Skip to Content
You are currently on the new version of our website. Access the old version .
MDPIMDPI
Magnetochemistry
Submit to Magnetochemistry

Magnetochemistry, Volume 4, Issue 2

2018 June - 10 articles

Cover Story: The synthesis and characterization by single-crystal X-ray diffraction of three new dinuclear copper(II) complexes—[Cu2(μ–HLn)2(μ-Cl)2Cl2]Cl2, where HLn is as follows: HL1 = N6-propyladeninium, HL2 = N6-butyladeninium, and HL3 = N6-isobutyladeninium—is reported herein. The solid state architectures of all three structures exhibit relevant anion-π+ contacts between the aromatic portion of the positively charged adenine ring and the chloride counterions. In addition, experimental magnetic measurements in the 2–300 K temperature range indicate antiferromagnetic behaviour in all cases, in good agreement with the calculations. View the paper here.
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (10)

  • Article
  • Open Access
9 Citations
3,683 Views
16 Pages
Download PDF

Adjusting the Magnetic Properties of ZrO2:Mn Nanocrystals by Changing Hydrothermal Synthesis Conditions

  • Izabela Kuryliszyn-Kudelska,
  • Witold Dobrowolski,
  • Monika Arciszewska,
  • Artur Małolepszy,
  • Leszek Stobinski and
  • Roman Minikayev
Magnetochemistry2018, 4(2), 28;https://doi.org/10.3390/magnetochemistry4020028

13 June 2018

The aim of the present work was to study the magnetic properties of ZrO2(Mn) nanocrystals prepared by microwave-assisted hydrothermal synthesis using three different precursors: KMnO4, MnCl2, and Mn(NO3)2. The structural characterization was performe...

Full Article
  • Article
  • Open Access
11 Citations
4,695 Views
20 Pages
Download PDF

Theory of Electron Spin Resonance in Ferromagnetically Correlated Heavy Fermion Compounds

  • Pedro Schlottmann
Magnetochemistry2018, 4(2), 27;https://doi.org/10.3390/magnetochemistry4020027

12 June 2018

We studied the electron spin resonance (ESR) line width for localized moments within the framework of the Kondo lattice model. Only for a sufficiently small Kondo temperature can an ESR signal be observed for a Kondo impurity. On the other hand, for...

Full Article
  • Article
  • Open Access
1 Citations
4,344 Views
10 Pages
Download PDF

One-Dimensional Chain-Type Dicopper Coordination Polymer Linked by 1,4-Di(4-pyridyl)benzene; Synthesis, Crystal Structure, Magnetic Property, and Gas-Adsorption Property

  • Natsumi Yano,
  • Makoto Handa,
  • Minoru Mitsumi and
  • Yusuke Kataoka
Magnetochemistry2018, 4(2), 26;https://doi.org/10.3390/magnetochemistry4020026

11 June 2018

A one-dimensional chain-type dicopper(II) coordination polymer with 1,4-di(4-pyridyl)-benzene (dpybz), [Cu2(O2C-tBu)4(dpybz)] (1), is synthesized and characterized by single crystal X-ray diffraction, infrared spectroscopy, and CHN elemental analysis...

Full Article
  • Article
  • Open Access
7 Citations
4,963 Views
15 Pages
Download PDF

Efficient Stereospecific Hβ2/3 NMR Assignment Strategy for Mid-Size Proteins

  • Alexandra Born,
  • Morkos A. Henen,
  • Parker Nichols,
  • Jing Wang,
  • David N. Jones and
  • Beat Vögeli
Magnetochemistry2018, 4(2), 25;https://doi.org/10.3390/magnetochemistry4020025

1 June 2018

We present a strategy for stereospecific NMR assignment of Hβ2 and Hβ3 protons in mid-size proteins (~150 residues). For such proteins, resonance overlap in standard experiments is severe, thereby preventing unambiguous assignment of a larg...

Full Article
  • Article
  • Open Access
2 Citations
4,896 Views
13 Pages
Download PDF

Cu(II)–N6-Alkyladenine Complexes: Synthesis, X-ray Characterization and Magnetic Properties

  • María Soledad Martínez,
  • Antonio Bauzá,
  • Amparo Caubet,
  • Ángel García-Raso,
  • Ángel Terrón,
  • Juan J. Fiol,
  • Elies Molins,
  • Miquel Barceló-Oliver and
  • Antonio Frontera
Magnetochemistry2018, 4(2), 24;https://doi.org/10.3390/magnetochemistry4020024

23 May 2018

Three new dinuclear copper(II) complexes [Cu2(μ–HLn)2(μ-Cl)2Cl2]Cl2 (1–3) have been synthesized and structurally characterized by single-crystal X-ray diffraction, where HLx, (HL1 = N6-propyladeninium, HL2 = N6-butyladeninium and HL...

Full Article
  • Article
  • Open Access
4 Citations
5,071 Views
9 Pages
Download PDF

Magnetic Characterization of Chromium Intermediates in the Reduction of Chromium (VI) by Glutathione in Acidic Solutions

  • Roberto A. Marín,
  • Rathindra Bose,
  • Bogdan Dabrowski and
  • Stanislaw Kolesnik
Magnetochemistry2018, 4(2), 23;https://doi.org/10.3390/magnetochemistry4020023

17 May 2018

Chromium (VI) is carcinogenic through intermediates formed in the cellular milieu by reduction with small reductants like glutathione (GSH), ascorbate, cysteine, and NADPH. Although the reduction of chromate by thiols has been investigated, the parti...

Full Article
  • Article
  • Open Access
19 Citations
6,167 Views
16 Pages
Download PDF

Chain Compounds Based on Paddle-wheel Copper(II) Carboxylate Bearing Four Nitroxide Radicals

  • Masahiro Mikuriya,
  • Renny Indrawati,
  • Rieko Hashido,
  • Shizuka Matsubara,
  • Chizu Nakamura,
  • Daisuke Yoshioka,
  • Kazuyuki Yokota,
  • Masafumi Fukuzaki and
  • Makoto Handa
Magnetochemistry2018, 4(2), 22;https://doi.org/10.3390/magnetochemistry4020022

10 May 2018

Chain compounds of paddle-wheel Cu2-clusters of 3-carboxy-2,2,5,5-tetramethyl-1-pyrrolidinyloxy (Hcaproxy) and 4-carboxy-2,2,6,6-tetramethylpiperidinyloxy (Hcatempo) and N,N’-bidentate ligands (L = 4,4′-bipyridine (4,4′-bpy), 1,2-bi...

Full Article
  • Article
  • Open Access
2 Citations
4,500 Views
12 Pages
Download PDF

Synthesis, Structure and Magnetic and Electrochmical Properties of Tetrakis(benzamidato)diruthenium(II,III) Tetrafluoroborate

  • Makoto Handa,
  • Natsumi Yano,
  • Airi Okuno,
  • Hiroki Nakai,
  • Minoru Mitsumi,
  • Masahiro Mikuriya and
  • Yusuke Kataoka
Magnetochemistry2018, 4(2), 21;https://doi.org/10.3390/magnetochemistry4020021

1 May 2018

A lantern-type diruthenium(II,III) complex [Ru2(HNOCPh)4(BF4)(H2O)] was prepared from [Ru2(HNOCPh)4Cl]n by removal of the axial chlorido-bridge using AgBF4 in THF. The room temperature magnetic moment (per Ru25+ unit) of [Ru2(HNOCPh)4(BF4)(H2O)] is 3...

Full Article
  • Article
  • Open Access
4 Citations
4,589 Views
14 Pages
Download PDF

Microstructure, Martensitic Transformation, and Inverse Magnetocaloric Effect in Ni48Mn39.5Sn12.5−xAlx Metamagnetic Shape Memory Alloys

  • P. Czaja,
  • R. Wróblewski,
  • J. Grzonka,
  • J. Przewoźnik and
  • W. Maziarz
Magnetochemistry2018, 4(2), 19;https://doi.org/10.3390/magnetochemistry4020019

23 March 2018

The effect of Al substitution on microstructure, martensitic transformation and magnetocaloric properties in Ni48Mn39.5Sn12.5−xAlx (x = 0, 1, 2, 3) alloys is reported. At room temperature, depending on Al concentration, the alloys have typical Heusle...

Full Article

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Magnetochemistry - ISSN 2312-7481
Imprint
Download Flyer