Search Results (202)

The Zhongdian Arc is an important copper polymetallic ore cluster in China’s Sanjiang Tethyan Metallogenic Domain, and the Langdu deposit is a representative porphyry–skarn Cu deposit in this region. This study aims to constrain the timing of magmatic activity at the Langdu deposit. It also seeks to reveal the magma’s physical–chemical properties and evolution, and to identify the factors controlling mineralization. To achieve these objectives, this study used LA-ICP-MS zircon U-Pb dating and elemental analysis, combined with halogen and trace element data from apatite. Zircon U–Pb dating shows that the Langdu intrusions were emplaced at ca. 216 Ma in a continental arc setting associated with the westward subduction of the Garzê–Litang oceanic crust during the Late Triassic. Geochemical and mineralogical features indicate that the Langdu intrusions are I-type granite. They originated from partial melting of the mantle wedge metasomatized by subduction fluids. During their ascent, these magmas experienced fractional crystallization dominated by amphibole, titanite, rutile, and monazite. Geochemical records from zircon and apatite further reveal that the ore-forming magma of the Langdu intrusions exhibited high oxygen fugacity (ΔFMQ = +1.53), elevated H₂O content (avg. 7.63 wt.%), and enrichment in S (avg. 560 ppm) and Cl (avg. 2141 ppm). This Cl-rich magma experienced fluid exsolution during its early evolutionary stage. This provided the necessary conditions for metal extraction and transport. In summary, the key factors controlling the formation of the Langdu porphyry–skarn Cu deposit are high-oxygen-fugacity magma enriched in water and volatiles (S and Cl), coupled with efficient fluid exsolution. This understanding is important for better understanding regional metallogeny and for guiding mineral exploration. Full article

This study investigates the origin and Nb–Ta enrichment mechanisms of the Middle Triassic Nare Alkaline Rocks in Gerze, central Tibet, using petrological, geochemical, and geochronological data. U–Pb zircon dating constrains the trachyte formation to the Middle Triassic, identifying NaOI as the oldest known seamount fragment in the zone and providing a key age for the early Meso-Tethyan Ocean. Whole-rock geochemistry data show the basalts possess typical OIB signatures, derived from a depleted mantle source modified by a mantle plume. The trachyte originated via a multi-stage process: Middle Triassic basaltic magmas underplated to form a deep-seated magma chamber, underwent high-pressure fractional crystallization, and the resulting crystal mush was later reheated and partially melted by subsequent magmas to generate trachytic melt. This model is supported by Hf isotopes and mineral chemistry. The rocks formed in a mature, thick-lithosphere intra-oceanic plate setting. Niobium occurs primarily as ilmenorutile with high Nb₂O₅ content, but its low modal abundance and very fine grain size imply low beneficiation recovery and limited current economic potential. However, the NaOI formed in an intra-oceanic island setting and hosts an early-stage Nb–Ta metallogenic system linked to alkaline magma differentiation, highlighting their potential for rare-metal exploration. Full article

The Dongqiyishan W-polymetallic deposit is a large porphyry deposit in the Beishan region, Inner Mongolia. Based on cross-cutting relationships of veins and distinct mineral assemblages, the hydrothermal evolution of the Dongqiyishan deposit can be divided into three mineralization stages, with corresponding characteristic alteration types: (1) early W mineralization stage, dominated by potassic–sodic alteration; (2) main W mineralization stage, characterized by extensive phyllic alteration; and (3) post-W-mineralization hydrothermal stage, associated with quartz–fluorite–calcite alteration. This study employs an integrated approach, including molybdenite Re-Os dating, microthermometry of fluid inclusions, and H-O-S isotopic analyses, to investigate the genesis of the deposit. The results show that: (1) the metallogenic age of the deposit is 222.2 ± 1.5 Ma (MSWD = 0.58; Middle Triassic), which was likely caused by the northward subduction of the Paleo-Tethys Ocean; (2) the metallogenic fluids of Stage I (homogenization temperature 350~400 °C, salinity 6.0~8.0 wt.% NaCl eqv.) and Stage II (homogenization temperature 300~350 °C, salinity 4.0~6.0 wt.% NaCl eqv.) are mainly from magmatic water, and Stage III (homogenization temperature 225~275 °C, salinity 4.0~8.0 wt.% NaCl eqv.) has a mixed fluid of magmatic water and meteoric water; (3) the ore-forming materials were mainly derived from magma, which is supported by the S isotopic results (δ³⁴S = −0.5‰~1.6‰, average 0.93‰); (4) mineralization depths calculated through fluid inclusions are 0.52–1.60 km (Stage I), 0.70–1.80 km (Stage II) and 0.10–0.49 km (Stage III); and (5) Stage I W precipitation was likely driven by fluid boiling and water–rock interaction, Stage II W precipitation by water–rock interaction principally, and Stage III fluorite precipitation by water–rock interaction plus fluid cooling. This research provides theoretical guidance for W-polymetallic prospecting in the Beishan of Inner Mongolia. Full article

The Duobaoshan porphyry copper–molybdenum deposit is located in the Great Xing’an Range, eastern segment of the Xing-Meng orogenic belt. It is the largest porphyry Cu-Mo deposit in NE China. Based on the contact relations of intrusive rocks and the results of LA-ICP-MS zircon U-Pb ages, we found that there were five stages of magmatism in the mining area, including the Early Ordovician (478.1 ± 3.2 Ma) granodiorite, the Middle Ordovician (462.1 ± 3.3 Ma, 459.5 ± 2.3 Ma) granodiorite porphyry, the Late Triassic (226.3 ± 0.4 Ma) oligoclase granite, the Middle Jurassic (170.1 ± 5.6 Ma) andesitic porphyrite, and the Early Cretaceous (118.1 ± 6.6 Ma) diorite. The Early and Middle Ordovician granodiorite and granodiorite porphyry are the principal host rocks for the mineralization in the deposit. However, Cu-Mo mineralization was also observed within the Late Triassic oligoclase granite, indicating that there are two stages of Cu-Mo mineralization in the Duobaoshan deposit. Combined with the previously reported Late Triassic skarn Cu mineralization occurring in the Xiaoduobaoshan deposit, and the Early Jurassic skarn Cu mineralization in the Sankuanggou and Yubaoshan deposits, we conclude that there are four metallogenetic stages in the Duobaoshan ore-concentration area. Regionally, there are five stages of Cu-Mo mineralization occurring in the northern Great Xing’an Range, including the Ordovician, Late Triassic, Early Jurassic, Late Jurassic, and Early Cretaceous. After discussing the tectonic setting for the generation of these deposits, we propose that the Duobaoshan ore-concentration area was influenced by the subduction of the Paleo-Asian Ocean, Mongol-Okhotsk, and Paleo-Pacific Plates during the Phanerozoic. Full article

Extant birds and the earliest dinosaurs may share fundamental metabolic features essential for aerobic exercise, suggesting that the extraordinary physical performance typical of avian species originated when dinosaurs first appeared during the Carnian Pluvial Episode (CPE). This physiological adaptation is complemented by hyperactive mitochondria that exhibit high oxygen consumption and low reactive oxygen species production. Molecular genomics of fossils, the so-called “Jurassic Genome,” indicates that these early dinosaurs possessed compact genomes, 50–60% the size of the human genome, and small cells, implying a highly stringent metabolic regime. We suggest that hyperactive mitochondria, closely associated with compact genomes and small cells, drive theropod adaptation to the hot, dry, and hypoxic environments of the Late Triassic period, ultimately enabling their ecological dominance. Early dinosaurs such as Herrerasaurus are hypothesized to have possessed advanced physiological traits shared with modern birds, including hyperactive mitochondria, compact genomes, small cells, and a developing air-sac system. Collectively, these features most likely may have contributed to exceptional metabolic capacity, locomotor performance, and adaptation to the harsh environment of the CPE. Full article

Several shale oil intervals, including those in offshore China, were deposited in paralic lacustrine basins that experienced marine incursions. Marine incursions could be either favorable or unfavorable for the accumulation of organic matter (OM) and shale oil. However, the influence and specific mechanisms of seawater on OM accumulation require further in-depth investigation. During the deposition of the Triassic Chang 7 Member in the Ordos Basin, seawater from the Paleo-Tethys Ocean intruded into the basin. Taking this interval as a case study, this paper employs comprehensive analyses to reveal the influence of marine incursion on water column conditions and OM accumulation. Under humid climatic conditions, the water body was fresh to brackish, characterized by high productivity and oxic–dysoxic conditions. The OM is primarily derived from algae, and its accumulation was jointly controlled by primary productivity, redox conditions, and terrigenous input. OM accumulation is controlled by fluctuations in the relative water level (RWL) associated with third-order sequences. During the period of high RWL, seawater incursions enhanced water column productivity and reduced conditions by increasing nutrient supply and salinity, resulting in the highest OM content. During the early and late periods of the RWL, as seawater receded, OM production declined while consumption and dilution increased, resulting in a gradual decrease in its content. The RWL fluctuations at the fourth-order scale also significantly influence OM accumulation. These results can enhance the understanding of OM accumulation in paralic lacustrine basins with a history of seawater incursion. While promoting shale oil exploration in the Ordos Basin, they can also serve as a research analog for shale oil exploration in basins with similar geological backgrounds, such as the Bohai Bay Basin. Full article

The Indosinian granitoids of Guangdong Province, South China, record a complex history of crust–mantle interactions during the Triassic assembly of the South China Block (SCB) and Indochina Block (ICB). Integrated zircon U–Pb geochronology, geochemistry, and Sr–Nd–Hf isotopes from these plutons reveal two magmatic episodes: an Early Indosinian phase (253–230 Ma) of large, west-to-east younging batholiths, and a later scattered phase (230–200 Ma). While most granitoids are peraluminous S-types formed by the melting of the Paleoproterozoic crust with limited mantle input (0–30%), the Taibao pluton and its enclaves are anomalous. They are more mafic and record a substantial mantle contribution (40–65%), pointing to focused, high-heat flux magmatism. This spatial and petrogenetic heterogeneity, coupled with the granitoids’ NE–SW trend orthogonal to the collisional zone, cannot be explained by simple crustal thickening. We propose that these features are the direct result of the slab tearing of the subducting Paleo-Tethys oceanic plate, triggered by an oblique collision between the SCB and ICB. This tearing induced asthenospheric upwelling, providing the thermal engine for widespread crustal anatexis and localized mantle melting. Our findings establish slab tearing as a key catalyst for syn-collisional, high-temperature magmatism, offering a unified framework for interpreting lithospheric processes during continental collisions. Full article

The Tawenchahanxi mining area, situated in the southeastern Qimantagh region of the East Kunlun Orogenic Belt, hosts a skarn-type Fe–polymetallic deposit associated with acidic granitic intrusions. Laser ablation–inductively coupled plasma–mass spectrometry zircon U–Pb dating yields ages of 233.3 ± 1.2 to 234.3 ± 1.1 Ma for a granodiorite and 397.7 ± 1.4 Ma for a quartz porphyry, indicating two magmatic intrusive events during the Early Devonian and Late Triassic. The Early Devonian quartz porphyry is characterized by high ${\mathrm{S}\mathrm{i}\mathrm{O}}_2$ (72.39%–74.04%), high total alkalis (7.81%–7.83%), high TFeO (>1.0%) and high crystallization temperatures (~865 °C), together with low CaO (1.64%–1.70%) and MgO (0.61–0.65%), which are all consistent with A-type granite affinity. The granodiorite exhibits aluminum saturation index (A/CNK) values of 0.67–1.07 (metaluminous to weakly peraluminous) and belongs to the high-K calc-alkaline series. It exhibits moderate negative Eu anomalies (δEu = 0.71–0.83), and zircon saturation temperatures of ~748 °C, collectively indicative of I-type granite affinity. Both rock suites display depletion in Nb, Ta, and Sr and enrichment in Rb and LREEs. Zircon Hf isotopic data show εHf(t) values of −0.64 to 0.57 for the quartz porphyry and −4.37 to −1.06 for the granodiorite, indicating derivation primarily from partial melting of ancient crust with variable mantle contributions. These intrusions formed during post-collisional extensional (Early Paleozoic) and collisional to post-collisional (Late Paleozoic–Early Mesozoic) stages, respectively, associated with mantle magma underplating and crust–mantle mixing. Such processes formed the material basis for the polymetallic mineralization in the Tawenchahanxi district by providing Fe–Cu–Pb–Zn and other ore-forming elements from deeper crust. Full article

Recent exploration has demonstrated significant prospecting potential at the Huayagou Au deposit in Longnan mineral Field, Gansu Province, West Qinling Orogen, Central China. However, the nature and evolution of the auriferous fluids responsible for gold enrichment remain poorly constrained, hindering effective exploration targeting of high-grade ores. In this study, apatite and tourmaline closely associated with gold mineralization are investigated as mineralogical recorders of fluid composition and evolution. Integrated petrographic observations, TIMA phase mapping, cathodoluminescence imaging, electron probe microanalysis, and in situ trace element analyses were used to distinguish magmatic, metamorphic, and syn-ore hydrothermal generations of apatite and tourmaline, together with in situ Nd isotopic analyses of apatite and B isotopic analyses of tourmaline. Syn-ore hydrothermal apatite is characterized by homogeneous blue cathodoluminescence, fluorapatite compositions, strong LREE depletion, and εNd(t) values overlapping those of Triassic magmatic apatite, whereas Early-Devonian magmatic and metamorphic apatites display more distinct signatures. Tourmaline records a systematic evolution from early dravite to late schorl, accompanied by trace element enrichment and a shift toward heavier δ¹¹B values. These mineralogical and isotopic features, together with published sulfur isotope constraints, indicate that gold mineralization at Huayagou was dominantly controlled by structurally focused metamorphic fluids, with localized Triassic magmatic–hydrothermal overprinting enhancing gold enrichment in high-grade ores. The Huayagou Au deposit is, therefore, best interpreted as an atypical orogenic gold system, highlighting enhanced exploration potential in structurally favorable zones at depth, particularly in the western part of the district where Triassic magmatism is inferred. Full article

The western Kuqa Foreland Basin exhibits complex hydrocarbon distribution with unclear accumulation processes. This study integrated seismic data, microscopic observations, crude oil properties, and basin modelling to establish a dynamic hydrocarbon migration model for the study area. The results indicated two distinct accumulation phases. During the early phase (16–5 Ma), hydrocarbons migrated eastward along a single unconformity and accumulated in the buried-hill reservoir of well E937 in the southern part of the Baicheng hydrocarbon-generating depression. In contrast, the southwestern region failed to accumulate hydrocarbons because of its distance from the Triassic source rock hydrocarbon generation centre and complex migration pathways. During the late phase (5–0 Ma), the Jurassic hydrocarbon generation centre shifted westward, and hydrocarbons migrated through a composite conduit system comprising faults, weathered crust, and sandstone structural ridges. This process promoted the expansion of the eastern E937 well trap, whereas well WEN54 and other southwestern wells exhibited hydrocarbon accumulation potential. The simulation results predicted that hydrocarbon reservoirs in the eastern region were mainly concentrated in the Qiulitage structural belt east of well E938. This study provides a theoretical basis and predictive guidance for hydrocarbon exploration in this area. Full article

Low-resistivity reservoirs characterized by weak log contrasts are highly concealed and therefore difficult to detect using conventional oil–water discrimination methods. Recent exploration and development indicate that low-resistivity reservoirs are widely developed in the Triassic Chang 3 Member of the Zhenbei area, Ordos Basin. However, contrasting tectonic evolution associated with the Tianhuan Depression and complex lithologic assemblages in the western and eastern sectors have resulted in complicated hydrocarbon migration and accumulation processes. In this study, integrated well-log and geochemical data were used to systematically investigate the genesis of low-resistivity reservoirs in the Chang 3 Member and to establish oil–water discrimination charts. Three-dimensional seismic flattening was applied to restore the Late Jurassic paleostructure of the western Chang 3 Member and to analyze its tectonic evolution. Reservoir petrology and pore–throat architecture in the western and eastern areas were comparatively examined using thin-section petrography, field-emission scanning electron microscopy (FESEM), and high-pressure mercury intrusion. Results indicate that the development of low-resistivity reservoirs in the Chang 3 Member is primarily controlled by highly saline formation water and elevated bound-water saturation. Based on these controls, the invasion factor–acoustic transit time cross-plot and the apparent spontaneous potential difference (ΔSP) method effectively discriminate oil- and water-bearing intervals in a total of 25 wells within the study area. Paleostructural restoration reveals that the western Chang 3 Member has undergone a tectonic inversion from a west-high–east-low configuration since the Late Jurassic to the present-day east-high–west-low geometry. Oil–source correlation indicates that hydrocarbons in the Chang 3 reservoirs were mainly derived from the underlying Chang 7 source rocks, whereas the bimodal distribution of fluid-inclusion homogenization temperatures suggests that the reservoirs experienced two distinct charging episodes. Integrated analysis suggests that tectonic inversion during the Yanshanian movement, combined with multistage hydrocarbon charging, led to secondary migration and partial destruction of early-formed reservoirs in the western area, resulting in predominantly scattered accumulations. In contrast, the eastern area experienced relatively limited tectonic modification, and laterally extensive accumulations are controlled by Type I–III lithologic–structural traps formed by the Chang 3 reservoir interval and its overlying strata. These findings provide an important geological basis for the identification of low-contrast reservoirs and for the exploration and development of hydrocarbon accumulations that are jointly controlled by tectonic evolution and lithologic heterogeneity. Full article

The influence of ocean chemistry on Early Triassic biotic recovery is poorly understood in the Chaohu Area. Here, we evaluate the influence of ocean chemistry following the Permian–Triassic crisis using pyrite content, δ¹³C_org, and S isotopic composition of pyrite. The pyrite content, V/(V + Ni) ratio, and S isotopic composition of pyrite in the Early Triassic from the northern Pingdingshan section of the Chaohu area in eastern China reveal recurrent and long-term ocean anoxia and two episodes of oxic conditions that occurred in the earliest Spathian and the late early Spathian. A positive δ¹³C_org shift of ~4‰ around the Smithian/Spathian boundary (SSB) in the lowermost Spathian was associated with significant biotic recovery, coincident with a positive δ³⁴S excursion of ~25‰ and a low V/(V + Ni) ratio. The results suggest that the oxic conditions contributed to this recovery. Enhanced global ocean circulation during the SSB climate cooling may also have promoted this recovery. Frequent environmental perturbations may have aborted the biotic recovery, although the second episode of oxic conditions occurred in the late early Spathian. Sustained recovery did not appear in the Early Triassic because of the recurrent and long-term ocean anoxia. Full article

The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad prospecting potential. This study focuses on samples from uranium ore holes and uranium-mineralized holes in the area, conducting grain-size analysis of uranium-bearing sandstones, heavy mineral assemblage analysis, and detrital zircon U-Pb dating to systematically investigate provenance characteristics. The results indicate that the uranium-bearing sandstones in the lower member of the Saihan Formation were primarily transported by rolling and suspension, characteristic of braided river channel deposits. The heavy mineral assemblage is dominated by zircon + limonite + garnet + ilmenite, suggesting that the sedimentary provenance is mainly composed of intermediate-acid magmatic rocks with minor metamorphic components. Detrital zircon U-Pb ages are mainly concentrated in the ranges of 294–217 Ma (Early Permian to Late Triassic), 146–112 Ma (Middle Jurassic to Early Cretaceous), 434–304 Ma (Late Carboniferous to Early Permian), and 495–445 Ma (Middle–Late Ordovician to Early Silurian). Combined with comparisons of the ages of surrounding rock masses, the provenance of the uranium-bearing sandstones is mainly derived from intermediate-acid granites of the Early Permian–Late Triassic and Middle Jurassic–Early Cretaceous periods in the southern part of the Sonid Uplift, with minor contributions from metamorphic and volcanic rock fragments. The average zircon uranium content is 520.53 ppm, with a Th/U ratio of 0.73, indicating that the provenance not only supplied detrital materials but also provided uranium-rich rock bodies that contributed essential metallogenic materials for uranium mineralization. This study offers critical insights for regional prospecting and exploration deployment. Full article

The basement of the Rattlesnake Creek terrane (RCT) in the Klamath Mountains is a mélange of metamorphosed sedimentary and igneous blocks. Recent work shows that the overlying RCT cover sequence has a North American provenance but formed after accretion to the continental margin, so it is unclear if the basement mélange formed exotic or endemic to North America. This study presents petrography and zircon geochronology from RCT metasedimentary blocks and crosscutting intrusions. The southernmost RCT preserves both Early Jurassic and Middle-Late Jurassic cover sequence deposits and records continental clasts and 33% pre-Mesozoic zircons at ~201 Ma, effectively none at ~191 Ma, and 79–90% from 168 to 163 Ma. During active magmatism 207–193 Ma, the RCT was receiving continental sediment, inconsistent with a distant intraoceanic arc. We interpret that the RCT subduction zone formed proximal to North America in the Late Triassic and that there was a sediment pathway to the RCT at ~201 Ma. During Middle to Late Jurassic rifting and subsequent Nevadan compression, the cover sequences were dismembered and incorporated into the mélange by tectonic and sedimentary processes. The age and provenance of metasedimentary deposits in the RCT is inconsistent with west-dipping subduction models in the Klamath Mountains region. Full article

Currently, the formation and evolution processes of overpressure in the Upper Paleozoic tight sandstones of the Ordos Basin are not clearly understood. Taking the Shan 1 Member of the Shanxi Formation in the Yanchang area, southeastern Ordos Basin, as an example, we adopted a numerical simulation method considering pressurization effects (e.g., hydrocarbon generation and disequilibrium compaction) to quantitatively reconstruct the paleo-overpressure evolution history of target sandstone and shale layers before the end of the Early Cretaceous. We calculated two types of formation pressure changes since the Late Cretaceous tectonic uplift: the pressure reduction induced by pore rebound, temperature decrease and pressure release from potential brittle fracturing of overpressured shales, and the pressure increase in tight sandstones caused by overpressure transmission, thus clarifying the abnormal pressure evolution process of the Upper Paleozoic Shanxi Formation tight sandstones in the study area. The results show that at the end of the Early Cretaceous, the formation pressures of the target shale and sandstone layers in the study area reached their peaks, with the formation pressure coefficients of shale and sandstone being 1.41–1.59 and 1.10, respectively. During tectonic uplift since the early Late Cretaceous, temperature decrease and brittle fracture-induced pressure release caused significant declines in shale formation pressure, by 12.95–17.75 MPa and 20.00–25.24 MPa, respectively, resulting in the current shale formation pressure coefficients of 1.00–1.06. In this stage, temperature decrease and pore rebound caused sandstone formation pressure to decrease by 12.07–13.85 MPa and 16.93–17.41 MPa, respectively. Meanwhile, the overpressure transfer from two phases of hydrocarbon charging during the Late Triassic–Early Cretaceous and pressure release from shale brittle fracture during the Late Cretaceous tectonic uplift induced an increase in adjacent sandstone formation pressure, with a total pressure increase of 7.32–8.58 MPa. The combined effects of these three factors have led to the evolution of the target sandstone layer from abnormally high pressure in the late Early Cretaceous to the current abnormally low pressure. This study contributes to a deeper understanding of the formation process of underpressured gas reservoir in the Upper Paleozoic of the Ordos Basin. Full article