Search Results (54)

In this study, fallen leaves of Azadirachta indica and Prunus dulcis were treated as waste materials for the production of energy-intensive bio-coal briquettes. The physical composition revealed that the moisture content ranged from 6.8% to 8.8%, fixed carbon from 10.7% to 14.0%, volatile matter from 71.2% to 77.1%, and ash content from 4.1% to 7.6%. The chemical structure of the biomass fuel, which included carbon, hydrogen, nitrogen, sulfur, and oxygen, was noted to be 44.56–50.69%, 7.12–7.33%, 0.14–0.25%, 0.47–0.79%, and 41.08–47.46%, respectively. The higher heating value ranged from 16.8 to 18.3 MJ/kg. With increasing pressure from 5 to 20 MPa, briquette density increased from 654 to 995 kg/m³, shatter index from 81% to 94%, durability from 67% to 92%, and resistance to water penetration from 57% to 77%. A low-pressure briquette (5 MPa) burned at a higher rate of 8.0 g/min, whereas a high-pressure briquette (20 MPa) burned at a lower rate of 2.5 g/min. All leaf types tested were able to boil 1000 mL of water with 100 g of briquettes in just 7 min. Full article

The presence of Giant Hogweed (Heracleum mantegazzianum) in agricultural landscapes raises concerns due to its impacts on agroecology. Physically removed biomass can serve as a feedstock for solid biofuel, representing a viable strategy reducing reliance on herbicides. Giant Hogweed’s bioenergy potential is currently underexplored, particularly regarding its seasonal variations in properties and the environmental impacts resulting from its use as a biofuel. This study assessed the processability of Giant Hogweed biomass into briquettes, to determine their mechanical durability and to evaluate their basic emission characteristics during combustion in a device commonly used at the household level. Biomass was sampled at two specific stages of plant development for a comparative study of briquette properties. For both summer- and autumn-harvested biomass, a high mechanical durability of the produced briquettes, approximately 97%, was achieved. Only carbon monoxide emissions from summer-harvested biomass exceeded the limits; nitrogen oxides concentrations were within the limits for both. Thermogravimetric analysis and differential scanning calorimetry revealed decomposition patterns. Autumn-harvested biomass showed better potential for briquetting, highlighting the advantages of later collection. The findings demonstrate the potential of plant and applied processing technology for valorisation as a solid biofuel, while certain aspects still need consideration. Full article

Solid fuels are still widely used in household heating in Europe and North America. Emissions from boilers are released in proximity to people. Therefore, there is a need to minimise the toxicity of emissions affecting human health to the greatest extent possible. This study compares the genotoxic potential of the emissions of four boilers of modern and old design (automatic, gasification, down-draft, over-fire) operating at reduced output to simulate the real-life combustion fed by various fossil and renewable solid fuels (hard coal, brown coal, brown coal briquettes, wood pellets, wet and dry spruce). Organic emissions were tested for genotoxic potential by analysing bulky DNA adducts and 8-oxo-dG adduct induction. There was no consistent genotoxic pattern among the fuels used within the boilers. Genotoxicity was strongly correlated with polycyclic aromatic hydrocarbon (PAH) content, and even stronger correlation was observed with particulate matter (PM). In all measured variables (PM, PAHs, genotoxicity), the technology of the boilers was a more important factor in determining the genotoxic potential than the fuels burned. The highest levels of both bulky and 8-oxo-dG DNA adducts were induced by organics originating from the over-fire boiler, while the automatic boiler exhibited genotoxic potential that was ~1000- and 100-fold lower, respectively. Full article

The generation of fine coal particles during mining and processing presents significant environmental and logistical challenges, particularly in coal-dependent, developing countries like South Africa (SA). This review critically evaluates the technical viability of fine coal briquetting as a sustainable waste-to-energy solution within a SA context, while drawing from global best practices and comparative benchmarks. It examines abundant feedstocks that can be used for valorization strategies, including fine coal and agricultural biomass residues. Furthermore, binder types, manufacturing parameters, and quality optimization strategies that influence briquette performance are assessed. The co-densification of fine coal with biomass offers a means to enhance combustion efficiency, reduce dust emissions, and convert low-value waste into a high-calorific, manageable fuel. Attention is also given to briquette testing standards (i.e., South African Bureau of Standards, ASTM International, and International Organization of Standardization) and end-use applications across domestic, industrial, and off-grid settings. Moreover, the review explores socio-economic implications, including rural job creation, energy poverty alleviation, and the potential role of briquetting in SA’s ‘Just Energy Transition’ (JET). This paper uniquely integrates technical analysis with policy relevance, rural energy needs, and practical challenges specific to South Africa, while offering a structured framework for bio-coal briquetting adoption in developing countries. While technical and economic barriers remain, such as binder costs and feedstock variability, the integration of briquetting into circular economy frameworks represents a promising path toward cleaner, decentralized energy and coal waste valorization. Full article

The Combined Cycle Combined Heat and Power (CCCHP) systems are an effective way to improve energy efficiency and reduce emissions. This paper examines the energy and environmental impact of CCCHP combustion using waste biomass like the biomass of spent wash (SW), waste crankcase oil (WCO), and bagasse (BA) using an advanced Ebsilon Professional 16 software simulation model. The simulations were designed to achieve 150 MW total power output and 25 MW heating energy. Simulation results indicate that the minimum fuel feed requirement of a 10.762 kg/s flow rate was recorded at the highest calorific value (CV) fuel briquette of 1:8 ratio BA–WCO. The BA–WCO system demonstrates a significantly higher heat recovery capacity in the heat recovery steam generator (HRSG) compared to the BA–SW system. At a 1:8 ratio, it recovers 1463 kJ/kg versus 583 kJ/kg, and 1391 kJ/kg versus 498 kJ/kg at a 1:3 ratio. The CCCHP efficiency was much higher for BA–WCO than those developed from spent wash–bagasse, yielding up to 41.1% compared to a maximum of 26.71%. Furthermore, the BA–WCO system showed a better result than the BA–SW CCCHP system by emitting a low amount of flue gas with low temperature. Full article

This study investigates the production of biomass briquettes using waste coconut shell charcoal and cinnamon sawdust, bound by eco-friendly, non-edible binders: cassava peel starch, giant taro starch, and pine resin. The production process involved carbonization of coconut shells, followed by crushing, blending with sawdust, pressing, and a 12-day sun-drying period. The briquettes were tested for calorific value, density, compressive strength, and shatter resistance. The calorific values ranged from 26.07–31.60 MJ/kg, meeting the industrial standards, while densities varied between 0.83 g/cm³ and 1.14 g/cm³, ensuring compactness and efficient combustion. Among the binders, cassava peel starch provided the best bonding strength, resulting in high-density briquettes with superior durability and energy release, showing a calorific value and compressive strength of 2.11 MPa. Giant taro starch also improved durability, though with slightly lower calorific values but better bonding than pine resin. Pine resin, while contributing to high calorific values, reduced compressive strength with increased resin content, making it less suitable for high mechanical strength applications. Proximate analysis revealed that cassava peel starch-based briquettes had moisture content from 6.5% to 8.6%, volatile matter from 15.2% to 23.5%, ash content from 2.1% to 3.2%, and fixed carbon between 69% and 76.2%. Giant taro starch-based briquettes exhibited 63.2% to 75% fixed carbon, while pine resin-based briquettes had the highest fixed carbon content (66.4% to 78.3%), demonstrating the potential of non-edible adhesives for sustainable, high-performance fuel production. Full article

The aim of this paper is to carry out a rheological study of the pressing of pine wood sawdust, after which obtaining briquettes from the same wood material with a hydraulic installation and analyzing their properties. In order to know the rheological behavior during pressing, the fractions resulting from sorting the sawdust with 4 × 4, 3 × 3, 2 × 2, and 1 × 1 mm² sieves were used, respectively, six fractions (the fraction larger than 4 × 4 mm² and the smaller one of 1 × 1 mm² are added) and a specific pressing device, placed on a universal testing machine. The results obtained in the rheological study showed that the obtained density does not increase proportionally with the pressure, the best results (density of 1030 kg/m³) being obtained at a pressure of 180 MPa. Within the briquettes, higher densities were obtained for the sawdust fraction smaller than 1 × 1 mm², but the breaking strength was higher for the fraction larger than 4 × 4 mm². As a general conclusion, it was found that pine sawdust is easily compressible, and the briquettes obtained from it have good properties for use in combustion. Full article

Cooking with firewood in inefficient stoves primarily affects the rural population in poor and developing countries, usually lacking access to clean and modern energy sources. La Guajira, Colombia, is especially affected, with 40% to 60% of the departmental households relying on firewood, which increases to 80% in rural areas. In the department, only 40.4% of the population have access to natural gas, which drops to 6% in the indigenous reservations, while 68.4% have access to electricity, which reduces to 22% in indigenous reservations. Rural areas with agricultural production in the department can benefit from biomass wastes to address firewood consumption. This study quantified the agricultural biomass waste inventory in La Guajira to assess their availability for energy valorization as cooking fuel or, when possible, for electricity generation. The geolocalization of biomass wastes and rural communities was developed to overlap biomass production with the demand for firewood. Moreover, briquetting, anaerobic digestion, and direct combustion were considered small- and medium-scale options for the energy valorization of biomass wastes. Results highlighted the department’s yearly production of 292,760 to 522,696 t of agricultural biomass wastes between 2010 and 2023. These wastes could yield an estimated 381 to 521 TJ/year of electricity using direct combustion, coinciding with some 21% to 28% of the electricity demand in 2022 in La Guajira. Furthermore, this electricity potential could replace 57% to 78% of the demand for firewood in the department using electric stoves. Moreover, anaerobic digestion could produce from 8.6 to 10 million m³/year, enough to replace between 16% and 18% of the demand for firewood using biogas stoves. Finally, briquettes could replace between 28% and 49% of the firewood demand, considering the adoption of improved biomass stoves. Considering that direct combustion and anaerobic digestion technologies would be efficient on the medium scale, briquettes surfaced as the most viable approach at the small scale to take advantage of agricultural wastes to replace firewood in households in rural areas. Full article

This study evaluates bio-briquettes and bio-pellets made from ramie (Boehmeria nivea), sacha inchi (Plukenetia volubilis), and palm kernel shell (Elaeis guineensis) as renewable fuel sources. Proximate analysis was conducted to measure moisture, ash, volatile matter, fixed carbon, and calorific values, while combustion tests assessed boiling efficiency and burn time. Results reveal that bio-briquettes generally outperform bio-pellets in calorific value, with sample B-S8R2 achieving the highest at 6455 kcal/kg and the fastest boiling time of 14 min at 88 °C. This enhanced performance is attributed to its high fixed carbon (71.81%) and low volatile matter, optimizing combustion and energy yield. In contrast, bio-pellets like sample P-PO7R3, with a calorific value of 4212 kcal/kg, offer moderate heat and durability, making them suitable for household use. The high density and low moisture content across all samples support efficient combustion, while the bio-briquettes’ low ash production indicates a more environmentally friendly fuel. The findings suggest that bio-briquettes are optimal for high-energy applications due to their superior combustion efficiency and environmental benefits, whereas bio-pellets provide a viable option for moderate-energy needs. This research supports the development of sustainable biofuel from biomass waste, providing a promising alternative to traditional fossil fuels. Full article

As a by-product of wastewater treatment, sewage sludge can be used for natural, agricultural, or energy purposes. One method of preparing sludge for management and use is solar drying. To intensify the drying process, natural additives can be used to alter the structure of the sludge and accelerate the evaporation of water. This research aimed to evaluate the influences of different organic additives in sewage sludge mixtures on the physicochemical and energy parameters of briquettes. This research was carried out without thermal boosting in a 4 × 2.5 × 2 m plastic tunnel. The tunnel was equipped with three drying stations and control and measuring equipment. In two test series, sludge additives in the form of straw and lignocellulosic materials, sawdust, bark, woodchips, and walnut shells, were used. Briquettes were made from the resulting mixtures and then subjected to physical and chemical analyses. This research showed high variability in the contents of trace elements, nitrogen, and sulphur in relation to an increase in the amount of sludge in the briquettes, which, for the briquettes made from sewage sludge, was nearly twice as high as for the briquettes made from the mixtures. The results of the flue gas analysis for the briquettes with sawdust and wood chip additives were very similar. The briquettes made from sewage sludge with lignocellulosic materials (bark and wood chips) had fuel properties similar to woody biomass, with a calorific value and heat of combustion of 15–16 MJ/kg. Fibrous additives (straw) significantly increased the strength parameters of the briquettes, by more than 50% of the value. The compositions and properties of the mixtures affected the following briquetting parameters: temperature and compressive force. The briquettes made from sewage sludge and additives can be classified according to ISO 21640 as SRFs (solid recovered fuels). In most of the results, the net calorific value (NCV) was 3 to 4; the chlorine content (CL) was 2 to 1; and the mercury content (Hg) was 1. The sewage sludge mixtures facilitated the agricultural and energy use of the briquettes. Full article

From the uncontrolled proliferation of invasive plants, several challenges for the environment arise. Invasive wetland grasses biomass can be collected for biofuel production, thus offering a sustainable solution for invasive plants’ management and contributing to the renewable energy sector. The straw-like shoot biomass of common reed (Phragmites australis), widespread across temperate and tropical zones, has been examined to assess its potential use for energy purposes. We seek to determine the fuel-energy characteristics of common reed biomass, which are necessary for converting it into energy through combustion. A comprehensive analysis was conducted to determine the physical and chemical properties of biomass according to the ISO standards for solid biofuels. These properties included calorific values, moisture, ash and volatile matter contents, and contents of C, H, N, and major and minor elements, as well as ash melting behaviour. The measured values were also compared to standard limits for different classes of densified biofuels. Based on the results, the net calorific value (15.33 MJ/kg ar) and other parameters met the requirements for the class A quality of non-woody briquettes and pellets. The only parameters which exceeded the class A limits were ash content (7.1% d.b.) and Cl content (0.16% d.b.). The findings of this study are important for the potential utilisation of common reed biomass for bioenergy as a step towards contribution to the Sustainable Development Goals. Full article

The steel industry accounts, according to the International Energy Agency, for ~6.7% of global CO₂ emissions, and the major portion of its contribution is from steelmaking via the blast furnace (BF) route. In the short term, a significant reduction in fossil CO₂ emissions can be achieved through the introduction of bio-coal into the BF as part of cold bonded briquettes, by injection, or as part of coke. The use of bio-coal-containing residue briquettes was previously demonstrated in industrial trials in Sweden, whereas bio-coal injection was only tested on a pilot scale or in one-tuyere tests. Therefore, industrial trials replacing part of the pulverized coal (PC) were conducted. It was concluded that the grinding, conveying, and injection of up to 10% of charcoal (CC) with PC can be safely achieved without negative impacts on PC injection plant or BF operational conditions and without losses of CC with the dust. From a process point of view, higher addition is possible, but it must be verified that grinding and conveying is feasible. Through an experimentally validated computational fluid flow model, it was shown that a high moisture content and the presence of oversized particles delay devolatilization and ignition, lowering the combustion efficiency. By using CC with similar heating value to PC, compositional variations in the injected blend are not critical. Full article

This study aims to provide an overview of the growing need for renewable energy conversion and aligns with the broader context of environmentally friendly energy, specifically through producing syngas from biomass. Unlike natural gas, which is mainly composed of methane, syngas contains a mixture of combustible CO, H₂, and C_nH_m. Therefore, optimizing its production requires a thorough examination of various operational parameters such as the gasifying agent, the equivalence ratio, the biofuel type, and the state, particularly in densified forms like pellets or briquettes. As new biomass sources are continually discovered and tested, operational parameters are also constantly evaluated, and new techniques are continuously developed. Indeed, these techniques include different gasifier types and the use or non-use of catalysts during biofuel conversion. The present study focuses on these critical aspects to examine their effect on the efficiency of syngas production. It is worth mentioning that syngas is the primary gaseous product from gasification. Moreover, it is essential to note that the pyrolysis process (prior to gasification) can produce, in addition to tar and char, a mixture of gases. The common feature among these gases is their versatility in energy generation, heat production, and chemical synthesis. The analysis encompasses the resulting gas features, including the yield and composition, mainly through the hydrogen-to-carbon monoxide ratio and the carbon monoxide-to-carbon dioxide ratio, as well as the lower heating value and considerations of the tar yield. Full article

The combustion of briquettes made from organic and industrial residues in small boilers requires researchers to consider the characteristics of this type of fuel and methods of its combustion. For the efficient combustion of fuel briquettes, a layered combustion method with the ability to regulate the supply of combustion air is better suited. The purpose of this research is to study the thermal technical conditions of briquetted fuel combustion. In order to carry this out, a stand was created, which made it possible to determine the combustion efficiency of this type of fuel. Two types of briquettes were studied: one with 30% sunflower husks and 70% leaves, and one with and 70% sunflower husks and 30% coke breeze. The combustion results of the briquettes show that heat loss from chemical under-burning was no more than 6.25%. To determine the temperature distribution in the fuel layer, a model of unsteady heat transfer in a fixed layer was used. A calculation of the temperature fields in the layer of burned fuel briquettes was carried out, which showed that the most favorable conditions for burning briquettes were created with a layer about 15–20 cm thick for both burned briquette options. The temperature was in the range of 450–750 °C, which on the one hand corresponds to experimental data and on the other hand provides a combustion regime that occurs with a relatively low loss to the environment. This installation and mathematical model will help future studies based on the processes of other types of organic waste combustion with a grate system. Full article

This study analyzes the combustion of pellets and briquettes made of plant biomass in low-power heating devices powered periodically with fuel being placed on the grate, as well as after modification using an automatic fuel feeding system in the gutter burner. The use of herbaceous biomass in the form of pellets in low-power heating devices with automatic fuel feeding and combustion in a gutter burner is not widely promoted and popular. Therefore, this study used four types of herbaceous waste biomass (wheat straw, rye straw, oat straw and hay) and one type of woody waste biomass (birch sawdust) for testing. The basic chemical characteristics were determined for the raw materials. After appropriate preparation, the selected starting materials were subjected to briquetting and pelleting processes. Selected physical properties were also determined for the obtained biofuels. Biofuels made from birch sawdust had the lowest heat value (16.34 MJ·kg⁻¹), although biofuels made from wheat, rye and hay straw had a slightly lower calorific value, respectively: 16.29; 16.28 and 16.26 MJ·kg⁻¹. However, the calorific value of oat straw biofuels was only 15.47 MJ kg⁻¹. Moreover, the ash content for herbaceous biomass was 2–4 times higher than for woody biomass. Similar differences between herbaceous and woody biomass were also observed for the nitrogen and sulfur content. To burn the prepared biofuels, a domestic grate-fired biomass boiler was used, periodically fed with portions of fuel in the form of pellets or briquettes (type A tests), which was then modified with a gutter burner enabling the automatic feeding of fuel in the form of pellets (type B tests). During the combustion tests with simultaneous timing, the concentration of CO₂, CO, NO and SO₂ in the exhaust gases was examined and the temperature of the supplied air and exhaust gases was measured. The stack loss (qA), combustion efficiency index (CEI) and toxicity index (TI) were also calculated. The research shows that the use of automatic fuel feeding stabilizes the combustion process. The combustion process is balanced between herbaceous and woody biomass biofuels. Disparities in CO₂, CO and T_gas emissions are decreasing. However, during type B tests, an increase in NO emissions is observed. At the same time, the research conducted indicates that the combustion of herbaceous biomass pellets with their automatic feeding into the combustion chamber is characterized by an increase in combustion efficiency, indicating that when the combustion process is automated, they are a good replacement for wood biofuels—both pellets and briquettes. Full article