Special Issue "Free Radicals in Organic Synthesis"
Deadline for manuscript submissions: closed (10 May 2016).
Interests: free radical organic and polymer chemistry; heterocyclic and medicinal chemistry
Special Issues and Collections in MDPI journals
Special Issue in Molbank: Heterocycle Reactions
Special Issue in Molecules: Synthetic Heterocyclic Chemistry
Over the past twenty years, the use of free radicals in organic synthesis has become commonplace. In this Special issue, we welcome reports on the use of free radicals in the development of new synthetic methodology, target orientated synthesis, and as reaction intermediates. These reactive free radicals typically have fleeting lifetimes, however, new reports on the synthesis of stable free radicals are also welcome. Stable free radicals, such as nitroxides, have found uses as spin traps, profluorescent probes, and importantly as mediators in controlled/living radical polymerizations. A synthetic transformation that has been revolutionized over the past five years is homolytic aromatic substitution (HAS) with traditional non-chain Group 14 organometal hydride-mediated and photochemical techniques superseded by more efficient and benign visible-light photocatalysis and base-mediated HAS. Therefore we welcome reports circumventing the use of toxic heavy metals and expensive transition metal catalysts, and others demonstrating the green credentials of free radicals in organic synthesis.
Prof. Dr. Fawaz Aldabbagh
Manuscript Submission Information
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.
Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2000 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.
- green chemistry
- homolytic substitutions
- reaction mechanisms
- persistent radicals
- synthetic intermediates