Search Results (485)

This study investigates the hot deformation behaviour and flow stress prediction of metastable β-Ti-15Mo alloy, a promising material for biomedical applications requiring strength–modulus optimisation and thermomechanical tunability. Isothermal compression tests were performed within the temperature range of 923–1173 K and at strain rates of 0.17, 1.72, and 17.2 ${\mathrm{s}}^{-1}$ to assess the material’s response under industrially relevant hot working conditions. The alloy showed significant sensitivity to temperature and strain rate, with dynamic recovery (DRV) and dynamic recrystallisation (DRX) dominating the softening behaviour depending on the conditions. A strain-compensated Arrhenius-type constitutive model was developed and validated, resulting in an apparent activation energy of approximately 234 kJ/mol. Zener–Hollomon parameter analysis confirmed a transition in deformation mechanisms. Although microstructural and diffraction data suggest possible contributions from nanoscale phase transformations, including ω-phase dissolution at high temperatures, these aspects remain to be fully elucidated. The model offers reliable predictions of flow behaviour and supports optimisation of thermomechanical processing routes for biomedical β-Ti alloys. Full article

Using density functional theory (M06-2X-D3/def2-TZVP), we investigated the 1,2-addition reactions of NH₃ with a series of heavy imine analogues, G13=P-Rea (where G13 denotes a Group 13 element; Rea = reactant), featuring a mixed G13–P–Ga backbone. Theoretical analyses revealed that the bonding nature of the G13=P moiety in G13=P-Rea molecules varies with the identity of the Group 13 center. For G13=B, Al, Ga, and In, the bonding is best described as a donor–acceptor (singlet–singlet) interaction, whereas for G13=Tl, it is characterized by an electron-sharing (triplet–triplet) interaction. According to our theoretical studies, all G13=P-Rea species—except the Tl=P analogue—undergo 1,2-addition with NH₃ under favorable energetic conditions. Energy decomposition analysis combined with natural orbitals for chemical valence (EDA–NOCV), along with frontier molecular orbital (FMO) theory, reveals that the primary bonding interaction in these reactions originates from electron donation by the lone pair on the nitrogen atom of NH₃ into the vacant p-π* orbital on the G13 center. In contrast, a secondary, weaker interaction involves electron donation from the phosphorus lone pair of the G13=P-Rea species into the empty σ* orbital of the N–H bond in NH₃. The calculated activation barriers are primarily governed by the deformation energy of ammonia. Specifically, as the atomic weight of the G13 element increases, the atomic radius and G13–P bond length also increase, requiring a greater distortion of the H₂N–H bond to reach the transition state. This leads to a higher geometrical deformation energy of NH₃, thereby increasing the activation barrier for the 1,2-addition reaction involving these Lewis base-stabilized, heavy imine-like G13=P-Rea molecules and ammonia. Full article

The majority of studies of fungal utilization of chitosan are associated with the production of a specific enzyme, chitosanase, which catalyzes the hydrolytic cleavage of the macrochain. In our opinion, the development of approaches to obtaining materials with new functional properties based on non-destructive chitosan transformation by living organisms and their enzyme systems is promising. This study was conducted using a wide range of classical and modern methods of microbiology, biochemistry, and physical chemistry. The ability of the ascomycete Fusarium oxysporum Schltdl. to modify films of chitosan with average-viscosity molecular weights of 200, 450, and 530 kDa was discovered. F. oxysporum was shown to use chitosan as the sole source of carbon/energy and actively overgrew films without deformations and signs of integrity loss. Scanning electron microscopy (SEM) recorded an increase in the porosity of film substrates. An analysis of the FTIR spectra revealed the occurrence of oxidation processes and crosslinking of macrochains without breaking β-(1,4)-glycosidic bonds. After F. oxysporum growth, the resistance of the films to mechanical dispersion and the degree of ordering of the polymer structure increased, while their solubility in the acetate buffer with pH 4.4 and sorption capacity for Fe²⁺ and Cu²⁺ decreased. Elemental analysis revealed a decrease in the nitrogen content in chitosan, which may indicate its inclusion into the fungal metabolism. The film transformation was accompanied by the production of extracellular hydrolase (different from chitosanase) and peroxidase, as well as biosurfactants. The results obtained indicate a specific mechanism of aminopolysaccharide transformation by F. oxysporum. Although the biochemical mechanisms of action remain to be analyzed in detail, the results obtained create new ways of using fungi and show the potential for the use of Fusarium and/or its extracellular enzymes for the formation of chitosan-containing materials with the required range of functional properties and qualities for biotechnological applications. Full article

Biomimetic lattice structures, inspired by natural architectures such as bone, coral, mollusk shells, and Euplectella aspergillum, have gained increasing attention for their exceptional strength-to-weight ratios, energy absorption, and deformation control. These properties make them ideal for advanced engineering applications in aerospace, biomedical devices, and structural impact protection. This study presents a comprehensive bibliometric analysis of global research on biomimetic lattice structures published between 2020 and 2025, aiming to identify thematic trends, collaboration patterns, and underexplored areas. A curated dataset of 3685 publications was extracted from databases like PubMed, Dimensions, Scopus, IEEE, Google Scholar, and Science Direct and merged together. After the removal of duplication and cleaning, about 2226 full research articles selected for the bibliometric analysis excluding review works, conference papers, book chapters, and notes using Cite space, VOS viewer version 1.6.20, and Bibliometrix R packages (4.5. 64-bit) for mapping co-authorship networks, institutional affiliations, keyword co-occurrence, and citation relationships. A significant increase in the number of publications was found over the past year, reflecting growing interest in this area. The results identify China as the most prolific contributor, with substantial institutional support and active collaboration networks, especially with European research groups. Key research focuses include additive manufacturing, finite element modeling, machine learning-based design optimization, and the performance evaluation of bioinspired geometries. Notably, the integration of artificial intelligence into structural modeling is accelerating a shift toward data-driven design frameworks. However, gaps remain in geometric modeling standardization, fatigue behavior analysis, and the real-world validation of lattice structures under complex loading conditions. This study provides a strategic overview of current research directions and offers guidance for future interdisciplinary exploration. The insights are intended to support researchers and practitioners in advancing next-generation biomimetic materials with superior mechanical performance and application-specific adaptability. Full article

This investigation is centered on the analysis of frequency response characteristics of a p-i-n photodiode using InxGa_1−xAs/InP. The InGaAs/InP can be developed under three conditions: compression, tensile strain, and lattice matching. Initially, we performed calculations on strain, bandgap energy (E_g), and absorption coefficient. We then optimized the influence of indium concentration (x) on stability, critical thickness, bandgap energy, and absorption coefficient. The effects of temperature and deformation on E_g were also studied. Finally, we optimized the cutoff frequency (f_c), capacitive effects, and response frequency by considering the impact of x, active layer thickness (d), and surface area (S). For our future endeavors, we intend to explore additional parameters that may affect the p-i-n response. In future work, we can add transparent double layers in the i. InGaAs layer to reduce the transit time, leading to the development of an ultrafast photodiode. Full article

To address the frequent failure of anti-falling devices in inclined shaft tunnel boring machines caused by cyclic loading and fatigue during construction, this study proposes an optimized self-responsive anti-falling device design. Based on the operational conditions of the “Tianyue” tunnel boring machine, a three-dimensional model was constructed using SolidWorks. Finite element static analysis was employed to validate structural integrity, revealing a maximum stress of 461.19 MPa with a safety factor of 1.71. Explicit dynamic simulations further demonstrated the dynamic penetration process of propellant-driven telescopic columns through concrete lining walls, achieving a penetration depth exceeding 500 mm. The results demonstrate that the device can respond to falling signals within 12 ms and activate mechanical locking. The Q690D steel structure exhibits a deformation of 5.543 mm with favorable stress distribution, meeting engineering safety requirements. The energy release characteristics of trinitrotoluene propellant and material compatibility were systematically verified. Compared to conventional hydraulic support systems, this design offers significant improvements in response speed, maintenance cost reduction, and environmental adaptability, providing an innovative solution for fall protection in complex geological environments. Full article

The Charpy impact toughness of single-phase austenitic Fe-32Mn-0.6C steel was systematically investigated across a wide temperature spectrum from 25 °C to −196 °C using Charpy V-notch impact tests. The material exhibited a remarkable temperature dependence of impact energy, decreasing dramatically from 120 J at ambient temperature (25 °C) to 13 J under cryogenic conditions (−196 °C). Notably, a steep transition in impact energy occurred within the critical temperature window of −100 °C to −150 °C. Microstructural analysis revealed that synergistic effects of high strain rates and low temperatures significantly restrict dislocation slip and multiplication mechanisms, while also suppressing deformation twinning activation. This restricted plasticity accommodation mechanism fundamentally differs from the deformation characteristics reported in conventional low-carbon high-manganese steels and other face-centered cubic (FCC) alloy systems. Full article

It is essential to develop the optimal hot-working process of the (CoCrNi)₉₄Al₃Ti₃ alloy, a recently developed precipitation-hardened medium-entropy alloy with promising mechanical properties, for its industrial application. In this study, the hot workability of the as-forged (CoCrNi)₉₄Al₃Ti₃ alloy was investigated over a temperature range of 1000 °C to 1150 °C and a strain rate ranging from 0.001 to 1 s⁻¹ using a Gleeble-1500D thermal simulation machine of Dynamic Systems Inc., USA. As a result, the constitutive relationship was established, and the hot deformation activation energy was calculated as 433.2 kJ/mol, suggesting its well-defined plastic flow behavior under low-energy-input conditions. Hot-processing maps were constructed to identify the stable hot-working regions. Microstructure analysis revealed that the hot-forged (CoCrNi)₉₄Al₃Ti₃ alloy exhibited continuous dynamic recrystallization (CDRX) behavior under optimal hot-working conditions. Considering the hot-processing maps and DRX characteristics, the optimal hot-working window of hot-forged (CoCrNi)₉₄Al₃Ti₃ alloy was identified as 1100 °C with a strain rate of 0.1 s⁻¹. This work offers valuable guidance for developing high-efficiency forming processes for (CoCrNi)₉₄Al₃Ti₃ medium-entropy alloy. Full article

In this study, we studied the dual role of magnesium on the high-temperature deformation mechanisms and microstructural evolution of high-Mg 5383 aluminum alloys. We developed a quantitative framework to characterize high-temperature flow behavior and constructed 3D processing maps to identify processing instabilities. The results indicate that solid solution strengthening induced by Mg atoms leads to a substantial increase in peak flow stress. The thermal activation energy rises significantly from 182 kJ/mol to 209 kJ/mol at a Mg content of 5 wt.%, which highlights the pronounced solute drag effects on dislocations. Moreover, Mg-modified grain boundary dynamics enhance power dissipation efficiency by 34% (from 35% to 47%). With an increasing Mg content, the processing instability domains expand, thereby shifting the optimal processing parameters towards higher-temperature and lower-strain-rate regions (500 °C/0.05 s⁻¹). The results provide a theoretical foundation for optimizing the thermal processing characteristics and mechanical properties of high-Mg aluminum 5xxx series alloys. Full article

Low-energy bone fractures refer to injuries that occur from minimal trauma or impact. These fractures are often a result of activities, such as falls from standing height or minor accidents, where the force exerted on the bone is insufficient to cause a break under normal conditions. To design an effective orthotic splint, it is critical to select the appropriate material that mimics the mechanical properties of traditional materials like plaster, which has long been used for immobilization purposes. In this case, Ansys CES Edupack 2025 software was utilized to evaluate and identify materials with mechanical characteristics similar to those of plaster. The software provided a list of six materials that met these criteria, but selecting the most suitable material involved more than just mechanical properties. Three different multicriteria decision-making methods were employed to ensure the best choice: TOPSIS, VIKOR, and COPRAS. These methods were applied to consider various factors, such as strength, flexibility, weight, cost, and ease of manufacturing. The results of the analyses revealed a strong consensus across all three methods. Each approach identified PLA (Polylactic Acid) as the most appropriate material for the orthotic design. Following the material selection process, simulations were conducted to assess the structural performance of the orthotic splint. The results determined that the minimum thickness required for the PLA orthosis was 4 mm, ensuring that it met all necessary criteria for acceptable stresses and deformations during the four primary movements exerted by the wrist. This thickness was sufficient to maintain the orthosis’s functionality without compromising comfort or effectiveness. Moreover, a significant improvement in the design was achieved through topological optimization, where the mass of the preliminary design was reduced by 9.58%, demonstrating an efficient use of material while maintaining structural integrity. Full article

In this article, we consider the roles of transcrustal magma- and fluid-conducting faults (TCMFCFs) in the formation of mineral deposits, showing the importance of deep sources of heat and hydrothermal solutions in the genesis and history of deposit formation. As a result of the impact on the lithosphere of mantle plumes rising along TCMFCFs, intense block deformations and tectonic movements are generated; rift systems, and volcanic–plutonic belts spatially combined with them, are formed; and intrusive bodies are introduced. These processes cause epithermal ore formation as a consequence of the impact of mantle plumes rising along TCMFCF to the lithosphere. At hydrocarbon fields, they play extremely important roles in conductive and convective heat, as well as in mass transfer to the area of hydrocarbon generation, determining the relationship between the processes of lithogenesis and tectogenesis, and activating the generation of hydrocarbons from oil and gas source rock. Detection of TCMFCFs was carried out using MMSS (the method of microseismic sounding) and MTSM (the magnetotelluric sounding method), in combination with other geological and geophysical data. Practical examples are provided for mineral deposits where subvertical transcrustal columns of increased permeability, traced to considerable depths, have been found; the nature of these unique structures is related to faults of pre-Paleozoic emplacement, which determined the fragmentation of the sub-crystalline structure of the Earth and later, while developing, inherited the conditions of volumetric fluid dynamics, where the residual forms of functioning of fluid-conducting thermohydrocolumns are granitoid batholiths and other magmatic bodies. Experimental modeling of deep processes allowed us to identify the quantum character of crystal structure interactions of minerals with “inert” gases under elevated thermobaric conditions. The roles of helium, nitrogen, and hydrogen in changing the physical properties of rocks, in accordance with their intrastructural diffusion, has been clarified; as a result of low-energy impact, stress fields are formed in the solid rock skeleton, the structures and textures of rocks are rearranged, and general porosity develops. As the pressure increases, energetic interactions intensify, leading to deformations, phase transitions, and the formation of chemical bonds under the conditions of an unstable geological environment, instability which grows with increasing gas saturation, pressure, and temperature. The processes of heat and mass transfer through TCMFCFs to the Earth’s surface occur in stages, accompanied by a release of energy that can manifest as explosions on the surface, in coal and ore mines, and during earthquakes and volcanic eruptions. Full article

As a key load-bearing component in building structures, the effective strengthening of reinforced concrete (RC) columns is critical to enhancing their structural reliability and service life. To tackle the issue of excessive self-weight from the increasing section strengthening method and further optimize the seismic performance of encased steel strengthening, this paper presents a novel composite strengthening method for RC columns, which is characterized by using Lightweight Alkali-Activated Slag Concrete (LAASC) as the strengthening layer and an X-type encased steel structure. By conducting axial compression tests on six columns and utilizing in-depth research on small eccentric compression and hysteresis performance through numerical simulation, the specific effects of different strengthening materials and encased steel forms on the mechanical properties of the columns are systematically explored. Experimental results indicate that compared to ordinary concrete strengthening layers, LAASC can reduce the self-weight of the strengthening layer by 25%, boost the bearing capacity of the strengthened components by 37%, and enhance the vertical deformation capacity by 100%. Numerical simulation also confirms that X-type encased steel composite strengthening can effectively control bending deformation under small eccentric compression, reducing lateral deflection by 30–35% compared to un-strengthened columns. Under horizontal reciprocating loading, the cumulative energy dissipation of X-type encased steel composite-strengthened columns is 15–30% higher than that of traditional steel encased composite-strengthened columns, reflecting the diagonal bracing effect of the X-type batten plates. Full article

Based on the engineering conditions of the 1303 working face in Zhaoxian Coal Mine, this study investigates the characteristics of mine pressure behavior and the stress-relief mechanism of advanced presplit blasting in a working face with a thick and hard roof in an extra-thick coal seam. Through a combination of numerical simulations and field experiments, the effects of advanced presplit blasting on stress distribution, roadway stability, and microseismic activity are analyzed. Corresponding mitigation measures and optimization strategies are proposed. The results indicate that the primary cause of deformation in the gob-side roadway is the superposition of lateral abutment pressure from the goaf and the front abutment pressure of the advancing working face. Advanced presplit blasting effectively reduces the magnitude of front abutment stress, inhibits its transmission, decreases the hanging area of the goaf roof, and alleviates vertical stress on the roadway side adjacent to the goaf. Furthermore, both the daily average and peak microseismic energy levels decrease as the working face approaches the advanced blasting zone. The implementation of advanced presplit blasting technology in working faces with thick and hard roofs within extra-thick coal seams significantly mitigates rockburst hazards, enhances roadway stability, and improves overall mining safety. Full article

In this study, high toughness and superplastic deformability were achieved in Mg-9Li alloys through dual-phase microstructure optimization. Solid solution (SS) and equal channel angular pressing (ECAP) treatments were employed to refine the alloy’s microstructure. The effects of these treatments on room-temperature and low-temperature high-strain-rate superplasticity were systematically investigated under varying microstructural conditions. Results demonstrate that the SS-ECAP alloy exhibits outstanding superplasticity at room temperature and remarkable high-strain-rate deformation capability, achieving a maximum fracture elongation of 602.1%. Grain refinement and reduced dislocation density promote uniform void nucleation under high strain. Calculations of the strain rate sensitivity index (m-value) and activation energy (Q) reveal that the superplastic behavior in the SS-ECAP state is predominantly governed by grain boundary sliding facilitated by grain boundary diffusion. These findings provide critical insights into advancing the superplastic forming technology of Mg-9Li alloys. Full article

To address the seismic vulnerability of high-speed railway bridges (HSRBs) in seismically active regions, this study proposes a hierarchical curved steel damper (CSD) designed to mitigate excessive girder displacements induced by conventional isolation devices. The CSD integrates U-shaped and hollow diamond-shaped steel plates to achieve stable energy dissipation through coupled bending deformation. A finite element model is developed, and its hysteretic behavior is confirmed, with an energy dissipation coefficient of 1.82 and an equivalent damping ratio of 12.7%. An integrated high-speed railway track–bridge-CSD spatial coupling model is developed in OpenSees, which incorporates nonlinear springs for interlayer track interactions. Nonlinear time–history analyses under 40 spectrum-matched ground motions reveal that the CSD reduces transverse girder displacements by 73.7–79.2% and attenuates track slab acceleration peaks by 52.4% compared with uncontrolled cases. However, it increases the maximum bending moment at pier bases by up to 18.3%, necessitating supplemental energy-dissipating components for balanced force redistribution. This work provides a theoretical foundation and practical methodology for seismic response control and retrofitting of the HSRB in high-intensity seismic regions. Full article