Search Results (2,311)

The rising demand for energy resources and industrial goods presents significant challenges to sustainable development. Sunflower oil, commonly utilized in the food sector, biofuels, and various industrial applications, is notably affected by this demand. In Bulgaria, it serves as a primary source of vegetable fats, ranking second to butter in daily consumption. The aim of this study is to evaluate and propose methods to improve energy and resource efficiency in sunflower oil production in Bulgaria. The analysis is based on data from an energy audit conducted in 2023 at an industrial sunflower oil production facility. Reconstruction and modernization initiatives, which included the installation of high-performance, energy-efficient equipment, led to a 34% increase in energy efficiency. The findings highlight the importance of adjusting the technological parameters such as temperature, pressure, grinding level, and pressing time to reduce energy use and operational costs. Additionally, resource efficiency is improved through more effective raw material utilization and waste reduction. These strategies not only enhance the economic and environmental performance of sunflower oil production but also support sustainable development and competitiveness within the industry. The improvement reduces hexane use by approximately 2%, resulting in energy savings of 12–15 kWh/t of processed seeds and a reduction in CO₂ emissions by 3–4 kg/t, thereby improving the environmental profile of sunflower oil production. Full article

Using waste biomass as a raw material for the combined production of electricity and heat offers corresponding energy, economic, environmental and resource efficiency benefits. The study examines both the performance of a system for combined energy production based on the Organic Rankine Cycle (ORC) utilizing wood biomass and the market interest in its deployment within Bulgaria. Its objective is to propose a technically and economically viable solution for the recovery of waste biomass through the combined production of electricity and heat while simultaneously assessing the readiness of industrial and municipal sectors to adopt such systems. The cogeneration plant incorporates an ORC module enhanced with three additional economizers that capture residual heat from flue gases. Operating on 2 t/h of biomass, the system delivers 1156 kW of electric power and 3660 kW of thermal energy, recovering an additional 2664 kW of heat. The overall energy efficiency reaches 85%, with projected annual revenues exceeding EUR 600,000 and a reduction in carbon dioxide emissions of over 5800 t/yr. These indicators can be achieved through optimal installation and operation. When operating at a reduced load, however, the specific fuel consumption increases and the overall efficiency of the installation decreases. The marketing survey results indicate that 75% of respondents express interest in adopting such technologies, contingent upon the availability of financial incentives. The strongest demand is observed for systems with capacities up to 1000 kW. However, significant barriers remain, including high initial investment costs and uneven access to raw materials. The findings confirm that the developed system offers a technologically robust, environmentally efficient and market-relevant solution, aligned with the goals of energy independence, sustainability and the transition to a low-carbon economy. Full article

This study investigates the strengthening mechanisms of char in silicon dioxide thermal reduction through systematic high-temperature experiments using three char types (YQ1, CW1, HY1) characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, and scanning electron microscopy. HY1 char demonstrated superior reactivity due to its highly ordered microcrystalline structure, characterized by the largest aromatic cluster size (L_a) and lowest defect ratio (I_D/I_G = 0.37), which directly correlated with enhanced reaction completeness. The carbon–silicon reaction reactivity increased progressively with temperature, achieving optimal performance at 1550 °C. Addition of Fe and Fe₂O₃ significantly accelerated the reduction process, with Fe₂O₃ exhibiting superior catalytic performance by reducing activation energy and optimizing reaction kinetics. The ferrosilicon formation mechanism proceeds through a two-stage pathway: initial char-SiO₂ reaction producing SiC and CO, followed by SiC–iron interaction generating FeSi, which catalytically promotes further reduction. These findings establish critical structure–performance relationships for char selection in industrial silicon production, where microcrystalline ordering emerges as the primary performance determinant. The identification of optimal temperature and additive conditions provides practical pathways to enhance energy efficiency and product quality in silicon metallurgy, enabling informed raw material selection and process optimization to reduce energy consumption and improve operational stability. Full article

Environmental protection has become one of the key challenges of our time. This has led to an increase in pro-environmental activities in the field of cosmetics and household chemicals, where manufacturers are increasingly trying to meet the expectations of consumers who are aware of the potential risks associated with the production of cosmetics and household chemistry products. This is one of the most important challenges of today’s industry, given that some of the raw materials still commonly used, such as surfactants, may be toxic to aquatic organisms. Many companies are choosing to use natural raw materials that have satisfactory performance properties but are also environmentally friendly. In addition, modern products are also characterized by reduced consumption of water, resources, and energy in production processes. These measures reduce the carbon footprint and reduce the amount of plastic packaging required. In the present study, seven formulations of environmentally friendly car shampoo concentrates were developed, based entirely on mixtures of bio-based surfactants. The developed formulations were tested for application on the car body surface, allowing the selection of the two best products. For these selected formulations, an in-depth physicochemical analysis was carried out, including pH, density, and viscosity measurements. Comparison of the results with commercial products available on the market was also performed. Additionally, using the multiple light scattering method, the foamability and foam stability were determined for the car shampoos developed. The results obtained indicate the very high application potential of the products under study, which combine high performance and environmental concerns. Full article

This study explores the application of low-power vibrothermography (LVT) for detecting barely visible impact damage (BVID) in carbon fibre-reinforced polymer (CFRP) laminates. Composite specimens with varying impact energies (2.5–20 J) were excited using a single piezoelectric transducer with a nominal centre frequency of 28 kHz, operated at a fixed excitation frequency of 28 kHz. Thermal data were captured using an infrared camera. To enhance defect visibility and suppress background noise, the raw thermal sequences were processed using principal component analysis (PCA) and robust principal component analysis (RPCA). In LVT, RPCA and PCA provided comparable signal-to-noise ratios (SNR), with no consistent advantage for either method across all cases. In contrast, for pulsed thermography (PT) data, RPCA consistently resulted in higher SNR values, except for one sample. The LVT results were further validated by comparison with PT and phased array ultrasonic testing (PAUT) data to confirm the location and shape of detected damage. These findings demonstrate that LVT, when combined with PCA or RPCA, offers a reliable method for identifying BVID and can support safer, more efficient structural health monitoring of composite materials. Full article

The transition to sustainable energy systems demands efficient recycling methods for critical raw materials like lithium. In this study, we present a new class of pH- and light-switchable flotation collectors based on isomeric derivatives of the natural product Punicine, termed inverse Punicines. These amphoteric molecules were synthesized via a straightforward four-step route and structurally tuned for hydrophobization by alkylation. Their performance as collectors was evaluated in microflotation experiments of lithium aluminate (LiAlO₂) and silicate matrix minerals such as melilite and calcium silicate. Characterization techniques including ultraviolet-visible (UV-Vis), nuclear magnetic resonance (NMR) and electron spin resonance (ESR) spectroscopy as well as contact angle, zeta potential (ζ potential) and microflotation experiments revealed strong pH- and structure-dependent interactions with mineral surfaces. Notably, N-alkylated inverse Punicine derivatives showed high flotation yields for LiAlO₂ at pH of 11, with a derivative possessing a dodecyl group attached to the nitrogen as collector achieving up to 86% recovery (collector conc. 0.06 mmol/L). Preliminary separation tests showed Li upgrading from 5.27% to 6.95%. Radical formation and light-response behavior were confirmed by ESR and flotation tests under different illumination conditions. These results demonstrate the potential of inverse Punicines as tunable, sustainable flotation reagents for advanced lithium recycling from complex slag systems. Full article

The following investigation presents concrete cement obtained with the Viterbo O’Reilly Diaz method, introduced to quantify the concrete mixture by using an aggregate gradation method. This research uses this procedure to decrease the amount of cement in the mix, thus reducing the CO₂ footprint and production costs, which directly impact the environmental and economical sustainability of the material. The formulations used structural and general use Portland cements. As aggregates, fine sand and 3/4” gravel were included. Several characterization techniques were used, including granulometry testing for the aggregates, compression strength testing for the concrete samples, and granulometry testing for the raw materials. Compressive tests were conducted on samples after 28 days of curing, while scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS) was used to understand the microstructure. The results revealed the optimal amounts of water, cement, and aggregates. Combinations of fine and coarse aggregates were determined as well. The main novelty in this manuscript is the use of the Viterbo O’Reilly mix design method to innovatively enhance concrete mixes by analyzing material properties and behavior in detail, an unexplored method in the literature. This research considers not only strength but also durability and workability, using mathematical tools for data analysis. This data-driven approach ensures effective aggregate gradation towards sustainability when compared to other traditional methods. Full article

This paper discusses the possibilities of using stump wood as a raw material for energy generation. The research was based on an analysis of the state of knowledge, forest field studies, and participatory observations. A formula was sought to optimise the procurement cost of stump wood appropriate to Polish conditions. Conceptualisation was carried out in a selected area of the Notecka Forest in the Wielkopolska region, located in western Poland. A pilot study was designed to test a computational formula to assess the profitability of harvesting wood from stump wood resources for energy generation. The potential of stump wood is estimated to be around half a million cubic metres per year from the Notecka Forest area alone. This resource provides an opportunity for business development in both forestry and the renewable energy sources (RESs) sector, despite the barriers and risks shown in this study. Full article

This study aimed to assess the use of selected raw materials, such as whole-grain oat flakes, pumpkin seeds, sunflower seeds, and flaxseeds, to obtain bars using baking and drying methods. Modifying the bars’ composition involved selecting the fibre preparation, replacing water with NFC juice, and using fresh apple juice and apple pomace. The Psyllium fibre preparation, also in the form of a mixture with apple fibre, was the most useful in dough cohesion and the quality of the bars. Baked bars were characterised by higher sensory quality than those obtained by drying. Microwave–convection drying was a good alternative to baking, primarily due to the lower temperature resulting in a lower acrylamide content and comparable product quality. The basic grain ingredients and fibre preparations mainly shaped the nutritional and energy value and the sensory and microbiological quality. Modifying the recipe using NFC or fresh juice and apple pomace allowed the bars to develop new properties and quality characteristics. The use of NFC juices resulted in a reduction in the pH of the bars, which is associated with a higher microbiological quality of the bars. All bars had low acrylamide content, significantly lower than the permissible level. Using fresh pomace or fibre preparations made from by-products is a possibility to increase the fibre content in the bars and a method of managing by-products. Full article

Biomass is gaining increasing importance as a renewable energy source in the global energy mix, offering a viable alternative to fossil fuels and contributing to the decarbonization of the energy sector. Among various types of biomass, agricultural residues such as bean stalks represent a promising feedstock for the production of solid biofuels. This study analyzes the impact of particle size and selected briquetting parameters (pressure and temperature) on the physical quality of briquettes made from bean stalks. The experimental procedure included milling the raw material using #8, #12, and #16 mesh screens, followed by compaction under pressures of 27, 37, and 47 MPa. Additionally, the briquetting die was heated to 90 °C to improve the mechanical durability of the briquettes. The results showed that both particle size and die temperature significantly influenced the quality of the produced briquettes. Briquettes made from the 16 mm fraction, compacted at 60 °C and 27 MPa, exhibited a durability of 55.76%, which increased to 82.02% when the die temperature was raised to 90 °C. Further improvements were achieved by removing particles smaller than 1 mm. However, these measures did not enable achieving a net calorific value above 14.5 MJ·kg⁻¹. Therefore, additional work was undertaken, involving the addition of biomass with higher calorific value to the bean stalk feedstock. In the study, maize straw and miscanthus straw were used as supplementary substrates. The results allowed for determining their minimum proportions required to exceed the 14.5 MJ·kg⁻¹ threshold. In conclusion, bean stalks can serve as a viable feedstock for the production of solid biofuels, especially when combined with other biomass types possessing more favorable energy parameters. Their utilization aligns with the concept of managing local agricultural residues within decentralized energy systems and supports the development of sustainable bioenergy solutions. Full article

The paper investigates the process of degumming substandard soybean oil using an enzyme complex of phospholipases to prepare it as a feedstock for biodiesel production. Dehumidification is an important refining step aimed at reducing the phosphorus content, which exceeds the permissible limits according to ASTM, EN, and ISO standards, by re-moving phospholipids. The enzyme complex of phospholipases includes phospholipase C, which specifically targets phosphatidylinositol, and phospholipase A2, which catalyzes the hydrolysis of phospholipids into water-soluble phosphates and lysophospholipids. This process contributes to the efficient removal of phospholipids, increased neutral oil yield, and reduced residual oil in the humic phase. The use of an enzyme complex of phospholipases provides an innovative, cost-effective, and environmentally friendly method of oil purification. The results of the study demonstrate the high efficiency of using the phospholipase enzyme complex in the processing of substandard soybean oil, which allows reducing the content of total phosphorus to 0.001% by weight, turning it into a high-quality raw material for biodiesel production. The proposed approach contributes to increasing the profitability of agricultural raw materials and the introduction of environmentally friendly technologies in the field of renewable energy. Full article

The stretch film production is highly energy intensive. The components of the technological line are powered by electrical energy, and the heat is used to change the physical state of the raw material (granules). The raw material is poured into FCR (the first calender roller). To solidify the liquid raw material, the calendar must be cooled. The low-temperature heat, treated as waste heat, has dissipated in the atmosphere. Technological innovations were proposed: (a) the raw material comprises raw material (primary) and up to 80% recyclate (waste originating mainly from agriculture), (b) the use of low-temperature waste heat (the cooling of FCR in the process of foil stretch production). A heat recovery line based on two compressor heat pumps (HP, hydraulically coupled) was designed. The waste heat (by low-temperature HP) was transformed into high-temperature heat (by high-temperature HP) and used to prepare the raw material. The proposed technological line enables the management of difficult-to-manage post-production waste (i.e., agriculture and other economic sectors). It reduces energy consumption and raw materials from non-renewable sources (CO₂ and other greenhouse gas emissions are reducing). It implements a closed-loop economy based on renewable energy sources (according to the European Green Deal). Full article

Residential and agricultural buildings must prioritize environmental sustainability, employing locally sourced, bio/geologically sustainable materials, and reversible construction methods. Hence, adobe construction and earth-based building methods are experiencing a comeback. This article describes the hygrothermal performances of a real scale agricultural building prototype, in real field conditions, built and designed to be energy-efficient, environmentally friendly, and well-suited for the hot, dry climates typical of the Mediterranean region during summer. The building prototype is a small modular two room construction, one room based on wood (for control purpose) and the other one on raw earth. The experimental set up highlights the passive cooling and humidity regulation potential provided by raw earth and adobe brick technology in agricultural buildings used for fruit and vegetable storage. Such passive cooling alternatives in the Mediterranean climate could reduce the need for energy-intensive and environmentally impactful cold storage rooms. Full article

Due to increasing environmental concerns and the constant development of the bottling industry, research into the environmental impact of beverage packaging processes is crucial. The aim of this article is to determine the environmental impact, in selected aspects, of automated beverage bottling and packaging processes using life cycle analysis (LCA). The analysis covers key process stages, such as filling, packaging and internal transport, in the context of raw material consumption, but also energy and waste generation. This work focuses primarily on the impact of changing the raw material used for bottle and shrink film production on the environmental impact of the studied technical facility within the adopted system boundaries and on analyzing scenarios for the management of these post-consumer materials. This research has shown that the stage associated with the greatest negative environmental impact is the shrinking of the film around the bottles. Furthermore, it has been demonstrated that recycling plastic film and bottle waste is a more environmentally friendly solution than landfill disposal. The analysis shows that using recycled materials in the tested production line allows for the reduction of harmful emissions and a reduction in the overall environmental footprint of the tested system. Full article