Search Results (1,129)

Biomass briquettes are an environmentally friendly fuel and have extensive utilization prospects. Compaction pressure is a crucial factor during the production of biomass briquettes, affecting its densification and subsequent potassium release behavior. The release of alkali metals during combustion is typically studied using offline analytical techniques. However, these methods fail to provide real-time measurement of alkali metals release during the combustion process. Therefore, FES, through its equipment simplicity, low operational cost, real-time measurement, and robust adaptability to industrial environments, is commonly employed. In this study, the effect of compaction pressure (80, 130, and 180 MPa) of camphor wood briquettes on potassium release in a premixed flame was investigated by means of Flame Emission Spectroscopy. A spectrometer was used to obtain flame spontaneous emission spectra at three heights above the burner. Based on the proposed spectral analysis method and a calibration procedure, time-resolved flame temperature and concentration of gas-phase potassium in camphor wood briquette combustion were simultaneously measured. The experimental results at the three measurement heights showed that both peak concentration and the amount of gas-phase potassium released from biomass briquettes decreased with the increase in compaction pressure. Furthermore, the amount of potassium released from biomass briquettes at a compaction pressure of 180 MPa was the lowest at all three measurement heights, at 28.0, 14.5, and 21.8 ppm·s. Moreover, the potassium release rate from 0 to 63 s was rapid, and there was an exponential increase in the release ratio curve. The release ratio of potassium reached 50% before entering the ash stage under a compaction pressure of 80 and 130 MPa; in comparison, it only reached 35% under 180 MPa. The potassium release ratio at HAB = 4 cm under compaction pressures of 80, 130, and 180 MPa was 54%, 50%, and 35%, respectively. The findings of this study directly link compaction pressure to K release and demonstrate the applicability of FES for real-time alkali metal detecting, offering both theoretical and practical pathways toward cleaner biomass combustion. Full article

The passage of a premixed stoichiometric methane-air flame through a hole in an internal barrier in a Hele-Shaw channel with one end closed was studied experimentally. It was found that for the same initial conditions, a flame propagating from the closed channel end can either pass through the hole in the barrier or be extinguished. The passage probability dependence on the hole width was found to be non-monotonic, with a sharp maximum at small hole sizes, followed by a minimum at intermediate sizes and a gradual increase as the blockage ratio tends to zero. The nature of this non-monotonic behavior of flame passage probability was analyzed by analyzing the flame front histories leading to flame passage or extinction at the same experimental parameters. A likely cause of this behavior is the development of an alternating-direction gas jet blowing from the hole due to the pressure difference between the channel compartments. Cooling of hot combustion products with cold channel walls can cause a pressure drop in the closed channel part and development of a reverse (open-to-closed compartment) gas jet affecting the approaching flame. Therefore, flame passage or extinguishment is a feature of the whole two-chamber system, rather than an intrinsic flame property. Full article

This study focuses on the development and physicochemical evaluation of an alternative liquid carrier for coal dust combustion modifiers containing solid catalyst particles. A commercially used acrylic-polymer-based carrier, whose viscosity is regulated by sodium hydroxide addition, was investigated and compared with a proposed safer substitute based on an aqueous sodium carboxymethyl cellulose (Na-CMC) solution. Rheological properties were measured in the shear-rate range relevant to industrial transport and injection systems, while sedimentation behavior was assessed using image-based analysis. The results show that the Na-CMC carrier exhibits shear-thinning behavior and viscosity levels comparable to the commercial formulation, enabling stable suspension of catalyst particles without the need for alkali additives. Unlike the reference system, the alternative carrier does not generate gas during storage, eliminating potential safety hazards associated with hydrogen evolution. Although no direct combustion experiments were performed, the obtained rheological and stability characteristics indicate that the proposed Na-CMC-based carrier is suitable for short-term storage and injection of catalyst-containing modifiers in coal dust combustion systems. Direct validation of combustion performance is planned in future work. Full article

During on-site welding operations, the sealant coated on anchor bolt surfaces can be ignited by hot particles or localized sparks, potentially triggering a fire hazard. This combustion process involves a complex multi-physics coupling among sealant combustion, convective and radiative heat transfer, and three-dimensional heat conduction in solids. To resolve this coupling, a simulation strategy is proposed that correspondingly integrates the Fire Dynamics Simulator (FDS, version 6.7.6) for modeling combustion and radiation with ABAQUS (2024) for simulating conductive heat transfer in solids. The proposed method is validated against experimental measurements, showing close agreement in temperature evolution. It also demonstrates robustness across varying geometric scales, thereby confirming its reliability for predicting thermal response. Using this validated method, simulations are performed to analyze the fire behavior of an anchor rod-sealant system. Results show that the burning sealant can raise anchor rod temperatures above 900 °C and lead to rapid flame spread between adjacent rods. Furthermore, a sensitivity analysis of thermophysical parameters identifies critical thresholds for fire safety optimization: sealants with an ignition temperature > 280 °C and thermal conductivity ≥ 0.26 W/(m·K) demonstrate effective self-extinguishing properties, while specific heat capacity can retard flame growth. These findings provide a robust numerical framework and quantitative guidelines for the fire-safe design of bridge anchorage systems. Full article

The article presents issues related to fossil fuel energy consumption and CO₂ emissions from motor vehicles. It identifies the main areas of research in this field in the context of motor vehicles, namely driver behavior, fuel consumption, and OBD systems. The research sample consisted of experimental data containing records of a series of test drives conducted with a passenger vehicle equipped with a gasoline-powered internal combustion engine, collected via an OBD diagnostic interface. Three subsets related to engine operation and energy demand patterns were distinguished for the study: during vehicle start-up and low-speed driving (vehicle start-up mode), during urban driving, and during extra-urban driving. Multiple regression models were constructed for the analyzed subsets to predict CO₂ emissions based on engine energy output parameters (power, load) and vehicle kinematic parameters. The developed models were subjected to detailed evaluation and mutual comparison, taking into account their predictive performance and the interpretability of the results. The analysis made it possible to identify the variables with the most substantial impact on CO₂ emissions and fuel energy consumption. The models allow individual drivers to monitor and optimize vehicle energy efficiency in real-time. The extra-urban driving model achieved the highest predictive accuracy, with a mean absolute error (MAE) of 19.62 g/km, which makes it suitable for real-time emission monitoring during highway driving. Full article

The presented work is part of a comprehensive study exploring the feasibility of spark-ignited engines operating on fuels enhanced with additives derived from renewable sources. The investigation focuses on understanding how these alternative fuel mixtures influence engine performance and durability. In particular, attention was given to the thermal behavior of the cylinder head during engine operation with gasoline–ethanol blends. The cylinder head was selected for detailed analysis because it is one of the most thermally stressed components in the engine, directly exposed to combustion heat and pressure. Understanding its thermal state is crucial for assessing the impact of renewable fuel additives on engine reliability, efficiency, and emission characteristics. This study aims to provide insights into optimizing engine design and fuel formulation to accommodate sustainable fuel alternatives while maintaining or improving engine operation under varying conditions. Full article

To reveal the physical evolution of methanol spray under different environmental conditions and injection strategies, this study focuses on the atomization and evaporation behavior of low-pressure methanol spray. The coupled effects of temperature, pressure, and injection parameters are systematically investigated based on constant-volume combustion chamber experiments and three-dimensional CFD simulations. The formation, evolution, and interaction mechanisms of the liquid column core and cooling core are revealed. The results indicate that temperature is the dominant factor influencing methanol spray atomization. When the temperature increases from 255 K to 333 K, the spray penetration distance increases by approximately 70%, accompanied by a pronounced shortening of the liquid-core length and enhanced evaporation and air entrainment. Under low-temperature conditions, a stable liquid-core structure and a strong cooling core are formed, characterized by a high-density, long-axis morphology and an extensive low-temperature region, which suppress fuel–air mixing and ignition. Increasing the ambient pressure improves spray–air mixing but reduces penetration; at 255 K, increasing the ambient pressure from 0.05 MPa to 0.2 MPa increases the spray cone angle by approximately 10% while reducing the penetration distance by about 50%. Furthermore, optimizing the injection pressure or shortening the injection pulse width effectively enhances atomization performance: increasing the injection pressure from 0.4 MPa to 0.6 MPa and reducing the pulse width from 5 ms to 2 ms increases the penetration distance by approximately 30% and reduces the mean droplet diameter by about 20%. Full article

The characteristics of litter combustion have a significant impact on the spread of surface fires in the central Yunnan Province, a high-risk forest fire zone. The burning behavior of individual and mixed-species litter samples from five dominant tree species (Pinus yunnanensis Franch., Keteleeria evelyniana Mast., Quercus variabilis Blume., Quercus aliena var. acutiserrata, and Alnus nepalensis D. Don.) was assessed in this study using cone calorimeter tests. Fern fronds and fine branches were included in additional tests to evaluate their effects on specific combustion parameters, such as Fire Performance Index (FPI), Flame Duration (FD), Time to Ignition (TTI), Mass Loss Rate (MLR), Residual Mass Fraction (RMF), Peak Heat Release Rate (PHRR), and Total Heat Release (THR). There were remarkable differences in the burning properties of the three types of litter (broadleaf, pine needles, and short pine needles). The THR and PHRR values of P. yunnanensis were the highest, whereas the PHRR of the other species varied very little. Short pine needle litter showed incomplete combustion and a long flame duration. When measured against pure pine needle litter, mixtures of P. yunnanensis and broadleaf litter showed lower PHRR. When set side by side to pure pine needle litter, P. yunnanensis and broadleaf litter showed lower PHRR. THR rose when fine branches were included, underlining the significance of fine woody fuels in fire behavior. The insertion of ferns increases the percentage of unburned biomass, prolongs TTI, and dramatically reduces PHRR. Full article

In the pursuit of cleaner and more efficient internal combustion engines, dual-fuel strategies combining diesel and hydrogen are gaining increasing attention. This study employs detailed computational fluid dynamics (CFD) simulations to investigate the behaviour of pilot diesel injections in dual-fuel diesel–hydrogen engines. The study aims to characterize spray formation, ignition delay and early combustion phenomena under various energy input levels. Two combustion models were evaluated to determine their performance under these specific conditions: Tabulated Well Mixed (TWM) and Representative Interactive Flamelet (RIF). After an initial numerical validation using dual-fuel constant-volume vessel experiments, the models are further validated using in-cylinder pressure measurements and high-speed natural combustion luminosity imaging acquired from a large-bore optical engine. Particular attention was given to ignition location due to its influence on subsequent hydrogen ignition. Results show that both combustion models reproduce the experimental behavior reasonably well at high energy input levels (EILs). At low EILs, the RIF model better captures the ignition delay; however, due to its single-flamelet formulation, it predicts an abrupt ignition of all available premixed charge in the computational domain once ignition conditions are reached in the mixture fraction space. Full article

The reactions of hydrogen transfer by hydroxyl radicals involving polycyclic aromatic hydrocarbons (PAH) are important, because these compounds contribute to environmental pollution and negatively affect human health. Hydroxyl radicals play a key role in atmospheric processes. This study analyzed the influence of the substituent and the number of aromatic rings in the compound on the kinetics of the hydrogen-transfer reaction. This work proposes for the first time a quantitative structure–activity relationship-based statistical framework combining design of experiments and tunneling corrections to predict PAH + ·OH kinetics. The main objective of this research was to identify which molecular features and substituent effects most strongly govern tunneling and reactivity, thereby enabling the rational prediction of PAH behavior in atmospheric and combustion environments. For this purpose, a quantitative structure–activity relationship model was developed using 22 descriptors, and their relationship with the kinetic parameters of the reaction was determined using statistical tools such as design of experiments and partial least squares. Full article

Sealing tunnel portals is widely recognized as a pivotal strategy for mitigating fire hazards in tunnel safety management. Nevertheless, the interplay between fire source locations—both longitudinally and transversely—and its impact on flame behavior and ceiling temperature profiles within enclosed structures has not been fully elucidated. Utilizing a 1:15 reduced-scale rectangular tunnel model, this research investigates how varying the fire source position affects the maximum ceiling temperature under enclosed scenarios. Dimensionless parameters, including the longitudinal dimensionless distance D and transverse dimensionless distance Z′, were derived through dimensional analysis. Observations indicate that as the fire approaches the enclosed end, the flame initially leans toward the boundary, peaking in inclination at D = 0.73, and subsequently exhibits a “wall-attached combustion” pattern due to wall confinement. While lateral displacement of the fire source pushes the high-temperature zone toward the corresponding side wall, the longitudinal temperature rise follows a non-monotonic pattern: declining continuously in in Region I (0 ≤ D ≤ 0.73) and rebounding in Region II (0.73 < D < 1). Based on these findings, a dimensionless prediction model incorporating heat release rate (HRR), transverse offset, and longitudinal fire location was developed. Furthermore, a thermal accumulation factor was introduced to refine the predictive model in Region II. The results offer theoretical insights to support fire protection design and risk assessment in enclosed tunnels. Full article

Fluidized bed combustion of biomass requires maintaining stable properties of the inert bed material, which plays a key role in heat transfer, temperature stabilization and uniform fuel distribution in circulating fluidized bed (CFB) boilers. During long-term operation, quartz sand, i.e., the most commonly used inert material, undergoes physical and chemical degradation processes such as attrition, sintering and coating with alkali-rich ash, leading to changes in particle size distribution (PSD), deterioration of fluidization quality, temperature non-uniformities and an increased risk of bed agglomeration. This study analyzes quality management strategies for inert bed materials in biomass-fired CFB systems, with particular emphasis on the influence of PSD on boiler hydrodynamics and thermal behavior. Based on industrial operating data, sieve analyses and CFD simulations performed under representative operating conditions, a recommended mean particle diameter range of approximately 150–200 μm is identified as critical for maintaining stable circulation and uniform temperature fields. Numerical results demonstrate that deviations toward coarser bed materials significantly reduce solids circulation, promote segregation in the lower furnace region and lead to local temperature increases, thereby increasing agglomeration risk. The study further discusses practical approaches to bed material monitoring, regeneration and make-up management in relation to biomass type and ash characteristics. The results confirm that systematic control of inert bed material quality is an essential prerequisite for reliable, efficient and low-emission operation of biomass-fired CFB boilers. Full article

On 2021, in the intensive care unit of a County Emergency Hospital where oxygen therapy treatment was applied to COVID patients, located in the municipality of Ploiesti, Prahova County, a fire occurred that resulted in the destruction by burning of the ICU room, the death of two people, and the injury of a medical professional. In order to elucidate the accelerating causes of the combustion phenomenon of materials in the ICU room, a combustion stand was designed whose atmosphere can be controlled in terms of achieving high oxygen concentrations of 40% vol., in accordance with the treatment schemes applied to the patients and with the configuration of the room and the frequency of use of the access door. In this experimental stand, a series of combustion tests of flexible polyurethane foam samples were performed, which highlighted the acceleration of combustion and the complete consumption of the mass. The purpose of this work is to explain the rapidity of the fire in a hospital ward, both with experimental methods and with the help of FDS. Full article

Marine combustible ice, as a potential clean energy resource, has attracted widespread attention in recent years. To enhance its production efficiency, hydraulic fracturing is considered a promising technique, in which fracture conductivity is one of the key parameters for evaluating stimulation performance. However, experimental investigations on low-strength sediments remain limited, and the evolution of fracture conductivity in hydrate-bearing sediments has not been systematically understood. Since ice and combustible ice share similar characteristics in terms of crystal structure, spectral features, mechanical behavior, and thermal expansion, and ice remains stable under low-temperature conditions, ice was employed as an experimental analog for combustible ice. This study systematically investigated the effects of proppant particle size, proppant concentration, and ice saturation on the short-term fracture conductivity. The results indicate that fracture conductivity increases with higher ice saturation and sand concentration. Larger proppant particles exhibit higher initial conductivity but experience greater conductivity loss. A multi-factor prediction model for the short-term fracture conductivity of fractured marine combustible ice reservoirs was established. The effects of properties of rock plates and sanding induced fracture clogging on conductivity are further discussed. These findings provide an experimental basis and theoretical reference for understanding the fracture conductivity characteristics and optimizing fracturing operations in marine combustible ice reservoirs. Full article

Carbon capture and storage (CCS) technologies are an important step to mitigate CO₂ emissions. This study focuses on CO₂ capture from biomass combustion in fluidized bed boilers using a vacuum pressure swing adsorption (VPSA) process. A pilot-scale VPSA unit was used to evaluate the dynamic adsorption behavior of zeolite 13X and clinoptilolite under realistic operating conditions. Moreover, a simplified one-dimensional isothermal mathematical model of a fixed-bed adsorption column was developed to simulate breakthrough curves to validate whether the model reproduces the observed experimental trends. Experimental results confirmed that fresh zeolite 13X exhibited the highest CO₂ adsorption capacity, while clinoptilolite showed moderate uptake. For both sorbents, a decrease in derived adsorption capacity was observed after prior use. The developed mathematical model successfully reproduced the experimental breakthrough curves, achieving coefficients of determination (R²) up to 0.99 and percentage fit (%Fit) values close to 94% for fresh sorbents, while lower correlations were observed for used sorbents. The model reliably captured the breakthrough curves, validating its applicability for process prediction. These results highlight the effectiveness of combining experimental measurements with modeling to assess sorbent performance and guide further optimization of VPSA processes under realistic flue gas conditions. Full article