Structure, Magnetic and Thermal Properties of Nanocrystalline Materials

A special issue of Magnetochemistry (ISSN 2312-7481).

Deadline for manuscript submissions: 30 October 2025 | Viewed by 309

Special Issue Editors


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Guest Editor
Département de Physique, Faculté des Sciences, Université Badji Mokhtar-Annaba, B.P. 12, Annaba 23000, Algerie
Interests: nanocrystalline materials; mechanical alloying; self laser melting; electrodeposition; magnetocaloric effect; XRD; rietveld refinement; magnetic properties; thermal analysis; mössbauer spectrometry

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Department of Physics, Campus Montilivi s/n, University of Girona, 17003 Girona, Spain
Interests: powder metallurgy; structural analysis; thermal analysis; mechanical alloying; nanocrystalline
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Special Issue Information

Dear Colleagues,

Nanocrystalline materials have functional properties, such as magnetic properties, that depend largely on their structure. In this special issue, experimental, theoretical or review articles in which nanocrystalline materials are produced and analyzed are welcome. Studies of the structure at macroscopic, micro or nanostructural level, as well as crystallographic defects are appreciated. Studies on thermal stability or mechanical properties are also welcome. Regarding magnetism, the behavior can be ferromagnetic (soft or hard); paramagnetic; ferrimagnetic and so on. Among the manufacturing techniques, in addition to traditional ones, nanocrystalline alloys are being produced using additive manufacturing techniques. In addition to theoretical or simulation studies, work using big data is also expected.

Prof. Dr. Safia Alleg
Prof. Dr. Joan-Josep Suñol
Guest Editors

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Keywords

  • nanocrystalline
  • structure
  • microstructure
  • nanostructure
  • thermal analysis
  • magnetic behavior
  • production
  • simulation

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Published Papers (1 paper)

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Research

25 pages, 5300 KiB  
Article
Microstructural, Mechanical, Thermal, and Magnetic Properties of the Mechanically Alloyed and Consolidated Al–16 wt. % Mn–7 wt. % Cu Alloy
by Ahlem Saad Bekhouche, Safia Alleg, Abdelaziz Bouasla, Hacene Hachache and Joan José Sunol
Magnetochemistry 2025, 11(7), 59; https://doi.org/10.3390/magnetochemistry11070059 - 11 Jul 2025
Abstract
The effect of severe plastic deformation during milling and conventional and Spark Plasma Sintering (SPS) on the wt. % microstructural, structural, thermal, magnetic, and mechanical properties of the Al–16 wt. % Mn–7 wt. % Cu alloy was studied. A milling process for up [...] Read more.
The effect of severe plastic deformation during milling and conventional and Spark Plasma Sintering (SPS) on the wt. % microstructural, structural, thermal, magnetic, and mechanical properties of the Al–16 wt. % Mn–7 wt. % Cu alloy was studied. A milling process for up to 24 h (A24) leads to microstructure refinement and the presence of Al, Mn, and Cu solid solutions. The energy dispersive spectroscopy (EDS) analysis reveals the existence of Cu–Al, Mn–Al, and Al–Mn enriched particles. The powders exhibit weak ferromagnetism and an exchange bias (EB) behaviour that decreases with increasing milling time. The Ms values fitted using the law of approach to saturation (LAS) are comparable to the experimental values. The exothermic and endothermic peaks that appear in the differential scanning calorimetry (DSC) scans in the 500–900 °C range on heating/cooling are related to different phase transformations. The crystal structure of the A24 powders heated up to 900 °C (A24_900 °C) consists of a dual-phase microstructure of Al20Cu2Mn3 nanoprecipitates (~28%) and Al matrix (~72%). The sintering of the A24 powders at 500 °C for one hour (A24S) leads to the precipitation of Al6Mn, Al2Cu, and the Al20Cu2Mn3 T-phase into the Al-enriched matrix. In contrast, the consolidation by SPS (A24SPS) leads to a mixture of an Al solid solution, Al6Mn, T-phase, and α-Mn with an increased weight fraction of the T-phase and Al6Mn. The sintered samples exhibit the coexistence of a significant PM/AFM contribution to the M-H curves, with increasing Hc and decreasing EB. A higher microhardness value of about 581 HV is achieved for the A24SPS sample compared to those of the A24 (68 HV) and A24S (80 HV) samples. Full article
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