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Open AccessArticle

Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion

Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Magdeburg 39106, Germany
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Academic Editor: Thomas M. Klapötke
Crystals 2015, 5(3), 405-417; https://doi.org/10.3390/cryst5030405
Received: 31 July 2015 / Revised: 27 August 2015 / Accepted: 8 September 2015 / Published: 18 September 2015
(This article belongs to the Special Issue Energetic Materials)
Two new potentially energetic salts comprising the 5,5'-azotetrazolate dianion have been prepared and structurally characterized. The new azotetrazolates are tetraphenylphosphonium-5,5'-azotetrazolate (1) and 1H-1,2,4-triazole-1-carboxamidine-5,5'-azotetrazolate (2). The crystal structures of both compounds have been determined by single-crystal X-ray diffraction and their energetic properties have been tested. Due to its high nitrogen-content of 73.14%, compound 2 was found to be significantly impact-sensitive. View Full-Text
Keywords: energetic salts; azotetrazolate; phosphonium; 1H-1,2,4-triazole-1-carboxamidine; hydrogen bonds energetic salts; azotetrazolate; phosphonium; 1H-1,2,4-triazole-1-carboxamidine; hydrogen bonds
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Deblitz, R.; Hrib, C.G.; Edelmann, F.T. Structures and Energetic Properties of Two New Salts Comprising the 5,5'-Azotetrazolate Dianion. Crystals 2015, 5, 405-417.

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