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20 pages, 16348 KiB  
Article
The Recent Extinction of the Carihuairazo Volcano Glacier in the Ecuadorian Andes Using Multivariate Analysis Techniques
by Pedro Vicente Vaca-Cárdenas, Eduardo Antonio Muñoz-Jácome, Maritza Lucia Vaca-Cárdenas, Diego Francisco Cushquicullma-Colcha and José Guerrero-Casado
Earth 2025, 6(3), 86; https://doi.org/10.3390/earth6030086 (registering DOI) - 1 Aug 2025
Abstract
Climate change has accelerated the retreat of Andean glaciers, with significant recent losses in the tropical Andes. This study evaluates the extinction of the Carihuairazo volcano glacier (Ecuador), quantifying its area from 1312.5 m2 in September 2023 to 101.2 m2 in [...] Read more.
Climate change has accelerated the retreat of Andean glaciers, with significant recent losses in the tropical Andes. This study evaluates the extinction of the Carihuairazo volcano glacier (Ecuador), quantifying its area from 1312.5 m2 in September 2023 to 101.2 m2 in January 2024, its thickness (from 2.5 m to 0.71 m), and its volume (from 2638.85 m3 to 457.18 m3), before its complete deglaciation in February 2024; this rapid melting and its small size classify it as a glacierette. Multivariate analyses (PCA and biclustering) were performed to correlate climatic variables (temperature, solar radiation, precipitation, relative humidity, vapor pressure, and wind) with glacier surface and thickness. The PCA explained 70.26% of the total variance, with Axis 1 (28.01%) associated with extreme thermal conditions (temperatures up to 8.18 °C and radiation up to 16.14 kJ m−2 day−1), which probably drove its disappearance. Likewise, Axis 2 (21.56%) was related to favorable hydric conditions (precipitation between 39 and 94 mm) during the initial phase of glacier monitoring. Biclustering identified three groups of variables: Group 1 (temperature, solar radiation, and vapor pressure) contributed most to deglaciation; Group 2 (precipitation, humidity) apparently benefited initial stability; and Group 3 (wind) played a secondary role. These results, validated through in situ measurements, provide scientific evidence of the disappearance of the Carihuairazo volcano glacier by February 2024. They also corroborate earlier projections that anticipated its extinction by the middle of this decade. The early disappearance of this glacier highlights the vulnerability of small tropical Andean glaciers and underscores the urgent need for water security strategies focused on management, adaptation, and resilience. Full article
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15 pages, 1849 KiB  
Article
Evolution of Gait Biomechanics During a Nine-Month Exercise Program for Parkinson’s Disease: An Interventional Cohort Study
by Dielise Debona Iucksch, Elisangela Ferretti Manffra and Vera Lucia Israel
Biomechanics 2025, 5(3), 53; https://doi.org/10.3390/biomechanics5030053 (registering DOI) - 1 Aug 2025
Abstract
It is well established that combining exercise with medication may benefit functionality in individuals with PD (Parkinson’s disease). However, the long-term evolution of gait biomechanics under this combination remains poorly understood. Objectives: This study aims to analyze the evolution of spatiotemporal gait parameters, [...] Read more.
It is well established that combining exercise with medication may benefit functionality in individuals with PD (Parkinson’s disease). However, the long-term evolution of gait biomechanics under this combination remains poorly understood. Objectives: This study aims to analyze the evolution of spatiotemporal gait parameters, kinetics, and kinematics throughout a long-term exercise program conducted in water and on dry land. Methods: We have compared the trajectories of biomechanical variables across the treatment phases using statistical parametric mapping (SPM). A cohort of fourteen individuals with PD (mean age: 65.6 ± 12.1 years) participated in 24 sessions of aquatic exercises over three months, followed by a three-month retention phase, and then 24 additional sessions of land-based exercises. Three-dimensional gait data and spatiotemporal parameters were collected before and after each phase. Two-way ANOVA with repeated measures was used to compare spatiotemporal parameters. Results: The walking speed increased while the duration of the double support phase decreased. Additionally, the knee extensor moment consistently increased in the entire interval from midstance to midswing (20% to 70% of the stride period), approaching normal gait patterns. Regarding kinematics, significant increases were observed in both hip and knee flexion angles. Furthermore, the abnormal ankle dorsiflexion observed at the foot strike disappeared. Conclusions: These findings collectively suggest positive adaptations in gait biomechanics during the observation period. Full article
(This article belongs to the Special Issue Gait and Balance Control in Typical and Special Individuals)
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14 pages, 863 KiB  
Article
The Effect of the Extraction Temperature on the Colligative, Hydrodynamic and Rheological Properties of Psyllium Husk Mucilage Raw Solutions
by Anna Ptaszek, Marta Liszka-Skoczylas and Urszula Goik
Molecules 2025, 30(15), 3219; https://doi.org/10.3390/molecules30153219 (registering DOI) - 31 Jul 2025
Abstract
The aim of the research was to analyse the effect of different extraction temperatures on the colligative, hydrodynamic, and rheological properties of a water-soluble AXs fractions. The research material consisted of raw water extracts of arabinoxylans obtained from the husk at the following [...] Read more.
The aim of the research was to analyse the effect of different extraction temperatures on the colligative, hydrodynamic, and rheological properties of a water-soluble AXs fractions. The research material consisted of raw water extracts of arabinoxylans obtained from the husk at the following temperatures: 40 °C (AX40), 60 °C (AX60), 80 °C (AX80), and 100 °C (AX100). These were characterised in terms of their hydrodynamic, osmotic, and rheological properties, as well as the average molecular mass of the polysaccharide fractions. An increase in extraction temperature resulted in an increase in weight-average molecular mass, from 2190 kDa (AX40) to 3320 kDa (AX100). The values of the osmotic average molecular mass were higher than those obtained from GPC, and decreased with increasing extraction temperature. The dominance of biopolymer–biopolymer interactions was evident in the shape of the autocorrelation function, which did not disappear as the extraction temperature and concentration increased. Furthermore, the values of the second virial coefficient were negative, which is indicative of the tendency of biopolymer chains to aggregate. The rheological properties of the extracts changed from being described by a power-law model (AX40 and AX60) to being described by the full non-linear De Kee model (AX80 and AX100). Full article
(This article belongs to the Section Physical Chemistry)
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35 pages, 4940 KiB  
Article
A Novel Lightweight Facial Expression Recognition Network Based on Deep Shallow Network Fusion and Attention Mechanism
by Qiaohe Yang, Yueshun He, Hongmao Chen, Youyong Wu and Zhihua Rao
Algorithms 2025, 18(8), 473; https://doi.org/10.3390/a18080473 - 30 Jul 2025
Viewed by 137
Abstract
Facial expression recognition (FER) is a critical research direction in artificial intelligence, which is widely used in intelligent interaction, medical diagnosis, security monitoring, and other domains. These applications highlight its considerable practical value and social significance. Face expression recognition models often need to [...] Read more.
Facial expression recognition (FER) is a critical research direction in artificial intelligence, which is widely used in intelligent interaction, medical diagnosis, security monitoring, and other domains. These applications highlight its considerable practical value and social significance. Face expression recognition models often need to run efficiently on mobile devices or edge devices, so the research on lightweight face expression recognition is particularly important. However, feature extraction and classification methods of lightweight convolutional neural network expression recognition algorithms mostly used at present are not specifically and fully optimized for the characteristics of facial expression images, yet fail to make full use of the feature information in face expression images. To address the lack of facial expression recognition models that are both lightweight and effectively optimized for expression-specific feature extraction, this study proposes a novel network design tailored to the characteristics of facial expressions. In this paper, we refer to the backbone architecture of MobileNet V2 network, and redesign LightExNet, a lightweight convolutional neural network based on the fusion of deep and shallow layers, attention mechanism, and joint loss function, according to the characteristics of the facial expression features. In the network architecture of LightExNet, firstly, deep and shallow features are fused in order to fully extract the shallow features in the original image, reduce the loss of information, alleviate the problem of gradient disappearance when the number of convolutional layers increases, and achieve the effect of multi-scale feature fusion. The MobileNet V2 architecture has also been streamlined to seamlessly integrate deep and shallow networks. Secondly, by combining the own characteristics of face expression features, a new channel and spatial attention mechanism is proposed to obtain the feature information of different expression regions as much as possible for encoding. Thus improve the accuracy of expression recognition effectively. Finally, the improved center loss function is superimposed to further improve the accuracy of face expression classification results, and corresponding measures are taken to significantly reduce the computational volume of the joint loss function. In this paper, LightExNet is tested on the three mainstream face expression datasets: Fer2013, CK+ and RAF-DB, respectively, and the experimental results show that LightExNet has 3.27 M Parameters and 298.27 M Flops, and the accuracy on the three datasets is 69.17%, 97.37%, and 85.97%, respectively. The comprehensive performance of LightExNet is better than the current mainstream lightweight expression recognition algorithms such as MobileNet V2, IE-DBN, Self-Cure Net, Improved MobileViT, MFN, Ada-CM, Parallel CNN(Convolutional Neural Network), etc. Experimental results confirm that LightExNet effectively improves recognition accuracy and computational efficiency while reducing energy consumption and enhancing deployment flexibility. These advantages underscore its strong potential for real-world applications in lightweight facial expression recognition. Full article
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18 pages, 439 KiB  
Article
Is the Concept of Food Sovereignty Still Aligned with Sustainability Principles? Insights from a Q-Methodology Study
by Serena Mandolesi, Ahmed Saidi, Teresa Del Giudice, Simona Naspetti, Raffaele Zanoli and Carla Cavallo
Sustainability 2025, 17(15), 6912; https://doi.org/10.3390/su17156912 - 30 Jul 2025
Viewed by 111
Abstract
Food sovereignty has gained significant political attention in recent years, proven by the recent change of the name of Italian Ministry of Agriculture. Coined by the transnational movement “La Via Campesina” in 1996, food sovereignty emphasizes sustainable food security and the right of [...] Read more.
Food sovereignty has gained significant political attention in recent years, proven by the recent change of the name of Italian Ministry of Agriculture. Coined by the transnational movement “La Via Campesina” in 1996, food sovereignty emphasizes sustainable food security and the right of populations to determine their own food policies. However, the concept is often misunderstood in the light of rising sovereigntist debate, and its original meaning, intertwined with long-term sustainability, is gradually disappearing. This study uses Q methodology to explore consumer perspectives on food sovereignty, identifying distinct groups that reflect how the concept has evolved and how it is perceived by the general population. The analysis is based on a sample of 24 participants from Italy. Starting from all sustainability issues contained in food sovereignty, relevant opinion groups have been identified. Results show that half of the groups still recognize their traditional meaning, while the other half understands food sovereignty as a modern form of autarchy. Full article
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22 pages, 414 KiB  
Article
The Appearance and Disappearance of Ryukyu: The Historical Views of Tō Teikan, Motoori Norinaga, and Ueda Akinari
by Mark Thomas McNally
Histories 2025, 5(3), 32; https://doi.org/10.3390/histories5030032 - 24 Jul 2025
Viewed by 213
Abstract
Two of the renowned figures of Edo-era Kokugaku (National Learning), Motoori Norinaga and Ueda Akinari, famously debated the merits of their scholarly approaches to Japanese antiquity during the latter half of the eighteenth century. Their intellectual dispute was the result of the radical [...] Read more.
Two of the renowned figures of Edo-era Kokugaku (National Learning), Motoori Norinaga and Ueda Akinari, famously debated the merits of their scholarly approaches to Japanese antiquity during the latter half of the eighteenth century. Their intellectual dispute was the result of the radical conclusions reached by Tō Teikan in his Shōkōhatsu (An Outburst of Provocations; 1781) in which he argued that the Korean peninsula and China influenced ancient Japan, and that Japan’s first emperor, Jimmu, was from Ryukyu. While Akinari supported the notion of continental influence on ancient Japan, Norinaga did not, and while the former was mostly agnostic about Jimmu’s Ryukyuan roots, the latter opposed that as well. Norinaga, however, was not opposed to the idea of ancient ties between Ryukyu and Japan, an issue with which Akinari’s silence seemed to signify some degree of agreement. This commonality between these two intellectual giants demonstrated the extent to which Japanese intellectuals of the Edo period viewed the Ryukyu Kingdom (now Okinawa Prefecture) as occupying an ambivalent geopolitical space, in which it was neither fully foreign nor fully native. At the same time, Akinari’s historiographical approach to Japanese antiquity, which emerged in his debate with Norinaga, exerted an influence on nineteenth-century depictions of Ryukyu’s historical and cultural ties to Japan, chiefly Kyokutei Bakin’s Chinsetsu yumiharizuki (Fantastic Tales of the Moon Bow; 1811). Full article
(This article belongs to the Section Cultural History)
12 pages, 262 KiB  
Article
Sex Differences in Bench Press Strength and Power: A Velocity-Based Analysis Adjusted for Body Composition
by Olga López-Torres, Raúl Nieto-Acevedo, Amelia Guadalupe-Grau and Valentín Emilio Fernández Elías
J. Funct. Morphol. Kinesiol. 2025, 10(3), 284; https://doi.org/10.3390/jfmk10030284 - 24 Jul 2025
Viewed by 624
Abstract
Background: Resistance training (RT) promotes muscle hypertrophy and strength gains in both men and women. However, sex differences in neuromuscular performance, muscle fiber composition, and the hormonal environment influence strength and power adaptations. While men generally exhibit greater absolute and relative strength, it [...] Read more.
Background: Resistance training (RT) promotes muscle hypertrophy and strength gains in both men and women. However, sex differences in neuromuscular performance, muscle fiber composition, and the hormonal environment influence strength and power adaptations. While men generally exhibit greater absolute and relative strength, it remains unclear to what extent these differences persist across various load intensities. A better understanding of sex-specific strength and power profiles may help optimize training strategies. The aim of this study was to compare strength and power performance during the bench press exercise in physically active males and females, relative to body mass and fat-free mass (FFM). Methods: Twenty-nine physically active individuals (16 men: 21.3 ± 4.1 years, 13 women: 22.6 ± 4.9 years) performed a one-repetition maximum (1RM) test and an incremental velocity-based assessment at 45%, 55%, 65%, 75%, and 85% of the 1RM using a Smith machine. The barbell velocity was measured via a linear transducer, with the mean propulsive velocity (MPV) recorded for each load. Power-related variables (e.g., peak force [F0], maximal velocity [V0], and maximal power [Pmax]) were analyzed. To account for differences in body composition, data were adjusted for body mass and FFM. Results: Men exhibited significantly greater strength and power than women across most loads when adjusted for both body mass and fat-free mass (FFM) (p < 0.05). These differences were particularly pronounced when normalized to FFM (45–75%1RM; p = 0.001–0.031), with large effect sizes observed (ηp2 = 0.185–0.383). Notably, sex differences in mean propulsive velocity (MPV) disappeared at 85%1RM (p = 0.208; ηp2 = 0.06), suggesting that maximal neuromuscular recruitment may minimize sex-related disparities at higher intensities. Furthermore, men demonstrated significantly higher values in six of the seven power-related variables, with no significant differences in the %1RM required to achieve an optimal power output. Conclusions: These findings confirm that men exhibit greater strength and power than women, even after adjusting for body composition. However, at high relative loads (≥85%1RM), sex differences in movement velocity appear to diminish, likely due to similar recruitment patterns of high-threshold motor units. These results highlight the importance of sex-specific resistance training programs, particularly in relation to load prescription and the application of velocity-based training methods. Full article
49 pages, 21554 KiB  
Article
A Disappearing Cultural Landscape: The Heritage of German-Style Land Use and Pug-And-Pine Architecture in Australia
by Dirk H. R. Spennemann
Land 2025, 14(8), 1517; https://doi.org/10.3390/land14081517 - 23 Jul 2025
Viewed by 219
Abstract
This paper investigates the cultural landscapes established by nineteenth-century German immigrants in South Australia and the southern Riverina of New South Wales, with particular attention to settlement patterns, architectural traditions and toponymic transformation. German immigration to Australia, though numerically modest compared to the [...] Read more.
This paper investigates the cultural landscapes established by nineteenth-century German immigrants in South Australia and the southern Riverina of New South Wales, with particular attention to settlement patterns, architectural traditions and toponymic transformation. German immigration to Australia, though numerically modest compared to the Americas, significantly shaped local communities, especially due to religious cohesion among Lutheran migrants. These settlers established distinct, enduring rural enclaves characterized by linguistic, religious and architectural continuity. The paper examines three manifestations of these cultural landscapes. A rich toponymic landscape was created by imposing on natural landscape features and newly founded settlements the names of the communities from which the German settlers originated. It discusses the erosion of German toponyms under wartime nationalist pressures, the subsequent partial reinstatement and the implications for cultural memory. The study traces the second manifestation of a cultural landscapes in the form of nucleated villages such as Hahndorf, Bethanien and Lobethal, which often followed the Hufendorf or Straßendorf layout, integrating Silesian land-use principles into the Australian context. Intensification of land use through housing subdivisions in two communities as well as agricultural intensification through broad acre farming has led to the fragmentation (town) and obliteration (rural) of the uniquely German form of land use. The final focus is the material expression of cultural identity through architecture, particularly the use of traditional Fachwerk (half-timbered) construction and adaptations such as pug-and-pine walling suited to local materials and climate. The paper examines domestic forms, including the distinctive black kitchen, and highlights how environmental and functional adaptation reshaped German building traditions in the antipodes. Despite a conservation movement and despite considerable documentation research in the late twentieth century, the paper shows that most German rural structures remain unlisted and vulnerable. Heritage neglect, rural depopulation, economic rationalization, lack of commercial relevance and local government policy have accelerated the decline of many of these vernacular buildings. The study concludes by problematizing the sustainability of conserving German Australian rural heritage in the face of regulatory, economic and demographic pressures. With its layering of intangible (toponymic), structural (buildings) and land use (cadastral) features, the examination of the cultural landscape established by nineteenth-century German immigrants adds to the body of literature on immigrant communities, settler colonialism and landscape research. Full article
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14 pages, 7931 KiB  
Article
Characteristics of Surface Temperature Inversion at the Muztagh-Ata Site on the Pamir Plateau
by Dai-Ping Zhang, Wen-Bo Gu, Ali Esamdin, Chun-Hai Bai, Hu-Biao Niu, Li-Yong Liu and Ji-Cheng Zhang
Atmosphere 2025, 16(8), 897; https://doi.org/10.3390/atmos16080897 - 23 Jul 2025
Viewed by 197
Abstract
In this paper, based on all the data from September 2021 to June 2024 collected by a 30 m meteorological tower and a differential image motion monitor (DIMM) at the Muztagh-Ata site located on the Pamir Plateau in western Xinjiang, China, we study [...] Read more.
In this paper, based on all the data from September 2021 to June 2024 collected by a 30 m meteorological tower and a differential image motion monitor (DIMM) at the Muztagh-Ata site located on the Pamir Plateau in western Xinjiang, China, we study the characteristics of the surface temperature inversion and its effect on astronomical seeing at the site. The results show the following: The temperature inversion at the Muztagh-Ata site is highly pronounced at night; it is typically distributed below a height of about 18 m; it weakens and disappears gradually after sunrise, while it forms gradually after sunset and remains stable during the night; and it is weaker in spring and summer but stronger in autumn and winter. Correlation studies with meteorological parameters show the following: increases in both cloud coverage and humidity weaken temperature inversion; the distribution of inversion with wind speed exhibits a bimodal distribution; southwesterly winds prevail at a frequency of 73.76% and are typically accompanied by strong temperature inversions. Finally, by statistical patterns, we found that strong temperature inversion at the Muztagh-Ata site usually bring better seeing by suppressing atmospheric optical turbulence. Full article
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14 pages, 619 KiB  
Article
Carcass Color in Broilers When Replacing Wheat with Corn in the Diet
by Maria del Mar Campo and Leticia Mur
Foods 2025, 14(15), 2558; https://doi.org/10.3390/foods14152558 - 22 Jul 2025
Viewed by 197
Abstract
The effect of replacing wheat with corn on the color distribution across various locations in the carcasses of broilers was assessed. One thousand two hundred ROSS 308 one-day-old male chicks were reared in an experimental farm, with ten pens per treatment, based on [...] Read more.
The effect of replacing wheat with corn on the color distribution across various locations in the carcasses of broilers was assessed. One thousand two hundred ROSS 308 one-day-old male chicks were reared in an experimental farm, with ten pens per treatment, based on the primary cereal ingredient during both the starter (1–14 d) and grower (15–41 d) phases: corn and wheat. At 41 days old, slaughtering was performed. At 24 h post slaughter, color measurements were taken in 15 carcasses per treatment using a MINOLTA CM600d reflectance spectrocolorimeter in the CIEL*a*b* space. Twelve locations were measured: drumette, apterial latero-pectoral area, neck, the back at the seventh thoracic vertebra, saddle, thigh, ham, hock and around the vent, shanks, and the surface and interior of the breast. The results indicate that the color distribution in the broiler carcass is not homogeneous. Very small color differences can be found between the surface and the interior of the breast, but they differ greatly from areas where there is skin. Corn produces a darker color than wheat, though the intact skin homogenizes lightness* across the entire carcass, reducing differences between regions. Corn increased mainly yellowness, influencing color saturation. The pronounced color differences between the shank and other locations almost disappear when corn is excluded from the feed. Hue° could serve as a potential indicator of color variations in the breast resulting from differences in dietary ingredients. Full article
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20 pages, 4045 KiB  
Review
“Winners” and “Losers” of the Bivalve Evolution
by Jasenka Sremac and Marija Bošnjak
Diversity 2025, 17(7), 500; https://doi.org/10.3390/d17070500 - 21 Jul 2025
Viewed by 428
Abstract
Bivalves are nowadays represented by several thousand species of variable sizes and shapes. Additionally, thousands more species occurred during their 500-million-year long evolution. Present on Earth since the Cambrian, the class Bivalvia experienced periods of gradual evolution, interspersed with periods of rapid changes. [...] Read more.
Bivalves are nowadays represented by several thousand species of variable sizes and shapes. Additionally, thousands more species occurred during their 500-million-year long evolution. Present on Earth since the Cambrian, the class Bivalvia experienced periods of gradual evolution, interspersed with periods of rapid changes. Some groups of bivalves, namely clams, oysters, scallops, and marine mussels, managed to survive a series of extinctions, and their descendants still thrive in modern oceans and seas. Other groups, such as the rudists, completely disappeared from marine environments, after undergoing successful evolutionary radiation. In this study, we consider the possible reasons for the longevity of some bivalve orders and discuss the possible causes of demise of several once-successful clades. As expected, a small body size, large number of specimens, infaunal mode of life, motility, and long-living planktonic larvae proved to be evolutionary advantages during stress periods. The ability to harbor chemosymbionts could be an additional benefit during biotic crises. Full article
(This article belongs to the Special Issue Diversity, Biogeography, Fossil Record and Evolution of Bivalvia)
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21 pages, 8441 KiB  
Article
Upper Pleistocene Marine Levels of the Es Copinar–Es Estufadors (Formentera, Balearic Islands, West Mediterranean)
by Laura del Valle, Guillem X. Pons and Joan J. Fornós
Quaternary 2025, 8(3), 38; https://doi.org/10.3390/quat8030038 - 21 Jul 2025
Viewed by 244
Abstract
Late Pleistocene coastal deposits on the southeastern coast of Formentera (Es Ram–Es Estufadors) provide a high-resolution record of sea-level and climatic fluctuations associated with Marine Isotope Stage (MIS) 5. Three distinct beach levels (Sef-1, Sef-2, Sef-3) were identified, corresponding to substages MIS 5e, [...] Read more.
Late Pleistocene coastal deposits on the southeastern coast of Formentera (Es Ram–Es Estufadors) provide a high-resolution record of sea-level and climatic fluctuations associated with Marine Isotope Stage (MIS) 5. Three distinct beach levels (Sef-1, Sef-2, Sef-3) were identified, corresponding to substages MIS 5e, 5c, and possibly 5a, based on sedimentological features, fossil assemblages, and Optically Stimulated Luminescence (OSL) dating. The oldest beach level (Sef-1) is attributed to MIS 5e (ca. 128–116 ka) and is characterised by the widespread presence of thermophilic Senegalese fauna—including Thetystrombus latus, Conus ermineus, and Linatella caudata—which mark the onset of this interglacial phase and are associated with two peaks in relative sea-level highstand. A subsequent cooling event during MIS 5d is recorded by the development of thin palaeosols and the disappearance of these warm-water taxa. The second beach level (Sef-2) reflects renewed sea-level rise and warmer conditions during MIS 5c, with abundant macrofauna and red algae. The transition to MIS 5b (~97 ka) is marked by a significant sea-level drop (down to –60 m), cooler climate, and enhanced colluvial sedimentation linked to increased runoff and erosion. In total, 54 macrofaunal species were identified—16 from Sef-1 and 46 from Sef-2—highlighting ecological shifts across substages. These results improve our understanding of coastal response to sea-level oscillations and paleoenvironmental dynamics in the western Mediterranean during the Late Pleistocene. Full article
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18 pages, 1988 KiB  
Article
What Can Ground-Dwelling Ants Tell Us About Different Land-Use Systems in the Brazilian Amazon?
by Elisangela Silva, Cristina Machado Borges, Emília Zoppas Albuquerque, Daniela Faria Florencio, Izaias Fernandes, Mariana Tolentino, Vanesca Korasaki, Júlio Louzada and Ronald Zanetti
Forests 2025, 16(7), 1190; https://doi.org/10.3390/f16071190 - 19 Jul 2025
Viewed by 327
Abstract
Tropical rainforests are rapidly disappearing due to human activities, particularly land-use changes, resulting in a heterogeneous mosaic of landscapes that substantially contribute to global terrestrial biodiversity loss. We investigated how changes in land-use affect species richness, composition, and functional guilds of ground-dwelling ants [...] Read more.
Tropical rainforests are rapidly disappearing due to human activities, particularly land-use changes, resulting in a heterogeneous mosaic of landscapes that substantially contribute to global terrestrial biodiversity loss. We investigated how changes in land-use affect species richness, composition, and functional guilds of ground-dwelling ants within various land-use systems at a local scale in the Amazonian rainforest. Our focus was to respond to the following: (i) How do local species richness and community composition reflect differences among land-use systems? (ii) Are ground-dwelling ants, especially specialists, negatively impacted by intensified land-use changes? We surveyed 55 sites representing five land-use systems: primary forest, secondary forest, forest corridor, selective logging, and Eucalyptus plantation. We registered 150 ant species, and species richness ranged from 43 to 94. Richness varies according to the land-use systems, likely influenced by differences in habitat structural complexity both vertically and horizontally. Ant species composition and guilds distribution also varied among land-use systems studied. Environments characterized by reduced structural complexity or higher disturbed levels, such as Eucalyptus plantations, tend to support lower resource availability, which may lead to decreased species richness. However, the surrounding matrix appears to play a key role in maintaining regional biodiversity, as evidenced by the absence of differences in ground-dwelling ants diversity across all land-use systems studied. Full article
(This article belongs to the Section Forest Biodiversity)
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29 pages, 4982 KiB  
Article
Comprehensive Investigation of Polymorphic Stability and Phase Transformation Kinetics in Tegoprazan
by Joo Ho Lee, Ki Hyun Kim, Se Ah Ryu, Jason Kim, Kiwon Jung, Ki Sung Kang and Tokutaro Yamaguchi
Pharmaceutics 2025, 17(7), 928; https://doi.org/10.3390/pharmaceutics17070928 - 18 Jul 2025
Viewed by 406
Abstract
Background/Objectives: Tegoprazan (TPZ) is a potassium-competitive acid blocker (P-CAB) used to treat conditions such as gastroesophageal reflux disease, peptic ulcer, and Helicobacter pylori infection. It exists in three solid forms: amorphous, Polymorph A, and Polymorph B. This study investigates the molecular basis of [...] Read more.
Background/Objectives: Tegoprazan (TPZ) is a potassium-competitive acid blocker (P-CAB) used to treat conditions such as gastroesophageal reflux disease, peptic ulcer, and Helicobacter pylori infection. It exists in three solid forms: amorphous, Polymorph A, and Polymorph B. This study investigates the molecular basis of polymorph selection, focusing on conformational bias and solvent-mediated phase transformations (SMPTs). Methods: The conformational energy landscapes of two TPZ tautomers were constructed using relaxed torsion scans with the OPLS4 force field and validated by nuclear Overhauser effect (NOE)-based nuclear magnetic resonance (NMR). Hydrogen-bonded dimers were analyzed using DFT-D. Powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), solubility, and slurry tests were conducted using methanol, acetone, and water. Kinetic profiles were modeled with the Kolmogorov–Johnson–Mehl–Avrami (KJMA) equation. Results: Polymorph A was thermodynamically stable across all analyses. Both amorphous TPZ and Polymorph B converted to A in a solvent-dependent manner. Methanol induced direct A formation, while acetone showed a B → A transition. Crystallization was guided by solution conformers and hydrogen bonding. Conclusions: TPZ polymorph selection is governed by solution-phase conformational preferences, tautomerism, and solvent-mediated hydrogen bonding. DFT-D and NMR analyses showed that protic solvents favor the direct crystallization of stable Polymorph A, while aprotic solvents promote the transient formation of metastable Polymorph B. Elevated temperatures and humidity accelerate polymorphic transitions. This crystal structure prediction (CSP)-independent strategy offers a practical framework for rational polymorph control and the mitigation of disappearing polymorph risks in tautomeric drugs. Full article
(This article belongs to the Special Issue Drug Polymorphism and Dosage Form Design, 2nd Edition)
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Article
Mixed Ensiling Increases Degradation Without Altering Attached Microbiota Through In Situ Ruminal Incubation Technique
by Xuanxuan Pu, Min Zhang, Jianjun Zhang, Xiumin Zhang, Shizhe Zhang, Bo Lin, Tianwei Wang, Zhiliang Tan and Min Wang
Animals 2025, 15(14), 2131; https://doi.org/10.3390/ani15142131 - 18 Jul 2025
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Abstract
Mixed silage can disrupt the girder structure of rape straw, and thus facilitate ruminal degradation. Further investigation is warranted to validate this observation in vivo. The objective of this study was to investigate the degradation kinetics and bacterial colonization of mixed silage during [...] Read more.
Mixed silage can disrupt the girder structure of rape straw, and thus facilitate ruminal degradation. Further investigation is warranted to validate this observation in vivo. The objective of this study was to investigate the degradation kinetics and bacterial colonization of mixed silage during digestion using an in situ ruminal incubation technique. The experiment comprised two treatments: a mixture of rape straw and corn silage (control), and a mixed silage treatment of rape straw and whole crop corn (mixed silage). Three ruminally cannulated Holstein bulls were employed. Substrates were incubated for varying durations (4, 12, 24, 48, 72, 96, 120 and 216 h) to assess substrate degradation kinetics. Bacterial colonization were analyzed after 4- and 48-h incubation time. Mixed ensiling disrupted the fiber structure of rape straw, and thus had lower fiber content compared to the control, as NDF and ADF content ‌decreased by 55 g/kg (678 vs. 623 g/kg) and 27 g/kg (440 vs. 413 g/kg), respectively. Compared to the control group, ruminal DM disappearance of mixed silage significantly (p ≤ 0.05) increased from 315 to 366 g/kg (+16.2%) at an incubation time of 4 h, 552 to 638 g/kg (+15.6%) at 120 h, and 563 to 651 g/kg (+15.6%) at 216 h. Similarly, compared to the control group, NDF disappearance of mixed silage significantly (p ≤ 0.05) rose from 112 to 201 g/kg (+79.5%) at 4 h, 405 to 517 g/kg (+27.7%) at 120 h, and 429 to 532 g/kg (+24.0%) at 216 h. Compared to the control group, soluble and washout nutrient fractions (a) of DM or NDF fraction in mixed silage significantly (p ≤ 0.05) rose from 289 to 340 g/kg (+17.6%), potentially degradable fractions (b) of NDF increased from 310 to 370 g/kg (+19.4%), and the undegraded fraction of NDF (μNDF) decreased from 582 to 471 g/kg (−19.1%). Incubation time, apart from in the mixed ensiling treatment, altered the bacterial community. The study highlights that higher total potentially degradable fractions account for enhanced ruminal substrate degradation of mixed silage. Full article
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