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Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes
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Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes

A special issue of Reactions (ISSN 2624-781X).

Deadline for manuscript submissions: closed (31 August 2024) | Viewed by 18946

Special Issue Editors

Dr. Diogo M.F. Santos

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Guest Editor
Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal
Interests: renewable gases; green hydrogen; water electrolysis; hydrogen evolution reaction; oxygen evolution reaction; hydrogen economy
Special Issues, Collections and Topics in MDPI journals
Dr. Catarina Nobre

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Guest Editor
VALORIZA—Research Center for Endogenous Resource Valorization, Campus Politécnico, 10, 7300-555 Portalegre, Portugal
Interests: bioenergy; biofuels; biochar; pyrolysis; gasification; refuse derived fuels; biomass wastes
Special Issues, Collections and Topics in MDPI journals
Dr. Paulo Brito

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Guest Editor
VALORIZA—Researche Center for Endogenous Resources Valorization, Polytecnic Institute of Portalegre Campus Politécnico, 10, 7300-555 Portalegre, Portugal
Interests: bioenergy; thermal gasification; waste valorization; electrolysis; corrosion
Special Issues, Collections and Topics in MDPI journals
Dr. Margarida Gonçalves

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Guest Editor
Mechanical Engineering and Resource Sustainability Center, Faculty of Science and Technology, NOVA University of Lisbon, 2829-516 Caparica, Portugal
Interests: biofuels; biomass; thermochemical processes; waste valorization; microalgae; biorefineries
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

By 2030, the bio-based economy is expected to have grown significantly in Europe. One of the pillars of this bioeconomy is the concept of biorefinery, the sustainable processing of several kinds of waste and biomass into a spectrum of marketable products and energy. While many research efforts have been conducted toward understanding, modelling, and designing conversion processes that can sustain a true circular economy, this knowledge is fragmented and unevenly distributed across Europe. Several countries lack appropriate policies and public engagement to endeavour the challenges ahead. Harmonisation must start with robust knowledge and the ability to cover the whole value chain, from source materials to marketable products. That is the mission of COST Action CA20127—Waste biorefinery technologies for accelerating sustainable energy processes (WIRE).

The WIRE COST Action is broadly organised into 4 key Working Groups (WG) that bring together experts from academia, industry, and technology transfer organisations and cover (1) raw materials, (2) biorefinery conversion technologies, (3) biorefinery applications, and (4) communication and dissemination. These WG will proactively contribute to promoting (i) the circular economy, (ii) bioenergy and bioeconomy, (iii) research and innovation in the field, (iv) applied research towards biorefineries’ implementation, and (v) EU-wide harmonisation of the scientific and technical approaches, thus facilitating engagement with policy makers and industry, paving the ground for a more effective link with the relevant industry sectors and attracting their interest.

This Special Issue in Reactions aims to publish some of the outcomes of WIRE COST Action and other research works that fall within the topic of the issue. We hope that this issue can positively influence the future landscape in science and technology in the critical field of waste biorefineries.

Dr. Diogo M.F. Santos
Dr. Catarina Nobre
Dr. Paulo Brito
Dr. Margarida Gonçalves
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Reactions is an international peer-reviewed open access quarterly journal published by MDPI.

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Related Special Issue

Published Papers (11 papers)

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Research

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14 pages, 3249 KiB  
Article
Capture and UV-Fluorescence Characterization of Primary Aerosols Ejected During the Fast Pyrolysis of Biomass in a Hot Plate Reactor
by Mario A. Sánchez, Estefanía Orrego-Restrepo, Mariana Bustamante-Durango, Juan C. Maya, Farid Chejne, Brennan Pecha and Adriana M. Quinchía-Figueroa
Reactions 2024, 5(4), 1013-1026; https://doi.org/10.3390/reactions5040053 - 1 Dec 2024
Viewed by 576
Abstract
This study focuses on the collection and UV characterization of the bio-oil phase from primary aerosols ejected from the liquid intermediate phase during the fast pyrolysis of biomass in a hot plate reactor. The effects of the reactor pressure and aerosol-collecting surface temperature [...] Read more.
This study focuses on the collection and UV characterization of the bio-oil phase from primary aerosols ejected from the liquid intermediate phase during the fast pyrolysis of biomass in a hot plate reactor. The effects of the reactor pressure and aerosol-collecting surface temperature on the bio-oil yield and characteristics were evaluated. The study found that lower reactor pressures and a lower temperature of the collecting surface significantly enhanced the aerosol yield (up to 85%). UV-fluorescence was employed to assess the influence of these parameters on the light-to-heavy compound ratio (monomers vs. oligomers). The heavy fraction of bio-oil from the hot plate reactor was predominantly composed of dimers and trimers (340–370 nm), similar to pyrolytic lignin and the heavy fraction of the bio-oil, which also showed peaks in this range. In contrast, pyrolysis oils from auger and fluidized bed reactors displayed two peaks in the UV spectrum, with a maximum around 300 nm, indicating that they are mainly composed of light monomeric compounds. The UV characterization of the primary aerosols and the comparison with the UV spectra of the bio-oil and its fractions (light and heavy fraction and pyrolignin) revealed similar UV prints, highlighting the importance of aerosol ejection in the final composition of bio-oil. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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19 pages, 2525 KiB  
Article
Optimization of Hydrocarbon Production in Catalytic Pyrolysis of Macaúba Epicarp and Macaúba and Baru Endocarps
by Reginaldo José Cavallaro, Claudio Roberto Duarte, Carla Eponina Hori and Marcos Antonio de Souza Barrozo
Reactions 2024, 5(4), 823-841; https://doi.org/10.3390/reactions5040043 - 1 Nov 2024
Viewed by 822
Abstract
The objective of this study was to examine the catalytic pyrolysis process of three distinct types of biomasses: baru endocarp (ENB), macaúba endocarp (ENM), and macaúba epicarp (EPM). This was performed with the aim of optimizing the production of hydrocarbons and other volatile [...] Read more.
The objective of this study was to examine the catalytic pyrolysis process of three distinct types of biomasses: baru endocarp (ENB), macaúba endocarp (ENM), and macaúba epicarp (EPM). This was performed with the aim of optimizing the production of hydrocarbons and other volatile compounds of interest through the use of different catalysts. The catalysts utilized in this study were calcium oxide (CaO), phosphate mining waste (PO), niobium pentoxide (Nb2O5), and Ni/Nb2O5. The methodology entailed pyrolyzing the biomass at temperatures spanning from 508 °C to 791 °C, utilizing a micropyrolyzer in conjunction with a gas chromatograph with mass spectrometry (GC/MS) for product analysis. An experimental design was implemented to assess the impact of catalyst concentration and temperature on the yield and composition of the volatile products. The findings demonstrated that CaO was efficacious in deoxygenating the compounds, particularly at elevated temperatures, thereby promoting the generation of saturated and unsaturated hydrocarbons. In contrast, Nb2O5 was effective in the formation of oxygenated compounds, particularly carboxylic acids and phenols. Ni/Nb2O5 has been shown to be effective in the production of cyclic, aromatic, alkadienes, and alkenes hydrocarbons. Phosphate mining waste exhibited moderate performance, with potential for specific applications at high temperatures, with important production of cyclic, aromatic, and alkane hydrocarbons. Among the biomasses, EPM demonstrated the greatest potential for hydrocarbon production, indicating its suitability for the development of advanced biofuels. This study advances our understanding of the catalytic pyrolysis of alternative biomasses and underscores the pivotal role of catalysts in optimizing the process, offering invaluable insights for the sustainable production of biofuels and interest in renewable chemicals. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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13 pages, 1870 KiB  
Article
Production of Sugars and Ethanol from Acid–Alkaline-Pretreated Agave sisalana Residue
by Habila Yusuf Thomas, José Demétrio Nery Cavalcante, Willame Marinho dos Santos, Domingos Fabiano de Santana Souza, Carlos Eduardo de Araújo Padilha, Rômulo Simões Cezar Menezes, Rafael Barros de Souza and Emmanuel Damilano Dutra
Reactions 2024, 5(4), 765-777; https://doi.org/10.3390/reactions5040038 - 14 Oct 2024
Viewed by 1051
Abstract
Drylands in Brazil have been exploring sisal (Agave sisalana) as an essential source of income. However, the solid residues generated because of this activity still need suitable destinations; therefore, research has been carried out to transform them into added-value products. Therefore, [...] Read more.
Drylands in Brazil have been exploring sisal (Agave sisalana) as an essential source of income. However, the solid residues generated because of this activity still need suitable destinations; therefore, research has been carried out to transform them into added-value products. Therefore, the present study evaluated the potential of sisal or agave solid residue as a precursor feedstock for second-generation ethanol production. Acid and acid–alkaline pretreatments were carried out on sisal residues to enrich the biomass with cellulose and maximize enzymatic digestibility. Second-generation ethanol production was carried out using Semi-simultaneous saccharification and fermentation (SSSF). Regardless of catalyst dosage and incubation time, oxalic acid pretreatments generated samples with a similar chemical composition to those pretreated with sulfuric acid. However, samples pretreated with oxalic acid showed lower enzymatic digestibility. Samples pretreated with oxalic acid and sodium hydroxide obtained 14.28 g/L of glucose and cellulose conversion of 79.1% (at 5% solids), while 21.49 g/L glucose and 91.2% of cellulose conversion were obtained in the hydrolysis of pretreated samples with sulfuric acid and sodium hydroxide combined pretreatments. The pretreatment sequence efficiently reduced cellulase dosage from 20 to 10 FPU/g without compromising sugar release. SSSF achieved maximum production of 40 g/L ethanol and 43% ethanol conversion using 30% solids and gradually adding biomass and cellulases. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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16 pages, 2389 KiB  
Article
Enhancing Laccase Production by Trametes hirsuta GMA-01 Using Response Surface Methodology and Orange Waste: A Novel Breakthrough in Sugarcane Bagasse Saccharification and Synthetic Dye Decolorization
by Guilherme Guimarães Ortolan, Alex Graça Contato, Guilherme Mauro Aranha, Jose Carlos Santos Salgado, Robson Carlos Alnoch and Maria de Lourdes Teixeira de Moraes Polizeli
Reactions 2024, 5(3), 635-650; https://doi.org/10.3390/reactions5030032 - 19 Sep 2024
Viewed by 1381
Abstract
Trametes hirsuta GMA-01 was cultivated in a culture medium supplemented with orange waste, starch, wheat bran, yeast extract, and salts. The fungus produced several holoenzymes, but the laccase levels were surprisingly high. Given the highlighted applicability of laccases in various biotechnological areas with [...] Read more.
Trametes hirsuta GMA-01 was cultivated in a culture medium supplemented with orange waste, starch, wheat bran, yeast extract, and salts. The fungus produced several holoenzymes, but the laccase levels were surprisingly high. Given the highlighted applicability of laccases in various biotechnological areas with minimal environmental impact, we provided a strategy to increase its production using response surface methodology. The immobilization of laccase into ionic supports (CM-cellulose, DEAE-agarose, DEAE-cellulose, DEAE-Sephacel, MANAE-agarose, MANAE-cellulose, and PEI-agarose) was found to be efficient and recuperative, showcasing the technical prowess of research. The crude extract laccase (CE) and CM-cellulose-immobilized crude extract (ICE) showed optimum activity in acidic conditions (pH 3.0) and at 70 °C for the CE and 60 °C for the ICE. The ICE significantly increased thermostability at 60 °C for the crude extract, which retained 21.6% residual activity after 240 min. The CE and ICE were successfully applied to sugarcane bagasse hydrolysis, showing 13.83 ± 0.02 µmol mL−1 reducing sugars after 48 h. Furthermore, the CE was tested for dye decolorization, achieving 96.6%, 71.9%, and 70.8% decolorization for bromocresol green, bromophenol blue, and orcein, respectively (0.05% (w/v) concentration). The properties and versatility of T. hirsuta GMA-01 laccase in different biotechnological purposes are interesting and notable, opening several potential applications and providing valuable insights into the future of biotechnological development. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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20 pages, 7700 KiB  
Article
Sewage Sludge Plasma Gasification: Characterization and Experimental Rig Design
by Nuno Pacheco, André Ribeiro, Filinto Oliveira, Filipe Pereira, L. Marques, José C. Teixeira, Cândida Vilarinho and Flavia V. Barbosa
Reactions 2024, 5(2), 285-304; https://doi.org/10.3390/reactions5020014 - 16 Apr 2024
Cited by 1 | Viewed by 1703
Abstract
The treatment of wastewater worldwide generates substantial quantities of sewage sludge (SS), prompting concerns about its environmental impact. Various approaches have been explored for SS reuse, with energy production emerging as a viable solution. This study focuses on harnessing energy from domestic wastewater [...] Read more.
The treatment of wastewater worldwide generates substantial quantities of sewage sludge (SS), prompting concerns about its environmental impact. Various approaches have been explored for SS reuse, with energy production emerging as a viable solution. This study focuses on harnessing energy from domestic wastewater treatment (WWT) sewage sludge through plasma gasification. Effective syngas production hinges on precise equipment design which, in turn, depends on the detailed feedstock used for characterization. Key components of plasma gasification include the plasma torch, reactor, heat exchanger, scrubber, and cyclone, enabling the generation of inert slag for landfill disposal and to ensure clean syngas. Designing these components entails considerations of sludge composition, calorific power, thermal conductivity, ash diameter, and fusibility properties, among other parameters. Accordingly, this work entails the development of an experimental setup for the plasma gasification of sewage sludge, taking into account a comprehensive sludge characterization. The experimental findings reveal that domestic WWT sewage sludge with 40% humidity exhibits a low thermal conductivity of approximately 0.392 W/mK and a calorific value of LHV = 20.78 MJ/kg. Also, the relatively low ash content (17%) renders this raw material advantageous for plasma gasification processes. The integration of a detailed sludge characterization into the equipment design lays the foundation for efficient syngas production. This study aims to contribute to advancing sustainable waste-to-energy technologies, namely plasma gasification, by leveraging sewage sludge as a valuable resource for syngas production. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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21 pages, 3960 KiB  
Article
Dry and Hydrothermal Co-Carbonization of Mixed Refuse-Derived Fuel (RDF) for Solid Fuel Production
by Andrei Longo, Octávio Alves, Ali Umut Sen, Catarina Nobre, Paulo Brito and Margarida Gonçalves
Reactions 2024, 5(1), 77-97; https://doi.org/10.3390/reactions5010003 - 16 Jan 2024
Cited by 1 | Viewed by 2053
Abstract
The present study aims to test several conditions of the thermochemical pretreatment of torrefaction and carbonization to improve the physical and combustible properties of the Portuguese RDF. Therefore, two different types of RDF were submitted alone or mixed in 25%, 50%, and 75% [...] Read more.
The present study aims to test several conditions of the thermochemical pretreatment of torrefaction and carbonization to improve the physical and combustible properties of the Portuguese RDF. Therefore, two different types of RDF were submitted alone or mixed in 25%, 50%, and 75% proportions to dry carbonization processes in a range of temperatures between 250 to 350 °C and residence time between 15 and 60 min. Hydrothermal carbonization was also carried out with RDF samples and their 50% mixture at temperatures of 250 and 300 °C for 30 min. The properties of the 51 chars and hydrochars produced were analyzed. Mass yield, apparent density, proximate and elemental analysis, ash mineral composition, and higher heating value (HHV), among others, were determined to evaluate the combustion behavior improvement of the chars. The results show that after carbonization, the homogeneity and apparent density of the chars were increased compared to the raw RDF wastes. The chars and hydrochars produced present higher HHV and lower moisture and chlorine content. In the case of chars, a washing step seems to be essential to reduce the chlorine content to allow them to be used as an alternative fuel. In conclusion, both dry and wet carbonization demonstrated to be important pretreatments of the RDF to produce chars with improved physical and combustion properties. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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18 pages, 3021 KiB  
Article
Immobilization of Cellulolytic Enzymes in Accurel® MP1000
by Julia R. S. Baruque, Adriano Carniel, Júlio C. S. Sales, Bernardo D. Ribeiro, Rodrigo P. do Nascimento and Ivaldo Itabaiana, Jr.
Reactions 2023, 4(2), 311-328; https://doi.org/10.3390/reactions4020019 - 16 Jun 2023
Viewed by 1802
Abstract
Cellulases are a class of enzymes of great industrial interest that present several strategic applications. However, the high cost of enzyme production, coupled with the instabilities and complexities of proteins required for hydrolytic processes, still limits their use in several protocols. Therefore, enzyme [...] Read more.
Cellulases are a class of enzymes of great industrial interest that present several strategic applications. However, the high cost of enzyme production, coupled with the instabilities and complexities of proteins required for hydrolytic processes, still limits their use in several protocols. Therefore, enzyme immobilization may be an essential tool to overcome these issues. The present work aimed to evaluate the immobilization of cellulolytic enzymes of the commercial enzyme cocktail Celluclast® 1.5 L in comparison to the cellulolytic enzyme cocktail produced from the wild strain Trichoderma harzianum I14-12 in Accurel® MP1000. Among the variables studied were temperature at 40 °C, ionic strength of 50 mM, and 72 h of immobilization, with 15 m·L −1 of proteins generated biocatalysts with high immobilization efficiencies (87% for ACC-Celluclast biocatalyst and 95% for ACC-ThI1412 biocatalyst), high retention of activity, and specific activities in the support for CMCase (DNS method), FPase (filter paper method) and β-glucosidase (p-nitrophenyl-β-D-glucopyranoside method). Presenting a lower protein concentration (0.32 m·L−1) than the commercial Celluclast® 1.5 L preparation (45 m·L−1), the ACC-ThI1412-derived immobilized biocatalyst showed thermal stability at temperatures higher than 60 °C, maintaining more than 90% of the residual activities of FPase, CMCase, and β-glucosidase. In contrast, the commercial-free enzyme presented a maximum catalytic activity at only 40 °C. Moreover, the difference in molecular weight between the component enzymes of the extract was responsible for different hydrophobic and lodging interactions of proteins on the support, generating a robust and competitive biocatalyst. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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16 pages, 5825 KiB  
Article
Biofuels from Pyrolysis of Third-Generation Biomass from Household and Garden Waste Composting Bin: Kinetics Analysis
by Bruna Rijo, Ana Paula Soares Dias, Novi Dwi Saksiwi, Manuel Francisco Costa Pereira, Rodica Zăvoianu, Octavian Dumitru Pavel, Olga Ferreira and Rui Galhano dos Santos
Reactions 2023, 4(2), 295-310; https://doi.org/10.3390/reactions4020018 - 12 Jun 2023
Cited by 1 | Viewed by 2296
Abstract
The modern society produces large amounts of household waste with high organic matter content. The vermicomposting of household waste produces high-value humic substances and is a way to stabilize organic material for later use as raw material (3rd generation biomass) for bioenergy proposes. [...] Read more.
The modern society produces large amounts of household waste with high organic matter content. The vermicomposting of household waste produces high-value humic substances and is a way to stabilize organic material for later use as raw material (3rd generation biomass) for bioenergy proposes. A 6-month matured compost, combining vegetable and fruit scraps from domestic trash and grass and shrub clippings from yard waste, was evaluated to assess its potential as a raw material in pyrolysis processes. The pyrolysis activation energy (Kissinger) of the composted material showed values in the range of 200–300 kJ/mol, thus confirming its suitability for pyrolysis processes with promising H2 yields. The treatment of the composted material with H2SO4 and NaOH solution (boiling; 1 mol/L) led to the production of solid residues that present higher pyrolysis activation energies, reaching 550 kJ/mol for the most resilient fraction, which makes them suitable to produce carbonaceous materials (biochar) that will have incorporated the inorganics existing in the original compost (ashes 37.6%). The high content of inorganics would play a chief role during pyrolysis since they act as gasification promoters. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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23 pages, 3789 KiB  
Article
Preliminary Studies on the Electrochemical Conversion of Liquefied Forest Biomass
by Tiago Silva, José Condeço and Diogo M. F. Santos
Reactions 2022, 3(4), 553-575; https://doi.org/10.3390/reactions3040037 - 31 Oct 2022
Cited by 2 | Viewed by 2085
Abstract
Bio-oils produced from three different biomass sources, namely cork, pinewood, and olive stones, are evaluated concerning their suitability and prospects of including their electrochemical transformations in a biorefinery scenario for the production of added-value compounds. Different types and concentrations of electrolytes (e.g., H [...] Read more.
Bio-oils produced from three different biomass sources, namely cork, pinewood, and olive stones, are evaluated concerning their suitability and prospects of including their electrochemical transformations in a biorefinery scenario for the production of added-value compounds. Different types and concentrations of electrolytes (e.g., H2SO4, KOH) are added to the bio-oils to increase the samples’ initially low ionic conductivity. The samples prepared by mixing bio-oil with 2 M KOH aqueous solution (50 vol.%) lead to a stable and homogeneous bio-oil alkaline emulsion suitable for electrochemical studies. The bio-oil samples are characterized by physicochemical methods (e.g., density, viscosity, conductivity), followed by analyzing their electrochemical behavior by voltammetric and chronoamperometric studies. The organics electrooxidation and the hydrogen evolution reaction in the bio-oils are assessed using Pt electrodes. Single- and two-compartment cell laboratory bio-oil electrolyzers are assembled using nickel plate electrodes. Electrolysis is carried out at 2.5 V for 24 h. Attenuated Total Reflection-Fourier-Transform Infrared Spectroscopy and Mass Spectrometry are applied to identify possible changes in the bio-oil samples’ chemical structure during the electrolysis experiments. Comparing the analyses of the bio-oil samples subjected to electrolysis with the blank samples demonstrates that bulk electrolysis significantly changes the bio-oil composition. The bio-oil obtained from cork biomass shows the most promising results, but further studies are required to understand the nature of the actual changes. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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Review

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18 pages, 961 KiB  
Review
Efficient Production of Platform Chemicals from Lignocellulosic Biomass by Using Nanocatalysts: A Review
by Sapna Jain and Samuel Kassaye
Reactions 2024, 5(4), 842-859; https://doi.org/10.3390/reactions5040044 - 4 Nov 2024
Viewed by 876
Abstract
This paper discusses significant advancements in using lignocellulosic biomass for the sustainable production of biofuels and chemicals. As fossil-based resources decline and environmental concerns rise, the paper emphasizes the role of integrated biorefineries in producing renewable liquid fuels and high-value chemicals from biomass. [...] Read more.
This paper discusses significant advancements in using lignocellulosic biomass for the sustainable production of biofuels and chemicals. As fossil-based resources decline and environmental concerns rise, the paper emphasizes the role of integrated biorefineries in producing renewable liquid fuels and high-value chemicals from biomass. It highlights exploring various green pathways for biomass conversion, with a particular focus on nanocatalysis. Due to their large surface area-to-volume ratio, nanocatalysts provide enhanced catalytic activity and efficiency in biomass transformation processes. The review delves into the synthesis of value-added and furfural platform chemicals alongside the hydrogenolysis of 5-hydroxymethylfurfural (5-HMF) into biofuels like 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF). The paper ultimately underscores the importance of nanotechnology in achieving high yield and selectivity in the biomass conversion process, positioning it as a promising approach for future sustainable energy and chemical production. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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66 pages, 8444 KiB  
Review
Transformations of Glycerol into High-Value-Added Chemical Products: Ketalization and Esterification Reactions
by Federico M. Perez, Martin N. Gatti, Gerardo F. Santori and Francisco Pompeo
Reactions 2023, 4(4), 569-634; https://doi.org/10.3390/reactions4040034 - 8 Oct 2023
Cited by 3 | Viewed by 2546
Abstract
Biomass allows us to obtain energy and high-value-added compounds through the use of different physical and chemical processes. The glycerol obtained as a by-product in the synthesis of biodiesel is considered a biomass compound that has the potential to be used as a [...] Read more.
Biomass allows us to obtain energy and high-value-added compounds through the use of different physical and chemical processes. The glycerol obtained as a by-product in the synthesis of biodiesel is considered a biomass compound that has the potential to be used as a raw material to obtain different chemical products for industry. The development and growth of the biodiesel industry allows for the projection of glycerol biorefineries around these plants that efficiently and sustainably integrate the biodiesel production process together with the glycerol transformation processes. This work presents a review of the ketalization and esterification of glycerol to obtain solketal and acetylglycerols, which are considered products of high added value for the chemical and fuel industry. First, the general aspects and mechanisms of both reactions are presented, as well as the related chemical equilibrium concepts. Subsequently, the catalysts employed are described, classifying them according to their catalytic nature (zeolites, carbons, exchange resins, etc.). The reaction conditions used are also described, and the best results for each catalytic system are presented. In addition, stability studies and the main deactivation mechanisms are discussed. Finally, the work presents the kinetic models that have been formulated to date for some of these systems. It is expected that this review work will serve as a tool for the advancement of studies on the ketalization and esterification reactions that allow for the projection of biorefineries based on glycerol as a raw material. Full article
(This article belongs to the Special Issue Waste Biorefinery Technologies for Accelerating Sustainable Energy Processes)
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