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Chemistry, Volume 7, Issue 2

April 2025 - 38 articles

Cover Story: Quinoidal structures contain a diradical character and possess characteristic electronic properties, including multiple redox systems and absorption bands in visible and near-infrared regions. Consequently, quinoids are significant structural motifs in organic materials, and considerable efforts have been made to develop synthetic methods for quinoid compounds. Dearomative cycloaddition is an effective approach for constructing quinoid compounds from readily available aromatic compounds. Herein, we report a photochemical dearomative cycloaddition of corannulene with an isolable dialkylsilylene (silicon analogue of carbene) to furnish a π-expanded o-quinodimethane derivative. We discuss the structure, electronic properties, and reactions of the product. View this paper
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Articles (38)

  • Article
  • Open Access
2 Citations
1,583 Views
11 Pages

Foam quality is an important index for judging the quality of beer. In this experiment, the interaction between PZ and iso-α-acid extracted from hops and its effect on beer foam production were investigated. According to the results of fluoresc...

  • Article
  • Open Access
1 Citations
1,279 Views
14 Pages

Dynamical Resolution of QM/MM Near-UV Circular Dichroism Spectra of Low-Symmetry Systems

  • Jérémy Morere,
  • Tanguy Leyder,
  • Catherine Michaux,
  • Claude Millot,
  • Emmanuelle Bignon and
  • Thibaud Etienne

Near-UV circular dichroism (CD) spectroscopy is a widely used method that provides, among others, information about the tertiary structure of biomolecular systems such as proteins, RNA, or DNA. Experimental near-UV CD spectra of proteins reflect the...

  • Article
  • Open Access
2 Citations
3,903 Views
18 Pages

To ensure high-quality honey, and to delay crystallization or fermentation, honey is subjected to heat treatment. The heating process, as well as the duration and storage conditions, can lead to an increased level of 5-HMF (5-hydroxymethylfurfural),...

  • Article
  • Open Access
4 Citations
1,177 Views
10 Pages

Remarkably Efficient [4+4] Dimerization of [n]-Cyclacenes

  • Ankit Somani,
  • Divanshu Gupta and
  • Holger F. Bettinger

Cyclacenes with the general formula C4nH2n are cyclic analogs of acenes. Acenes are well-known for their high reactivity, which increases with the number of fused benzene rings. The cyclic strain, absence of a Clar sextet, and diradical or polyradica...

  • Review
  • Open Access
19 Citations
9,788 Views
39 Pages

Types of Crosslinkers and Their Applications in Biomaterials and Biomembranes

  • Paolo Yammine,
  • Ali El Safadi,
  • Rima Kassab,
  • Hanna El-Nakat,
  • Pierre J. Obeid,
  • Zeina Nasr,
  • Tony Tannous,
  • Nouha Sari-Chmayssem,
  • Agapy Mansour and
  • Ayman Chmayssem

Biomaterials and biomembranes play a crucial role in a variety of applications, particularly in the medical field due to their ability to mimic natural biological structures and functions. Crosslinkers play also an important role in enhancing the str...

  • Article
  • Open Access
2 Citations
1,808 Views
14 Pages

A plasma-assisted electrochemical deposition (PAECD) technology was introduced to coat a cast iron brake disc for the possible reduction of brake wear and brake wear particle (BWP) emission. The majority of the coating consisted of alumina (Al2O3), d...

  • Article
  • Open Access
1,849 Views
9 Pages

Beyond L-Proline: Investigation into the Catalytic Properties of Other Natural Amino Acids in an Organocatalytic Warfarin Synthesis

  • Anna I. Wurz,
  • Arhemy Franco-Gonzalez,
  • Naomi R. Benson,
  • Hope L. Jankowski,
  • Sierra N. Carr,
  • Ketan Chamakura,
  • Lizbeth Chirinos,
  • Sydney P. Coll,
  • Kayla F. Ivory and
  • Trinity J. Lamb
  • + 11 authors

Proline is considered the model organocatalytic amino acid. However, other naturally occurring amino acids remain a potent and perhaps overlooked source of organocatalytic potential. In this work, we investigated the capacity of various natural amino...

  • Article
  • Open Access
1 Citations
1,417 Views
15 Pages

This study presents a comprehensive analysis of the chemical composition and bioactive properties of six newly cultivated varieties of pigmented and non-pigmented rice: Neunkeunheukchal (NKH), Neunkeunssal, Heukjagwang 709 (H709), Heukjagwang 1601, H...

  • Article
  • Open Access
1 Citations
1,824 Views
24 Pages

Complexation of Lanthanides(III) Ions with Terephthalic Acid in Aqueous Solutions by Potentiometric Titration Combined with Photoluminescence Spectroscopy

  • Polina B. Guseva,
  • Alexander R. Badikov,
  • Oleg S. Butorlin,
  • Yulia N. Toikka,
  • Sergey N. Orlov,
  • Mikhail N. Ryazantsev,
  • Nikita A. Bogachev,
  • Mikhail Yu. Skripkin and
  • Andrey S. Mereshchenko

The complexation behavior of lanthanide(III) ions with terephthalic acid (1,4-benzene-dicarboxylic acid) in 0.01 M KNO3 aqueous solutions was studied across a broad pH range and at two metal-to-ligand ratios using potentiometric titration combined wi...

  • Article
  • Open Access
1,113 Views
10 Pages

The electronic and phonon bands of Skaergaardite are investigated using density functional theory (DFT) as implemented in Quantum ESPRESSO. Skaergaardite is a copper palladium mineral (CuPd) found in the Skaergaard intrusion with a CsCl-type (B2) str...

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Chemistry - ISSN 2624-8549