Ring-Opening Polymerization (ROP) and Catalytic Rearrangement as a Way to Obtain Siloxane Mono- and Telechelics, as Well as Well-Organized Branching Centers: History and Prospects
Abstract
:1. Introduction
2. Preparation of Diorganosiloxane Telechelics by the ROP Method
2.1. Preparation of Organosiloxane Telechelics by Anionic ROP
2.1.1. AROP Initiators
2.1.2. Influence of the Structure of the Initial Organocyclosiloxane on the AROP Process
2.1.3. Preparation of Monochelical PDMS by AROP
2.1.4. Obtaining Functional Telechelics by AROP
2.2. Preparation of Organosiloxane Telechelics by Cationic ROP
2.2.1. CROP Initiators
2.2.2. Obtaining Siloxane Telechelics by CROP
2.3. Catalytic Rearrangement Reactions for the Preparation of PDMS Copolymers
3. Conclusions
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Bezlepkina, K.A.; Milenin, S.A.; Vasilenko, N.G.; Muzafarov, A.M. Ring-Opening Polymerization (ROP) and Catalytic Rearrangement as a Way to Obtain Siloxane Mono- and Telechelics, as Well as Well-Organized Branching Centers: History and Prospects. Polymers 2022, 14, 2408. https://doi.org/10.3390/polym14122408
Bezlepkina KA, Milenin SA, Vasilenko NG, Muzafarov AM. Ring-Opening Polymerization (ROP) and Catalytic Rearrangement as a Way to Obtain Siloxane Mono- and Telechelics, as Well as Well-Organized Branching Centers: History and Prospects. Polymers. 2022; 14(12):2408. https://doi.org/10.3390/polym14122408
Chicago/Turabian StyleBezlepkina, Kseniya A., Sergey A. Milenin, Natalia G. Vasilenko, and Aziz M. Muzafarov. 2022. "Ring-Opening Polymerization (ROP) and Catalytic Rearrangement as a Way to Obtain Siloxane Mono- and Telechelics, as Well as Well-Organized Branching Centers: History and Prospects" Polymers 14, no. 12: 2408. https://doi.org/10.3390/polym14122408