.56 RMB yuan; annual energy-conserving benefits of 82.77, 102.35, and 51.88 RMB yuan·yr−1; and payback periods of 7.5, 7.5, and 3.75 years. A dynamic thermal load analysis confirmed that GSGs with optimized walls required no heating during a sunny winter solstice night. Cooling loads of 33.15–35.27 kW further indicated the potential to maintain thermal comfort under colder weather conditions. This approach improves plant thermal comfort cost-effectively, advancing sustainable Gobi agriculture. Full article
(This article belongs to the Section Agricultural Technology)
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27 pages, 47905 KiB  
Article
FDS-Based Study on Fire Spread and Control in Modern Brick-Timber Architectural Heritage: A Case Study of Faculty House at a University in Changsha
by Simian Liu, Gaocheng Liang, Lei Shi, Ming Luo and Meizhen Long
Sustainability 2025, 17(15), 6773; https://doi.org/10.3390/su17156773 - 25 Jul 2025
Viewed by 345
Abstract
The modern Chinese architectural heritage combines sturdy Western materials with delicate Chinese styling, mainly adopting brick-timber structural systems that are highly vulnerable to fire damage. The study assesses the fire spread characteristics of the First Faculty House, a 20th-century architectural heritage located at [...] Read more.
The modern Chinese architectural heritage combines sturdy Western materials with delicate Chinese styling, mainly adopting brick-timber structural systems that are highly vulnerable to fire damage. The study assesses the fire spread characteristics of the First Faculty House, a 20th-century architectural heritage located at a university in China. The assessment is carried out by analyzing building materials, structural configuration, and fire load. By using FDS (Fire Dynamics Simulator (PyroSim version 2022)) and SketchUp software (version 2023) for architectural reconstruction and fire spread simulation, explores preventive measures to reduce fire risks. The result show that the total fire load of the building amounts to 1,976,246 MJ. After ignition, flashover occurs at 700 s, accompanied by a sharp increase in the heat release rate (HRR). The peak ceiling temperature reaches 750 °C. The roof trusses have critical structural weaknesses when approaching flashover conditions, indicating a high potential for collapse. Three targeted fire protection strategies are proposed in line with the heritage conservation principle of minimal visual and functional intervention: fire sprinkler systems, fire retardant coating, and fire barrier. Simulations of different strategies demonstrate their effectiveness in mitigating fire spread in elongated architectural heritages with enclosed ceiling-level ignition points. The efficacy hierarchy follows: fire sprinkler system > fire retardant coating > fire barrier. Additionally, because of chimney effect, for fire sources located above the ceiling and other hidden locations need to be warned in a timely manner to prevent the thermal plume from invading other sides of the ceiling through the access hole. This research can serve as a reference framework for other Modern Chinese Architectural Heritage to develop appropriate fire mitigation strategies and to provide a methodology for sustainable development of the Chinese architectural heritage. Full article
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19 pages, 474 KiB  
Review
A Review on the Technologies and Efficiency of Harvesting Energy from Pavements
by Shijing Chen, Luxi Wei, Chan Huang and Yinghong Qin
Energies 2025, 18(15), 3959; https://doi.org/10.3390/en18153959 - 24 Jul 2025
Viewed by 345
Abstract
Dark asphalt surfaces, absorbing about 95% of solar radiation and warming to 60–70 °C during summer, intensify urban heat while providing substantial prospects for energy extraction. This review evaluates four primary technologies—asphalt solar collectors (ASCs, including phase change material (PCM) integration), photovoltaic (PV) [...] Read more.
Dark asphalt surfaces, absorbing about 95% of solar radiation and warming to 60–70 °C during summer, intensify urban heat while providing substantial prospects for energy extraction. This review evaluates four primary technologies—asphalt solar collectors (ASCs, including phase change material (PCM) integration), photovoltaic (PV) systems, vibration-based harvesting, thermoelectric generators (TEGs)—focusing on their principles, efficiencies, and urban applications. ASCs achieve up to 30% efficiency with a 150–300 W/m2 output, reducing pavement temperatures by 0.5–3.2 °C, while PV pavements yield 42–49% efficiency, generating 245 kWh/m2 and lowering temperatures by an average of 6.4 °C. Piezoelectric transducers produce 50.41 mW under traffic loads, and TEGs deliver 0.3–5.0 W with a 23 °C gradient. Applications include powering sensors, streetlights, and de-icing systems, with ASCs extending pavement life by 3 years. Hybrid systems, like PV/T, achieve 37.31% efficiency, enhancing UHI mitigation and emissions reduction. Economically, ASCs offer a 5-year payback period with a USD 3000 net present value, though PV and piezoelectric systems face cost and durability challenges. Environmental benefits include 30–40% heat retention for winter use and 17% increased PV self-use with EV integration. Despite significant potential, high costs and scalability issues hinder adoption. Future research should optimize designs, develop adaptive materials, and validate systems under real-world conditions to advance sustainable urban infrastructure. Full article
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17 pages, 6623 KiB  
Article
Numerical Study on Flow Field Optimization and Wear Mitigation Strategies for 600 MW Pulverized Coal Boilers
by Lijun Sun, Miao Wang, Peian Chong, Yunhao Shao and Lei Deng
Energies 2025, 18(15), 3947; https://doi.org/10.3390/en18153947 - 24 Jul 2025
Viewed by 150
Abstract
To compensate for the instability of renewable energy sources during China’s energy transition, large thermal power plants must provide critical operational flexibility, primarily through deep peaking. To investigate the combustion performance and wear and tear of a 600 MW pulverized coal boiler under [...] Read more.
To compensate for the instability of renewable energy sources during China’s energy transition, large thermal power plants must provide critical operational flexibility, primarily through deep peaking. To investigate the combustion performance and wear and tear of a 600 MW pulverized coal boiler under deep peaking, the gas–solid flow characteristics and distributions of flue gas temperature, wall heat flux, and wall wear rate in a 600 MW tangentially fired pulverized coal boiler under variable loads (353 MW, 431 MW, 519 MW, and 600 MW) are investigated in this study employing computational fluid dynamics numerical simulation method. Results demonstrate that increasing the boiler load significantly amplifies gas velocity, wall heat flux, and wall wear rate. The maximum gas velocity in the furnace rises from 20.9 m·s−1 (353 MW) to 37.6 m·s−1 (600 MW), with tangential airflow forming a low-velocity central zone and high-velocity peripheral regions. Meanwhile, the tangential circle diameter expands by ~15% as the load increases. The flue gas temperature distribution exhibits a “low-high-low” profile along the furnace height. As the load increases from 353 MW to 600 MW, the primary combustion zone’s peak temperature rises from 1750 K to 1980 K, accompanied by a ~30% expansion in the coverage area of the high-temperature zone. Wall heat flux correlates strongly with temperature distribution, peaking at 2.29 × 105 W·m−2 (353 MW) and 2.75 × 105 W·m−2 (600 MW) in the primary combustion zone. Wear analysis highlights severe erosion in the economizer due to elevated flue gas velocities, with wall wear rates escalating from 3.29 × 10−7 kg·m−2·s−1 (353 MW) to 1.23 × 10−5 kg·m−2·s−1 (600 MW), representing a 40-fold increase under full-load conditions. Mitigation strategies, including ash removal optimization, anti-wear covers, and thermal spray coatings, are proposed to enhance operational safety. This work provides critical insights into flow field optimization and wear management for large-scale coal-fired boilers under flexible load operation. Full article
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16 pages, 5647 KiB  
Article
Performance Degradation of Ground Source Heat Pump Systems Under Ground Temperature Disturbance: A TRNSYS-Based Simulation Study
by Yeqi Huang, Zhongchao Zhao and Mengke Sun
Energies 2025, 18(15), 3909; https://doi.org/10.3390/en18153909 - 22 Jul 2025
Viewed by 171
Abstract
Ground temperature (GT) variation significantly affects the energy performance of ground source heat pump (GSHP) systems. Both long-term thermal accumulation and short-term dynamic responses contribute to the degradation of the coefficient of performance (COP), especially under cooling-dominated conditions. This study develops a mechanism-based [...] Read more.
Ground temperature (GT) variation significantly affects the energy performance of ground source heat pump (GSHP) systems. Both long-term thermal accumulation and short-term dynamic responses contribute to the degradation of the coefficient of performance (COP), especially under cooling-dominated conditions. This study develops a mechanism-based TRNSYS simulation that integrates building loads, subsurface heat transfer, and dynamic heat pump operation. A 20-year case study in Shanghai reveals long-term performance degradation driven by thermal boundary shifts. Results show that GT increases by over 12 °C during the simulation period, accompanied by a progressive increase in ΔT by approximately 0.20 K and a consistent decline in COP. A near-linear inverse relationship is observed, with COP decreasing by approximately 0.038 for every 1 °C increase in GT. In addition, ΔT is identified as a key intermediary linking subsurface thermal disturbance to efficiency loss. A multi-scale response framework is established to capture both annual degradation and daily operational shifts along the Load–GT–ΔT–COP pathway. This study provides a quantitative explanation of the thermal degradation process and offers theoretical guidance for performance forecasting, operational threshold design, and thermal regulation in GSHP systems. Full article
(This article belongs to the Section B: Energy and Environment)
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13 pages, 3880 KiB  
Article
Low-Velocity Impact Damage Behavior and Failure Mechanism of 2.5D SiC/SiC Composites
by Jianyong Tu, Xingmiao Duan, Xingang Luan, Dianwei He and Laifei Cheng
J. Compos. Sci. 2025, 9(8), 388; https://doi.org/10.3390/jcs9080388 - 22 Jul 2025
Viewed by 206
Abstract
Continuous SiC fiber-reinforced SiC matrix composites (SiC/SiC), as structural heat protection integrated materials, are often used in parts for large-area heat protection and sharp leading edges, and there are a variety of low-velocity impact events in their service. In this paper, a drop [...] Read more.
Continuous SiC fiber-reinforced SiC matrix composites (SiC/SiC), as structural heat protection integrated materials, are often used in parts for large-area heat protection and sharp leading edges, and there are a variety of low-velocity impact events in their service. In this paper, a drop hammer impact test was conducted using narrow strip samples to simulate the low-velocity impact damage process of sharp-edged components. During the test, different impact energies and impact times were set to focus on investigating the low-velocity impact damage characteristics of 2.5D SiC/SiC composites. To further analyze the damage mechanism, computed tomography (CT) was used to observe the crack propagation paths and distribution states of the composites before and after impact, while scanning electron microscopy (SEM) was employed to characterize the differences in the micro-morphology of their fracture surfaces. The results show that the in-plane impact behavior of a 2.5D needled SiC/SiC composite strip samples differs from the conventional three-stage pattern. In addition to the three stages observed in the energy–time curve—namely in the quasi-linear elastic region, the severe load drop region, and the rebound stage after peak impact energy—a plateau stage appears when the impact energy is 1 J. During the impact process, interlayer load transfer is achieved through the connection of needled fibers, which continuously provide significant structural support, with obvious fiber pull-out and debonding phenomena. When the samples are subjected to two impacts, damage accumulation occurs inside the material. Under conditions with the same total energy, multiple impacts cause more severe damage to the material compared to a single impact. Full article
(This article belongs to the Special Issue Functional Composites: Fabrication, Properties and Applications)
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25 pages, 4844 KiB  
Article
Numerical Investigations and Optimized Design of the Active Cooling Performance with Phase Change for Aircraft Rudder Shaft
by Xiangchun Sun, Kaiyan Jin, Kuan Zhao, Hexuan Zhang, Guice Yao and Dongsheng Wen
Appl. Sci. 2025, 15(14), 8105; https://doi.org/10.3390/app15148105 - 21 Jul 2025
Viewed by 202
Abstract
During hypersonic flight, the air rudder shaft can undergo huge aerodynamic heating load, where it is necessary to design the thermal protection system of the air rudder shaft. Aiming to prevent the rudder shaft from thermal failure due to the heat endurance limit [...] Read more.
During hypersonic flight, the air rudder shaft can undergo huge aerodynamic heating load, where it is necessary to design the thermal protection system of the air rudder shaft. Aiming to prevent the rudder shaft from thermal failure due to the heat endurance limit of materials, numerical investigations are conducted systemically to predict the active cooling performance of the rudder shaft with liquid water considering phase change. The validation of the numerical simulation method considering phase-change heat transfer is further investigated by experiments. The effect of coolant injection flow velocity on the active cooling performance is further analyzed for both the steady state and transient state. Finally, to achieve better cooling performance, an optimized design of the cooling channels is performed in this work. The results of the transient numerical simulation show that, employing the initial cooling structures, it may undergo the heat transfer deterioration phenomenon under the coolant injection velocity below 0.2 m/s. For the rudder shaft with an optimized structure, the heat transfer deterioration can be significantly reduced, which significantly reduces the risk of thermal failure. Moreover, the total pressure drop of the optimized rudder shaft under the same coolant injection condition can be reduced by about 19% compared with the initial structure. This study provides a valuable contribution to the thermal protection performance for the rudder shaft, as a key component of aircraft under the aero heating process. Full article
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12 pages, 1442 KiB  
Article
Reversible Binding of Nitric Oxide in a Cu(II)-Containing Microporous Metal-Organic Framework
by Konstantin A. Bikov, Götz Schuck and Peter A. Georgiev
Molecules 2025, 30(14), 3007; https://doi.org/10.3390/molecules30143007 - 17 Jul 2025
Viewed by 231
Abstract
We studied the adsorption thermodynamics and mechanism behind the binding of nitric oxide (NO) in the interior surfaces and structural fragments of the high metal center density microporous Metal-Organic Framework (MOF) CPO-27-Cu, by gas sorption, at a series of temperatures. For the purpose [...] Read more.
We studied the adsorption thermodynamics and mechanism behind the binding of nitric oxide (NO) in the interior surfaces and structural fragments of the high metal center density microporous Metal-Organic Framework (MOF) CPO-27-Cu, by gas sorption, at a series of temperatures. For the purpose of comparison, we also measured the corresponding CO2 adsorption isotherms, and as a result, the isosteric heats of adsorption for the two studied adsorptives were derived, being in the range of 12–15 kJ/mol for NO at loadings up to 0.5 NO molecules per formula unit (f.u.) of the bare compound (C4O3HCu), and 23–25 kJ/mol CO2 in the range 0–1 CO2 per f.u. Microscopically, the mode of NO binding near the square pyramid Cu(II) centers was directly accessed with the use of in situ NO gas adsorption X-ray Absorption Spectroscopy (XAS). Additionally, during the vacuum/temperature activation of the material and consequent NO adsorption, the electronic state of the Cu-species was monitored by observing the corresponding X-ray Near Edge Spectra (XANES). Contrary to the previously anticipated chemisorption mechanism for NO binding at Cu(II) species, we found that at slightly elevated temperatures, under ambient, but also cryogenic conditions, only relatively weak physisorption takes place, with no evidence for a particular adsorption preference to the coordinatively unsaturated Cu-centers of the material. Full article
(This article belongs to the Special Issue Functional Porous Frameworks: Synthesis, Properties, and Applications)
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