2018 September - 13 articles
A three-dimensional cyanide-bridged coordination polymer based on FeII (S = 2) and NbIV (S = 1/2) {[FeII(H2O)2]2[NbIV(CN)8]·4H2O}n (Fe2Nb) was modified at the self-assembly stage by inserting an additional formate HCOO− bridge into its c...
Magnetoelectrolysis (electrolysis in magnetic fields) has potential to produce chiral surfaces on metal films. The Lorentz force causes two types of magnetohydrodynamic (MHD) flows; a vertical MHD flow and micro-MHD vortices, and the combination of t...
The complexes [Ln2(hfac)6(L)]·nC6H14 (Ln = Dy (1) n = 0, Yb (2) n = 1) with the L chiral 3,14-di-(2-pyridyl)-4,13-diaza[6]helicene ligand (hfac− = 1,1,1,5,5,5-hexafluoroacetylacetonate) have been synthesized in their racemic form and str...
The synthesis, crystal structure and magnetic properties of the coordination polymers of formula [EDAP{Li6(H2O)8[(Cu2(μ-mpba)2)2(H2O)2]}]n (1) and [(EDAP)2{K(H2O)4[Cu2(μ-mpba)2(H2O)2]}Cl·2H2O]n (2), in which mpba = N,N′-1,3-phenyle...
This study describes the first example of a hybrid material comprising corrole- and silica-coated magnetite nanoparticles. Firstly, cuboid and spheroid magnetite nanoparticles were prepared using a simple hydrothermal route, followed by a silica coat...
Magneto-electrochemistry (MEC) is a unique paradigm in science, where electrochemical experiments are carried out as a function of an applied magnetic field, creating a new horizon of potential scientific interest and technological applications. Over...
Magneto-optic surface plasmon resonance (MOSPR)-based sensors are highly attractive as next-generation biosensors. However, these sensors suffer from oxidation leading to degradation of performance, reproducibility of the sensor surface, because of t...
The synthesis, structures and magnetic properties of a new trinuclear spin crossover complex [FeII3(pyrtrz)6(TsO)6]·10H2O·2CH3OH (C2) and its analogue binuclear [FeII2(pyrtrz)5(SCN)4]·7H2O (C1), are reported here. These two compo...
Nuclear magnetic resonance relaxation dispersion (rd) experiments provide kinetics and thermodynamics information of molecules undergoing conformational exchange. Rd experiments often use a Carr-Purcell-Meiboom-Gill (CPMG) pulse train equally separat...
17β-Hydroxysteroid dehydrogenase type 10 (17β-HSD10) is a steroidogenesis enzyme known for its potential role in Alzheimer’s disease. For comparison purposes between steroidal and nonsteroidal 17β-HSD10 inhibitors 1 and 2, respec...
Machine learning is gaining popularity in the commercial world, but its benefits are yet to be well-utilised by many in the microfluidics community. There is immense potential in bridging the gap between applied engineering and artificial intelligenc...
Solid-state nuclear magnetic resonance (NMR) spectroscopy provides significant structural information regarding the conformation and dynamics of a variety of solid samples. In this study, we recorded the 13C and 15N solid-state NMR spectra of a self-...
Two isostructural lanthanide amino-phosphonate complexes [Ln10(μ3-OH)3(µ-OH)(CO3)2(O2CtBu)15(O3PC6H10NH2)3(O3PC6H10NH3)2(H2O)2][Et2NH2] (Ln = Gd(III), 1 and Tb(III), 2) have been obtained through reflux reactions of lanthanide pivalates with...
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