Geochemistry, Petrogenesis and Exploration of Li-Rich Granite-Pegmatite Systems

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Deposits".

Deadline for manuscript submissions: 30 June 2026 | Viewed by 2187

Special Issue Editors


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Guest Editor
Natural History Museum, University of Oslo, 0318 Oslo, Norway
Interests: mineralogy; petrology; geochemistry; economic geology

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Guest Editor
Camborne School of Mines, University of Exeter, Penryn Campus, Penryn TR10 9FE, UK
Interests: exploration geochemistry; exploration targeting; economic geology

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Guest Editor
1. Geological Survey of Queensland, Brisbane, Australia
2. School of Geography, Environment, and Earth Sciences, Victoria University of Wellington, Wellington, New Zealand
Interests: exploration geochemistry; economic geology; structural geology

Special Issue Information

Dear Colleagues,

Lithium-rich granites, and their very coarse (>2 cm)-grained variants, pegmatites (also referred to as lithium–cesium–tantalum (LCT) pegmatites), are magmatic rock types generated from highly evolved, typically peraluminous, silicic melts. The high Li concentrations in granitic melts can accumulate through fractional crystallization leading to Li enrichment in residual melts. Lithium-rich pegmatites can crystallize from the residual melts of larger granitic plutons, or from low-degree partial melting of metasedimentary rocks during high-grade metamorphism (anatexis), where Li mobilizes from the host rock into melts that are emplaced at structurally higher levels. Lithium-rich granite–pegmatites can host a variety of magmatic (e.g., pegmatite) to hydrothermal (e.g., greisen, vein) deposit types containing Li minerals such as spodumene, petalite, eucryptite, amblygonite, lepidolite and zinnwaldite, and are also commonly rich in a range of other rare metals of economic importance (e.g., Be, Cs, Nb, Si, Sn, Ta). Lithium-rich granite–pegmatites have gained notable interest in the past decade due to the demand for battery-grade lithium for the electric vehicle (EV) market and the ‘green transition’. As a result, commercial exploration for Li-rich granite–pegmatite deposits has dramatically increased, and innovation in exploration techniques for targeting such deposit types has also increased. A better understanding of granite–pegmatite systems and further refinement of exploration tools, especially in areas of transported overburden, will be needed to keep pace with the market demand for Li and accompanying rare metals.

The aim of this Special Issue is to spotlight studies on the geochemical and petrological attributes of Li-rich granite–pegmatite systems and their exploration. We look forward to receiving your contributions.

Dr. William Keyser
Dr. Benedikt Steiner
Dr. Benjamin Hines
Guest Editors

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Keywords

  • granite and pegmatite
  • lithium-cesium-tantalum (LCT)
  • residual melts
  • highly evolved peraluminous silicic melts
  • high-grade metamorphism
  • anatexis
  • greisen alteration
  • spodumene–petalite–lepidolite–zinnwaldite
  • incompatible elements
  • rare metal exploration

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Published Papers (2 papers)

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Research

39 pages, 47748 KB  
Article
Lithium Replenishment by Percolative Reactive Fluid Flow During Crystallization of Poorly Zoned Spodumene Pegmatites: An Example from the Leinster Pegmatite Belt, SE Ireland
by Louis R. G. Penfound-Marks, Ben J. Williamson and Julian F. Menuge
Minerals 2026, 16(5), 467; https://doi.org/10.3390/min16050467 - 29 Apr 2026
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Abstract
The critical metal lithium (Li) is increasingly sourced from spodumene and petalite pegmatite deposits due to their relatively high grades, lower mining environmental impacts and widespread global distribution. However, there are numerous gaps in our understanding of their genesis and the formation of [...] Read more.
The critical metal lithium (Li) is increasingly sourced from spodumene and petalite pegmatite deposits due to their relatively high grades, lower mining environmental impacts and widespread global distribution. However, there are numerous gaps in our understanding of their genesis and the formation of unzoned or poorly zoned Li pegmatites is particularly difficult to explain. To investigate this, both spodumene-bearing and non-mineralized pegmatites and aplites are studied in the Moylisha segment of the Leinster pegmatite belt of SE Ireland, which were emplaced within the East Carlow Deformation Zone (ECDZ). Trace element modeling suggests that granite melts can achieve Li concentrations high enough (~5000 ppm) to crystallize spodumene. However, once crystallization begins, Li levels will drop rapidly below this threshold. While Li could be replenished by incoming melts, there is no supporting textural evidence for this, such as internal magmatic contacts, crosscutting relationships, or mingling. We test the hypothesis that low viscosity, Li-rich fluids from underlying reservoirs, most likely almost fully crystallized granite magmas or mush, continuously migrate through the heterogeneously crystallizing pegmatite-forming melts by percolative reactive flow, refertilizing interstitial melt by diffusion under favorable geochemical gradients. The flow of fluids is likely maintained due to their low relative density and periodic shearing within the ECDZ. Fluids with >10,000 ppm Li, derived by >95% crystallization (Rayleigh fractionation) of a granite magma, are shown to be capable of refertilizing a pegmatitic crystal mush after its emplacement. Supporting evidence includes macro- and micro-textures indicative of paragenetically late spodumene crystallization along apparent fluid flow pathways in mineralized pegmatites and aplites. Similar features are common in spodumene pegmatites worldwide and suggest that Li upgrading by fluid flow through crystallizing spodumene pegmatites may be a key process in enhancing Li grades and in some cases in producing economically favored low-Fe spodumene. Full article
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18 pages, 4008 KB  
Article
Micro-XRF-Based Quantitative Mineralogy of the Beauvoir Li Granite: A Tool for Facies Characterization and Ore Processing Optimization
by Zia Steven Kahou, Michel Cathelineau, Wilédio Marc-Emile Bonzi, Lise Salsi and Patrick Fullenwarth
Minerals 2026, 16(1), 29; https://doi.org/10.3390/min16010029 - 26 Dec 2025
Cited by 2 | Viewed by 781
Abstract
Quantitative mineralogy plays a vital role in exploration geology by defining mineral assemblages, identifying metal-bearing phases, and providing clues to optimize ore processing. In peraluminous rare-metal granites such as those at Beauvoir (France), mineral quantification is challenging, especially in altered facies where partial [...] Read more.
Quantitative mineralogy plays a vital role in exploration geology by defining mineral assemblages, identifying metal-bearing phases, and providing clues to optimize ore processing. In peraluminous rare-metal granites such as those at Beauvoir (France), mineral quantification is challenging, especially in altered facies where partial replacement complicates the estimation of muscovite and feldspars. The present study applies micro-X-ray fluorescence (micro-XRF) to quantify mineral assemblages of the Beauvoir granite. Modal abundances were compared with normative proportions derived from whole-rock geochemistry. In fresh facies with Li contents between 4000 and 6000 ppm, albite and quartz dominate (~40% and 25%), respectively, while lepidolite averages 20%–25%. During alteration to greisen, feldspars and lepidolite are partly replaced by muscovite, reducing lepidolite by up to threefold and increasing muscovite to ~30%. The obtained results demonstrate that micro-XRF provides a fast and reliable method for quantifying mineral distributions in rare-metal granites. Combined with complementary microscale techniques, quantitative mineralogy offers a powerful approach to characterize Li-bearing granites, assess alteration intensity, and improve predictions of ore quality and processability. Full article
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