Search Results (228)

Co-firing large-sized straw biomass in pulverized coal boilers is a potential pathway for carbon emission reduction in China’s thermal power plants. However, experimental data on large-sized straw combustion under pulverized coal boiler combustion conditions are critically lacking. This study selected typical large-sized wheat straw particles. Employing a two-mode experimental setup in a drop tube furnace (DTF) system simulating pulverized coal boiler conditions, we systematically investigated the combustion behavior and alkali metal release characteristics of this large-sized straw biomass, with combustion processes summarized for diverse particle types. The findings reveal asynchronous combustion progression across particle surfaces due to heterogeneous mass transfer and gas diffusion; unique behaviors distinct from denser woody biomass, including bending deformation, fiber branching, and fragmentation, occur; significant and morphology-specific deformations occur during devolatilization; fragmentation universally produces particles of varied shapes (needle-like, flaky, blocky, semi-tubular) during char combustion; and potassium release exceeds 35% after complete devolatilization and surpasses 50% at a burnout degree exceeding 80%. This work provides essential experimental data on the fundamental combustion characteristics and alkali metal release of large-sized wheat straw particles under pulverized coal boiler combustion conditions, offering engineering application guidance for the direct co-firing of large-sized flexible straw biomass in pulverized coal boilers. Full article

To compensate for the instability of renewable energy sources during China’s energy transition, large thermal power plants must provide critical operational flexibility, primarily through deep peaking. To investigate the combustion performance and wear and tear of a 600 MW pulverized coal boiler under deep peaking, the gas–solid flow characteristics and distributions of flue gas temperature, wall heat flux, and wall wear rate in a 600 MW tangentially fired pulverized coal boiler under variable loads (353 MW, 431 MW, 519 MW, and 600 MW) are investigated in this study employing computational fluid dynamics numerical simulation method. Results demonstrate that increasing the boiler load significantly amplifies gas velocity, wall heat flux, and wall wear rate. The maximum gas velocity in the furnace rises from 20.9 m·s⁻¹ (353 MW) to 37.6 m·s⁻¹ (600 MW), with tangential airflow forming a low-velocity central zone and high-velocity peripheral regions. Meanwhile, the tangential circle diameter expands by ~15% as the load increases. The flue gas temperature distribution exhibits a “low-high-low” profile along the furnace height. As the load increases from 353 MW to 600 MW, the primary combustion zone’s peak temperature rises from 1750 K to 1980 K, accompanied by a ~30% expansion in the coverage area of the high-temperature zone. Wall heat flux correlates strongly with temperature distribution, peaking at 2.29 × 10⁵ W·m⁻² (353 MW) and 2.75 × 10⁵ W·m⁻² (600 MW) in the primary combustion zone. Wear analysis highlights severe erosion in the economizer due to elevated flue gas velocities, with wall wear rates escalating from 3.29 × 10⁻⁷ kg·m⁻²·s⁻¹ (353 MW) to 1.23 × 10⁻⁵ kg·m⁻²·s⁻¹ (600 MW), representing a 40-fold increase under full-load conditions. Mitigation strategies, including ash removal optimization, anti-wear covers, and thermal spray coatings, are proposed to enhance operational safety. This work provides critical insights into flow field optimization and wear management for large-scale coal-fired boilers under flexible load operation. Full article

Based on the low-carbon transition needs of coal-fired boilers, this study conducted industrial trials of direct biomass co-firing on a 620 t/h high-temperature, high-pressure circulating fluidized bed (CFB) boiler, gradually increasing the co-firing ratio. It used compressed biomass pellets, achieving stable 20 wt% (weight percent) operation. By analyzing boiler parameters and post-shutdown samples, the comprehensive impact of biomass co-firing on the boiler system was assessed. The results indicate that biomass pellets were blended with coal at the last conveyor belt section before the furnace, successfully ensuring operational continuity during co-firing. Further, co-firing biomass up rates of to 20 wt% do not significantly impact the fuel combustion efficiency (gaseous and solid phases) or boiler thermal efficiency and also have positive effects in reducing the bottom ash and SO_x and NO_x emissions and lowering the risk of low-temperature corrosion. The biomass co-firing slightly increases the combustion share in the dense phase zone and raises the bed temperature. The strong ash adhesion characteristics of the biomass were observed, which were overcome by increasing the ash blowing frequency. Under 20 wt% co-firing, the annual CO₂ emissions reductions can reach 130,000 tons. This study provides technical references and practical experience for the engineering application of direct biomass co-firing in industrial-scale CFB boilers. Full article

This study investigates the mechanical and microstructural performance of three alkali-activated geopolymer formulations, constituted of metakaolin (MK), blast furnace slag (BFS), and a ternary blend of MK, BFS, and fly ash (MIX), for the immobilization of simulated radioactive liquid organic waste (RLOW). Thermal ageing tests were performed to evaluate geopolymer durability, including fire exposure (800 °C) and climatic chamber cycles (from −20 to 40 °C). Characterization through thermogravimetric analysis (TGA), compression tests, and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS) was carried out to assess material degradation after thermal ageing. Preliminary results showed substantial strength and microstructural degradation in oil-loaded specimens after cyclic climatic ageing, while fire-exposed blank matrices retained partial mechanical integrity. BFS matrices exhibited the best thermal resistance, attributable to the formation of Ca-Al-Si-hydrate (C-A-S-H) gels. These findings support the use of optimized geopolymer formulations for safe RLOW immobilization, while contributing to the advancement of knowledge on sustainable and regulatory-compliant direct conditioning technology. Full article

Porcelain ware typically undergoes multiple firing stages, including decoration firing at temperatures that depend on the desired effect. Conventional decorative firing in gas tunnel kilns takes up to 90 min, whereas microwave heating offers a faster alternative, of around 50 min firings for both low- (~800 °C) and high-fire colors (~1200 °C). However, temperature assessment during microwave firing remains challenging. This study investigates the color changes in overglaze-decorated hard microwave and conventional porcelain firing. Decals with temperature-sensitive pigments (silver and blue) were applied to the porcelain pieces. Color coordinates (L*, a*, b*) were analyzed, comparing microwave and electrically fired samples with the gas-fired reference counterparts. Microwave-fired samples required lower temperatures to match the color of electrically fired samples. Electrically fired pieces at 900 °C are visually comparable to those processed in both a microwave furnace and a gas kiln at the same temperature of 800 °C. Color differences among different heating methods decrease as firing temperature increases. Microwave firing allows similar decorative results to be achieved as with conventional gas firing, while being faster and more energy efficient. Microwave porcelain firing is thus a viable and eco-friendly alternative for porcelain decoration, and the decals’ color changes can be used for temperature assessment during firing. Full article

Fire safety design for steel beams is crucial in the construction of steel structures. However, there remains a significant gap in the fire resistance testing of insulated steel beams. This study focuses on full-scale experimental research examining the fire resistance performance of steel beams with varying fire protection methods, cross-sectional dimensions, and heating curves. During the tests, the furnace temperature, specimen temperature, and deflection at mid-span were measured. The test results indicated that specimens mainly failed in lateral–torsional buckling. Additionally, a markedly non-uniform temperature distribution was observed across the cross-section, and the predictions made by GB 51249-2017 were found to be unsafe. The use of fiber cement board for fire protection may be ineffective, as it tends to become brittle at elevated temperatures, making it susceptible to breakage and detachment when the beams begin to bend. Furthermore, due to potential creep deformation, specimens subjected to longer heating durations exhibited lower critical temperatures compared to those with shorter heating durations. Finally, the design method outlined in BS EN 1993-1-2 and ANSI/AISC 360-22 was evaluated against the test results, indicating an accurate prediction of these methods for specimens with shorter heating durations, but an unconservative prediction for specimens with longer heating durations due to ignorance of creep deformation. Full article

This study explores the potential of using sustainable materials in brick manufacturing by designing a novel brick mix in the laboratory, incorporating sand, lime kiln dust (LKD) waste, tyre rubber, and ground granulated blast furnace slag (GGBFS) waste. These cementless bricks blended LKD–GGBFS wastes as the binder agent and fine crumb rubber from waste tyres as a partial replacement for sand in measured increments of 0%, 5%, and 10% by volume of sand. Ordinary Portland cement (OPC) and fired clay bricks were sourced from the industry, and their properties were compared to those of the laboratory bricks. Tests performed on the industry and laboratory bricks included compressive strength (CS), freeze-thaw (F-T), and water absorption (WA) tests for comparison purposes. Additionally, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analyses were performed on the bricks to assess the morphological and mineralogical changes responsible for the observed strengths and durability. The CS and WA values of the engineered bricks were 12, 6, and 4 MPa, and 7, 12, and 15%, respectively, for 0, 5, and 10% crumb rubber replacements. The industry bricks’ average CS and WA values were 13 MPa and 8%, respectively. From the results obtained, the green laboratory bricks passed the minimum strength requirements for load-bearing and non-load-bearing bricks, which can be used to construct small houses. Lastly, the engineered bricks demonstrated strength and durability properties comparable to those of the industry-standard bricks, indicating their potential as a sustainable alternative to help divert waste from landfills, reduce the pressure on natural fine sand extraction, and support eco-conscious brick production for a sustainable environment. Full article

This paper describes the recent attempts to apply the zonal model of thermal radiation in numerical simulations of pulverized coal-fired furnaces. Three methods are described: temporary correction of the total exchange areas (TCTEA), repeated run of the numerical simulation (RRNS), and current correction of the total exchange areas (CCTEA). The TCTEA and RRNS methods are based on successive runs of the numerical simulation. The CCTEA method is proof that the zonal model can be used in numerical simulations by the correction of the total exchange areas on the basis of current and initialized surface zone emissivity. Full article

This study presents an advanced NO_x reduction strategy for a 330 MW lignite-fired boiler using an immunological AI system: the SILO (Stochastic Immune Layer Optimizer) combustion optimizer inspired by artificial immune systems. The immunological AI optimizer adaptively models multi-variable interactions and fireball shape in real time, optimizing fuel–air mixing to reduce NO_x formation at the source. Unlike reactive secondary methods, the combustion optimizer reshapes the combustion process to reduce emissions while improving efficiency. Real-time temperature data from the AGAM acoustic system inform the combustion optimizer’s fireball modeling, ensuring combustion uniformity. A urea-based SNCR system serves as a secondary layer, controlled based on local furnace conditions to target thermal zones. Field results confirmed that SILO reduced NO_x emissions below 200 mg/Nm³, decreased urea consumption by up to 34%, and improved boiler efficiency by 0.29%. The architecture offers a scalable, DCS-integrated solution for aligning fossil-fueled operations with tightening emission standards. Full article

Coal combustion generates significant volumes of ash, a technogenic by-product that poses a serious threat to regional environmental sustainability (environmental chemical contamination and air pollution). This study aims to assess the feasibility of utilizing this type of ash as a raw material component in the fabrication of refractory bricks and to investigate the fundamental properties of the resulting experimental products. Ash was incorporated into the batch composition at concentrations ranging from 10% to 40% by weight, blended with clay and water, then shaped through pressing and subjected to firing at 1000 °C and 1100 °C in an air atmosphere for 2 h. After complete cooling, the samples were subjected to compressive strength testing. Samples containing 40 wt% coal ash exhibited insufficient compressive strength and were therefore excluded from subsequent investigations. For the remaining samples, apparent density, open porosity and slag resistance were determined. The microstructural characterization was performed, and the phase composition of the samples was analyzed. The results revealed that the phase composition of the experimental samples differs significantly from that of the reference sample (ShA-grade chamotte brick in accordance with GOST 390-96, currently used as lining in metallurgical furnaces across the country), exhibiting a higher mullite content and the absence of muscovite. A small amount of kaolinite was detected in the experimental samples even after a 2-h firing process. This observation may be attributed to the effect of kaolinite crystallinity on the transformation process from kaolinite to metakaolinite. The mechanical strength of the experimental samples meets the relevant standards, while slag resistance demonstrated an improvement of approximately 15%. Open porosity was found to decrease in the experimental samples. In addition, a change in the pore size distribution was observed. Notably, the proportion of pores larger than 10,000 nm was significantly reduced. These findings confirm the feasibility of incorporating coal ash as a viable raw material component in the formulation of refractory materials. Full article

The combustion behavior and thermal performance of industrial-scale borax pentahydrate (Na₂B₄O₇·5H₂O) melting furnaces remain underexplored despite their critical role in boric oxide (B₂O₃) production, a key input for high-performance manufacturing. This study addressed this gap by employing three-dimensional computational fluid dynamics (CFD) simulations to model two operational natural gas-fired furnaces with distinct burner configurations (four-burner and six-burner systems). The analysis focused on optimizing burner placement, specifically, the axial distance and inclination angle, to enhance thermal uniformity and reduce refractory wall damage caused by aggressive high-temperature borate corrosion. A comprehensive parametric study of twelve burner configurations revealed that tilting the burners at 5–10° significantly improved temperature uniformity while reducing peak wall temperatures and mitigating localized hot spots. The optimal design, incorporating a 10° burner angle and a staggered burner arrangement (Case 11), attained a melt pool temperature of 1831.3 K and a charging average wall temperature of 1812.0 K. These values represent essential benchmarks for maximizing furnace efficiency and operational stability. The modified designs for the four- and six-burner systems led to improved temperature distributions and a notable reduction in maximum wall temperatures, directly contributing to longer maintenance intervals and improved refractory durability. The findings of this study confirm that minor geometrical and angular adjustments in burner placement can yield significant performance gains. The validated CFD approach and proposed design modifications offer a scalable, low-cost strategy for improving combustion efficiency and furnace lifespan in borax processing facilities. Full article

The interaction mechanism of multi-physical fields in a 330 MW tangentially fired boiler is explored by coupling the CFD (computational fluid dynamics) model and the working fluid side hydrodynamic model under steady-state conditions. The research focuses on the flue gas flow field, the hydrodynamic safety of the water wall, the variation of the working fluid parameters and the formation and distribution characteristics of sulfide (SO₂, H₂S) under different steady loads (35%, 50%, 75%, 100% Boiler Maximum Continuous Rating). The results show that under high load, the flue gas attaches to the wall. The overall stagnation differential pressure ratio (1.85–2.07) and reversal differential pressure ratio (1.22–1.30) of the G1 tube group with the lowest heat flux are higher than the safety threshold (1.05), proving reliable operational safety under equilibrium conditions. The temperature distribution of the furnace center obtained by numerical simulation is consistent with the actual situation. The mass fraction of sulfide increases significantly with the increase in load. SO₂ is mainly distributed in the wall area of the middle and upper burners, while H₂S is mainly distributed in the wall area between the secondary air and the main burner. The maximum mass fractions of SO₂ and H₂S at 330 MW are 0.120% and 0.0524%, respectively. It is suggested that a wall-attached air system be added to inhibit the enrichment of corrosive gases. This work may provide theoretical support and engineering guidance for multi-objective optimization design and high temperature corrosion prevention and control of tangentially fired boilers. Full article

This paper focuses on the behavior of anchor channels in the event of fire. The contribution of this project lies in the necessity coming from the market to study the fire resistance of anchor channels more thoroughly, considering the modes of failure to which they are subjected. The aim of this paper is to transform the method based on tests into a numerical method that allows calculation of the fire resistance at any time under fire conditions, for all fire scenarios (whether it is a standard fire or using performance-based design approaches). A 3D transient thermal model was developed using ANSYS 19.1 to determine the thermal distribution of anchor channels, simulated in uncracked concrete under ISO 834-1 fire conditions. Subsequently, a design model for steel-related failure modes under fire conditions was employed. The model consists of coupling the characteristic resistances of the anchor channel at ambient temperature with temperature-based reduction factors for steel-related failure modes to obtain the calculated fire resistances. The model was compared with fire test results available in the literature, and the comparison yielded satisfactory results, confirming its reliability and accuracy in capturing the relevant phenomena under fire conditions. The results of this research show that the model presents a good candidate to replace the current method of qualification of anchor channels under fire conditions. Full article

To evaluate the fire safety of 110 kV ultra-high-voltage flame-retardant polyvinyl chloride (PVC) cables in the service process, the effects of thermal aging on the pyrolysis and combustion behavior of the cable sheaths were studied using thermogravimetric (TG), limiting oxygen index (LOI), UL-94 vertical burning, cone calorimeter, open flame, and muffle furnace tests. The results showed that thermal aging causes a slight decrease in the LOI value of the cable sheath (28.3% vs. 28.5%), but it also passed the UL-94 V-0 test. The butane torch test showed that the cable sheath was more easily ignited after aging; however, a better char layer was formed in the later stage of burning, which led to a longer failure time. Interestingly, the aging treatment prolonged the ignition time of the cable sheaths and reduced the peak heat release rate (pHRR) and total heat release (THR) by 17.5% and 24.4%, respectively, in the cone calorimeter test, indicating that aging resulted in a reduction in the fire hazard of the cable sheaths. Moreover, aging mechanisms were proposed based on the composition and structural evolution of the cable sheaths. In summary, this work comprehensively evaluated the fire hazard of 110 kV ultra-high-voltage cables and provided theoretical support for the formulation improvement, durability enhancement, and fire protection design of cable sheath materials. Full article

Modern industrial systems and biomass-fired furnaces require surface treatments that can withstand aggressive chemical, thermal, and corrosive environments. This study investigates the corrosion and thermal resistance of plasma-sprayed Al₂O₃-TiO₂ coatings produced using a DC air–hydrogen plasma spray process. Coatings of compositions of Al₂O₃, Al₂O₃-3 wt.% TiO₂, Al₂O₃-13 wt.% TiO₂, and Al₂O₃-40 wt.% TiO₂ were deposited on steel substrates with a Ni/Cr bond layer by plasma spraying. The coatings were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) to evaluate their morphology, elemental composition, and crystalline phases. Electrochemical tests were performed in a naturally aerated 0.5 mol/L NaCl solution and cyclic thermal–chemical exposure tests (500 °C using 35% KCl) to assess their corrosion kinetics and thermal stability. The results indicate that pure Al₂O₃ and low TiO₂ (3 wt.%) coatings exhibit fine barrier properties, while coatings with a higher TiO₂ content develop additional phases (e.g., Ti₃O₅, Al₂TiO₅) that improve thermal resistance but reduce chemical durability. Full article