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39 pages, 4643 KB  
Article
Machine Learning-Based Prediction of Irrigation Water Quality Index with SHAP Interpretability: Application to Groundwater Resources in the Semi-Arid Region, Algeria
by Mohamed Azlaoui, Salah Karef, Atif Foufou, Nadjib Haied, Nesrine Azlaoui, Abdelaziz Rabehi, Mustapha Habib and Aziez Zeddouri
Water 2026, 18(8), 959; https://doi.org/10.3390/w18080959 - 17 Apr 2026
Cited by 1 | Viewed by 977
Abstract
In semi-arid regions, sustainable groundwater management for irrigation is critical for agricultural productivity and food security. This study presents an integrated methodological framework combining hydrochemical characterization, machine learning (ML) modeling, and explainable artificial intelligence (XAI) to predict the Irrigation Water Quality Index (IWQI) [...] Read more.
In semi-arid regions, sustainable groundwater management for irrigation is critical for agricultural productivity and food security. This study presents an integrated methodological framework combining hydrochemical characterization, machine learning (ML) modeling, and explainable artificial intelligence (XAI) to predict the Irrigation Water Quality Index (IWQI) in the Ain Oussera plain, Djelfa Province, Algeria. A total of 191 groundwater samples were collected from November 2023 to September 2024 and analyzed for major ions and physicochemical parameters. Multiple irrigation suitability indices were calculated, including Sodium Adsorption Ratio (SAR), Sodium Percentage (Na%), Magnesium Hazard (MH), Permeability Index (PI), Residual Sodium Carbonate (RSC), Soluble Sodium Percentage (SSP), and Kelly’s Ratio (KR). Five ML models were developed and evaluated for IWQI prediction: Random Forest, Gradient Boosting, XGBoost, K-Nearest Neighbors, and Support Vector Regression. Results showed that 55% of groundwater samples exhibited low to no restrictions for irrigation use, while 19% required high to severe restrictions. The XGBoost model demonstrated superior performance, with the highest R2 (0.95) and the lowest RMSE (3.22) among all tested algorithms. SHAP (SHapley Additive exPlanations) analysis provided a transparent interpretation of model predictions, identifying electrical conductivity and Sodium Adsorption Ratio as the most influential parameters affecting IWQI, while chloride, sodium, total hardness, and magnesium had minimal impact. Spatial mapping using Inverse Distance Weighting (IDW) interpolation in ArcGIS 10.8 revealed considerable spatial variability in water quality throughout s the plain. This research addresses a critical gap in North African groundwater management by integrating ML predictive capabilities with XAI transparency, providing water resource managers and agricultural stakeholders with interpretable, data-driven tools for sustainable irrigation planning in water-stressed semi-arid environments. Full article
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24 pages, 4562 KB  
Article
Hydrochemical Appraisal of Groundwater Quality for Managed Aquifer Recharge (MAR) in Southern Punjab, Pakistan
by Ghulam Zakir-Hassan, Lee Baumgartner, Catherine Allan and Jehangir F. Punthakey
Geosciences 2026, 16(1), 43; https://doi.org/10.3390/geosciences16010043 - 14 Jan 2026
Cited by 2 | Viewed by 1382
Abstract
Water quality assessment is crucial for the sustainable use and management of groundwater resources. This study was carried out in the irrigated plains of Vehari District, Punjab, Pakistan, to evaluate groundwater suitability for a managed aquifer recharge (MAR) project. Twenty groundwater samples were [...] Read more.
Water quality assessment is crucial for the sustainable use and management of groundwater resources. This study was carried out in the irrigated plains of Vehari District, Punjab, Pakistan, to evaluate groundwater suitability for a managed aquifer recharge (MAR) project. Twenty groundwater samples were collected in June 2021 from an area of 1522 km2 and analysed for major physicochemical parameters including electrical conductivity (EC), total dissolved solids (TDS), pH, turbidity, calcium (Ca), magnesium (Mg), chloride (Cl), alkalinity (Alk), bicarbonate (HCO3), hardness, potassium (K), sulphate (SO42−), sodium (Na), and nitrate (NO3). Water quality was assessed using WHO and PID standards, alongside derived hydrochemical indices such as sodium percentage (%Na), Kelly’s ratio (KR), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), and the water quality index (WQI). The dataset was interpreted using geo-statistical, geospatial, multivariate, and correlation analyses. Cations and anion dominance followed the order Na+ > Ca2+ > Mg2+ > K+ and HCO3 > SO42− > Cl > NO3. According to the WQI analysis, 35% of the water samples are classified as “poor,” half (50%) as “very poor,” and the remaining 15% as “unsuitable” for drinking purposes. However, irrigation suitability indices confirmed that groundwater is generally acceptable for agricultural use, though unfit for drinking. The outcomes of this study provide essential insights for groundwater management in the region, where the Punjab Irrigation Department (PID) has initiated a MAR project. Considering that the irrigation sector is the major groundwater consumer in the area, the compatibility of groundwater and surface water quality supports the implementation of MAR to enhance agricultural sustainability. Full article
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29 pages, 76370 KB  
Article
Hydrogeochemical and GIS-Integrated Evaluation of Drainage Water for Sustainable Irrigation Management in Al-Jouf, Saudi Arabia
by Raid Alrowais, Mahmoud M. Abdel-Daiem, Mohamed Ashraf Maklad, Wassef Ounaies and Noha Said
Water 2026, 18(1), 78; https://doi.org/10.3390/w18010078 - 27 Dec 2025
Cited by 1 | Viewed by 1359
Abstract
This study evaluates the quality and irrigation suitability of drainage water in the Al-Jouf Region, Saudi Arabia, where water scarcity necessitates the reuse of nonconventional resources. Eighteen drainage water samples were analyzed for physicochemical parameters and irrigation indices, including electrical conductivity (EC), sodium [...] Read more.
This study evaluates the quality and irrigation suitability of drainage water in the Al-Jouf Region, Saudi Arabia, where water scarcity necessitates the reuse of nonconventional resources. Eighteen drainage water samples were analyzed for physicochemical parameters and irrigation indices, including electrical conductivity (EC), sodium percentage (Na+%), sodium adsorption ratio (SAR), magnesium hazard (MH), Kelly’s ratio (KR), permeability index (PS), and irrigation water quality index (IWQI). Multivariate statistical tools were applied to identify dominant hydrogeochemical processes. Inverse Distance Weighting (IDW) interpolation in ArcGIS Desktop 10.8 was employed to map significant physicochemical data and irrigation indicators. Results revealed that while EC values indicated low to moderate salinity (0.74–25.2 μS/cm), most samples showed high Na+%, SAR, and KR, classifying them as doubtful to unsuitable for irrigation. The IWQI ranged from 84.47 to 1617.87, indicating poor to inferior quality due to evaporation, fertilizer leaching, and sodium accumulation. Furthermore, the results highlight the importance of precise geographic modeling in determining whether drainage water is suitable for long-term agricultural use in arid regions such as Al-Jouf. Sustainable reuse of such drainage water requires freshwater blending, gypsum application, and the cultivation of salt-tolerant crops, aligning with Saudi Vision 2030 objectives for sustainable water management in arid regions. Full article
(This article belongs to the Section Water Quality and Contamination)
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22 pages, 2167 KB  
Article
Assessment of Boron Phytotoxicity Risk and Its Relationship with Sodicity and Major Cations in Irrigation Groundwater from the La Yarada Los Palos Coastal Agroecosystem, Caplina Basin, Tacna, Peru
by Luis Johnson Paúl Mori Sosa, Dante Ulises Morales Cabrera and Walter Dimas Florez Ponce De León
Sustainability 2025, 17(24), 11104; https://doi.org/10.3390/su172411104 - 11 Dec 2025
Cited by 1 | Viewed by 701
Abstract
Across ten months of monitoring (1 October 2024–1 July 2025) at three drilled irrigation wells in the La Yarada Los Palos coastal aquifer, this study evaluates boron phytotoxicity risk and its interaction with salinity and sodicity in a hyper-arid coastal agroecosystem. Groundwater samples [...] Read more.
Across ten months of monitoring (1 October 2024–1 July 2025) at three drilled irrigation wells in the La Yarada Los Palos coastal aquifer, this study evaluates boron phytotoxicity risk and its interaction with salinity and sodicity in a hyper-arid coastal agroecosystem. Groundwater samples (n = 10 per well; n = 30) were analyzed for boron, major cations (Ca2+, Mg2+, Na+, K+) and EC. Salinity–sodicity indices (EC-based classes, SAR, Kelly Index, %Na, Mg/Ca ratio) were computed, and relationships among boron, cations, and EC/TDS were examined using correlation analysis and principal components. Boron concentrations ranged from 1.18 to 2.47 mg/L; all samples exceeded the FAO guideline for sensitive crops (0.7 mg/L), and 56.7% were ≥1.5 mg/L. Southern Border exhibited the highest boron (mean ≈ 2.10 mg/L), Ashlands intermediate (≈1.65 mg/L), and Bio Garden Los Palos the lowest (≈1.35 mg/L). EC remained ≈1–1.5 dS/m at Southern Border and Bio Garden Los Palos but reached ≈3–4 dS/m at Ashlands; all SAR values were <9, indicating low sodicity risk. Spearman correlations revealed weak associations between boron and EC/TDS, but moderate positive correlations with Ca2+ and Mg2+, highlighting partly decoupled controls on boron and salinity. For tolerant crops such as olive and orange, and more sensitive ones such as oregano and quinoa, these conditions imply risks that require combined management of salinity, boron, and cation balance. A risk-based monitoring scheme centered on EC, SAR, boron, and Ca–Mg–Na ratios is proposed to support irrigation decisions in La Yarada Los Palos and similar hyper-arid coastal agroecosystems. Full article
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34 pages, 4359 KB  
Article
Groundwater Suitability for Irrigation in the Hennaya Region, Northwest Algeria: A Hydrochemical and GIS-Based Multi-Criteria Assessment
by Abderrahim Badraoui, Chérifa Abdelbaki, Madani Bessedik, Sidi Mohamed Tiar, Yacine Abdelbaset Berrezel, Mahdi Ziane, Amaria Slimani, Ahmed Souafi, Nourredine Boudadi, Bernhard Tischbein and Navneet Kumar
Water 2025, 17(20), 3025; https://doi.org/10.3390/w17203025 - 21 Oct 2025
Viewed by 1564
Abstract
This study investigated groundwater suitability for irrigation in the Hennaya Irrigated region of Northwest Algeria. The research pursued two primary objectives: first, to establish the hydrochemical origin of the groundwater through comprehensive analyses including hydrochemical parameters, diagrams, and hierarchical clustering; and second, to [...] Read more.
This study investigated groundwater suitability for irrigation in the Hennaya Irrigated region of Northwest Algeria. The research pursued two primary objectives: first, to establish the hydrochemical origin of the groundwater through comprehensive analyses including hydrochemical parameters, diagrams, and hierarchical clustering; and second, to assess its suitability for irrigation based on key criteria such as the Water Quality Index (WQI), Wilcox, and US Salinity diagrams. The analysis revealed a high level of groundwater suitability for irrigation, as indicated by various indices: Sodium Adsorption Ratio (SAR) values ranged from 1.69 to 2.55 (Excellent), Sodium Percentage (Na%) ranged from 24.22% to 36.98% (Good), and the Residual Sodium Carbonate (RSC) was negative, falling between −8.91 to −1.70 meq/L (Safe). Kelly’s Ratio (KR) ranged from 0.32 to 0.59 (Good), and the Permeability Index (PI) was between 62% and 99% (Moderate). Supported by the Analytic Hierarchy Process (AHP) and spatial analysis, the Water Quality Index (WQI) values ranged from 69.25 to 88.71, categorizing the groundwater in the study area as ‘Good’ quality. While suitable for irrigation, the groundwater showed slight salinity (EC 1247–2010 μS/cm) and alkalinity (pH 7.09–8.02), with elevated total dissolved solids (TDSs) ranging from 990 to 1930 mg/L, approaching the permissible limits for optimal agricultural use. The dominant ion concentrations (Ca2+ > Na+ > Mg2+ > K+; HCO3 > Cl > SO42− > NO3) indicate a mixed hydrochemical facies influenced by both water–rock interactions and evaporative processes. Although these findings are promising, they highlight the necessity for preventive measures. Ongoing proactive management and continuous monitoring are essential to ensure the long-term sustainability and protection of groundwater resources in the region. Full article
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26 pages, 2434 KB  
Article
Assessment of Soil and Water Quality Indices in Agricultural Soils of Manouba Governorate, North-East Tunisia
by Oumayma Hmidi, Feyda Srarfi, Nadhem Brahim, Carmelo Dazzi and Giuseppe Lo Papa
Soil Syst. 2025, 9(3), 105; https://doi.org/10.3390/soilsystems9030105 - 19 Sep 2025
Cited by 4 | Viewed by 3619
Abstract
Assessing soil and water quality in irrigated farming is vital for sustainable agriculture management. Low-quality irrigation water, particularly in semi-arid regions, poses environmental challenges and leads to soil salinization. This study was conducted in the Jedaida district, Manouba province, NE Tunisia. Forty-three soil [...] Read more.
Assessing soil and water quality in irrigated farming is vital for sustainable agriculture management. Low-quality irrigation water, particularly in semi-arid regions, poses environmental challenges and leads to soil salinization. This study was conducted in the Jedaida district, Manouba province, NE Tunisia. Forty-three soil and water samples were collected to develop indices for assessing soil quality. Sixteen indicators were selected using principal component analysis (PCA) for the minimum soil data set (MSD), including electrical conductivity, sand, organic soil carbon, and pH. The linear method shows a correlation with physical and chemical properties, classifying Jedaida soils into three quality metrics: good, moderate, and poor. The non-linear method displays the lowest indicator contribution in Zahira soils, followed by Mansoura soils (high and moderate). MSD combined with linear scoring is the most acceptable method of assessing the soil quality index (SQI). Water quality indices (WQIs) identify the suitability of irrigation. The results show a Kelly’s ratio > 1, a sodium adsorption ratio (SAR) > 10, and a sodium soluble percentage (SSP) varying from 40 to 60%. This highlights the negative effects of long-term irrigation with poor-quality water on soil health. Accordingly, groundwater was found to be unsuitable for irrigating surface soils. This finding emphasizes the importance of selecting suitable irrigation water to ensure soil quality. Full article
(This article belongs to the Special Issue Research on Soil Management and Conservation: 2nd Edition)
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32 pages, 2285 KB  
Article
Bridging the Construction Productivity Gap—A Hierarchical Framework for the Age of Automation, Robotics, and AI
by Michael Max Bühler, Konrad Nübel, Thorsten Jelinek, Lothar Köhler and Pia Hollenbach
Buildings 2025, 15(16), 2899; https://doi.org/10.3390/buildings15162899 - 15 Aug 2025
Cited by 5 | Viewed by 6566
Abstract
The construction sector, facing a persistent productivity gap compared to other industries, is hindered by fragmented value streams, inconsistent performance metrics, and the limited scalability of process improvements. We introduce a pioneering, four-tiered hierarchical productivity framework to respond to these challenges. This innovative [...] Read more.
The construction sector, facing a persistent productivity gap compared to other industries, is hindered by fragmented value streams, inconsistent performance metrics, and the limited scalability of process improvements. We introduce a pioneering, four-tiered hierarchical productivity framework to respond to these challenges. This innovative approach integrates operational, tactical, strategic, and normative layers. At its core, the framework applies standardised, repeatable process steps—mapped using Value Stream Mapping (VSM)—to capture key indicators such as input efficiency, output effectiveness, and First-Time Quality (FTQ). These are then aggregated through takt time compliance, schedule reliability, and workload balance to evaluate trade synchronisation and flow stability. Higher-level metrics—flow efficiency, multi-resource utilisation, and ESG-linked performance—are integrated into an Overall Productivity Index (OPI). Building on a modular production model, the proposed framework supports real-time sensing, AI-driven monitoring, and intelligent process control, as demonstrated through an empirical case study of continuous process monitoring for Kelly drilling operations. This validation illustrates how sensor-equipped machinery and machine learning algorithms can automate data capture, map observed activities to standardised process steps, and detect productivity deviations in situ. This paper contributes to a multi-scalar measurement architecture that links micro-level execution with macro-level decision-making. It provides a foundation for real-time monitoring, performance-based coordination, and data-driven innovation. The framework is applicable across modular construction, digital twins, and platform-based delivery models, offering benefits beyond specialised foundation work to all construction trades. Grounded in over a century of productivity research, the approach demonstrates how emerging technologies can deliver measurable and scalable improvements. Framing productivity as an integrative, actionable metric enables sector-wide performance gains. The framework supports construction firms, technology providers, and policymakers in advancing robust, outcome-oriented innovation strategies. Full article
(This article belongs to the Special Issue Robotics, Automation and Digitization in Construction)
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25 pages, 3133 KB  
Article
Wastewater Impact on Surface Water Quality and Suitability of Water Reuse in Agriculture Using a Comprehensive Methodology Based on PCA and Specific Indices
by Iulia Ajtai, Anda Anton, Carmen Roba, Camelia Botezan, Ioana Piștea, Marius Oprea and Călin Baciu
Water 2025, 17(13), 2011; https://doi.org/10.3390/w17132011 - 4 Jul 2025
Cited by 2 | Viewed by 2101
Abstract
Effluents from wastewater treatment plants (WWTPs) represent a potential pollution risk to surface waters. Moreover, the growing practice of using treated wastewater for irrigation has recently received increased attention in terms of its suitability, raising concerns about its impact on soil health, agricultural [...] Read more.
Effluents from wastewater treatment plants (WWTPs) represent a potential pollution risk to surface waters. Moreover, the growing practice of using treated wastewater for irrigation has recently received increased attention in terms of its suitability, raising concerns about its impact on soil health, agricultural productivity, and human well-being. The aim of this study is to apply a comprehensive approach to assess the impact of wastewater from a Romanian WWTP on surface water quality and its suitability for irrigation practices. For this purpose, a set of physico-chemical parameters were analyzed, and a Water Quality Index (WQI) was developed based on Principal Component Analysis (PCA). The irrigation suitability of the effluent was further assessed using key parameters (electrical conductivity—EC; total dissolved solids—TDSs; turbidity; Biochemical Oxygen Demand—BOD5) and specific irrigation indices (Sodium Adsorption Ratio—SAR; Permeability Index—PI; Residual Sodium Carbonate—RSC; Sodium percentage—%Na; Kelly’s ratio—KR). The results for the surface water quality indicated high contents of Na+ (10.2–42.5 mg/L), Cl (11.9–48.4 mg/L), and SO42− (10.7–68.5 mg/L) downstream of the wastewater discharge point. The WQI, which reflects overall water quality for environmental health, showed excellent water quality, with a mean of 34 upstream and 47 downstream, suggesting the potential impact of treated wastewater discharge downstream. However, the irrigation indices revealed elevated sodium levels in the effluent, with %Na (up to 86%) categorizing 70% of the samples as unsuitable, while KR (up to 6.2) classified all samples as unsuitable. These findings suggest that despite a low impact on the river water, elevated sodium levels in effluent may limit suitability for irrigation, highlighting the importance of monitoring effluent water reuse. Full article
(This article belongs to the Special Issue Ecological Wastewater Treatment and Resource Utilization)
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21 pages, 2330 KB  
Article
Hydrochemical Characterization, Source Identification, and Irrigation Water Quality Assessment in the Voghji River Catchment Area, Southern Armenia
by Gor Gevorgyan, Gor Khachatryan, Anita Varagyan, Vahagn Varagyan and Ashok Vaseashta
Water 2025, 17(6), 854; https://doi.org/10.3390/w17060854 - 17 Mar 2025
Cited by 3 | Viewed by 2544
Abstract
Water quality is a fundamental parameter for assessing the suitability of surface waters. Likewise, the hydrochemical behavior is critically important to understand for rivers used in irrigation. This study aims to evaluate and characterize the surface water quality of the Voghji River catchment [...] Read more.
Water quality is a fundamental parameter for assessing the suitability of surface waters. Likewise, the hydrochemical behavior is critically important to understand for rivers used in irrigation. This study aims to evaluate and characterize the surface water quality of the Voghji River catchment basin for irrigation, as it reveals the hydrochemical origins in the catchment basin. Nine key parameters, including EC, Cl, SO42−, Ca2+, Mg2+, Na+, K+, CO32−, and HCO3, were measured at seven sampling points in July and September 2017. The ion concentration patterns in July followed the sequence: Ca2+ > Na+ > K+ > Mg2+ and HCO3 > SO42− > Cl > CO32−, while in September, they were Ca2+ > Na+ > Mg2+ > K+ and HCO3 > SO42− > Cl > CO32−. The sequences were almost similar between the two months, with minor differences in cation distribution, particularly between Mg2+ and K+. Overall, Ca2+ and HCO3 were the dominant ions in the studied surface water samples. The concentrations of K+, Na+, Mg2+, Ca2+, Cl, SO42−, and HCO3 were found to be well below the FAO irrigation water standards, indicating that the waters of the Voghji River and its tributaries (Achanan, Vachagan, and Geghi) were generally safe for irrigation. However, the FAO threshold value was exceeded only for CO32− in the Vachagan River in Kapan Town. The chemical analysis of surface waters in the Voghji River catchment basin revealed dominant Ca2+-HCO3 and mixed Ca2+-K+-SO42−-Cl facies, with key geochemical processes including carbonate and gypsum dissolution, silicate weathering, and cation exchange. Ionic correlations indicated that Na+ and Cl sources were influenced by both natural (e.g., halite dissolution, weathering) and anthropogenic inputs, while Ca2+ and Mg2+ primarily originated from carbonate dissolution. The Gibbs diagram suggested that rock–water interactions were the primary natural mechanism controlling the water chemistry, with evaporation also playing a significant role. Various indices, including the Kelly index, magnesium adsorption ratio, sodium percentage, sodium adsorption ratio, permeability index, potential salinity, residual sodium carbonate, soluble sodium percentage, and irrigation water quality index, were applied, along with US Salinity Laboratory diagram and Wilcox diagram, to further assess the irrigation suitability. Most indices confirmed the suitability of the waters for irrigation; however, the Achanan River near the mouth and the Voghji River downstream of Kapan Town exhibited moderate salinity levels, underscoring the need for water management to prevent potential soil degradation. Full article
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26 pages, 2485 KB  
Article
Evaluation of Water Quality of Groundwater of Sanghar District, Sindh, Pakistan: Chemical and Multivariate Analysis
by Abdul Qayoom Landar, Taj Muhammad Jahangir, Muhammad Yar Khuhawar, Muhammad Farooque Lanjwani and Faheem Yar Khuhawar
Water 2024, 16(6), 856; https://doi.org/10.3390/w16060856 - 16 Mar 2024
Cited by 6 | Viewed by 8853
Abstract
Sanghar District is located in the central part of Sindh Province and shares a boarder with India to the east. This work examines the water quality of the groundwater of three subdistricts, Sanghar, Khipro, and Jan Nawaz Ali, mostly used for human consumption, [...] Read more.
Sanghar District is located in the central part of Sindh Province and shares a boarder with India to the east. This work examines the water quality of the groundwater of three subdistricts, Sanghar, Khipro, and Jan Nawaz Ali, mostly used for human consumption, cattle farming, and irrigation. A total of 74 representative samples were collected and analyzed for 26 different parameters, including anions, cations, trace, and toxic elements. The total dissolved salts (TDSs) contained in 41 samples (55.4%), the major cations, K, Na, Mg, and Ca, in 44.6–93.2% of samples, and the major anions, Cl, HCO3, and SO4, in 68.6–81.0% of samples were within the permissible guidelines of the World Health Organization (WHO). The samples containing elements Cr (24.0%), Pb (29.7%), Ni (39.2%), Cd (40.5%), As (10.8%), and F (39.18%) were above the permissible limits of the WHO. The groundwater samples were examined for water quality index (WQI), contamination index (Cd), chronic daily intake indices (CDIs), hazard quotient indices (HQ), principal component analysis (PCA), piper diagrams, Gibbs diagrams, and cluster analysis to ascertain nature of the groundwater present in the study area. The samples were also examined for suitability for irrigation by sodium percentage (Na%), sodium adsorption ratio (SAR), Kelly’s index (KI), permeability index (PI), and Wilcox diagrams. Samples in the range of 0 to 58.33% were inappropriate for irrigation. Full article
(This article belongs to the Special Issue Groundwater Chemistry and Quality in Coastal Aquifers)
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17 pages, 992 KB  
Article
Reuse of Treated Wastewater for Crop Irrigation: Water Suitability, Fertilization Potential, and Impact on Selected Soil Physicochemical Properties
by Solomon Ofori, David Kwesi Abebrese, Iveta Růžičková and Jiří Wanner
Water 2024, 16(3), 484; https://doi.org/10.3390/w16030484 - 1 Feb 2024
Cited by 37 | Viewed by 10017
Abstract
This study evaluates the suitability of treated wastewater (TWW: secondary effluent and membrane effluent) for crop irrigation and the resultant impact on crop growth and soil physicochemical characteristics. Carrot seeds (Daucus carota subsp. sativus) were grown on loam soil and irrigated [...] Read more.
This study evaluates the suitability of treated wastewater (TWW: secondary effluent and membrane effluent) for crop irrigation and the resultant impact on crop growth and soil physicochemical characteristics. Carrot seeds (Daucus carota subsp. sativus) were grown on loam soil and irrigated with tap water (Tap), secondary effluent (SE), and membrane effluent (ME) until maturity. Bacteriological analyses showed four log counts of E. coli and thermotolerant coliforms for secondary effluent, making it unsafe for the irrigation of carrots. Tap water and membrane effluent fulfilled the microbial limit for water reuse and were suitable for irrigation. The sodium absorption ratio, Kelly index, and magnesium hazard assessments indicated that all three irrigation water streams were suitable for irrigation. The average mass of carrot fruits for Tap, SE, and ME was 2.14 g, 3.96 g, and 3.03 g, respectively. A similar trend was observed for the dry matter composition: Tap had 15.9%, SE had 18.3%, and ME had 16.6%. The soil pH increased from 7.08 to 7.26, 7.39, and 7.33 for tap water-, secondary effluent-, and membrane effluent-irrigated soils, respectively. Nitrate-nitrogen and potassium levels increased in the TWW-irrigated soil, while that of the tap water-irrigated soil decreased. Sodium levels in the TWW-irrigated soil increased significantly but did not induce soil sodicity. The application of the TWW enhanced the growth of the carrot plants and increased the soil nutrient levels. Hence, using TWW in agricultural irrigation could promote food production and also limit the overdependency on freshwater resources. However, TWW should be disinfected by using UV disinfection and ozonation to reduce the risk of microbial contamination. Such disinfection methods may not lead to the formation of toxic byproducts, and therefore secondary pollution to crops is not anticipated. Full article
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18 pages, 5221 KB  
Article
Hydrochemical Characteristics and Suitability Assessment of Groundwater Quality for Irrigation
by Milica Vranešević, Radoš Zemunac, Jasna Grabić and Andrea Salvai
Appl. Sci. 2024, 14(2), 615; https://doi.org/10.3390/app14020615 - 11 Jan 2024
Cited by 19 | Viewed by 3162
Abstract
The hydrochemical properties of groundwater play a crucial role in crop growth and soil health, as well as the maintenance of irrigation equipment. To ensure suitable water quality for irrigation, the present study was conducted to evaluate the hydrochemical properties of irrigation groundwater [...] Read more.
The hydrochemical properties of groundwater play a crucial role in crop growth and soil health, as well as the maintenance of irrigation equipment. To ensure suitable water quality for irrigation, the present study was conducted to evaluate the hydrochemical properties of irrigation groundwater in a typical agricultural region of Serbia. Groundwater was sampled at three monitoring locations in the Srem region in Republic of Serbia between 2011 and 2020. Examined parameters included electrical conductivity (EC), total dissolved salts (TDS), pH values, and the concentrations of cations (sodium (Na+), calcium (Ca2+), magnesium (Mg2+) and potassium (K+)) and anions (bicarbonate (HCO3), chloride (Cl), sulfate (SO42−), and nitrate (NO3)). Further assessment was done using three classification systems; Nejgebauer’s, the US USSL, and the FAO classification. To obtain a more detailed assessment, additional indices were included, such as Soluble Sodium Percentage (SSP), Sodium Adsorption Ratio (SAR), Residual Sodium Carbonate (RSC), Permeability Index (PI), Kelly’s Ratio (KR), Magnesium Adsorption Ratio (MAR), and Total Hardness (TH). The PCA analysis detected that the concentration of K+, Ca2+, and Na+ in the irrigation water were lower in recent years, while the concentration of Cl was higher. The cluster analysis grouped the parameters into three clusters; I—electroconductivity, II—dry residue and HCO3, and III—other water parameters for all three monitoring localities. According to the applied classifications, the majority of underground water samples were suitable for irrigation. However, some samples fell out of the range of the first class, indicating the need for regular water quality monitoring. In light of climate changes that influence water deficiency, the urgent need for wise and sustainable water use implies the application of a comprehensive approach to irrigation water quality assessment, as shown in this study. Full article
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24 pages, 18505 KB  
Article
Groundwater Quality and Suitability Assessment for Irrigation Using Hydrogeochemical Characteristics and Pollution Indices: A Case Study of North Al-Quwayiyah Governorate, Central Saudi Arabia
by Haya M. Alogayell, Eman Mohamed M. EL-Bana and Mohamed Abdelfattah
Water 2023, 15(18), 3321; https://doi.org/10.3390/w15183321 - 21 Sep 2023
Cited by 17 | Viewed by 4481
Abstract
The present work focuses on a comprehensive hydrochemical assessment of groundwater within a shallow aquifer located in the central region of Saudi Arabia. This aquifer serves as the principal source of groundwater supply for agricultural irrigation purposes. A total of twelve groundwater samples [...] Read more.
The present work focuses on a comprehensive hydrochemical assessment of groundwater within a shallow aquifer located in the central region of Saudi Arabia. This aquifer serves as the principal source of groundwater supply for agricultural irrigation purposes. A total of twelve groundwater samples were systematically collected and subjected to thorough analysis to determine various physicochemical parameters. These parameters encompassed electrical conductivity (EC), pH, temperature, total dissolved solids (TDS), as well as concentrations of major ions. Analysis of major ion analysis was employed to elucidate the chemical attributes of groundwater within the research area. This approach facilitated an understanding of the geochemical evolution and the potential suitability of the groundwater for agriculture irrigation. The recorded range of electrical conductivity (EC) for the groundwater in this region falls between 3283 and 11,000 µS/cm, with an average value of 6709.4 µS/cm. The pH levels of the groundwater exhibited a slightly alkaline nature, ranging from 7.8 to 8.6. All sampled wells exhibited brackish water conditions (TDS > 1000 mg/L) based on TDS concentrations. The findings of this investigation demonstrated that the average ion concentration followed the order: Na+ > Ca+ > Mg2+ > K+ and Cl > SO42− > HCO3 > NO32−. Applying Piper’s classification system, the groundwater samples were classified into two predominant categories: Ca-Cl and mix-Ca-Mg-Cl. The predominance of Ca2+ and Mg2+ over alkalis indicated mixed groundwater facies influenced by processes of reverse ion exchange and extensive interactions between water and rock formations. The distinct chemical characteristics of the groundwater were attributed to a combination of factors, including the percolation of irrigation-returned water, chemical transformations within the vadose zone, and extensive interactions with subsurface lithology. Despite major ion concentrations surpassing the permissible limits outlined by the World Health Organization (WHO) for drinking water, the assessment of quality indices was conducted to ascertain the suitability of the groundwater for irrigation purposes. These quality indices encompassed the permeability index (PI), magnesium hazard (MH), Kelly’s ratio (KR), sodium-adsorption ratio (SAR), residual sodium carbonate (RSC), sodium percentage (Na%), and magnesium ratio (MR). A meticulous evaluation of groundwater quality for agricultural utilization indicated that all sampled groundwater sources were deemed suitable for irrigation purposes. Full article
(This article belongs to the Section Water Quality and Contamination)
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21 pages, 5307 KB  
Article
An Assessment of Irrigation Water Quality with Respect to the Reuse of Treated Wastewater in Al-Ahsa Oasis, Saudi Arabia
by El-Sayed A. Badr, Rady T. Tawfik and Mortada S. Alomran
Water 2023, 15(13), 2488; https://doi.org/10.3390/w15132488 - 6 Jul 2023
Cited by 38 | Viewed by 9261
Abstract
Irrigation water quality is important to sustain agricultural productivity. The primary irrigation water sources in Al-Ahsa Oasis, KSA, are groundwater wells, mixed with treated wastewater and agricultural drainage. This study sought to evaluate irrigation water quality in Al-Ahsa Oasis with the aid of [...] Read more.
Irrigation water quality is important to sustain agricultural productivity. The primary irrigation water sources in Al-Ahsa Oasis, KSA, are groundwater wells, mixed with treated wastewater and agricultural drainage. This study sought to evaluate irrigation water quality in Al-Ahsa Oasis with the aid of using irrigation water quality indices (IWQIs). One hundred and forty-eight different water samples were collected from various irrigation water resources throughout Al-Ahsa Oasis. The investigated physiochemical characteristics include pH, temperature, TDS, EC, turbidity, free chlorine, total hardness, cations (Na, K, Ca, Mg), anions (Cl, CO3, HCO3, SO4), organic matter indices (DO, BOD, COD), and nutrients (NH4, NO3, PO4). The IWQIs used in this study include salinity hazard, sodium adsorption ratio (SAR), Kelly’s ratio (KR), soluble sodium percentage (SSP), Permeability index (PI), residual sodium carbonate (RSC), and magnesium hazard (MH). The results indicated that treated wastewater mixed with groundwater is acceptable for irrigation. Spatial variations in irrigation water quality throughout Al-Ahsa are associated with water resources. For instance, groundwater mixed with agricultural drainage has the highest values of TDS, cations, and anions, whereas the lowest values were reported for treated wastewater, reflecting the good efficiency of wastewater treatment plants. The IWQI results revealed that 4.1% and 62.1% of the investigated irrigation water samples were considered good (class III) and satisfactory (class IV) for irrigation, respectively, whereas 33.8% of the collected water samples fall within the severe irrigation restrictions. Moreover, 79.7% of the investigated water samples were classified to have high to very high salinity hazards (C3, C4) and medium to high sodium hazards (S2, S3). Regular monitoring and assessment of treated water quality and wastewater treatment plant efficiency are important factors in achieving the sustainability of treated wastewater reuse in irrigation and consequently food security. Full article
(This article belongs to the Special Issue Water and Sediment Quality Assessment)
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20 pages, 10962 KB  
Article
Effects of Seawater Intrusion on the Groundwater Quality of Multi-Layered Aquifers in Eastern Saudi Arabia
by Mohammed Benaafi, S. I. Abba and Isam H. Aljundi
Molecules 2023, 28(7), 3173; https://doi.org/10.3390/molecules28073173 - 3 Apr 2023
Cited by 22 | Viewed by 4403
Abstract
The degradation of groundwater (GW) quality due to seawater intrusion (SWI) is a major water security issue in water-scarce regions. This study aims to delineate the impact of SWI on the GW quality of a multilayered aquifer system in the eastern coastal region [...] Read more.
The degradation of groundwater (GW) quality due to seawater intrusion (SWI) is a major water security issue in water-scarce regions. This study aims to delineate the impact of SWI on the GW quality of a multilayered aquifer system in the eastern coastal region of Saudi Arabia. The physical and chemical properties of the GW were determined via field investigations and laboratory analyses. Irrigation indices (electrical conductivity (EC), potential salinity (PS), sodium adsorption ratio (SAR), Na%, Kelly’s ratio (KR), magnesium adsorption ratio (MAR), and permeability index (PI)) and a SWI index (fsea) were obtained to assess the suitability of GW for irrigation. K-mean clustering, correlation analysis, and principal component analysis (PCA) were used to determine the relationship between irrigation hazard indices and the degree of SWI. The tested GW samples were grouped into four clusters (C1, C2, C3, and C4), with average SWI degrees of 15%, 8%, 5%, and 2%, respectively. The results showed that the tested GW was unsuitable for irrigation due to salinity hazards. However, a noticeable increase in sodium and magnesium hazards was also observed. Moreover, increasing the degree of SWI (fsea) was associated with increasing salinity, sodium, and magnesium, with higher values observed in the GW samples in cluster C1, followed by clusters C2, C3, and C4. The correlation analysis and PCA results illustrated that the irrigation indices, including EC, PS, SAR, and MAR, were grouped with the SWI index (fsea), indicating the possibility of using them as primary irrigation indices to reflect the impact of SWI on GW quality in coastal regions. The results of this study will help guide decision-makers toward proper management practices for SWI mitigation and enhancing GW quality for irrigation. Full article
(This article belongs to the Special Issue Chemometrics in Analytical Chemistry)
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