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Polymers, Volume 13, Issue 6

2021 March-2 - 146 articles

Cover Story: The understanding of the basic physical relationships between molecular-scale structural variables and the macroscale properties of hydrogels exposed to different water milieus remains in its infancy. The primary objective of this article is to make progress toward the understanding and prediction of the macroscopic properties of biomedically relevant hydrogels. We emphasize that the different water environments within hydrogels, for example, pure water or phosphate buffer, lead to distinct molecular processes due to interactions between macromolecular chains and individual water molecules, resulting in systematic and predictable variation in hydrogel behavior. View this paper.
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Articles (146)

  • Article
  • Open Access
18 Citations
3,476 Views
12 Pages

Nanosized SnO2 Prepared by Electrospinning: Influence of the Polymer on Both Morphology and Microstructure

  • Alberto Rubin Pedrazzo,
  • Claudio Cecone,
  • Sara Morandi,
  • Maela Manzoli,
  • Pierangiola Bracco and
  • Marco Zanetti

23 March 2021

An electrospinning (ES) procedure of polymeric solutions containing metal oxide precursors, followed by thermal treatments, was exploited to obtain SnO2 nanofibers. Attention was focused on the effect of different templating polymers (polyvinyl pyrro...

  • Article
  • Open Access
13 Citations
2,841 Views
16 Pages

23 March 2021

The response of fiber-reinforced polymer composites to an externally applied mechanical excitation is closely related to the microscopic stress transfer mechanisms taking place in the fiber–matrix interphasial region. In particular, in the case of vi...

  • Article
  • Open Access
10 Citations
2,886 Views
19 Pages

23 March 2021

This study reports the results of a series of experiments, particularly paying attention to the early-age behavior and response of hardening mortars incorporating different types and contents of superabsorbent polymer (SAP) under autogenous (sealed)...

  • Article
  • Open Access
23 Citations
3,454 Views
13 Pages

3D Thermal Network Supported by CF Felt for Improving the Thermal Performance of CF/C/Epoxy Composites

  • Xinfeng Wu,
  • Yuan Gao,
  • Tao Jiang,
  • Lingyu Zheng,
  • Ying Wang,
  • Bo Tang,
  • Kai Sun,
  • Yuantao Zhao,
  • Wenge Li and
  • Jinhong Yu
  • + 1 author

23 March 2021

The heat generated by a high-power device will seriously affect the operating efficiency and service life of electronic devices, which greatly limits the development of the microelectronic industry. Carbon fiber (CF) materials with excellent thermal...

  • Article
  • Open Access
7 Citations
4,222 Views
14 Pages

Gram Scale Synthesis of Dual-Responsive Dendritic Polyglycerol Sulfate as Drug Delivery System

  • Felix Reisbeck,
  • Alexander Ozimkovski,
  • Mariam Cherri,
  • Mathias Dimde,
  • Elisa Quaas,
  • Ehsan Mohammadifar,
  • Katharina Achazi and
  • Rainer Haag

23 March 2021

Biocompatible polymers with the ability to load and release a cargo at the site of action in a smart response to stimuli have attracted great attention in the field of drug delivery and cancer therapy. In this work, we synthesize a dual-responsive de...

  • Review
  • Open Access
35 Citations
5,074 Views
26 Pages

23 March 2021

Semiconducting polymer nanoparticles (SPN) have been emerging as novel functional nano materials for phototherapy which includes PTT (photo-thermal therapy), PDT (photodynamic therapy), and their combination. Therefore, it is important to look into t...

  • Article
  • Open Access
16 Citations
6,690 Views
15 Pages

23 March 2021

Phase diagrams of ternary conjugated polymer solutions were constructed based on Flory-Huggins lattice theory with a constant interaction parameter. For this purpose, the poly(3-hexylthiophene-2,5-diyl) (P3HT) solution as a model system was investiga...

  • Article
  • Open Access
9 Citations
4,070 Views
15 Pages

23 March 2021

Fire-protection coatings with a self-monitoring ability play a critical role in safety and security. An intelligent fire-protection coating can protect humans from personal and property damage. In this work, we report the fabrication of a low-cost an...

  • Article
  • Open Access
2 Citations
3,748 Views
15 Pages

23 March 2021

Lithium-ion batteries are today among the most efficient devices for electrochemical energy storage. However, an improvement of their performance is required to address the challenges of modern grid management, portable technology, and electric mobil...

  • Article
  • Open Access
16 Citations
5,938 Views
21 Pages

Rice Husk Ash/Silicone Rubber-Based Binary Blended Geopolymer Coating Composite: Fire Retardant, Moisture Absorption, Optimize Composition, and Microstructural Analysis

  • Mohd Salahuddin Mohd Basri,
  • Tee Hui Yek,
  • Rosnita A. Talib,
  • Intan Syafinaz Mohamed Amin Tawakkal,
  • Siti Hasnah Kamarudin,
  • Norkhairunnisa Mazlan,
  • Nurul Ain Maidin and
  • Mohd Hidayat Ab Rahman

23 March 2021

Geopolymer coating using rice husk ash (RHA) as the aluminosilicate source has shown excellent fire retardant properties. However, incorporation of rice husk ash into the geopolymer matrix increased water absorption properties of the polymer composit...

  • Article
  • Open Access
13 Citations
7,129 Views
18 Pages

23 March 2021

Responsive (smart, intelligent, adaptive) polymers have been widely explored for a variety of advanced applications in recent years. The thermoresponsive poly(N,N-diethylacrylamide) (PDEAAm), which has a better biocompatibility than the widely invest...

  • Article
  • Open Access
17 Citations
4,893 Views
20 Pages

Performance Evaluation of a Novel Biosourced Co-Processed Excipient in Direct Compression and Drug Release

  • Rihab Benabbas,
  • Noelia M. Sanchez-Ballester,
  • Adrien Aubert,
  • Tahmer Sharkawi,
  • Bernard Bataille and
  • Ian Soulairol

23 March 2021

This study exposes the potential usefulness of a new co-processed excipient, composed of alginic acid and microcrystalline cellulose (Cop AA-MCC), for the preparation of immediate drug release tablets by direct compression. Evaluation of the physical...

  • Article
  • Open Access
3 Citations
4,157 Views
19 Pages

Composite P(3HB-3HV)-CS Spheres for Enhanced Antibiotic Efficiency

  • Oana Gherasim,
  • Alexandru Mihai Grumezescu,
  • Anton Ficai,
  • Valentina Grumezescu,
  • Alina Maria Holban,
  • Bianca Gălățeanu and
  • Ariana Hudiță

23 March 2021

Natural-derived biopolymers are suitable candidates for developing specific and selective performance-enhanced antimicrobial formulations. Composite polymeric particles based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and chitosan, P(3HB-3HV)-CS...

  • Article
  • Open Access
11 Citations
5,235 Views
13 Pages

Tough Hydrogels Based on Maleic Anhydride, Bulk Properties Study and Microfiber Formation by Electrospinning

  • Faiza Bettahar,
  • Fadila Bekkar,
  • Leyre Pérez-Álvarez,
  • Mohammed Issam Ferahi,
  • Rachid Meghabar,
  • José Luis Vilas-Vilela and
  • Leire Ruiz-Rubio

22 March 2021

Hydrogels present a great number of advantages, such as their swelling capacity or their capability to mimic tissues, which make them very interesting biomaterials. However, one of their main disadvantages is their lack of good mechanical properties,...

  • Article
  • Open Access
24 Citations
4,765 Views
15 Pages

22 March 2021

A trachea has a structure capable of responding to various movements such as rotation of the neck and relaxation/contraction of the conduit due to the mucous membrane and cartilage tissue. However, current reported tubular implanting structures are d...

  • Article
  • Open Access
17 Citations
3,768 Views
14 Pages

22 March 2021

In this work, the effect of ion bombardment on the optical properties of Polymethylmethacrylate (PMMA) was studied. Polymer samples were implanted with 500 keV Cu+ ions with a fluence ranging from 1 × 1012 to 1 × 1014 ions/cm2. X-ray Diffractometer (...

  • Review
  • Open Access
181 Citations
10,979 Views
28 Pages

Advances in Molecularly Imprinted Polymers Based Affinity Sensors (Review)

  • Simonas Ramanavicius,
  • Arunas Jagminas and
  • Arunas Ramanavicius

22 March 2021

Recent challenges in biomedical diagnostics show that the development of rapid affinity sensors is very important issue. Therefore, in this review we are aiming to outline the most important directions of affinity sensors where polymer-based semicond...

  • Article
  • Open Access
11 Citations
4,123 Views
14 Pages

Mechanical, Wear and Thermal Behavior of Polyethylene Blended with Graphite Treated in Ball Milling

  • Annamaria Visco,
  • Antonio Grasso,
  • Giuseppe Recca,
  • Domenico Carmelo Carbone and
  • Alessandro Pistone

22 March 2021

Additive manufacturing, civil, and biomechanical applications are among the most important sectors, where the filler’s presence can significantly improve the quality of polymeric products blends. The high market demand of new low-cost material to be...

  • Article
  • Open Access
32 Citations
4,858 Views
17 Pages

Development of Polyvinylidene Fluoride Membrane via Assembly of Tannic Acid and Polyvinylpyrrolidone for Filtration of Oil/Water Emulsion

  • Normi Izati Mat Nawi,
  • Syasya Ong Amat,
  • Muhammad Roil Bilad,
  • Nik Abdul Hadi Md Nordin,
  • Norazanita Shamsuddin,
  • Saiful Prayogi,
  • Thanitporn Narkkun and
  • Kajornsak Faungnawakij

22 March 2021

Wastewater containing oil/water emulsion has a serious ecological impact and threatens human health. The impact worsens as its volume increases. Oil/water emulsion needs to be treated before it is discharged or reused again for processing. A membrane...

  • Review
  • Open Access
9 Citations
3,196 Views
19 Pages

22 March 2021

Epoxy micro-nano composites are well-known to exhibit enhanced electrical, mechanical as well as thermal properties compared to base epoxy resin. Yet, a clear understanding need to be achieved on the long-term aging performance of the epoxy micro-nan...

  • Article
  • Open Access
6 Citations
3,740 Views
15 Pages

New Method for Optimization of Polymer Powder Plasma Treatment for Composite Materials

  • Zuzana Weberová,
  • Hana Šourková,
  • Jakub Antoň,
  • Taťána Vacková and
  • Petr Špatenka

22 March 2021

This paper describes a newly developed testing method for determination of the adhesivity of a film sintered from thermoplastic powder. This method is based on the modified EN 15337 standard. Application of this method enables an effective developmen...

  • Article
  • Open Access
9 Citations
3,169 Views
16 Pages

Steady and Oscillatory Shear Flow Behavior of Different Polysaccharides with Laponite®

  • Marcos Blanco-López,
  • Álvaro González-Garcinuño,
  • Antonio Tabernero and
  • Eva M. Martín del Valle

22 March 2021

The rheological behavior, in terms of steady and oscillatory shear flow, of Laponite® with different polysaccharides (alginate, chitosan, xanthan gum and levan) in salt-free solutions was studied. Results showed that a higher polymer concentration in...

  • Article
  • Open Access
3 Citations
4,064 Views
18 Pages

22 March 2021

Stretch blow moulding (SBM) has been employed to manufacture bioresorbable vascular scaffold (BVS) from poly (l-lactic acid) (PLLA), whilst an experience-based method is used to develop the suitable processing conditions by trial-and-error. FEA model...

  • Article
  • Open Access
9 Citations
3,745 Views
14 Pages

22 March 2021

The conversion of cornstalk lignin derived from the co-product of bio-refinery into value-added products such as polymeric material has remarkable environmental and economic potential. A novel bio-based methyl methacrylate copolymerized with butyl ac...

  • Review
  • Open Access
18 Citations
7,283 Views
25 Pages

22 March 2021

Fiber-reinforced composite structures are used in different applications due to their excellent strength to weight ratio. Due to cost and tool handling issues in conventional manufacturing processes, like resin transfer molding (RTM) and autoclave, v...

  • Review
  • Open Access
102 Citations
24,116 Views
37 Pages

Covalent Organic Frameworks: Synthesis, Properties and Applications—An Overview

  • Tiago F. Machado,
  • M. Elisa Silva Serra,
  • Dina Murtinho,
  • Artur J. M. Valente and
  • Mu. Naushad

22 March 2021

Covalent Organic Frameworks (COFs) are an exciting new class of microporous polymers with unprecedented properties in organic material chemistry. They are generally built from rigid, geometrically defined organic building blocks resulting in robust,...

  • Article
  • Open Access
8 Citations
3,229 Views
22 Pages

Leflunomide Sustained Skin Delivery Based on Sulfobetaine-Modified Chitosan Nanoparticles Embedded in Biodegradable Polyesters Films

  • Stavroula G. Nanaki,
  • Evi Christodoulou,
  • Nikolaos D. Bikiaris,
  • Afroditi Kapourani,
  • Konstantinos N. Kontogiannopoulos,
  • Souzan Vergkizi-Nikolakaki and
  • Panagiotis Barmpalexis

21 March 2021

The aim of the present study was to prepare a leflunomide (LFD) sustained release transdermal delivery system for the treatment of psoriasis. In this context, LFD-loaded nanoparticles (NPs) based on either neat chitosan (CS) or CS modified with [2-(m...

  • Article
  • Open Access
8 Citations
3,074 Views
13 Pages

The Entangled Conductive Structure of CB/PA6/PP MFCs and Their Electromechanical Properties

  • Yu Wang,
  • Song Liu,
  • Huihao Zhu,
  • Huajian Ji,
  • Guo Li,
  • Zhou Wan,
  • Yulu Ma and
  • Linsheng Xie

21 March 2021

In this work, carbon black (CB)/polyamide 6 (PA6)/polypropylene (PP) microfibrillar composites (MFCs) were fabricated through an extrusion (hot stretching) heat treatment process. The CB-coated conductive PA6 microfibrils with high aspect ratio were...

  • Article
  • Open Access
14 Citations
3,037 Views
18 Pages

21 March 2021

Poly-γ-glutamate/apatite (PGA-AP) nanoparticles were prepared by chemical coprecipitation method in the presence of various concentrations of poly-γ-glutamate (γ-PGA). Powder X-ray diffraction pattern and energy-dispersive spectroscopy revealed that...

  • Article
  • Open Access
130 Citations
8,803 Views
15 Pages

Characterization of Chitosan Film Incorporated with Curcumin Extract

  • Pornchai Rachtanapun,
  • Warinporn Klunklin,
  • Pensak Jantrawut,
  • Kittisak Jantanasakulwong,
  • Yuthana Phimolsiripol,
  • Phisit Seesuriyachan,
  • Noppol Leksawasdi,
  • Thanongsak Chaiyaso,
  • Warintorn Ruksiriwanich and
  • Thi Minh Phuong Ngo
  • + 4 authors

21 March 2021

Curcumin is a phenolic compound derived from turmeric roots (Curcuma longa L.). This research studied the effects of curcumin extract on the properties of chitosan films. The film characteristics measured included mechanical properties, visual aspect...

  • Article
  • Open Access
36 Citations
4,955 Views
12 Pages

Physical Aging Behavior of a Glassy Polyether

  • Xavier Monnier,
  • Sara Marina,
  • Xabier Lopez de Pariza,
  • Haritz Sardón,
  • Jaime Martin and
  • Daniele Cangialosi

20 March 2021

The present work aims to provide insights on recent findings indicating the presence of multiple equilibration mechanisms in physical aging of glasses. To this aim, we have investigated a glass forming polyether, poly(1-4 cyclohexane di-methanol) (PC...

  • Article
  • Open Access
20 Citations
5,221 Views
18 Pages

Remarkable Thermal Conductivity of Epoxy Composites Filled with Boron Nitride and Cured under Pressure

  • Sasan Moradi,
  • Frida Román,
  • Yolanda Calventus and
  • John M. Hutchinson

20 March 2021

This work demonstrates that the application of even moderate pressures during cure can result in a remarkable enhancement of the thermal conductivity of composites of epoxy and boron nitride (BN). Two systems have been used: epoxy-thiol and epoxy–dia...

  • Article
  • Open Access
5 Citations
2,943 Views
14 Pages

20 March 2021

There is an urgent need for the development of elastic dielectric materials for flexible organic field effect transistors (OFETs). In this work, detailed analysis of the AC and DC electrical conductivity of a series of flexible poly(dimethylsiloxane)...

  • Article
  • Open Access
15 Citations
3,992 Views
21 Pages

20 March 2021

In this work, anion exchange membranes based on polymer semi-interpenetrating networks were synthesized and characterized for the first time. The networks are composed of sulfonated polysulfone and 1-methylimidazolium-functionalized polysulfone cross...

  • Article
  • Open Access
15 Citations
4,974 Views
14 Pages

Thermochemical Mechanism of the Epoxy-Glutamic Acid Reaction with Sn-3.0 Ag-0.5 Cu Solder Powder for Electrical Joining

  • Gwang-Mun Choi,
  • Ki-Seok Jang,
  • Kwang-Seong Choi,
  • Jiho Joo,
  • Ho-Gyeong Yun,
  • Chanmi Lee and
  • Yong-Sung Eom

20 March 2021

An epoxy-based solder paste (ESP) is a promising alternative to conventional solder pastes to improve the reliability of fine-pitch electrical joining because the epoxy encapsulates the solder joint. However, development of an appropriate epoxy formu...

  • Article
  • Open Access
28 Citations
5,230 Views
20 Pages

20 March 2021

Sulfonated Polysulfone (sPSU) is emerging as a concrete alternative to Nafion ionomer for the development of proton exchange electrolytic membranes for low cost, environmentally friendly and high-performance PEM fuel cells. This ionomer has recently...

  • Article
  • Open Access
3 Citations
2,926 Views
17 Pages

Properties of Starve-Fed Extrusion on a Material Containing a VHMWPE Fraction

  • Raffael Rathner,
  • Davide Tranchida,
  • Wolfgang Roland,
  • Franz Ruemer,
  • Klaus Buchmann,
  • Philipp Amsüss and
  • Georg Steinbichler

19 March 2021

Single-screw extruders are usually operated with the screw fully filled (flood-fed mode) and not partially filled (starve-fed mode). These modes result in completely different processing characteristics, and although starve-fed mode has been shown to...

  • Article
  • Open Access
15 Citations
6,255 Views
10 Pages

19 March 2021

To enable highly conductive electronic textiles (E-textiles), we herein demonstrate a simple solution treatment of poly (3,4-ethylenedioxythiophene): poly (styrene sulfonate) (PEDOT:PSS)-coated textiles by dimethyl sulfoxide (DMSO) and methanol. The...

  • Article
  • Open Access
8 Citations
3,729 Views
18 Pages

Reliability Prediction of Acrylonitrile O-Ring for Nuclear Power Applications Based on Shore Hardness Measurements

  • Alvaro Rodríguez-Prieto,
  • Ernesto Primera,
  • Mariaenrica Frigione and
  • Ana María Camacho

19 March 2021

The degradation of polymeric components is of considerable interest to the nuclear industry and its regulatory bodies. The objective of this work was the development of a methodology to determine the useful life—based on the storage temperature—of ac...

  • Review
  • Open Access
81 Citations
9,958 Views
36 Pages

Recent Developments in Polyurethane-Based Materials for Bone Tissue Engineering

  • Piotr Szczepańczyk,
  • Monika Szlachta,
  • Natalia Złocista-Szewczyk,
  • Jan Chłopek and
  • Kinga Pielichowska

19 March 2021

To meet the needs of clinical medicine, bone tissue engineering is developing dynamically. Scaffolds for bone healing might be used as solid, preformed scaffolding materials, or through the injection of a solidifiable precursor into the defective tis...

  • Article
  • Open Access
8 Citations
4,146 Views
11 Pages

19 March 2021

The advent of the Hydrogen Society created great interest around hydrogen-based energy a decade ago, with several types of vehicles based on hydrogen fuel cells already being produced in the automotive sector. For highly efficient fuel cell systems,...

  • Article
  • Open Access
40 Citations
7,891 Views
11 Pages

Toward Physicochemical and Rheological Characterization of Different Injectable Hyaluronic Acid Dermal Fillers Cross-Linked with Polyethylene Glycol Diglycidyl Ether

  • Nicola Zerbinati,
  • Sabrina Sommatis,
  • Cristina Maccario,
  • Maria Chiara Capillo,
  • Giulia Grimaldi,
  • Giuseppe Alonci,
  • Marina Protasoni,
  • Raffaele Rauso and
  • Roberto Mocchi

19 March 2021

(1) Background: Injectable hyaluronic acid (HA) dermal fillers are used to restore volume, hydration and skin tone in aesthetic medicine. HA fillers differ from each other due to their cross-linking technologies, with the aim to increase mechanical a...

  • Article
  • Open Access
22 Citations
4,415 Views
22 Pages

19 March 2021

Homogeneous dispersion of graphene into thermoplastic polymer matrices during melt-mixing is still challenging due to its agglomeration and weak interfacial interactions with the selected polymer matrix. In this study, an ideal dispersion of graphene...

  • Article
  • Open Access
14 Citations
3,380 Views
19 Pages

Matching Rheology, Conductivity and Joule Effect in PU/CNT Nanocomposites

  • Leire Sangroniz,
  • Maite Landa,
  • Mercedes Fernández and
  • Antxon Santamaria

19 March 2021

We investigated polyurethane (PU)–carbon nanotube (CNT) nanocomposites (PU/CNT) in a range of concentrations from 1 to 8 wt% CNT as hot melt adhesives. We studied the thermal properties of the nanocomposites, which is relevant from an applied point o...

  • Article
  • Open Access
20 Citations
3,495 Views
21 Pages

19 March 2021

(1) Background: The aim of the work is to determine the influence of selected aqueous environments of various types of liquids on the strength of adhesive compositions prepared from epoxy resin based on bisphenol A combined with two different curing...

  • Article
  • Open Access
11 Citations
4,082 Views
17 Pages

Monovalent Salt and pH-Induced Gelation of Oxidised Cellulose Nanofibrils and Starch Networks: Combining Rheology and Small-Angle X-ray Scattering

  • Kazi M. Zakir Hossain,
  • Vincenzo Calabrese,
  • Marcelo A. da Silva,
  • Saffron J. Bryant,
  • Julien Schmitt,
  • Jennifer H. Ahn-Jarvis,
  • Frederick J. Warren,
  • Yaroslav Z. Khimyak,
  • Janet L. Scott and
  • Karen J. Edler

19 March 2021

Water quality parameters such as salt content and various pH environments can alter the stability of gels as well as their rheological properties. Here, we investigated the effect of various concentrations of NaCl and different pH environments on the...

  • Article
  • Open Access
7 Citations
4,499 Views
20 Pages

19 March 2021

Coarse-grained modeling is an outcome of scientific endeavors to address the broad spectrum of time and length scales encountered in polymer systems. However, providing a faithful structural and dynamic characterization/description is challenging for...

  • Article
  • Open Access
15 Citations
4,454 Views
18 Pages

Gas Separation by Mixed Matrix Membranes with Porous Organic Polymer Inclusions within o-Hydroxypolyamides Containing m-Terphenyl Moieties

  • Cenit Soto,
  • Edwin S. Torres-Cuevas,
  • Alfonso González-Ortega,
  • Laura Palacio,
  • Ángel E. Lozano,
  • Benny D. Freeman,
  • Pedro Prádanos and
  • Antonio Hernández

18 March 2021

A hydroxypolyamide (HPA) manufactured from 2,2-bis(3-amino-4-hydroxy phenyl)-hexafluoropropane (APAF) diamine and 5′-terbutyl-m-terphenyl-4,4′′-dicarboxylic acid chloride (tBTpCl), and a copolyimide produced by stochiometric copolymerization of APAF...

  • Article
  • Open Access
33 Citations
6,006 Views
16 Pages

Novel Hydrogel Scaffolds Based on Alginate, Gelatin, 2-Hydroxyethyl Methacrylate, and Hydroxyapatite

  • Simonida Lj. Tomić,
  • Jasmina Nikodinović-Runić,
  • Marija Vukomanović,
  • Marija M. Babić and
  • Jovana S. Vuković

18 March 2021

Hydrogel scaffolding biomaterials are one of the most attractive polymeric biomaterials for regenerative engineering and can be engineered into tissue mimetic scaffolds to support cell growth due to their similarity to the native extracellular matrix...

  • Article
  • Open Access
20 Citations
5,420 Views
15 Pages

18 March 2021

Transdermal delivery of naltrexone (NTX) can be enhanced using microneedles, although micropores generated this way can reseal by 48 h in humans, which prevents further drug delivery from a formulation. Poloxamer 407 (P407) is a thermosensitive polym...

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Polymers - ISSN 2073-4360