Search Results (393)

The Cuitzeo Groundwater Flow System, located in central Mexico within a volcanic rock region, encompasses two of the largest lakes in the country: Lake Cuitzeo and Lake Pátzcuaro. These lakes are sustained by both surface water and groundwater discharge, playing a critical role in local ecosystems and the surrounding population. Groundwater is particularly important for maintaining the lakes’ existence. However, the behavior of the groundwater flow system in this region has not been previously described. This study compiles historical data from 170 groundwater sites within the system from different years and includes temperature (°C), pH, total dissolved solids (TDS), major ions, and geology in detail. The historical data provide a spatial analysis and initial characterization to study the hydrochemistry of the system, identify recharge and discharge zones, assess water-rock interaction processes, and trace the evolution of groundwater. The results highlight distinct chemical behaviors across the different zones of the study area, with the most notable being ion exchange consistent with the weathering of volcanic silicates and interaction with lacustrine sediments. This study is crucial as it offers valuable insights into the hydrochemistry and water levels of the groundwater flow system and highlights areas where additional data are needed to better understand its dynamics. Full article

Groundwater–surface water interactions were investigated in the Highwood River (3952 km²) and Sheep River watersheds (1568 km²), originating in the Rocky Mountains headwaters of the South Saskatchewan River (Alberta, Canada), to improve understanding of hydrological processes that potentially influence water use and vulnerability to climatic change in representative, alpine-fed mixed-use watersheds. Similar to adjacent regions of the Bow, Red Deer and Oldman watersheds, the upper reaches of these watersheds are sparsely populated with significant seasonal glacier and snowmelt influence, while the lower watersheds are currently under increasing water supply pressure from competing agricultural–municipal interests, with notable risk of flooding during high-flow events and drought during the growing season. Investigations included mapping of hydrologic and hydrogeologic controls (aquifers, buried channels, colluvial deposits, etc.,) and synoptic geochemical and isotopic surveys (δ²H, δ¹⁸O, δ¹³C-DIC, ²²²Rn) to characterize evolution in water type and seasonal progression in streamflow sources and underlying mechanisms. Our findings confirm seasonal progression in streamflow water sources, characterized by a pronounced snowmelt-dominated spring freshet, but with a sustained recession fed by colluvial, moraine, fluvial, and fractured bedrock sources. Seasonal isotopic variations establish that shallow groundwater sources are actively maintained throughout the spring freshet, often accounting for a dominant portion of streamflow, which indicates active displacement of groundwater storage by snowmelt recharge during spring melt. The contrast in the proportion of alpine contributions in each watershed suggests these systems may respond very differently to climate change, which needs to be carefully considered in developing sustainable water-use strategies for each watershed. Full article

This study develops a conjunctive-use framework that couples a surface water allocation model with the MODFLOW groundwater model to evaluate the interactions between surface water operations and groundwater recharge and pumping. The framework enables coordinated surface–groundwater management through iterative feedback between allocation decisions and groundwater responses. Three representative managed aquifer recharge cases in Taiwan are examined, each reflecting a distinct operational logic: (1) a space-for-time strategy that extends wet-season benefits through distributed recharge using irrigation surplus; (2) a centralized support–distributed feedback approach in subsidence-prone areas, where concentrated surface water is delivered to targeted zones while maintaining flexibility for upstream allocation; and (3) a time-for-volume mechanism that converts short-duration flood events into stable, long-term baseflow supply. The simulation results show that these strategies reduce downstream irrigation deficit ratios (e.g., from 0.58 to 0.22), raise groundwater levels by up to approximately 3.5 m in subsidence-sensitive zones, and substantially enhance drought resilience by reducing extreme reservoir depletion during prolonged dry periods. Overall, the proposed framework provides quantitative evidence and a practical planning tool for surface water-oriented conjunctive use, supporting more sustainable and resilient multi-source water management. Full article

The behavior of the carbon cycle within the Land-Ocean Aquatic Continuum (LOAC) is shaped not only by aquatic processes but also by chemical interactions occurring at the atmosphere–water interface. In particular, the transport of acid rain precursors such as SO₂ and NO_x to surface waters via deposition can alter the water’s pH balance, thereby affecting Dissolved Inorganic Carbon (DIC) fractions and CO₂ emission potential. In this study, air quality measurements from three monitoring stations (Bosna, Karatay, and Meram) in Konya province of Türkiye, along with precipitation and temperature data from a representative meteorological station for the period 2021–2023, were analyzed using the Mann–Kendall Trend Test. Additionally, seasonal pH values of groundwater were examined, and their trends were compared with those of the other variables. The findings reveal striking differences on a station basis. At the Bosna station, while NO (Z = 10.80), NO₂ (Z = 9.47), and NO_x (Z = 10.04) showed strong increasing trends, O₃ decreased significantly (Z = −15.14). At the Karatay station, significant increasing trends were detected for CO (Z = 10.01), PM₁₀ (Z = 8.59), SO₂ (Z = 5.55), and NO_x (Z = 2.44), whereas O₃ exhibited a negative trend (Z = −6.54). At the Meram station, a significant decrease was observed in CO (Z = −11.63), while NO₂ showed an increasing trend (Z = 3.03). Analysis of meteorological series indicated no significant trend in precipitation (Z = −0.04), but a distinct increase in temperature (Z = 2.90, p < 0.01). These findings suggest that the increasing NO_x load in the Konya atmosphere accelerates O₃ consumption and, combined with rising temperatures, creates a potential for change in the carbon chemistry of aquatic systems. The results demonstrate that atmospheric pollutant trends constitute an indirect but significant pressure factor on the aquatic carbon cycle in semi-arid regions and highlight the necessity of integrating atmospheric processes into carbon budget analyses within the scope of LOAC. Full article

For an alpine inland river basin affected by climate change, the interaction between groundwater (GW) and surface water (SW) within the watershed plays a crucial role in water resource management. To explore the bidirectional dynamic coupling of surface water and groundwater, this work adopted the extensively employed SWAT–MODFLOW model. Results indicate that statistical parameters including R² (0.81 for calibration periods and 0.79 for validation), NSE (0.79 for calibration periods and 0.75 for validation), RMSE (0.59~1.25 m), and PBIAS (15.21%) demonstrate the dependability of the SWAT–MODFLOW model in evaluating groundwater–surface water exchange processes within alpine inland river basins. Long-term monitoring data show that groundwater levels exhibited an upward trend, rising from 2895.35 m in 2005 to 2906.75 m in 2022. Notably, since 2018, groundwater levels have entered a period of being consistently above the long-term average. In terms of spatial distribution, the groundwater level patterns in 2005, 2010, and 2015 remained relatively consistent, marked by a west-to-east decreasing gradient. However, by 2020, this spatial distribution pattern shifted, marked by an east-to-west decreasing gradient. Meanwhile, our results reveal a pattern of upstream surface water recharge, bidirectional fluctuation in the middle reaches, and downstream groundwater-dominated recharge during the period of 2000~2023. During the 2000–2009 period, groundwater in sub5 received recharge from surface water, with the exchange rate ranging from −4987.75 to −374.82 m³/d. Conversely, during 2010–2023, groundwater in sub5 discharged into surface water, with the exchange rate ranging from 1136.75 to 56,646.56 m³/d. Moreover, there is seasonal variability in the SW–GW interchange relationship. In spring and summer, surface water primarily replenishes groundwater, whereas in autumn and winter, groundwater primarily replenishes surface water. This study provides a foundational method for assessing groundwater–surface water interactions in alpine inland river basins, which will contribute to the evaluation and management of local water resources. Full article

Groundwater is one of the main sources of water supply in tropical developing countries; however, its integrated management is often constrained by limited hydrogeological information and increasing anthropogenic pressures on aquifer systems. This study presents the numerical modeling of groundwater flow in the Neogene–Quaternary aquifer system of the Middle Magdalena Valley (Colombia), focusing on the rural area of Puerto Wilches, which is characterized by strong surface–groundwater interactions, particularly with the Yarirí wetland and the Magdalena River. A three-dimensional model was implemented and calibrated in FEFLOW v.8.1 under steady-state and transient conditions, integrating both primary and secondary data. The dataset included piezometric levels measured with water level meters and automatic loggers, hydrometeorological records, 21 physicochemical and microbiological parameters analyzed in 45 samples collected during three field campaigns under contrasting hydrological conditions, 79 pumping tests, detailed lithological columns from drilled wells, and complementary geological and geophysical models. The results indicate a predominant east–west groundwater flow from the Eastern Cordillera toward the Magdalena River, with seasonal recharge and discharge patterns controlled by the bimodal rainfall regime. Microbiological contamination (total coliforms in 69% of groundwater samples) and nitrate concentrations above 10 mg/L in 21% of wells were detected, mainly due to agricultural fertilizers and domestic wastewater infiltration. Particle tracking revealed predominantly horizontal flow paths, with transit times of up to 800 years in intermediate units of the Real Group and around 60 years in shallow Quaternary deposits, highlighting the differential vulnerability of the system to contamination. These findings provide scientific foundations for strengthening integrated groundwater management in tropical regions under agroindustrial and hydrocarbon pressures and emphasize the need to consolidate monitoring networks, promote sustainable agricultural practices, and establish preventive measures to protect groundwater quality. Full article

Soil salinization is an escalating global concern threatening agricultural productivity and ecological sustainability, particularly in coastal regions where complex interactions among hydrological, climatic, and anthropogenic factors govern salt accumulation. The vertical differentiation and spatial heterogeneity of salinity drivers remain poorly resolved. We present an integrated modeling framework combining ensemble machine learning and spatial statistics to investigate the depth-specific dynamics of soil salinity in the Yellow River Delta, a vulnerable coastal agroecosystem. Using multi-source environmental predictors and 220 field samples harmonized to 30 m resolution, the hybrid Gray Wolf Optimizer–Random Forest–XGBoost model achieved high predictive accuracy for surface salinity (R² = 0.91, RMSE = 0.03 g/kg, MAE = 0.02 g/kg). Spatial autocorrelation analysis (Global Moran’s I = 0.25, p < 0.01) revealed pronounced clustering of high-salinity hotspots associated with seawater intrusion pathways and capillary rise. The results reveal distinct vertical control mechanisms: vegetation indices and soil water content dominate surface salinity, while total dissolved solids (TDS), pH, and groundwater depth increasingly influence middle and deep layers. By applying SHAP (SHapley Additive Explanations), we quantified nonlinear feature contributions and ranked key predictors across layers, offering mechanistic insights beyond conventional correlation. Our findings highlight the importance of depth-specific monitoring and intervention strategies and demonstrate how explainable machine learning can bridge the gap between black-box prediction and process understanding. This framework offers a generalizable framework that can be adapted to other coastal agroecosystems with similar hydro-environmental conditions. Full article

Saltwater intrusion increasingly jeopardizes groundwater in low-lying coastal plains worldwide, where the combined effects of sea-level rise, land subsidence, and hydraulic regulation further exacerbate aquifer vulnerability and threaten the long-term sustainability of freshwater supplies. To move beyond sparse and fragmented piezometric observations, we propose “integrated coastal supersites”: wells equipped with multiparametric sensors and multilevel piezometers that couple high-resolution vertical conductivity–temperature–depth (CTD) profiling with continuous hydro-meteorological time series to monitor the hydrodynamic behavior of coastal aquifers and saltwater intrusion. This study describes the installation of two supersites and presents early insights from the first monitoring period, which, despite a short observation window limited to the summer season (July–September 2025), demonstrate the effectiveness of this approach. Two contrasting supersites were deployed in the coastal plain between the Brenta and Adige Rivers (Italy): Gorzone, characterized by a thick, laterally persistent aquitard, and Buoro, where the aquitard is thinner and discontinuous. Profiles and fixed sensors at both sites reveal a consistent fresh-to-saline transition in the phreatic aquifers and a secondary freshwater lens capping the confined systems. At Gorzone, the confining layer hydraulically isolates the deeper aquifer, preserving low salinity beneath a saline, tidally constrained phreatic zone. Groundwater heads oscillate by about 0.2 m, and rainfall events do not dilute salinity; instead, pressure transients—amplified by drainage regulation and inland-propagating tides—induce short-lived EC increases via upconing. Buoro shows smaller water-level variations, not always linked to rainfall, and, in contrast, exhibits partial vertical connectivity and faster dynamics: phreatic heads respond chiefly to internal drainage and local recharge, with rises rapidly damped by pumping, while salinity remains steady without episodic peaks. The confined aquifer shows buffered, delayed responses to surface forcings. Although the monitoring window is currently limited to 2025 through the summer season, these results offer compelling evidence that coastal supersites are reliable, scalable, and management-critical relevance platforms for groundwater calibration, forecasting, and long-term assessment. Full article

In coastal regions, the interaction between freshwater and seawater creates a dynamic system in which the spatial distribution of salinity critically constrains the use of freshwater for human consumption. Although saline intrusion is a globally widespread phenomenon, its inland extent varies significantly with hydrological conditions, posing a persistent threat to groundwater quality and sustainability. This study aimed to characterize salinity distribution using an integrated karst-watershed approach, thereby enabling the identification of both lateral and vertical salinity gradients. The study area is in the northwestern Yucatan Peninsula. Available hydrogeological data were analyzed to determine aquifer type, soil texture, evidence of saline intrusion, seawater fraction, vadose zone thickness, and field measurements. These included sampling from 42 groundwater sites (open sinkholes and dug wells), which indicated a fringe zone approximately 5 km in size influenced by seawater interaction, in mangrove areas and in three key zones of salinity patterns: west of Mérida (Celestun and Chunchumil), and northern Yucatan (Sierra Papacal, Motul, San Felipe). Vertical Electrical Sounding (VES) and conductivity profiling in two piezometers indicated an apparent seawater influence. The interface was detected at a depth of 28 m in Celestun and 18 m in Chunchumil. These depths may serve as hydrogeological thresholds for freshwater abstraction. Results indicate that saltwater can extend several kilometers inland, a factor to consider when evaluating freshwater availability. This issue is particularly critical within the first 20 km from the coastline, where increasing tourism exerts substantial pressure on groundwater reserves. A coastal-to-inland salinity was identified, and an empirical equation was proposed to estimate the seawater fraction (fsea%) as a function of distance from the shoreline in the Cenote Ring trajectory. Vertically, a four-layer model was identified in this study through VES in the western watershed: an unsaturated zone approximately 2.6 m thick, a confined layer in the coastal Celestun profile about 9 m thick, a freshwater lens floating above a brackish layer between 8 and 25 m, and a saline interface at 37 m depth. The novelty of this study, in analyzing all karstic water surfaces together as a system, including the vadose zone and the aquifer, and considering the interactions with the surface, is highlighted by the strength of this approach. This analysis provides a better understanding and more precise insight into the integrated system than analyzing each component separately. These findings have significant implications for water resource management in karst regions such as Yucatan, underscoring the urgent need for sustainable groundwater management practices to address seawater intrusion. Full article

Terrestrial water storage includes soil water storage, groundwater storage, surface water storage, snow water equivalent, plant canopy water storage, biological water storage, etc., which can comprehensively reflect the total change in water volume during processes such as precipitation, evapotranspiration, runoff, and human water use in the basin hydrological cycle. The Gravity Recovery and Climate Experiment (GRACE) satellite provides a powerful tool and a new approach for observing changes in terrestrial water storage and groundwater storage. The North China Plain (NCP) is a major agricultural region in the northern arid area of China, and long-term overexploitation of groundwater has led to increasingly prominent ecological vulnerability issues. This study uses GRACE and Global Land Data Assimilation System (GLDAS) hydrological model data to assess the spatiotemporal patterns of groundwater drought in the NCP and its various sub-regions from 2003 to 2022, identify the locations, occurrence probabilities, and confidence intervals of seasonal and trend mutation points, quantify the complex interactive effects of multiple climate factors on groundwater drought, and reveal the propagation time from groundwater drought to agricultural drought. The results show that: (1) from 2003 to 2022, the linear tendency rate of groundwater drought index (GDI) was −0.035 per 10 years, indicating that groundwater drought showed a gradually worsening trend during the study period; (2) on an annual scale, the most severe groundwater drought occurred in 2021 (GDI = −1.59). In that year, the monthly average GDI in the NCP ranged from −0.58 to −2.78, and the groundwater drought was most severe in July (GDI = −2.02); (3) based on partial wavelet coherence, the best univariate, bivariate for groundwater drought were soil moisture (PASC = 19.13%); and (4) in Beijing, Tianjin and Hebei, the propagation time was mainly concentrated in 1–5 months, with average lag times of 2.87, 3.20, and 2.92 months, respectively. This study can not only reduce and mitigate the harm of groundwater drought to agricultural production, social life, and ecosystems by monitoring changes in groundwater storage, but also provide a reference for the quantitative identification of the dominant factors of groundwater drought. Full article

Groundwater resources in Jordan are under severe stress due to rapidly increasing water demand and over-abstraction that far exceeds natural replenishment. In addition, water quality is threatened by pollution from the misuse of fertilizers and pesticides, leakage from septic tanks, and illegal waste disposal. This study focuses on the Aqeb, Corridor, and Special Economic Zone wellfields, where hydrological and hydrochemical investigations were carried out. A total of 36 groundwater samples were collected and analyzed for hydrochemical composition, stable isotopes of oxygen (δ¹⁸O) and hydrogen (δ²H), and trace elements. In addition, two exploration 2D seismic profiles crossing the study area were interpreted, providing critical insights into the activity of the subsurface Fuluk Fault zone and its relationship with the wellfields. The hydrochemical results reveal elevated total dissolved solids and nitrate concentrations, accompanied by more depleted δ¹⁸O and δ²H values in wells located in the central part of the study area. Three distinct hydrochemical groups were identified within the same aquifer, indicating heterogeneity in groundwater chemistry that reflects variations in recharge conditions, flow paths, and geochemical processes. The first group (high Na/Cl with low salinity) likely represents recently recharged waters with limited rock–water interaction. The second group (intermediate Na/Cl and moderate salinity) may be influenced by evaporation, irrigation return flow, or cation exchange. The third group (low Na/Cl with high salinity) suggests the dissolution of sulfate minerals or mixing with deeper mineralized groundwater, possibly facilitated by structural features such as the Fuluk Fault. Seismic interpretation indicates several active near-surface fault systems that are likely to serve as preferential pathways for salinity and nitrate enrichment, linked to intensive agricultural activities and wastewater leakage from nearby septic tanks. The findings emphasize the combined influence of geochemical processes, excessive groundwater abstraction, and structural features in controlling water quality in the region. Full article

The presented work is a logical continuation of the study of the chemical composition of the Lovozero district waters (the Kola Peninsula, Russia), an area inhabited by indigenous populations. The problem was posed due to the discovery of rare earth elements in drinking water in the Lovozero district (the Krasnoshchelye village). For monitoring, inductively coupled plasma was used, and the “water–rock” interaction was studied using “Selector” software. The results showed the Western Keivy Massif influence on the chemical composition of natural waters, which are used for drinking purposes for humans and animals. The interaction of water with magmatic rocks such as gabbro and subalkaline granites also leads to the formation of some major cations, anions, and heavy metals. Li, Sr, Y, La, and Ce concentrations are higher than in the Central’niy water intake located within the Khibiny Massif. The results of the modeling demonstrate the high migration capabilities of rare earth elements. The presence of rare elements and REEs in drinking surface and groundwaters, if consumed on a regular basis, can cause diseases of the nervous system and other organs. Full article

Concrete-lined river channels are generally assumed to prevent groundwater exchange, functioning as inert conduits that isolate surface flow. Along the Upper Los Angeles River of Southern California, United States, however, field observations show that during dry summer months, groundwater seepage contributes nearly half of the dry-weather flow to a 9.5-km concrete-lined reach above Sepulveda Basin. This baseflow substantially modifies river chemistry, diluting some solutes while enriching others. To characterize these interactions, hydrochemical sampling was conducted in summer 2022, with additional selenium and tritium analyses from 2024 to 2025, covering tributaries, river sites, groundwater seeps, wastewater discharges, and tap water. Analyses included major ions, nutrients, selenium, and tritium. Upstream tributaries were highly saline (TDS ≈ 1670 mg/L; sulfate up to 980 mg/L; chloride ≈ 280 mg/L), whereas groundwater was moderately saline (TDS 990 to 1765 mg/L) but contained elevated nitrate-nitrogen (5.8 to 12.9 mg/L) and selenium (4.5–44.0 µg/L). Mixing analysis indicated that approximately 45% of the river’s dry-weather flow (~70.5 L/s) originated from groundwater, increasing riverine selenium above the 5 µg/L aquatic-life criterion. Downstream, where the concrete lining ends, wastewater inflows from the Donald C. Tillman Water Reclamation Plant reduced salinity but introduced additional nitrate-nitrogen. The results reveal a three-part sequence; saline tributary inputs at the headwaters, groundwater-driven nitrate and selenium enrichment within the lined reach, and effluent dilution downstream. These findings demonstrate that even concrete-lined channels can host active groundwater–surface water exchange, highlighting the need to incorporate such interactions in urban river management and channel design. Full article

Fluoride contamination in groundwater is a pressing environmental and public health issue, with chronic exposure linked to skeletal and dental fluorosis. Here, we report the synthesis of magnesium oxide nanoparticles via a controlled co-precipitation method employing dimethylformamide (DMF) as solvent and either ammonium hydroxide (MgO-1) or ammonium carbonate (MgO-2) as precipitating agents. The resulting materials were comprehensively characterized using thermogravimetric analysis (TGA/DSC), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS). Additionally, BET surface area and porosity analyses revealed mesoporous structures, with MgO-1 showing a slightly higher surface area (14.12 m² g⁻¹) than MgO-2 (13.87 m² g⁻¹). Both MgO-1 and MgO-2 exhibited high crystallinity, nanoscale particle sizes (81.6 nm and 128.1 nm, respectively), and distinct morphological features. Batch adsorption studies revealed maximum fluoride uptake capacities of 117.6 mg/g (MgO-1) and 94.5 mg/g (MgO-2) at neutral pH, with MgO-1 exhibiting superior performance due to its smaller particle size and higher specific surface area. Fluoride removal remained above 98% between pH 3–9, confirming stability across a wide pH range, with a minor decline at pH 11 due to OH⁻ competition. Adsorption equilibrium data were best described by the Temkin isotherm model, suggesting heterogeneous surface interactions and an exothermic process, while kinetic analyses indicated pseudo-second-order behavior for MgO-1 and pseudo-first-order for MgO-2. Both materials maintained high fluoride selectivity in the presence of competing anions and successfully reduced fluoride in tap water from 2.11 mg/L to below the WHO limits without altering water hardness. These findings underscore the potential of engineered MgO nanomaterials as efficient, selective, and sustainable adsorbents for water defluoridation, offering a promising pathway toward scalable remediation technologies in fluoride-affected regions. Full article