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Multifunctional Thermoset Polymer Systems for Advanced Energy Storage Technologies

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 28 February 2026 | Viewed by 39

Special Issue Editor


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Guest Editor
Department of Fiber System Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea
Interests: polybenzoxazine; energy storage; bio polymers; surface modification; functional polymer; membranes; ring-opening polymers
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Special Issue Information

Dear Colleagues,

Multifunctional thermoset polymer systems are gaining prominence for their versatile applications in advanced energy storage technologies. These polymers, especially bio-based, epoxy, and benzoxazine resins, offer superior mechanical strength, thermal stability, and chemical resistance, making them ideal for integrating structural functions with energy storage capabilities. Recent advances focus on integrating thermosets with nanomaterials such as MXenes, carbon nanotubes, and graphene to enhance performance in supercapacitors, batteries and thermal energy storage systems. Bio-based thermosets derived from lignin and other renewable sources are gaining attraction due to their environmental benefits. These systems enable multifunctionality—combining structural integrity, energy storage, and thermal management—making them ideal for flexible electronics, aerospace, and renewable energy devices. Cutting-edge research also explores shape–memory thermosets and dynamic covalent networks for self-healing and reprocessing capabilities, positioning these materials at the forefront of energy storage technologies.

Dr. Shakila Parveen Asrafali
Guest Editor

Manuscript Submission Information

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Keywords

  • polymer hybrid composites
  • structural composites
  • bio-based thermosets
  • shape–memory thermoset composites
  • conducting thermoset composites

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Published Papers (1 paper)

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Review

21 pages, 3170 KiB  
Review
Properties of Polybenzoxazine-Based Conducting Materials in Energy-Related Applications
by Shakila Parveen Asrafali, Thirukumaran Periyasamy, Gazi A. K. M. Rafiqul Bari and Jaewoong Lee
Polymers 2025, 17(16), 2194; https://doi.org/10.3390/polym17162194 - 11 Aug 2025
Abstract
Polybenzoxazine (PBz)-based conducting materials have gained significant attention due to their unique combination of thermal stability, mechanical strength, and electrical conductivity. These polymers integrate the inherent advantages of polybenzoxazines—such as low water absorption, high glass transition temperature, and excellent chemical resistance—with the electrical [...] Read more.
Polybenzoxazine (PBz)-based conducting materials have gained significant attention due to their unique combination of thermal stability, mechanical strength, and electrical conductivity. These polymers integrate the inherent advantages of polybenzoxazines—such as low water absorption, high glass transition temperature, and excellent chemical resistance—with the electrical properties of conducting polymers like polyaniline, polypyrrole, and polythiophene. The incorporation of conductive elements in polybenzoxazine networks can be achieved through blending, in situ polymerization, or hybridization with nanostructures such as graphene, carbon nanotubes, or metallic nanoparticles. These modifications enhance their charge transport properties, making them suitable for applications in flexible electronics, energy storage devices, sensors, and electromagnetic shielding materials. Furthermore, studies highlight that polybenzoxazine matrices can improve the processability and environmental stability of conventional conducting polymers while maintaining high conductivity. The structure–property relationships of polybenzoxazine-based composites demonstrate that tailoring monomer composition and polymerization conditions can significantly influence their conductivity, thermal stability, and mechanical properties. This review summarizes recent advancements in PBz composites, focusing on their synthesis, structural modifications, conductivity mechanisms, and potential applications in advanced energy storage systems. Full article
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