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Novel Sensing Approaches Based on Functional Materials for Environmental Analysis

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Chemical Sensors".

Deadline for manuscript submissions: closed (10 September 2023) | Viewed by 2320

Special Issue Editor


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Guest Editor
Centro de Investigación Mariña, Universidade de Vigo, Departamento de Química Analítica e Alimentaria, Grupo QA2, Edificio CC Experimentais, Campus de Vigo, As Lagoas, Marcosende, 36310 Vigo, Spain
Interests: analytical nanoscience and nanotechnology; plasmonic and fluorescent nanosensors; nanosorbents; carbon quantum dots; metal nanoclusters; magnetic nanoparticles; noble metal nanoparticles; graphene; atomic and molecular analytical techniques; chemical speciation; miniaturized techniques for on-site detection; emerging contaminants in food; environmental and biological samples

Special Issue Information

Dear Colleagues,

Environmental monitoring is of primary importance to preserve the quality of ecosystems. It has been widely recognized that the environmental impact of contaminants can be exacerbated due to the concomitant climate change, as a result of increased concentrations of harmful chemical species in aquatic systems, changes in their mobility and bioavailability, acidification and eutrophication processes, etc. To promote environmental sustainability, a strict analytical control of the different environmental compartments (water, soil, sediment, atmosphere, and biota) is mandatory. Although central labs can tackle environmental analysis using well-established analytical techniques with high-quality benchtop instruments, there is an increasing need for fast chemical information with enough accuracy and precision and allowing spatial and temporal distribution of the different contaminants. For this purpose, there is an urgent need for novel detection technologies that are miniaturized, portable, robust, have minimal sample pretreatment, low in energy consumption, low in production costs, and able to be deployed in the field.

For this purpose, the implementation of suitable nanomaterials and functional materials with tailored properties for the detection of chemical species is an emerging area that needs to be explored. Carbon-based nanomaterials (e.g., graphene, carbon nanotubes, and carbon quantum dots), noble metal nanoparticles (e.g., gold and silver palladium), semiconductor nanomaterials (e.g., quantum dots), magnetic and non-magnetic oxides (e.g., magnetite, titanium dioxide, and silica), metal sulfides, supramolecular compounds (e.g., chitosan, dendrimers, calixarene, and metal organic frameworks), and composites (combination of one or two functional materials) possess excellent properties—mechanical, electrical, catalytic, magnetic, optical, etc.—that make them attractive for the design of novel sensing approaches in order to cope with challenges posed by the contamination of ecosystems. This Special Issue aims to gather the most recent advances in the applications of nanomaterials and functional materials for environmental analysis. Both innovative original papers and authoritative reviews are welcome. I look forward to your valuable contributions.

Prof. Dr. José Carlos Bendicho Hernández
Guest Editor

Manuscript Submission Information

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Keywords

  • environmental analysis
  • sensors
  • nanomaterials
  • functional materials
  • on-site detection
  • contaminants

Published Papers (1 paper)

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Research

17 pages, 50915 KiB  
Article
Elaboration and Characterization of a New Heavy Metal Sensor Functionalized by Extracellular Polymeric Substances Isolated from a Tunisian Thermophilic Microalga Strain Graesiella sp.
by Wejdene Gongi, Maxence Rube, Hafedh Ben Ouada, Hatem Ben Ouada, Ollivier Tamarin and Corinne Dejous
Sensors 2023, 23(2), 803; https://doi.org/10.3390/s23020803 - 10 Jan 2023
Cited by 5 | Viewed by 1885
Abstract
The present study aimed to develop and characterize new heavy metal sensors functionalized by extracellular polymeric substances (EPSs) isolated from a Tunisian thermophilic microalga strain Graesiella sp. The elaborated sensor showed a highly homogeneous character and revealed a microstructural lamellar arrangement, high crystalline [...] Read more.
The present study aimed to develop and characterize new heavy metal sensors functionalized by extracellular polymeric substances (EPSs) isolated from a Tunisian thermophilic microalga strain Graesiella sp. The elaborated sensor showed a highly homogeneous character and revealed a microstructural lamellar arrangement, high crystalline nature, and several functional groups. Electrochemical impedance spectroscopy (EIS) and acoustic wave sensing were used as sensing techniques to explore the ability of microalgae-EPS-functionalized sensors to detect cadmium and mercury as heavy metals. For impedimetric measurements, a two-dipole circuit was adopted and showed good-fitted results with a low total error. The acoustic sensor platforms showed good compatibility with EPS in adjacent water. For both EPS-functionalized sensors, metal ions (Cd2+, Hg2+) were successfully detected in the concentration range from 10−10 M to 10−4 M. Impedimetric sensor was more sensitive to Cd2+ at low concentrations before saturation at 10−7 M, while the acoustic sensor exhibited more sensitivity to Hg2+ over the full range. The results highlight a new potential alternative to use microalgae EPSs as a sensitive coating material for the detection of heavy metals. However, its use in a real liquid medium requires further investigation of its selectivity in the presence of other compounds. Full article
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