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Crystals, Volume 7, Issue 4

2017 April - 26 articles

Cover Story: Yang et al. review the development of borate-based ultraviolet (UV) nonlinear optical (NLO) crystals over the last decade. The structure–property relationship of the optical properties of these crystals is elucidated from the viewpoint of the subgroups of the B-O groups. It is believed that advanced understanding of the mechanisms could have profound significance when searching for novel borate-based crystals with good UV NLO performance. View this paper.
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Articles (26)

  • Article
  • Open Access
11 Citations
5,080 Views
13 Pages

Study on Micro Morphology of Potassium Dihydrogen Phosphate Crystals Grown at Elevated Temperatures

  • Weidong Li,
  • Shenglai Wang,
  • Jianxu Ding,
  • Guangwei Yu,
  • Duanliang Wang,
  • Pingping Huang,
  • Hui Liu,
  • Qingtian Gu and
  • Xinguang Xu

21 April 2017

Potassium dihydrogen phosphate crystals were grown around 65 °C. The growth rate of KDP (KH2PO4) crystal prismatic faces was measured by laser polarization interference system. The surface micro morphology of KDP crystals grown at various supersatura...

  • Review
  • Open Access
5 Citations
7,089 Views
29 Pages

20 April 2017

Protein structures as provided by structural biology such as X-ray crystallography, cryo-electron microscopy and NMR spectroscopy are key elements to understand the function of a protein on the molecular level. Nonetheless, they might be error-prone...

  • Article
  • Open Access
14 Citations
5,584 Views
10 Pages

19 April 2017

Single crystal diamond has been recognized as the optimal tool material in ultra-precision machining. However, the excessive tool wear prevents it from cutting ferrous materials. This paper conducts a series of thermal analysis tests under the condit...

  • Review
  • Open Access
46 Citations
15,496 Views
21 Pages

19 April 2017

Various spherulites or spherulitic crystals are widely encountered in polymeric materials when crystallized from viscous melts or concentrated solutions. However, the microstructures and growth processes are quite complicated and remain unclear and,...

  • Article
  • Open Access
18 Citations
6,756 Views
7 Pages

Fabrication of Low Dislocation Density, Single-Crystalline Diamond via Two-Step Epitaxial Lateral Overgrowth

  • Fengnan Li,
  • Jingwen Zhang,
  • Xiaoliang Wang,
  • Minghui Zhang and
  • And Hongxing Wang

18 April 2017

Continuous diamond films with low dislocation density were obtained by two-step epitaxial lateral overgrowth (ELO). Grooves were fabricated by inductively coupled plasma etching. Mo/Pd stripes sputtered in the grooves were used to inhibit the propaga...

  • Article
  • Open Access
2 Citations
4,807 Views
7 Pages

17 April 2017

A binuclear Zn(II) complex of formula {[Zn(BCPPO)H2O]•3C2H5OH}n (1) [H2BCPPO = Bis 4-carboxyphenyl phenyl phosphine oxide] has been synthesized and structurally characterized by single crystal X-ray diffraction, Powder X-ray diffraction (PXRD), Therm...

  • Article
  • Open Access
19 Citations
7,026 Views
15 Pages

Chiral Optical Tamm States: Temporal Coupled-Mode Theory

  • Ivan V. Timofeev,
  • Pavel S. Pankin,
  • Stepan Ya. Vetrov,
  • Vasily G. Arkhipkin,
  • Wei Lee and
  • Victor Ya. Zyryanov

17 April 2017

The chiral optical Tamm state (COTS) is a special localized state at the interface of a handedness-preserving mirror and a structurally chiral medium such as a cholesteric liquid crystal or a chiral sculptured thin film. The spectral behavior of COTS...

  • Review
  • Open Access
31 Citations
11,552 Views
40 Pages

14 April 2017

Metal sulphides, and in particular transition metal sulphide colloids, are a broad, versatile and exciting class of inorganic compounds which deserve growing interest and attention ascribable to the functional properties that many of them display. Wi...

  • Article
  • Open Access
34 Citations
5,531 Views
10 Pages

13 April 2017

The effects of pressure on the structural and elastic properties of orthorhombic TiAl are investigated using first-principles calculations based on density functional theory within the projector augmented wave method. The calculated lattice parameter...

  • Article
  • Open Access
59 Citations
6,964 Views
12 Pages

12 April 2017

A new family of quaternary diamond-like semiconductors (DLSs), Li2HgMS4 (M = Si, Ge, Sn), were successfully discovered for the first time. All of them are isostructural and crystallize in the polar space group (Pmn21). Seen from their structures, the...

  • Article
  • Open Access
13 Citations
7,103 Views
29 Pages

12 April 2017

The structure and the maximal nonlinear optical (NLO) susceptibility χ(2) are tabulated for more 700 acentric binary oxides, 220 crystals of simple, binary and complex borates and for the same set of 110 carbonates, tartrates, formates, oxalates, ace...

  • Article
  • Open Access
41 Citations
5,526 Views
29 Pages

11 April 2017

Organic charge-transfer (CT) crystals constitute an important class of functional materials, characterized by the directional charge-transfer interaction between π -electron Donor (D) and Acceptor (A) molecules, with the formation of one-dimensi...

  • Article
  • Open Access
14 Citations
8,372 Views
12 Pages

10 April 2017

When a second-order transition point is decreased to zero temperature, a continuous quantum phase transition between different ground states is realized at a quantum critical point (QCP). A recently synthesized organic charge-transfer complex, TTF-2,...

  • Article
  • Open Access
3 Citations
4,907 Views
9 Pages

9 April 2017

Abstract: Lead-free, high piezoelectric performance, Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-0.5BCT) sub-micron powders with perovskite structure were fabricated using the sol-gel process. A 0-3 type composite was obtained by choosing epoxy resin a...

  • Article
  • Open Access
3 Citations
4,810 Views
9 Pages

Structure and Optical Properties of K0.67Rb1.33Al2B2O7 Crystal

  • Qian Huang,
  • Lijuan Liu,
  • Mingjun Xia,
  • Yi Yang,
  • Shu Guo,
  • Xiaoyang Wang,
  • Zheshuai Lin and
  • Chuangtian Chen

7 April 2017

A UV nonlinear optical (NLO) crystal K0.67Rb1.33Al2B2O7 (KRABO) has been obtained by the top-seeded solution growth method for the first time. Its structure is formed of coplanar [BO3]3− triangle groups and [Al2O7]8− groups, which are built from two...

  • Article
  • Open Access
15 Citations
6,244 Views
13 Pages

5 April 2017

X-ray micro diffractometry, transmission electron microscopy, environmental scanning electron microscopy, energy dispersive spectrometry and Fourier transform infrared were employed to investigate the crystallographic characteristics of the inorganic...

  • Review
  • Open Access
5 Citations
7,598 Views
27 Pages

4 April 2017

A review of computer simulation studies on crystal growth in hard-sphere systems is presented. A historical view on the crystallization of hard spheres, including colloidal crystallization, is given in the first section. Crystal phase transition in a...

  • Article
  • Open Access
5 Citations
5,441 Views
13 Pages

2 April 2017

Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 (PIN–PMN–PT) piezoelectric single-crystal rectangular beams with the PIN:PMN:PT ratio of 0.33:0.35:0.32 are prepared, and their mode-coupling effect is investigated both theoretically and experimentally for ul...

  • Article
  • Open Access
10 Citations
7,567 Views
12 Pages

Morphology of Spherulites in Rapidly Solidified Ni3Ge Droplets

  • Nafisul Haque,
  • Robert F. Cochrane and
  • Andrew M. Mullis

1 April 2017

The congruently melting, single phase, L12 intermetallic β-Ni3Ge has been subject to rapid solidification via drop-tube processing. Four different cooling rates are used in this process, at very low cooling rates (≥850 μm diameter particles, ≥700 K s...

  • Article
  • Open Access
16 Citations
7,522 Views
11 Pages

Enhanced Framework Rigidity of a Zeolitic Metal-Azolate via Ligand Substitution

  • Hongqiang Gao,
  • Wenjuan Wei,
  • Liyuan Dong,
  • Guoqiang Feng,
  • Xingxing Jiang,
  • Rong Wu,
  • Zheshuai Lin and
  • Wei Li

31 March 2017

The elastic properties of a zeolitic metal-azolate framework, Zn(mtz)2 (MAF-7, mtz = 3-methyl-1,2,4-triazolate), have been examined from the view point of the first principles calculations and experiments. Our results demonstrate that the three inde...

  • Article
  • Open Access
8 Citations
6,901 Views
10 Pages

Epitaxial Defects in Nanoscale InP Fin Structures Revealed by Wet-Chemical Etching

  • Dennis van Dorp,
  • Manuel Mannarino,
  • Sophia Arnauts,
  • Hugo Bender,
  • Clement Merckling,
  • Alain Moussa,
  • Wilfried Vandervorst and
  • Andreas Schulze

30 March 2017

In this work, we report on wet-chemical defect revealing in InP fin structures relevant for device manufacturing. Both HCl and HBr solutions were explored using bulk InP as a reference. A distinct difference in pit morphology was observed between the...

  • Review
  • Open Access
8 Citations
5,400 Views
11 Pages

30 March 2017

This work is the first in the general natural ice literature to compare microstructures and fabrics of continent-type mountain ice in mid-low latitudes with polar ice in order to find out how they evolved based on similar fabric patterns of their ver...

  • Article
  • Open Access
25 Citations
6,160 Views
9 Pages

Microstructure Evolution and Thermoelectric Property of Pt-PtRh Thin Film Thermocouples

  • Xiaohui Zhao,
  • Xianguai Liang,
  • Shuwen Jiang,
  • Wanli Zhang and
  • Hongchuan Jiang

25 March 2017

Due to their small size, extremely fast response, and low cost, refractory metallic thin film thermocouples (TFTCs) are well suited for the surface temperature measurement of hot components. In this study, PtRh films with different amounts of Rhodium...

  • Review
  • Open Access
52 Citations
9,172 Views
16 Pages

Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

  • Yi Yang,
  • Xingxing Jiang,
  • Zheshuai Lin and
  • Yicheng Wu

25 March 2017

Borates have long been recognized as a very important family of nonlinear optical (NLO) crystals, and have been widely used in the laser frequency-converting technology in ultraviolet (UV) and deep-ultraviolet (DUV) regions. In this work, the borate-...

  • Letter
  • Open Access
5 Citations
5,489 Views
13 Pages

Formation of GaAs/GaSb Core-Shell Heterostructured Nanowires Grown by Molecular-Beam Epitaxy

  • Dong-Dong Wei,
  • Sui-Xing Shi,
  • Chen Zhou,
  • Xu-Tao Zhang,
  • Ping-Ping Chen,
  • Jing-Tao Xie,
  • Feng Tian and
  • Jin Zou

24 March 2017

In this paper, we demonstrated the growth of GaAs/GaSb core-shell heterostructured nanowires on GaAs substrates, with the assistance of Au catalysts by molecular-beam epitaxy. Time-evolution experiments were designed to study the formation of GaSb sh...

  • Article
  • Open Access
8 Citations
6,022 Views
11 Pages

23 March 2017

Mesoporous heteroatom molecular sieve MCM-41 bulk crystals with the crystalline phase were synthesized via a one-step hydrothermal method using an ionic complex as template. The ionic complex template was formed by interaction between cetyltrimethyla...

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Crystals - ISSN 2073-4352