Abstract
We present a brief review of a nontraditional but significant application for a high-temperature charged plasma. The unorthodox proposition was made by Barry Ninham concerning a contribution from Casimir forces across high-temperature electron–positron plasma in nuclear interactions. The key message in this review is that high temperatures (about K) are found to be essential. Certainly, classical, semi-classical, and quantum considerations for the background media impact both the Casimir effect and the physics of stars and the Universe.
1. Introduction
In the years following Casimir’s findings [1,2], quantum vacuum fluctuation-induced forces have been investigated thoroughly, both theoretically and experimentally. Vacuum and thermal fluctuations of the quantized field around a molecule or between surfaces differ from free space, resulting in attractive or repulsive intermolecular interactions. A valid concept of the nature of molecular forces was first put forward in 1894 by Peter (Pyotr) Lebedev [3,4]. In Ref. [4], the following is stated about Lebedev’s consideration: “In Hertz’s researches, in his interpretation of light oscillations as electromagnetic processes, there lies another problem which has hitherto not been considered, the problem of the sources of radiation, of the processes which take place in a molecular vibrator when it radiates light energy into space.” Meanwhile, Lebedev [3] stated the following: “This problem takes us, on the one hand, into the field of spectral analysis and, on the other, quite unexpectedly, into the theory of molecular forces, one of the most complicated problems of modern physics. This follows from the following considerations. From the standpoint of the electromagnetic theory of light, it must be admitted that between two light-emitting molecules, as between two vibrators in which electromagnetic oscillations arise, there exist mechanical forces, caused by the electrodynamic interaction of the alternating electric currents in the molecules (according to Ampere’s law), or of the alternating charges in them (according to Coulomb’s law). We must therefore admit that in this case there exist intermolecular forces whose origin is closely connected with radiation processes.” Surface force measurements [5,6,7,8,9] and theoretical advancement of the Lifshitz formula [10,11,12,13] of interaction energy (resulting from vacuum fluctuation of a quantized field) expanded to encompass magnetic [14] and conductive particles [15,16], as well as liquids between dissimilar surfaces. In the 1970s, Barry Ninham and collaborators at the Australian National University initiated these developments. The development and practical implementation of the theory of intermolecular forces, and its experimental verification, even reportedly led three of the main contributors to be short-listed for a Nobel Prize in chemistry. Actually, recently, a considerable amount of both novel and less novel studies have been conducted on modeling Casimir, Lifshitz, and van der Waals forces [17,18,19,20,21,22]. A thorough discussion on this was presented by Bo Sernelius [23]. Theories of intermolecular dispersion forces have been investigated so extensively that relatively little remains to be addressed. However, even lately, new applications are arising. Here, we review how the temperatures relevant for stellar physics may, indeed, be in the same range as those predicted for Casimir–Yukawa forces between a pair of neutrons in an atomic nucleus. A recent series of papers published by Ninham and his colleagues [24,25,26] proposed an impact from high-temperature plasma on the Casimir forces across intervening electron–positron plasma during nuclear interactions. Certainly, classical, semi-classical, and quantum considerations for the background media may impact the Casimir effect at the nuclear scale [27,28,29] and in the physics of stars and the Universe.
2. High-Temperature Electron–Positron Plasma and Casimir–Yukawa Forces
2.1. Can Meson Physics Be Linked to Casimir Theory?
In this Section, we address Casimir forces between particles in the presence of background plasma. We focus on the predicted temperatures relevant for the fundamental quantum electrodynamics of nuclear interactions. In our model we assume that the interactions among nuclear particles occur inside plasma composed of fluctuating, continuously created and destroyed electron–positron pairs. Nuclear particle interactions are generally described as having a screened Yukawa potential [30]. Ninham and the author of this paper [24] employed an approximation to compare the screened Casimir potential with the absolute asymptotic expression of this potential across the electron–positron plasma between surfaces. Significant similarities were observed that suggested a potential contribution of screened quantum vacuum interaction between the surfaces to the interactions between the nuclear particles. Refs. [24,25,26] Ninham and collaborators proposed estimating two nucleons as a pair of reflecting spheres approximated by two perfectly conducting plates with nucleon cross-sectional areas. The zero-temperature Casimir interaction energy and force are [1]
respectively.
Here, d is the surface separation distance between two protons, ħ is the reduced Planck constant, and c is the speed of light. The estimated surface area is , where r is the radius of the proton and taken to be 0.8 fm. The surface-to-surface distance between two nucleons is estimated to be 1 fermi. The binding energy between two nucleons, resulting from vacuum fluctuations of the quantized field, is around 5 Mev. The binding energies per nucleon typically range from 1.1 MeV to 8.8 MeV. This result was already known in the early 1970s and discussed in an unpublished manuscript by Ninham and Colin Pask (recently accepted for publication in a historical journal [31]). The problem is somewhat similar in spirit to some ideas by Hendrik Casimir for the stability of charged electrons [32,33]. Repulsive forces arise between several surface areas due to the distribution of negative charges on the surface of the electron. An attractive force has to balance this repulsive force in order to keep the electron stable and give it a finite size. Casimir proposed that zero-point energy from vacuum fluctuations of a quantized field may generate the attractive force known as Poincaré stress. Inspired by this consideration, various calculations of Casimir energy have been reported, all of which conclude that the magnitude of the interaction is right but with the incorrect sign. It gives a further repulsive force [33]. Ninham and the author of this paper demonstrated almost two decades ago that screened Casimir interactions may contribute to nuclear interactions [24]. Interestingly, when a nonrelativistic plasma is investigated, the relativistic energy , with m the particle mass, appears in the interaction energy in a curious way: it replaces the temperature. In a high-temperature K) system, the strength of interactions or fluctuations often depends on , with the Boltzmann constant. In the plasma model, the same dependence arises, but with appearing in the same place—as if the “energy scale” controlling the interaction were set by the particle’s rest energy rather than the thermal energy [25,29]. This shows that intriguing physics might not be apparent in the issue, emphasizing the importance of including a relativistic mass from the start.
2.2. The Casimir Interaction Energy Between Perfectly Reflecting Surfaces Across a Charged Plasma
As proposed by Lebedev [3,4], the origin of the Casimir interaction between metal surfaces (via fluctuations in the electromagnetic modes) is closely connected with radiation processes. The full formalism of quantum electrodynamics, including the formidable theory for intermolecular forces from Evgeny Lifshitz and collaborators [10], is rather complicated. The impact of the semi-classical theory [12], is largely due to the feature that much of the quantum electrodynamics (QED) formalism can be obtained using Maxwell’s equations by imposing proper boundary conditions when attributing to each quantized electromagnetic mode with its zero-temperature ground-state energy and the free energy at finite temperature. This point was pioneered, and explored, by Ninham and V. Adrian Parsegian, with colleagues [12].
For two identical planar objects in a medium, corresponding to the geometrical configuration 1|2|1, the reflection coefficients for transverse magnetic (TM) and transverse electric (TE) modes corresponding to a wave incident from medium-1 onto the interface with medium-2 are [23]
and
respectively. In Equations (2) and (3), are defined as
where is the dielectric function corresponding to the medium i and denotes the wave frequency.
The Casimir–Lifshitz energy between two identical planar surfaces interacting through a medium can be represented as [10,12,23]
Note that the interaction energy (5) represents the internal energy at zero temperature. This interaction energy at finite temperature is given as [10,12]
where the prime denotes that the interaction energy for must be halved. In Equation (5), frequency is replaced by discrete Matsubara frequencies
and the corresponding integral is replaced by a summation [10,12]. Ninham and Pask observed that the Casimir interaction at zero temperature, arising from vacuum fluctuation of the quantized field, is sufficient to provide the binding energy of nucleons within a nucleus [31]. Ninham and collaborators then considered the effects of temperature [10,12,24,25,26]:
Using Equation (8), in the absence of plasma between two planner surfaces, Ninham and John Daicic explicitly derived interaction energy [34] (see also [24,25,26]):
where is the Euler–Riemann zeta function.
Note that Equations (8) and (9) are derived for the case of two perfectly conducting (reflecting) planes (, ) with a vacuum (i.e., absence of plasma) between the plates. The above equation describes the high-temperature limit of the free energy in the case where no plasma is present between the planes. It is worth to note that the first term in Equation (9) represents the attractive Casimir energy at zero temperature. The third term represents the black body radiation energy (in a vacuum and at equilibrium) between the plates. This result contradicts the attractive Casimir interaction energy term reported in Ref. [24]. Following previous study [24] we assume that the first and third terms are equal at equilibrium. From this one finds the temperature based on the separation distance d between the plates: , where the attractive force balance out repulsive forces. Notably, distances of 1–2 fm correspond to a temperature range of about – K. Curiously, this is in the same temperature range as predicted, with a completely different theory and entirely different underlying physics, for critical temperatures for Bose filled star interiors [35,36]. As previously identified in this Section, here, the second term in Equation (9) is the chemical potential term associated with the Gibbs free energy. This can be identified based on the existence of electron–positron pair plasma, formed by the photon-mediated process [37] in the gap. Using the temperature at separation distance d, one can obtain the electron–positron pair density in the plasma. As discussed in the monograph [37], the numbers of electrons and positrons in this plasma are nearly equal and both numbers are exceptionally large even at temperatures in the order of . At higher densities, the electron–positron plasma behaves rather like an ideal gas, allowing ideal gas equations to be used while ignoring interparticle interactions. The second term in Equaition (9) can be analyzed further using the given density of electron–positron plasma [37]:
where with and denoting the densities of electrons and positrons, respectively. This way of expressing the chemical potential term leads to the equivalence which is looked for.
For two perfectly reflecting planes (, ), the vacuum fluctuation energy (6) across a dissipation-free plasma reads (inserting the dielectric function for electron–positron plasma, , into ):
where with denoting the plasma frequency. The zero-frequency term in the Matsubara sum takse the alternative form [24,25,34]
The derivation of an asymptotic Casimir interaction across a plasma was a nontrivial task carried out more than twenty five years ago by Ninham (for preliminary studies, see [24,34]), and much later published as an Appendix in Ref. [25]. At fixed separation distance for sufficiently high temperatures or at fixed temperatures, except for K, and for sufficiently large separations, one finds a following expansion [25]:
where , . The vacuum fluctuation energy terms for both and exhibit behavior similar to that of the Yukawa potential [25,26]. Both terms contribute to the Casimir–Yukawa binding energy, remarkably aligning with the experimentally reported binding energy per nucleon [26]. An extension that took into account the magnetic permeability of an electron–positron pair was recently explored by the authors and colleagues [29].
Due to electromagnetic fluctuation interactions, the Casimir–Yukawa binding energy at this separation comprises a contribution of −0.9 MeV coming from the term, and −3.6 MeV coming from the terms, therefore producing a total binding energy of 4.5 MeV. As the separation between nucleons decreases, the binding energy increases, reflecting the variation in binding energies among different nuclei. This behavior aligns with the influences of the local environment on the internal structure of nucleons. The binding energy per nucleon changes between atomic nuclei, ranging from 1.1 MeV in deuterium to 8.8 MeV in nickel-62.
2.3. The Klein–Gordon Equation and Semi-Classical Estimates for the Meson Mass
As pointed out in Ref. [26], the vacuum fluctuation interaction energy associated with perfectly refelecting plates within plasma can be calculated using Maxwell’s equations [12,14], which, after a Fourier transform and exploiting the expression for the dielectric function for an electron–positron plasma, reduces to
Hideki Yukawa [30] proposed that the interaction between nuclear particles could be obtained from the Klein–Gordon equation, which has the solution of [30], where g is the gauge coupling constant of meson and fermion fields and is the scaling constant which relates to the mass of the exchanged meson. The Yukawa potential () is, after a Fourier transformation, given by
where is the mass of pion.
Gian Carlo Wick [38] proposed that mesons operate through the emission and absorption of virtual excitations, with the time taken for the excitation to traverse between a pair of nucleons being measured from , where charactrises the range of the nuclear force in the theory. The relativistic energy, (which adheres to the Heisenberg uncertainty principle for energy and time [39]), gives the relationship . From Equations (14) and (15), one identifies . From this, one can find meson mass as follows:
where is the mass of electron.
From Equation (16), one finds the plasma frequency in terms of the electron density and mass as follows: . Then, the meson mass has been estimated to be [26], which is in agreement with the experimentally reported value of 264.
2.4. Lifetime of Plasmons and Mesons
In the consideration in Section 2.2 above, we assumed that the zero-point vacuum energy and the black body radiation energy completely cancel each other at equilibrium. The remaining entities are collective excitations, specifically plasmons inside the residual electron–positron plasma. These plasmons were recognized as neutral pions. Subsequently, we estimated the lifetime of a semi-classical analogue to the meson [26]. In this lifetime, a plasmon decays into two electron–positron pairs. These can undergo decay to provide two photons. The expansion of the plasmon peak and its duration are both theoretically established and empirically assessed [40]:
In Equation (17), the Fermi energy is represented by , the plasma frequency by , the Fermi wavevector by , and denotes the plasmon vawe vector. Note that , and , all have explicit dependence on density, and in our current study, these quantities have been shown to be dependent on the separation distance between the nucleons. According to Ninham [31], it is possible to, without further approximations, relate the wave vector with the electron and positron densities. However, after failing to find such a relation, to obtain the lifetime of the plasmon, Ninham and colleagues employed [26] an estimate inspired by Wick’s arguments [38] discussed briefly in Section 2.3 above. Specifically, the reasoning to correlate the q-vector with energy was employed [26]. The relativistic energy associated with plasmon excitation (a meson of mass ), [26], is assumed to be partitioned into the kinetic energy of each particle in two electron–positron pairs. This results in an approximation for the plasmon wave vector: . The estimate yielded an identical numerical value (to the first decimal place) as the “naive” (Weinberg’s term [41]) quantum field theory (QFT) approximation for the uncharged pion lifetime. Both our findings for the lifetime and the “naive” estimate exhibit the same order of magnitude (about s). This can be compared with the QFT result (about 0.80– s), which matches with the experimentally obtained result of about s [26].
3. Future Outlooks
We observed that advancing this field requires the extension of these concepts of nuclear interactions to incorporate a relativistic plasma response function and magnetic (spin) susceptibilities [29]. If the arguments supporting the contribution of vacuum fluctuation interactions to nuclear and meson physics—as in Refs. [24,25,26], which partially relate nuclear and electromagnetic interactions—are considered valid, it suggests that decomposition of nuclear forces into Coulomb and nuclear contributions may require revision. The issue appears to hold equal significance to that encountered in physical chemistry. The established theories are predicated on the assumption that electrostatic forces, analyzed via a nonlinear framework, and electrodynamic forces, examined using the linear approximation of Lifshitz theory, are distinct and separate. The ansatz contravenes both the Gibbs adsorption equation and the gauge requirement pertaining to the electromagnetic field [42]. In future research, a model assumption to be that the charged and mesons emerge as bound states of electron–plasmon and positron–plasmon.
4. Discussion: Critical Temperatures in Casimir–Yukawa Theory
In this mini-review, we discuss predicted critical temperatures based on the nucleon–nucleon Casimir–Yukawa contribution to nuclear binding energy, lifetime, and meson mass [26]. Remarkably, Casimir forces act between protons and neutrons on the nuclear scale [27,28,29]. Notably, the temperatures related to the creation of an electron–positron plasma in Casimir–Yukawa semi-classical theory for nuclear interactions are found to be of the same order of magnitude as the estimated critical temperatures for the creation of a charged Bose–Einstein stellar core. We observed that this temperature impacts meson mass and the Casimir–Yukawa potential contribution to the nuclear binding energy. In the considered theories, it has to be stressed that density, energy, and temperature are closely linked. This is similar to the appealing observation by Wick [38] that meson mass is related to the relevant distances via an uncertainty principle.
5. Final Remarks
The current understanding [43] of nuclear and particle physics apparently indicates—for instance, via detailed first-principle-lattice quantum chromodynamics (QCD) simuations—that the essential features of nuclear forces arise from the quark and gluon degrees of freedom described by QCD. The long-range behavior of the nuclear force may to be consistent with the pion-exchange potential [43]. Since lattice QCD simulations often neglect QED interactions, it has generally been assumed that electrons, positrons, and photons are not required to describe the main features of nuclear forces at the energy scale of pion exchange. Therefore, the model first presented by Ninham and one of the authors of this review, ref. [24] has been considered somewhat speculative. However, there is certainly enough energy from Casimir forces available to account for nucleon interactions. And, if it does not give a contribution to the canonical theory, where has that energy gone? There is more to this point: it is known that nuclear particles, both protons and neutrons, are polarizable particles [44,45,46,47]. It has even been shown that this polarizability can impact trajectories of nuclear particles in the vicinity of other nuclear particles [48].
To conclude, it is of historical interest that applications of the electrodynamical Casimir effect within nuclear physics have been proposed in the past. One can, for instance, recall the MIT (Massachusetts Institute of Technology) quark bag model, which shows that zero-point fluctuations for gluons and quarks could generate zero-point energy for quarks. This serves as a phenomenological framework for fitting experimental data. A recognized review in this field is that of Peter Hasenfratz and Julius Kuti [49]. Similar work was carried out by Iver Brevik in 1986 [50]. There are always roads to discovery for those who dare to challenge known and established research.
Author Contributions
All authors contributed equally to this mini-review article. All authors have read and agreed to the published version of the manuscript.
Funding
This research is part of project No. 2022/47/P/ST3/01236 co-funded by the National Science Centre and the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant (Agreement No. 945339). Institutional and infrastructural support for the ENSEMBLE3 Centre of Excellence was provided through the ENSEMBLE3 project (MAB/2020/14), delivered within the Foundation for Polish Science International Research Agenda Programme and co-financed by the European Regional Development Fund and the Horizon 2020 Teaming for Excellence initiative (Grant Agreement No. 857543), as well as the Ministry of Education and Science initiative “Support for Centres of Excellence in Poland under Horizon 2020” (MEiN/2023/DIR/3797).
Data Availability Statement
There were no numerical data used or generated in the current article.
Acknowledgments
We dedicate this work to Barry W. Ninham ahead of his 90th birthday.
Conflicts of Interest
The authors declare no conflicts of interest.
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