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11 pages, 3494 KB  
Article
A Simulation and Experimental Study of the Current Contact Notch Structure on the Fracture Capacity of Pyro-Breakers
by Jifei Ye, Guanghong Wang, Hua Li, Zhiquan Song and Peng Fu
Modelling 2025, 6(4), 159; https://doi.org/10.3390/modelling6040159 - 3 Dec 2025
Viewed by 196
Abstract
The current contact of pyro-breakers must rapidly interrupt current when the superconducting magnet loses its superconductivity. To enhance the microsecond-scale current-breaking capability of pyro-breakers in nuclear fusion devices, this study investigates the impact of current contact notch structures on dynamic fracture behavior. Through [...] Read more.
The current contact of pyro-breakers must rapidly interrupt current when the superconducting magnet loses its superconductivity. To enhance the microsecond-scale current-breaking capability of pyro-breakers in nuclear fusion devices, this study investigates the impact of current contact notch structures on dynamic fracture behavior. Through multi-physics field modeling and controlled explosive testing, it is revealed for the first time that the rectangular-notch structure demonstrates enhanced fracture performance relative to the V-notch configuration under explosive impact loading conditions, achieving a 27.3% reduction in fracture initiation time alongside a 47.5% increase in crack propagation width. These findings provide a robust theoretical basis for designing pyro-breakers with enhanced fast-break capabilities in fusion devices. Full article
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18 pages, 531 KB  
Article
Applied Research on the Impact of a Neuromotor Development Program on the Lower Limb Strength of Junior Athletes in Greco-Roman Wrestling
by Florentin Vasilescu, Nicoleta Leonte, Cristiana Maria Porfireanu and Virgil Tudor
Sports 2025, 13(12), 428; https://doi.org/10.3390/sports13120428 - 3 Dec 2025
Viewed by 261
Abstract
This study investigates the effects of a structured motor intervention program on the development of lower limb strength in junior athletes practicing Greco-Roman wrestling. Recognizing the crucial role of explosive strength in performing technical and decisive actions during combat, the research introduces a [...] Read more.
This study investigates the effects of a structured motor intervention program on the development of lower limb strength in junior athletes practicing Greco-Roman wrestling. Recognizing the crucial role of explosive strength in performing technical and decisive actions during combat, the research introduces a progressive, applied training protocol tailored to the neuromotor development of children aged 10 to 12 years (control group: M = 11.14, SD = 1.10; experimental group: M = 11.07, SD = 0.83). Conducted over 17 months, the study involved two groups of 14 registered wrestlers each from School Sports Club No. 5 in Bucharest. The experimental group participated in a complementary motor training program emphasizing plyometric drills, bodyweight strength exercises, and wrestling-specific movements, while the control group continued with the standard training routine. The intervention’s impact was evaluated using the OptoJump Next system, a biomechanical analysis tool measuring key indicators of explosive strength—jump height, ground contact time, flight time, and reactive strength index (RSI)—through the single-leg counter-movement jump (CMJ) test. Comparative analysis of pre- and post-intervention results showed significant improvements in neuromotor performance among athletes in the experimental group, confirming the effectiveness of the proposed methodology. This research thus provides a reproducible, evidence-based intervention model with direct applicability in optimizing the training of young Greco-Roman wrestlers. Full article
(This article belongs to the Special Issue Sport-Specific Testing and Training Methods in Youth)
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30 pages, 11915 KB  
Article
Structural Response of a Two-Side-Supported Square Slab Under Varying Blast Positions from Center to Free Edge and Beyond in a Touch-Off Explosion Scenario
by S. M. Anas, Rayeh Nasr Al-Dala’ien, Mohammed Benzerara and Mohammed Jalal Al-Ezzi
Buildings 2025, 15(23), 4371; https://doi.org/10.3390/buildings15234371 - 2 Dec 2025
Viewed by 172
Abstract
A touch-off explosion on concrete slabs is considered one of the simplest yet most destructive forms of adversarial loading on building elements. It causes far greater damage than explosions occurring at a distance. The impact is usually concentrated in a small area, leading [...] Read more.
A touch-off explosion on concrete slabs is considered one of the simplest yet most destructive forms of adversarial loading on building elements. It causes far greater damage than explosions occurring at a distance. The impact is usually concentrated in a small area, leading to surface cratering, scabbing of concrete, and even tearing or rupture of the reinforcement. Studies available on the behavior of reinforced concrete (RC) slabs under touch-off (contact) and standoff explosions commonly indicate that the maximum damage occurs when the blast is applied to the center of the slab. This observation raises an important question about how the position of an explosive charge, especially relative to the free edge of the slab, affects the overall damage pattern in slabs supported on only two sides with clamped supports. This study uses a modeling strategy combining Eulerian and Lagrangian domains using the finite element tools of Abaqus Explicit v2020 to examine the behavior of a square slab supported on two sides with clamped ends subjected to blast loads at different positions, ranging from the center to the free edge and beyond, under touch-off explosion conditions. The behavior of concrete was captured using the Concrete Damage Plasticity model, while the reinforcement was represented with the Johnson–Cook model. Effects of strain rate were included by applying calibrated dynamic increase factors. The developed numerical model is validated first with experimental data available in the published literature for the case where the explosive charge is positioned at the slab’s center, showing a very close agreement with the reported results. Along with the central blast position, five additional cases were considered for further investigation as they have not been investigated in the existing literature and were found to be worthy of study. The selected locations of the explosive charge included an intermediate zone (between the slab center and free edge), an in-slab region (partly embedded at the free edge), a partial edge (partially outside the slab), an external edge (fully outside the free edge), and an offset position (250 mm beyond the free edge along the central axis). Results indicated a noticeable transition in damage patterns as the detonation point shifted from the slab’s center toward and beyond the free edge. The failure mode changed from a balanced perforation under confined conditions to an asymmetric response near the free edge, dominated by weaker surface coupling but more pronounced tensile cracking and bottom-face perforation. The reinforcement experienced significantly varying tensile and compressive stresses depending on blast position, with the highest tensile demand occurring near free-edge detonations due to intensified local bending and uneven shock reflection. Full article
(This article belongs to the Section Building Structures)
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21 pages, 1589 KB  
Article
Low-Alkali Assisted Instant Catapult Steam Explosion Enhances Enzymatic Hydrolysis of Corn Stover by Alleviating Anti-Enzymatic Hydrolysis Factors Through Lignin Structural Rearrangement
by Hongsen Zhang, Wenjing Li, Yufei Yang, Guotao Mao, Fengqin Wang, Hui Xie, Zengping Su, Jingliang Xu and Andong Song
Polymers 2025, 17(23), 3148; https://doi.org/10.3390/polym17233148 - 26 Nov 2025
Viewed by 286
Abstract
The effective deconstruction of lignocellulosic biomass is essential for sustainable biorefineries. In this study, corn stover was pretreated by low-alkali (1–5 wt% NaOH) pre-impregnation assisted instant catapult steam explosion (ICSE) to investigate its influence on enzymatic hydrolysis efficiency and the mechanism of lignin-derived [...] Read more.
The effective deconstruction of lignocellulosic biomass is essential for sustainable biorefineries. In this study, corn stover was pretreated by low-alkali (1–5 wt% NaOH) pre-impregnation assisted instant catapult steam explosion (ICSE) to investigate its influence on enzymatic hydrolysis efficiency and the mechanism of lignin-derived anti-enzymatic factors. The results showed that this pretreatment effectively enhanced glucose yield. Under 4–5% NaOH conditions, washed samples achieved glucose yields above 98%. At 4% NaOH, the glucose yields of washed and unwashed groups were 98.88% and 56.34%, respectively, indicating that washing removed soluble inhibitors. LC-MS analysis identified three major water-soluble inhibitory compounds-vanillin, syringaldehyde, and 2-carboxybenzaldehyde-confirming their negative effects on cellulase activity. The alkali-soluble lignin content of unwashed samples (43.28%) was 1.36 times higher than that of washed samples (31.93%), demonstrating its role as a water-insoluble inhibitory factor. Moreover, SEM, XRD, FTIR, and contact angle analyses revealed that 5% NaOH treatment enhanced lignin solubilization, induced structural rearrangement and interfacial hydrophilic reconstruction, and increased cellulose crystallinity and enzyme accessibility. These findings elucidate the mechanistic pathways of lignin transformation and inhibition mitigation, providing valuable insights for efficient and sustainable biomass conversion. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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27 pages, 5819 KB  
Article
Dynamic Error Correction for Fine-Wire Thermocouples Based on CRBM-DBN with PINN Constraint
by Chenyang Zhao, Guangyu Zhou, Junsheng Zhang, Zhijie Zhang, Gang Huang and Qianfang Xie
Symmetry 2025, 17(11), 1831; https://doi.org/10.3390/sym17111831 - 1 Nov 2025
Viewed by 465
Abstract
In high-temperature testing scenarios that rely on contact, fine-wire thermocouples demonstrate commendable dynamic performance. Nonetheless, their thermal inertia leads to notable dynamic nonlinear inaccuracies, including response delays and amplitude reduction. To mitigate these challenges, a novel dynamic error correction approach is introduced, which [...] Read more.
In high-temperature testing scenarios that rely on contact, fine-wire thermocouples demonstrate commendable dynamic performance. Nonetheless, their thermal inertia leads to notable dynamic nonlinear inaccuracies, including response delays and amplitude reduction. To mitigate these challenges, a novel dynamic error correction approach is introduced, which combines a Continuous Restricted Boltzmann Machine, Deep Belief Network, and Physics-Informed Neural Network (CDBN-PINN). The unique heat transfer properties of the thermocouple’s bimetallic structure are represented through an Inverse Heat Conduction Equation (IHCP). An analysis is conducted to explore the connection between the analytical solution’s ill-posed nature and the thermocouple’s dynamic errors. The transient temperature response’s nonlinear characteristics are captured using CRBM-DBN. To maintain physical validity and minimize noise amplification, filtered kernel regularization is applied as a constraint within the PINN framework. This approach was tested and confirmed through laser pulse calibration on thermocouples with butt-welded and ball-welded configurations of 0.25 mm and 0.38 mm. Findings reveal that the proposed method achieved a peak relative error of merely 0.83%, superior to Tikhonov regularization by −2.2%, Wiener deconvolution by 20.40%, FBPINNs by 1.40%, and the ablation technique by 2.05%. In detonation tests, the corrected temperature peak reached 1045.7 °C, with the relative error decreasing from 77.7% to 5.1%. Additionally, this method improves response times, with the rise time in laser calibration enhanced by up to 31 ms and in explosion testing by 26 ms. By merging physical constraints with data-driven methodologies, this technique successfully corrected dynamic errors even with limited sample sizes. Full article
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14 pages, 2437 KB  
Article
Effects of Integrating Wearable Resistance into Regular Volleyball Training on Countermovement Jump Performance and Kinematics During the In-Season Period
by Milosz Mielniczek, Patrick Lunde and Roland van den Tillaar
Biomechanics 2025, 5(4), 75; https://doi.org/10.3390/biomechanics5040075 - 1 Oct 2025
Cited by 1 | Viewed by 1466
Abstract
Background/Objectives: This study aimed to examine the effects of an eight-week wearable resistance (WR) training program on jump performance and jump kinematics in experienced senior female volleyball players. It was hypothesised that using WR would increase training load, thereby enhancing vertical jump [...] Read more.
Background/Objectives: This study aimed to examine the effects of an eight-week wearable resistance (WR) training program on jump performance and jump kinematics in experienced senior female volleyball players. It was hypothesised that using WR would increase training load, thereby enhancing vertical jump performance and influencing kinematic movement patterns. Methods: Sixteen competitive female volleyball players (mean age: 23.5 ± 3.24 years; mean weight: 66.8 ± 6.9 kg; mean height: 174.7 ± 5.8 cm) participated in the study. Participants were randomly assigned to either a control group (n = 8) or an intervention group (n = 8) that trained with calf-mounted WR. The intervention group performed supervised resistance training sessions twice per week for eight weeks, totalling 16 sessions. Jump performance was assessed using an Infrared Optical Contact Grid (MuscleLab, Ergotest Innovation AS, Norway), and jump kinematics were measured with the Xsens Link motion capture system (Movella, The Netherlands). Results: The WR group demonstrated a statistically significant improvement in vertical jump height (p = 0.031), with no significant changes in kinematic variables. The control group, however, showed a significant increase in T8–pelvis flexion during the countermovement jump (CMJ) following the intervention period. Conclusions: Eight weeks of WR training can improve CMJ performance in-season among experienced female volleyball players without affecting movement kinematics. Future research should investigate optimal loading strategies and long-term adaptations. These findings suggest that integrating small wearable loads into regular volleyball practice can help athletes maintain and improve explosive performance without disrupting normal training routines. Full article
(This article belongs to the Section Sports Biomechanics)
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20 pages, 6754 KB  
Article
Study on the Wear Behavior Mechanism of SUS304 Stainless Steel During the Homogenization Process of LFP/NCM Slurry
by Xiangli Wen, Mingkun Bi, Lvzhou Li and Jianning Ding
Materials 2025, 18(19), 4457; https://doi.org/10.3390/ma18194457 - 24 Sep 2025
Viewed by 507
Abstract
During the homogenization process of lithium battery slurry, the slurry shearing process causes the surface of the homogenization equipment to wear and generate metal containing debris, which poses a risk of inducing battery self-discharge and even explosion. Therefore, inhibiting wear of homogenizing equipment [...] Read more.
During the homogenization process of lithium battery slurry, the slurry shearing process causes the surface of the homogenization equipment to wear and generate metal containing debris, which poses a risk of inducing battery self-discharge and even explosion. Therefore, inhibiting wear of homogenizing equipment is imperative, and systematic investigation into the wear behavior and underlying mechanisms of SUS304 stainless steel during homogenization is urgently required. In this study, lithium iron phosphate (LFP) and lithium nickel cobalt manganese oxide (NCM) cathode slurries were used as research objects. Changes in surface parameters, microstructure, and elemental composition of the wear region on SUS304 stainless steel under different working conditions were characterized. The results indicate that in the SUS304-lithium-ion battery slurry system, the potential wear mechanism of SUS304 gradually evolves with changes in load and rotational speed, following the order: adhesive wear (low speed, low load) → abrasive wear (medium speed, high load) → fatigue wear (high speed). Under high-load and high-rotational-speed conditions, oxidative corrosion wear on the ball–disc contact surface is particularly pronounced. Additionally, wear of SUS304 is more severe in the LFP slurry system compared to the NCM system. Macroscopic experiments also revealed that the speed effect is a core factor influencing the wear of SUS304, and the increase in its wear rate is more than twice that caused by the load effect. This study helps to clarify the wear behavior and wear mechanism evolution of homogenization equipment during the lithium battery homogenization process, providing data support and optimization direction for subsequent material screening and surface strengthening treatment of homogenization equipment components. Full article
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30 pages, 12986 KB  
Article
Hybrid FEM/SPH Modeling and CT Analysis of Dynamic Damage in Structural Steel Under Impact Loading
by Dariusz Pyka, Adam Kurzawa, Grzegorz Ziółkowski, Maciej Roszak and Martyna Strąg
Appl. Sci. 2025, 15(18), 10234; https://doi.org/10.3390/app151810234 - 19 Sep 2025
Viewed by 628
Abstract
This study analyzed the dynamic behavior of EN C45 structural steel under impulse loading generated by a pressure wave. The experiments were conducted on a special test rig using two load configurations: (I) direct contact of the load with the sample surface and [...] Read more.
This study analyzed the dynamic behavior of EN C45 structural steel under impulse loading generated by a pressure wave. The experiments were conducted on a special test rig using two load configurations: (I) direct contact of the load with the sample surface and (II) detonation at a distance of 30 mm. Depending on the loading conditions, the specimens were fragmented or developed extensive internal cracks and plastic deformations. To complement the experimental program, hybrid numerical simulations were performed using the finite element method (FEM), smoothed particles hydrodynamics (SPH), and coupled Euler–Lagrange (CEL) approach. A modified Johnson–Cook (JC) model was used to account for dynamic damage and cracks. Computed tomography (CT) and metallographic analyses provided detailed information on the formation of cracks in MnS inclusions, brittle cracks near the sample axis, and shear deformation zones away from the axis. These observations allowed direct correlation with the predicted numerical deformation and damage fields. The innovative nature of this work lies in the combination of three complementary computational techniques with computed tomography analysis and microstructure analysis, providing a comprehensive framework for describing and confirming the mechanisms of damage and fragmentation of structural steels under explosive loading. Full article
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22 pages, 6744 KB  
Article
Research on the Blast Mitigation Performance of Polyurea–Steel Composite Plates Based on Constrained Layer Damping Structures
by Rui Zhang, Qi Dong, Zhiqiang Fang, Yongjun Deng, Pengcheng Li, Hao Xu and Weibo Huang
Polymers 2025, 17(18), 2461; https://doi.org/10.3390/polym17182461 - 11 Sep 2025
Viewed by 807
Abstract
To address the challenge of balancing the damping performance with mechanical strength in conventional polyurea materials for blast mitigation, this study develops a constrained layer damping coating structure using Q413t viscoelastic polyurea (Q413t) as the damping layer and FPU-1 flexible polyurea (FPU-1) as [...] Read more.
To address the challenge of balancing the damping performance with mechanical strength in conventional polyurea materials for blast mitigation, this study develops a constrained layer damping coating structure using Q413t viscoelastic polyurea (Q413t) as the damping layer and FPU-1 flexible polyurea (FPU-1) as the constraining layer. The mechanical behaviors of both types of polyurea were characterized through tensile testing at varying loading speeds, while dynamic thermomechanical analysis was utilized to evaluate their damping properties. A 75 g TNT contact explosion test and finite element simulation were employed to explore the protective mechanism. The results show that Q413t demonstrates significant strain-rate sensitivity under intermediate-strain-rate conditions, whereas FPU-1 exhibits minimal variation in mechanical strength. Q413t demonstrates a superior damping performance over a frequency range of 0–104 Hz. FPU-1 achieved a loss factor of 0.3 when the loading frequency reached 104–105 Hz. Under the 75 g TNT contact explosion load, the configuration with a 1 mm damping layer and a 3 mm constraint layer achieved a maximum displacement reduction of 35.26%. In the constrained layer damping coating, the damping layer contributes to blast protection through energy dissipation and load distribution, while the constraining layer reduces structural deformation by limiting displacement. Relative motion between the layers further enhances the overall damping performance. The constrained layer damping coating provides optimal blast protection when the damping-to-constraining layer thickness ratio is 1:3. The constrained layer damping coating enables the synergistic optimization of mechanical strength and energy dissipation, effectively mitigating structural deformation induced by blast loading and demonstrating promising engineering application potential. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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26 pages, 6981 KB  
Article
Parametric Study of the Effect of Anchor Drive Bolt Geometry on Stress Distribution and Direction of Crack Formation in the Rock Medium
by Józef Jonak, Robert Karpiński and Andrzej Wójcik
Materials 2025, 18(17), 4136; https://doi.org/10.3390/ma18174136 - 3 Sep 2025
Viewed by 1003
Abstract
This paper presents an analysis of the influence of the termination geometry of an undercutting anchor drive bolt and the shape of the bottom of the anchor hole on the initiation and progression of failure processes in a rock medium. The study employed [...] Read more.
This paper presents an analysis of the influence of the termination geometry of an undercutting anchor drive bolt and the shape of the bottom of the anchor hole on the initiation and progression of failure processes in a rock medium. The study employed the finite element method (FEM) to model various bolt termination configurations, including cylindrical terminations with a 2 × 2 mm chamfer, a rounded termination with radius R, and a conical termination. The interaction of these bolt geometries with both cylindrical and conical hole bottoms was analyzed. The numerical simulations enabled the identification of stress concentration zones and crack propagation paths, which are critical to understanding the efficiency and mechanism of rock failure. The results indicate that the geometry of the bolt termination significantly influences stress distribution within the contact zone, as well as the extent and morphology of the resulting failure zone. Specifically, employing a cylindrical termination with a 2 × 2 mm chamfer in combination with a conical hole bottom promotes the development of deep fractures, which may lead to the detachment of larger rock fragments. This mechanism may be useful in the development of non-explosive rock fragmentation technologies. The findings provide a foundation for further optimization of anchor designs and the development of targeted excavation methods in mining and geotechnical engineering. Full article
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28 pages, 8933 KB  
Article
Clays as Dual-Function Materials for TNT Adsorption and Catalytic Degradation: An Experimental Approach
by Raluca Florenta Doroftei, Diana Mirila, Mihaela Silion, Daniela Ionita, Ana-Maria Rosu, Corneliu Munteanu, Bogdan Istrate, Gabriela Muntianu, Ana-Maria Georgescu and Ileana-Denisa Nistor
Materials 2025, 18(16), 3824; https://doi.org/10.3390/ma18163824 - 14 Aug 2025
Viewed by 3395
Abstract
This study explores the adsorption and catalytic degradation of 2,4,6-trinitrotoluene (TNT) from aqueous solutions, using montmorillonite-based catalysts. Commercially, montmorillonite K10 was modified through aluminum pillaring (K10-Al-PILC), followed by vanadium intercalation (K10-Al-PILC-V) and ozone activation. A novel aspect of this work is the use [...] Read more.
This study explores the adsorption and catalytic degradation of 2,4,6-trinitrotoluene (TNT) from aqueous solutions, using montmorillonite-based catalysts. Commercially, montmorillonite K10 was modified through aluminum pillaring (K10-Al-PILC), followed by vanadium intercalation (K10-Al-PILC-V) and ozone activation. A novel aspect of this work is the use of naturally contaminated water as the TNT source. The selected sample, collected from the Plaiul Arșiței–Cireșu–Leșunț region (Oituz, Bacau, Romania), originated from an area historically exposed to explosive residues, where TNT traces were previously identified. The adsorption performance of the materials was evaluated by varying adsorbent dosage, contact time, and solution pH. Catalytic ozonation experiments were conducted under different catalyst masses, ozone concentrations, and reaction times to assess degradation efficiency. The results demonstrated that aluminum pillaring significantly enhanced the adsorption capacity of the clay, while vanadium incorporation further improved both adsorption and catalytic activity. The vanadium-modified material exhibited superior performance in TNT removal, both through adsorption and oxidative degradation. Additionally, the catalytic ozonation process led to the formation of degradation products with reduced toxicity, confirming the potential of these materials for environmental remediation of nitroaromatic pollutants in real water systems. Full article
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14 pages, 1657 KB  
Article
How Do the Surroundings of the C-NO2 Fragment Affect the Mechanical Sensitivity of Trinitroaromatic Molecules? Evidence from Crystal Structures and Ab Initio Calculations
by Danijela S. Kretić, Aleksandra B. Đunović, Dragan B. Ninković and Dušan Ž. Veljković
Crystals 2025, 15(8), 692; https://doi.org/10.3390/cryst15080692 - 30 Jul 2025
Viewed by 684
Abstract
The dissociation of the C-NO2 bond is the initial step in the process of the detonation of nitroaromatic explosives. The strength of the C-NO2 bond is significantly influenced by the relative position of the nitro group with respect to the aromatic [...] Read more.
The dissociation of the C-NO2 bond is the initial step in the process of the detonation of nitroaromatic explosives. The strength of the C-NO2 bond is significantly influenced by the relative position of the nitro group with respect to the aromatic ring plane since the planar arrangement enables the delocalization of electron density, which strengthens this bond. In this study, we have combined a statistical analysis of geometrical parameters extracted from crystal structures of trinitroaromatic molecules with ab initio calculations of non-covalent index plots and Wiberg bond index values for selected trinitroaromatic molecules to elucidate the influence of nearby substituents on the relative position of nitro groups with respect to the aromatic ring plane. The results of the analysis showed that neighboring substituents have a significant impact on the geometry of nitro groups. The results also showed that this influence arises from the repulsive interaction of voluminous substituents, attractive non-covalent contacts, and the electronic effects of substituents. Full article
(This article belongs to the Section Organic Crystalline Materials)
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15 pages, 2997 KB  
Article
Volcanic Ash–Alkaline (Soda) Lake Water Interactions: Biogeochemical Effects in Lake Van as a Model System
by Nazlı Olgun
Water 2025, 17(15), 2171; https://doi.org/10.3390/w17152171 - 22 Jul 2025
Cited by 1 | Viewed by 1683
Abstract
Volcanic ash from explosive eruptions can significantly alter lake water chemistry through ash–water interactions, potentially influencing primary productivity. Alkaline (soda) lakes, mostly found in volcanic regions, are particularly sensitive due to their unique geochemical properties. However, the effects of volcanic ash on the [...] Read more.
Volcanic ash from explosive eruptions can significantly alter lake water chemistry through ash–water interactions, potentially influencing primary productivity. Alkaline (soda) lakes, mostly found in volcanic regions, are particularly sensitive due to their unique geochemical properties. However, the effects of volcanic ash on the biogeochemistry and phytoplankton dynamics of soda lakes remain poorly understood. This study presents the first nutrient release experiments using natural alkaline water from Lake Van (Türkiye) and volcanic ash from four volcanoes (Hekla, Arenal, Sakurajima, Rabaul-Tavurvur) with different compositions. Sixteen abiotic leaching experiments were conducted over contact durations ranging from 1 to 24 h. Results show rapid increases in pH (~0.4–0.5 units), enhanced silica and phosphate concentrations, and elevated levels of Na, K, Ca, Sr, and S. Nitrate and Mg were generally depleted. The low N:P ratio (~0.06) in Lake Van water indicated nitrogen limitation, partially mitigated by ash-derived inputs. Cyanobacteria dominated the phytoplankton community (95%), consistent with nitrogen fixation under low-nitrate conditions. Elevated silica may promote diatom growth, while changes in Mg/Ca ratios suggest possible impacts on carbonate precipitation and microbialite development. These findings highlight the biogeochemical and ecological relevance of volcanic ash inputs to soda lakes. Full article
(This article belongs to the Section Hydrogeology)
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14 pages, 1973 KB  
Article
The Effects of Short-Duration Ischemic Preconditioning on Horizontal and Vertical Jump Performance in Male and Female Track and Field Jumpers
by Varvara Nektaria Gkari, Athanasios Tsoukos, Nikolaos Aspradakis and Gregory C. Bogdanis
J. Funct. Morphol. Kinesiol. 2025, 10(3), 265; https://doi.org/10.3390/jfmk10030265 - 14 Jul 2025
Viewed by 2960
Abstract
Background: Ischemic preconditioning (IPC) is a non-invasive, time-efficient strategy that has been shown to acutely enhance athletic performance. The present study examined the effects of 5 min of IPC on vertical and horizontal jump performance. A secondary aim was to explore the [...] Read more.
Background: Ischemic preconditioning (IPC) is a non-invasive, time-efficient strategy that has been shown to acutely enhance athletic performance. The present study examined the effects of 5 min of IPC on vertical and horizontal jump performance. A secondary aim was to explore the associations between outcomes of the 5-Hop (5-H) test and drop jump performance, in order to provide further evidence supporting the validity of the 5-H test for assessing reactive strength characteristics in trained jumpers. Methods: Twelve trained track and field jumpers (nine males, three females, age: 23.2 ± 2.9 years; height: 1.76 ± 0.07 m; body mass: 71.5 ± 8.0 kg) completed two conditions: an IPC condition applied to one leg and a control condition applied to the contralateral leg. In the first week, one leg was assigned to IPC and the other to the control condition, while in the second week, the conditions for each leg were reversed. Vertical single-leg performance was evaluated by drop jump (DJ) height, ground contact time, and reactive strength index (RSI). Horizontal jump performance was assessed by a five-hop (5-H) test during which total distance (TD), total time (TT), and reactive hopping index (RHI) were obtained. Results: Compared to the control condition, IPC enhanced DJ height (+ 3.6%) and RSI (+ 7.8%) (p < 0.05, g = 0.16 and 0.32, respectively) and reduced contact time (−4.4% p < 0.05, g = 0.41). Also, IPC resulted in significant improvements in TD (+ 4.1%) and RHI (+ 3.9%) during the 5-H test (p < 0.05, g = 0.32 and 0.42, respectively), while TT remained unchanged. Conclusions: A single cycle of IPC acutely improved vertical and horizontal jump performance and reactive strength indices in trained jumpers. These findings support the use of IPC as a practical, time-efficient method to enhance neuromuscular performance in explosive tasks. Full article
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17 pages, 2559 KB  
Article
Thermal Strain and Microstrain in a Polymorphic Schiff Base: Routes to Thermosalience
by Teodoro Klaser, Marko Jaklin, Jasminka Popović, Ivan Grgičević and Željko Skoko
Molecules 2025, 30(12), 2567; https://doi.org/10.3390/molecules30122567 - 12 Jun 2025
Viewed by 793
Abstract
We present a comprehensive structural and thermomechanical investigation of N-salicylideneaniline, a Schiff base derivative that exhibits remarkable thermosalient phase transition behavior. By combining variable-temperature X-ray powder diffraction (VT-XRPD), differential scanning calorimetry (DSC), hot-stage microscopy, and Hirshfeld surface analysis, we reveal two distinct [...] Read more.
We present a comprehensive structural and thermomechanical investigation of N-salicylideneaniline, a Schiff base derivative that exhibits remarkable thermosalient phase transition behavior. By combining variable-temperature X-ray powder diffraction (VT-XRPD), differential scanning calorimetry (DSC), hot-stage microscopy, and Hirshfeld surface analysis, we reveal two distinct thermosalient mechanisms operating in different polymorphic forms. Form I displays pronounced anisotropic thermal expansion with negative strain along a principal axis, culminating in a sudden and explosive phase transition into Form IV. In contrast, Form III transforms more gradually through a microstrain accumulation mechanism. Fingerprint plots and contact evolution from Hirshfeld surface analysis further support this dual-mechanism model. These insights highlight the importance of integrating macro- and microscale structural descriptors to fully capture the mechanical behavior of responsive molecular solids. The findings not only enhance the fundamental understanding of thermosalience but also inform the rational design of functional materials for actuating and sensing applications. Full article
(This article belongs to the Section Materials Chemistry)
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