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Magneto-Optic Surface Plasmon Resonance Ti/Au/Co/Au/Pc Configuration and Sensitivity

by Conrad Rizal 1,2
1
Department of Electrical Engineering & Computer Science, York University, Toronto, ON M3J 1P3, Canada
2
GEM Systems Inc., Markham, ON L3R 5H6, Canada
Magnetochemistry 2018, 4(3), 35; https://doi.org/10.3390/magnetochemistry4030035
Received: 17 June 2018 / Revised: 10 August 2018 / Accepted: 13 August 2018 / Published: 17 August 2018
Magneto-optic surface plasmon resonance (MOSPR)-based sensors are highly attractive as next-generation biosensors. However, these sensors suffer from oxidation leading to degradation of performance, reproducibility of the sensor surface, because of the difficulty of removing adsorbed materials, and degradation of the sensor surface during surface cleaning and these limit their applications. In this paper, I propose MOSPR-based biosensors with 0 to 15 nm thick inert polycarbonate laminate plastic as a protective layer and theoretically demonstrate the practicability of my approach in water-medium for three different probing samples: ethanol, propanol, and pentanol. I also investigate microstructure and magnetic properties. The chemical composition and layered information of the sensor are investigated using X-ray reflectivity and X-ray diffraction analyses and these show distinct face-centered-cubic (fcc)-Au (111) phases, as dominated by the higher density of conduction electrons in Au as compared to Co. The magnetic characterization measured with the in-plane magnetic field to the sensor surface for both the as-deposited and annealed multilayers showed isotropic easy axis magnetization parallel to the multilayer interface at a saturating magnetic field of <100 Oersted (Oe). The sensor showed a maximum sensitivity of 5.5 × 104%/RIU (refractive index unit) for water–ethanol media and the highest detection level of 2.5 × 10−6 for water-pentanol media as the protective layer is increased from 0 to 15 nm. View Full-Text
Keywords: Ti/Au/Co/Au; X-ray diffraction; SPR; MOSPR; sensitivity; polycarbonate plastics; protective layer Ti/Au/Co/Au; X-ray diffraction; SPR; MOSPR; sensitivity; polycarbonate plastics; protective layer
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MDPI and ACS Style

Rizal, C. Magneto-Optic Surface Plasmon Resonance Ti/Au/Co/Au/Pc Configuration and Sensitivity. Magnetochemistry 2018, 4, 35.

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