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Membranes, Volume 10, Issue 4

2020 April - 24 articles

Cover Story: We prepared and characterized mixed-matrix membranes based on amorphous PPO and particles of the molecular sieve ZIF-8. The inclusion of ZIF-8 with loadings as high as 45 wt % led to a remarkable, up to eight-fold, increase in gas permeability and to a significant decrease in the activation energy of diffusion and permeation. The ideal He/CO2 selectivity also increased, albeit to a lower extent, reaching a maximum at a filler loading of 35 wt %. The additive behavior observed in density measurements and the morphological analysis of the composite films indicate good adhesion between the two phases. The use of commercial materials enables the possibility of scaling-up the technology, and the results encourage applications at high temperatures. View this paper
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Articles (24)

  • Article
  • Open Access
11 Citations
4,652 Views
10 Pages

Optimization of Air Backwash Frequency during the Ultrafiltration of Seawater

  • Clemence Cordier,
  • Tarik Eljaddi,
  • Nadjim Ibouroihim,
  • Christophe Stavrakakis,
  • Patrick Sauvade,
  • Franz Coelho and
  • Philippe Moulin

The main objective of this paper is to study the effect of new air backwash on dead-end ultrafiltration of seawater with a pilot at semi-industrial scale (20 m3/day). To control membrane fouling, two different backwashes were used to clean the membra...

(This article belongs to the Section Membrane Processing and Engineering)
  • Article
  • Open Access
40 Citations
9,330 Views
13 Pages

The stability of emulsion liquid membranes (ELMs) and their ability to extract Cr(VI) were investigated. The objective of this study is to compare different ELM formulations using combinations of two hydrophilic (Tween 20 and Tween 80) and two lipoph...

  • Article
  • Open Access
89 Citations
5,436 Views
22 Pages

This study investigated the impact of implanting TiO2-NPs within a membrane to minimize the influence of long-term operation on the membrane characteristics. Four poly vinyle chloride-titanium oxide (PVC-TiO2-NPs) membranes were prepared to create an...

(This article belongs to the Special Issue Membrane Preparation and Characterisation and Their Application in Environmental Field (Volume II))
  • Article
  • Open Access
30 Citations
8,390 Views
13 Pages

Enhanced O2/N2 Separation of Mixed-Matrix Membrane Filled with Pluronic-Compatibilized Cobalt Phthalocyanine Particles

  • S. A. S. C. Samarasinghe,
  • Chong Yang Chuah,
  • H. Enis Karahan,
  • G. S. M. D. P. Sethunga and
  • Tae-Hyun Bae

Membrane-based air separation (O2/N2) is of great importance owing to its energy efficiency as compared to conventional processes. Currently, dense polymeric membranes serve as the main pillar of industrial processes used for the generation of O2- an...

(This article belongs to the Special Issue Membranes for Gas Separation)
  • Article
  • Open Access
9 Citations
5,864 Views
33 Pages

Active pharmaceutical ingredients (API) are synthesized using highly reactive reagents, catalysts, and solvents. Some of those persist as impurities in the final product and are genotoxic or carcinogenic. The conventional processes used for API purif...

(This article belongs to the Section Membrane Processing and Engineering)
  • Article
  • Open Access
16 Citations
5,369 Views
14 Pages

Global warming is an environmental problem caused mainly by one of the most serious greenhouse gas, CO2 emissions. Subsequently, the capture of CO2 from flue gas and natural gas is essential. Aqueous potassium glycinate (PG) is a promising novelty so...

(This article belongs to the Special Issue Membranes: 10th Anniversary)
  • Article
  • Open Access
50 Citations
8,601 Views
17 Pages

Leveraging Nanocrystal HKUST-1 in Mixed-Matrix Membranes for Ethylene/Ethane Separation

  • Chong Yang Chuah,
  • S.A.S.C. Samarasinghe,
  • Wen Li,
  • Kunli Goh and
  • Tae-Hyun Bae

The energy-intensive ethylene/ethane separation process is a key challenge to the petrochemical industry. HKUST-1, a metal–organic framework (MOF) which possesses high accessible surface area and porosity, is utilized in mixed-matrix membrane f...

(This article belongs to the Special Issue Membranes for Gas Separation)
  • Article
  • Open Access
122 Citations
6,729 Views
25 Pages

Polymer blend electrolytes based on poly(vinyl alcohol):chitosan (PVA:CS) incorporated with various quantities of ammonium iodide were prepared and characterized using a range of electrochemical, structural and microscopic techniques. In the structur...

(This article belongs to the Special Issue Ionic Conductive Membranes for Fuel Cells)
  • Article
  • Open Access
18 Citations
5,516 Views
16 Pages

It is of great significance to separate hazardous methyl tert-butyl ether (MTBE) from water in terms of environmental protection and human health. In the present work, α-Al2O3-suppotred silica membranes were prepared by the sol-gel and dip-coat...

(This article belongs to the Special Issue Pervaporation, Vapour Permeation and Membrane Distillation: From Membrane Fabrication to Application)
  • Article
  • Open Access
27 Citations
5,677 Views
21 Pages

Growing environmental concerns have led to the development of cleaner processes, such as the substitution of cyanide in electroplating industries and changes in the treatment of wastewaters. Hence, we evaluated the treatment of cyanide-free wastewate...

(This article belongs to the Special Issue Electromembrane Processes: Emerging Applications, Materials and Process Configurations)
  • Article
  • Open Access
7 Citations
4,255 Views
17 Pages

Particle Track and Trace during Membrane Filtration by Direct Observation with a High Speed Camera

  • Mads Koustrup Jørgensen,
  • Kristian Boe Eriksen and
  • Morten Lykkegaard Christensen

A methodology was developed for direct observation and analysis of particle movements near a microfiltration membrane. A high speed camera (1196 frames per second) was mounted on a microscope to record a hollow fiber membrane in a filtration cell wit...

(This article belongs to the Section Membrane Processing and Engineering)
  • Article
  • Open Access
22 Citations
6,494 Views
23 Pages

This paper reports the study of the cross-flow microfiltration (MF) of glycerol fermentation broths with Citrobacter freundii bacteria. A single channel tubular ceramic membrane with a nominal pore size of 0.14 µm was used. It has been demonstr...

(This article belongs to the Special Issue Membranes: 10th Anniversary)
  • Review
  • Open Access
88 Citations
10,497 Views
18 Pages

The current situation with the problems associated with the removal of oil from wastewaters by membranes is being explored. Many types of membranes have been investigated—organic polymers, inorganic or ceramic species and hybrids of the two. Po...

(This article belongs to the Special Issue Theoretical and Experimental Investigation of the Mass and Heat Transfers in Membrane Separation Processes)
  • Article
  • Open Access
11 Citations
7,762 Views
17 Pages

Improved Performance of Polysulfone Ultrafiltration Membrane Using TCPP by Post-Modification Method

  • Yuandong Jia,
  • Shuangqing Sun,
  • Shunshun Li,
  • Zhikun Wang,
  • Fushan Wen,
  • Chunling Li,
  • Hideto Matsuyama and
  • Songqing Hu

Ultrafiltration (UF) membranes have found great application in sewage purification and desalination due to their high permeation flux and high rejection rate for contaminants under low-pressure conditions, but the flux and antifouling ability of UF m...

(This article belongs to the Section Polymeric Membranes)
  • Article
  • Open Access
36 Citations
8,381 Views
18 Pages

Influence of the Natural Zeolite Particle Size Toward the Ammonia Adsorption Activity in Ceramic Hollow Fiber Membrane

  • Mohd Ridhwan Adam,
  • Mohd Hafiz Dzarfan Othman,
  • Siti Hamimah Sheikh Abdul Kadir,
  • Mohd Nazri Mohd Sokri,
  • Zhong Sheng Tai,
  • Yuji Iwamoto,
  • Masaki Tanemura,
  • Sawao Honda,
  • Mohd Hafiz Puteh and
  • Juhana Jaafar
  • + 1 author

Natural zeolite is widely used in removing ammonia via adsorption process because of its superior ion-exchange properties. Ceramic particle size affects the adsorptivity of particles toward ammonia. In this study, hollow fiber ceramic membrane (HFCM)...

(This article belongs to the Special Issue Membranes: 10th Anniversary)
  • Article
  • Open Access
13 Citations
5,658 Views
14 Pages

Membrane filtration of biological suspensions is frequently limited by fouling. This mechanism is well understood for ultrafiltration of activated sludge in membrane bioreactors. A rather young application of ultrafiltration is the recovery of nutrie...

(This article belongs to the Section Membrane Applications)
  • Article
  • Open Access
25 Citations
5,416 Views
15 Pages

Assessment of Layer-By-Layer Modified Nanofiltration Membrane Stability in Phosphoric Acid

  • Kirsten Remmen,
  • Barbara Müller,
  • Joachim Köser,
  • Matthias Wessling and
  • Thomas Wintgens

Nanofiltration (NF) can enable P recovery from waste streams via retaining multivalent impurities from spent pickling acid. However, with the currently available membranes, an economically feasible process is impossible. Layer-by-layer modified NF me...

(This article belongs to the Section Membrane Applications)
  • Article
  • Open Access
30 Citations
6,284 Views
12 Pages

Effect of Bridgehead Methyl Substituents on the Gas Permeability of Tröger’s-Base Derived Polymers of Intrinsic Microporosity

  • Richard Malpass-Evans,
  • Ian Rose,
  • Alessio Fuoco,
  • Paola Bernardo,
  • Gabriele Clarizia,
  • Neil B. McKeown,
  • Johannes C. Jansen and
  • Mariolino Carta

A detailed comparison of the gas permeability of four Polymers of Intrinsic Microporosity containing Tröger’s base (TB-PIMs) is reported. In particular, we present the results of a systematic study of the differences between four related p...

(This article belongs to the Special Issue Membranes for Gas Separation)
  • Article
  • Open Access
12 Citations
7,466 Views
15 Pages

In this paper, three main methods of metal ion separation, i.e., liquid–liquid extraction, transport across polymer inclusion membranes (PIMs), and sorption/desorption, are described. In all of them, N,N’-bis(salicylidene)ethylenediamine...

  • Article
  • Open Access
14 Citations
5,061 Views
18 Pages

Structural Characterisation of Deposit Layer during Milk Protein Microfiltration by Means of In-Situ MRI and Compositional Analysis

  • Roland Schopf,
  • Nicolas Schork,
  • Estelle Amling,
  • Hermann Nirschl,
  • Gisela Guthausen and
  • Ulrich Kulozik

Milk protein fractionation by microfiltration membranes is an established but still growing field in dairy technology. Even under cross-flow conditions, this filtration process is impaired by the formation of a deposit by the retained protein fractio...

(This article belongs to the Section Membrane Analysis and Characterization)
  • Article
  • Open Access
13 Citations
4,067 Views
19 Pages

The paper presents a method of obtaining composite polyacrylonitrile-based (PAN) membranes with the addition of reduced graphene oxide (rGO). The membranes were obtained using phase inversion method from a homogeneous rGO dispersion in a solution of...

(This article belongs to the Special Issue Membranes for Water Disinfection)
  • Feature Paper
  • Article
  • Open Access
24 Citations
7,001 Views
34 Pages

Enhancing the Separation Performance of Glassy PPO with the Addition of a Molecular Sieve (ZIF-8): Gas Transport at Various Temperatures

  • Francesco M. Benedetti,
  • Maria Grazia De Angelis,
  • Micaela Degli Esposti,
  • Paola Fabbri,
  • Alice Masili,
  • Alessandro Orsini and
  • Alberto Pettinau

In this study, we prepared and characterized composite films formed by amorphous poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and particles of the size-selective Zeolitic Imidazolate Framework 8 (ZIF-8). The aim was to increase the permselectivity pr...

(This article belongs to the Special Issue Polymer Membranes for Gas Separation)
  • Article
  • Open Access
21 Citations
5,475 Views
15 Pages

In this work, a poly(1-trimethylsilyl-1-propyne) (PTMSP) mixed-matrix membrane was fabricated for the selective removal of 1-butanol from aqueous solutions through pervaporation. Silica nanoparticles (SNPs), which were surface-modified with surfactan...

  • Article
  • Open Access
14 Citations
5,848 Views
18 Pages

Influence of Spacer Design and Module Geometry on the Filtration Performance during Skim Milk Microfiltration with Flat Sheet and Spiral-Wound Membranes

  • Martin Hartinger,
  • Jonas Napiwotzki,
  • Eva-Maria Schmid,
  • Dominik Hoffmann,
  • Franziska Kurz and
  • Ulrich Kulozik

Spacer design in spiral-wound membranes (SWMs) significantly affects the axial pressure drop in the flow channel but also the deposit layer removal. However, the effects of the spacer design and feed flow distribution in the module on the filtration...

(This article belongs to the Section Membrane Processing and Engineering)
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Membranes - ISSN 2077-0375