Marine Karst Systems: Hydrogeology and Marine Environmental Dynamics

A special issue of Journal of Marine Science and Engineering (ISSN 2077-1312). This special issue belongs to the section "Geological Oceanography".

Deadline for manuscript submissions: 10 February 2026 | Viewed by 1442

Special Issue Editors


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Guest Editor
CSIC-IGME—Instituto Geológico y Minero de España, Madrid, Spain
Interests: karst geomorphology; costal sedimentology; marine pollution
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Guest Editor
CSIC—Centro Oceanográfico de Illes Balears (COB-IEO), Madrid, Spain
Interests: marine litter; coastal ecosystems; marine ecology
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Special Issue Information

Dear Colleagues,

Marine environment and coastal karst systems are diverse and highly dynamic, with direct interactions between the sea, the coast, and the land. There is exemplified across the planet, but the most interesting vital factors in the subsistence of ecosystems and habitats are coastal karst aquifers. The groundwater in these aquifers is in constant dynamic equilibrium with seawater. Any change in recharge or discharge, natural or otherwise, can modify this dynamic and alter the ecosystems that inhabit this area. Furthermore, the hydrogeology of these systems is complex since part of their relationship with the marine environment depends on the hierarchy of conduits that control the transit of groundwater, which is subsequently discharged into the sea. Furthermore, hydrogeological sites in contact with the sea are excellent proxies for research into climate change and the rise in sea level. The groundwater in these aquifers respond inertially and very rapidly to marine oscillations, whether through a rise in the water table, an increase in temperature, or alterations in the natural chemistry of the groundwater in these aquifers. Therefore, seawater intrusion is a very reliable indicator of sea level rise and, therefore, of a change in water chemistry. The salinization of these environments is probably one of the processes that most severely harms the planet's freshwater. Added to this is water pollution caused by human activities, as marine water, sediments and coastal areas are among the areas most subject to human pressure. Recent research highlights how coastal aquifer waters and marine coastal water contain high concentrations of heavy metals, microplastics, pathogens, and even viruses. Hydrogeology in marine karst systems serves as an excellent laboratory for the study of macro and microscopic life, since both the marine zone in contact with the coast and the subterranean zone of coastal aquifers contain unique ecosystems that survive thanks to the physicochemical characteristics of these environments. Marine karst systems controlled by hydrogeological dynamics and seawater are also noteworthy, such as wetlands, caves, underwater springs, or marine ecosystems. The rich hydrogeological marine karst heritage includes is expressed in the largest coastal cavities on the planet, Sac Actun or Ox Bel Ha (Mexico), the subaquatic springs near coastal reefs, lagoons, and wetland areas such as the Albufera of Mallorca and the Cabrera National Park, where caves, springs, endokarstic lakes, interesting coastal aquifers, and a pristine marine water environment can be found.

Dr. Pedro Robledo-Ardila
Dr. Carme Alomar
Guest Editors

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Keywords

  • coastal aquifers
  • groundwater dynamics
  • marine dynamics
  • groundwater pollution
  • marine pollution
  • marine sediments pollution
  • climate change
  • sea level oscillation
  • coastal caves
  • springs
  • wetlands
  • marine environmental and hydrogeological relationship
  • protected marine karst areas
  • seawater intrusion
  • marine ecosystems
  • marine habitats driven by hydrogeology
  • karst marine heritage
  • sedimentary processes in marine karst system

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Published Papers (2 papers)

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Research

21 pages, 5733 KB  
Article
Salinity Distribution as a Hydrogeological Limit in a Karstic Watershed in Yucatan
by Iris Neri-Flores, Ojilve Ramón Medrano-Pérez, Flor Arcega-Cabrera, Ismael Mariño-Tapia, César Canul-Macario and Pedro Agustín Robledo-Ardila
J. Mar. Sci. Eng. 2025, 13(12), 2317; https://doi.org/10.3390/jmse13122317 - 6 Dec 2025
Viewed by 560
Abstract
In coastal regions, the interaction between freshwater and seawater creates a dynamic system in which the spatial distribution of salinity critically constrains the use of freshwater for human consumption. Although saline intrusion is a globally widespread phenomenon, its inland extent varies significantly with [...] Read more.
In coastal regions, the interaction between freshwater and seawater creates a dynamic system in which the spatial distribution of salinity critically constrains the use of freshwater for human consumption. Although saline intrusion is a globally widespread phenomenon, its inland extent varies significantly with hydrological conditions, posing a persistent threat to groundwater quality and sustainability. This study aimed to characterize salinity distribution using an integrated karst-watershed approach, thereby enabling the identification of both lateral and vertical salinity gradients. The study area is in the northwestern Yucatan Peninsula. Available hydrogeological data were analyzed to determine aquifer type, soil texture, evidence of saline intrusion, seawater fraction, vadose zone thickness, and field measurements. These included sampling from 42 groundwater sites (open sinkholes and dug wells), which indicated a fringe zone approximately 5 km in size influenced by seawater interaction, in mangrove areas and in three key zones of salinity patterns: west of Mérida (Celestun and Chunchumil), and northern Yucatan (Sierra Papacal, Motul, San Felipe). Vertical Electrical Sounding (VES) and conductivity profiling in two piezometers indicated an apparent seawater influence. The interface was detected at a depth of 28 m in Celestun and 18 m in Chunchumil. These depths may serve as hydrogeological thresholds for freshwater abstraction. Results indicate that saltwater can extend several kilometers inland, a factor to consider when evaluating freshwater availability. This issue is particularly critical within the first 20 km from the coastline, where increasing tourism exerts substantial pressure on groundwater reserves. A coastal-to-inland salinity was identified, and an empirical equation was proposed to estimate the seawater fraction (fsea%) as a function of distance from the shoreline in the Cenote Ring trajectory. Vertically, a four-layer model was identified in this study through VES in the western watershed: an unsaturated zone approximately 2.6 m thick, a confined layer in the coastal Celestun profile about 9 m thick, a freshwater lens floating above a brackish layer between 8 and 25 m, and a saline interface at 37 m depth. The novelty of this study, in analyzing all karstic water surfaces together as a system, including the vadose zone and the aquifer, and considering the interactions with the surface, is highlighted by the strength of this approach. This analysis provides a better understanding and more precise insight into the integrated system than analyzing each component separately. These findings have significant implications for water resource management in karst regions such as Yucatan, underscoring the urgent need for sustainable groundwater management practices to address seawater intrusion. Full article
(This article belongs to the Special Issue Marine Karst Systems: Hydrogeology and Marine Environmental Dynamics)
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17 pages, 6537 KB  
Article
Diagenetic Barite Growths in the Mixing Zone of a Carbonate Coastal Aquifer
by Fernando Sola, Malva Mancuso and Ángela Vallejos
J. Mar. Sci. Eng. 2025, 13(11), 2090; https://doi.org/10.3390/jmse13112090 - 3 Nov 2025
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Abstract
Mixing zones in carbonate coastal aquifers are dynamic interfaces where freshwater and seawater converge, triggering complex biogeochemical processes. This study investigates diagenetic barite (BaSO4) precipitation within such a mixing zone in the dolomitic aquifer of the Sierra de Gádor (SE Spain). [...] Read more.
Mixing zones in carbonate coastal aquifers are dynamic interfaces where freshwater and seawater converge, triggering complex biogeochemical processes. This study investigates diagenetic barite (BaSO4) precipitation within such a mixing zone in the dolomitic aquifer of the Sierra de Gádor (SE Spain). Three sectors were analyzed: two active mixing zones—one associated with submarine discharge and the other affected by marine intrusion—and an uplifted, fossilized Pleistocene mixing zone. Mineralogical, petrographic, and geochemical analyses reveal extensive dissolution of the dolomitic bedrock, forming polygonal voids and fracture-controlled porosity, frequently covered by Fe and Mn oxides. Barite crystals were identified exclusively in the Fe oxide precipitates at depths where 80% of seawater is reached. The saturation index for barite in groundwater suggests near-equilibrium conditions across the fresh–brackish–saline transition; however, barite precipitation is localized where Fe oxides act as a geochemical barrier, concentrating Ba and enabling nucleation. SEM imaging shows well-formed euhedral barite crystals up to 100 µm in size. This form of crystallization would be similar to the marine diagenetic barite formation models involving organic matter degradation and Ba remobilization, translated to a coastal aquifer setting in this study. Trace metal analyses show significant enrichment of Pb (up to 20 wt%) and other elements (Zn, Ni, and Co), suggesting potential for ore-forming processes if redox conditions shift. This work proposes a conceptual model for diagenetic barite formation in coastal aquifers, emphasizing the role of Fe and Mn oxides as reactive substrates in metal cycling at the land–sea interface. Full article
(This article belongs to the Special Issue Marine Karst Systems: Hydrogeology and Marine Environmental Dynamics)
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