Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
8.6
4.6
Journals
Molecules
Special Issues
Functional Porous Frameworks: Synthesis, Properties, and Applications
molecules-logo
Submit to Special Issue Submit Abstract to Special Issue Review for Molecules Propose a Special Issue

Journal Menu

► Journal Menu

Journal Browser

► Journal Browser
share announcement

Functional Porous Frameworks: Synthesis, Properties, and Applications

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: 31 July 2025 | Viewed by 1676

Special Issue Editor

Prof. Dr. Raed Abu-Reziq

E-Mail Website
Guest Editor
Institute of Chemistry, Casali Center of Applied Chemistry, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Givat Ram, Jerusalem 91904, Israel
Interests: nanochemistry; sol-gel chemistry; organometallic chemistry; catalysis; green chemistry; micro- and nanoencapsulation
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Functional porous materials, including mesoporous silica, zeolites, periodic mesoporous organosilicas (PMOs), metal–organic frameworks (MOFs), covalent organic frameworks (COFs), hydrogen-bonded organic frameworks (HOFs), and porous organic polymers (POPs), have garnered significant interest over the past two decades owing to their distinctive properties and versatile applications. A plethora of synthetic strategies has been developed for the purpose of tailoring the pore sizes, structures, shapes, and functionalities of these materials. With their well-defined structures and high surface areas, these materials have been extensively explored for applications such as gas storage, catalysis, drug delivery, separations, environmental remediation, sensor technology, and beyond.

This Special Issue aims to highlight the latest advancements in the synthesis, characterization, properties, and applications of functional porous frameworks.

Prof. Dr. Raed Abu-Reziq
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • metal–organic frameworks
  • covalent organic frameworks
  • mesoporous silica
  • periodic mesoporous organosilicas
  • catalysis
  • biomedical applications
  • energy storage
  • environmental remediation

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • Reprint: MDPI Books provides the opportunity to republish successful Special Issues in book format, both online and in print.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (2 papers)

Download All Papers
Order results
Result details
Show export options expand_more Show export options expand_less
Select all
Export citation of selected articles as:

Research

Jump to: Review

12 pages, 2114 KiB  
Article
Interface-Sensitive Charge Storage and Activation Behavior of Mn(1,3,5-Benzenetricarboxylic Acid (BTC))-Derived Mn3O4/Carbon Cathodes for Aqueous Zinc-Ion Batteries
by Jieun Lee and Byoungnam Park
Molecules 2025, 30(12), 2566; https://doi.org/10.3390/molecules30122566 - 12 Jun 2025
Viewed by 258
Abstract
In this study, we couple precise interface engineering via alternating current electrophoretic deposition (AC–EPD) with performance-enhancing structural transformation via annealing, enabling the development of high-performance, stable, and tunable Mn-based cathodes for aqueous zinc-ion batteries (ZIBs). Using AC–EPD to fabricate Mn(BTC) (BTC = 1,3,5-benzenetricarboxylic [...] Read more.
In this study, we couple precise interface engineering via alternating current electrophoretic deposition (AC–EPD) with performance-enhancing structural transformation via annealing, enabling the development of high-performance, stable, and tunable Mn-based cathodes for aqueous zinc-ion batteries (ZIBs). Using AC–EPD to fabricate Mn(BTC) (BTC = 1,3,5-benzenetricarboxylic acid) cathodes followed by thermal annealing to synthesize MOF-derived Mn3O4 offers a synergistic approach that addresses several key challenges in aqueous ZIB systems. The Mn3O4 cathode prepared via AC–EPD from Mn(BTC) exhibited a remarkable specific capacity of up to 430 mAh/g at a current density of 200 mA/g. Interestingly, the capacity continued to increase progressively with cycling, suggesting dynamic structural or interfacial changes that improved Zn2+ transport and utilization over time. Such capacity enhancement behavior during prolonged cycling at elevated rates has not been observed in previously reported Mn3O4-based ZIB systems. Kinetic analysis further revealed that the charge storage process is predominantly governed by diffusion-controlled mechanisms. This behavior can be attributed to the intrinsic characteristics of the Mn3O4 phase formed from the MOF precursor, where the bulk redox reactions involving Zn2+ insertion require ion migration into the electrode interior. Even though the electrode was processed as an ultrathin film with enhanced electrolyte contact, the charge storage remains limited by solid-state ion diffusion rather than fast surface-driven reactions, reinforcing the diffusion-dominant nature of the system. Full article
(This article belongs to the Special Issue Functional Porous Frameworks: Synthesis, Properties, and Applications)
►▼ Show Figures

Figure 1

Review

Jump to: Research

35 pages, 19883 KiB  
Review
Design and Application of Mesoporous Catalysts for Liquid-Phase Furfural Hydrogenation
by Hyeongeon Lee, Shinjae Lee and Kwangjin An
Molecules 2025, 30(6), 1270; https://doi.org/10.3390/molecules30061270 - 12 Mar 2025
Cited by 1 | Viewed by 753
Abstract
Furfural (FAL), a platform molecule derived from biomass through acid-catalyzed processes, holds significant potential for producing various value-added chemicals. Its unique chemical structure, comprising a furan ring and an aldehyde functional group, enables diverse transformation pathways to yield products such as furfuryl alcohol, [...] Read more.
Furfural (FAL), a platform molecule derived from biomass through acid-catalyzed processes, holds significant potential for producing various value-added chemicals. Its unique chemical structure, comprising a furan ring and an aldehyde functional group, enables diverse transformation pathways to yield products such as furfuryl alcohol, furan, tetrahydrofuran, and other industrially relevant compounds. Consequently, optimizing catalytic processes for FAL conversion has garnered substantial attention, particularly in selectivity and efficiency. The liquid-phase hydrogenation of FAL has demonstrated advantages, including enhanced catalyst stability and higher product yields. Among the catalysts investigated, mesoporous materials have emerged as promising candidates because of their high surface area, tunable pore structure, and ability to support highly dispersed active sites. These attributes are critical for maximizing the catalytic performance across various reactions, including FAL hydrogenation. This review provides a comprehensive overview of recent advances in mesoporous catalyst design for FAL hydrogenation, focusing on synthesis strategies, metal dispersion control, and structural optimization to enhance catalytic performance. It explores noble metal-based catalysts, particularly highly dispersed Pd systems, as well as transition-metal-based alternatives such as Co-, Cu-, and Ni-based mesoporous catalysts, highlighting their electronic structure, bimetallic interactions, and active site properties. Additionally, metal–organic frameworks are introduced as both catalysts and precursors for thermally derived materials. Finally, key challenges that require further investigation are discussed, including catalyst stability, deactivation mechanisms, strategies to reduce reliance on external hydrogen sources, and the impact of solvent effects on product selectivity. By integrating these insights, this review provides a comprehensive perspective on the development of efficient and sustainable catalytic systems for biomass valorization. Full article
(This article belongs to the Special Issue Functional Porous Frameworks: Synthesis, Properties, and Applications)
►▼ Show Figures

Graphical abstract

Show export options expand_more Show export options expand_less
Select all
Export citation of selected articles as:
 
Displaying articles 1-2
Back to TopTop