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Catalysts, Volume 8, Issue 2

February 2018 - 52 articles

Cover Story: (S)-Rivastigmine is a blockbuster drug heavily used for the treatment of mild to moderate dementia of the Alzheimer’s type. An original whole-cell-based and environmentally friendly chemoenzymatic approach has been developed for the obtainment of the target eutomer in four steps, in overall 78% yield and 98% ee. The key step is the stereoselective bioreduction in a phosphate buffered saline medium of an aromatic ketone catalyzed by cheap and easily available Lactobacillus reuteri DSM 20016 whole cells. Interestingly, the described protocol has also been successfully performed on a gram scale, and is amenable for being scaled-up to industrial level. View this paper
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Articles (52)

  • Article
  • Open Access
19 Citations
4,891 Views
10 Pages

Aerobic Oxidation of Benzyl Alcohol on a Strontium-Based Gold Material: Remarkable Intrinsic Basicity and Reusable Catalyst

  • Karla Patrícia R. Castro,
  • Marco Aurélio S. Garcia,
  • Wiury C. de Abreu,
  • Samuel Anderson A. de Sousa,
  • Carla Verônica R. de Moura,
  • Jean Cláudio S. Costa and
  • Edmilson M. de Moura

15 February 2018

The development of stable and active gold catalysts has arisen as a significant strategy for oxidation of alcohols. Nano-size PVA-stabilized gold nanoparticles immobilized on Sr(OH)2 by colloidal deposition presented high catalytic activity for benzy...

  • Article
  • Open Access
60 Citations
9,323 Views
16 Pages

Optimization of Biodiesel Production from Waste Cooking Oil Using Waste Eggshell as a Base Catalyst under a Microwave Heating System

  • Yen-Ping Peng,
  • Kassian T. T. Amesho,
  • Chin-En Chen,
  • Syu-Ruei Jhang,
  • Feng-Chih Chou and
  • Yuan-Chung Lin

14 February 2018

This paper intends to explore the most affordable and environmentally friendly method for the synthesis of biodiesel. Substitute fuel is presently a significant topic all over the world, attributable to the efforts of reducing global warming, which i...

  • Article
  • Open Access
52 Citations
5,858 Views
13 Pages

Catalytic Fast Pyrolysis of Kraft Lignin over Hierarchical HZSM-5 and Hβ Zeolites

  • Yadong Bi,
  • Xiaojuan Lei,
  • Guihua Xu,
  • Hui Chen and
  • Jianli Hu

14 February 2018

The hierarchical HZSM-5 and Hβ zeolites were prepared by alkaline post-treatment methods adopting Na2CO3, TMAOH/NaOH mixture, and NaOH as desilication sources, respectively. More mesopores are produced over two kinds of zeolites, while the micropores...

  • Article
  • Open Access
10 Citations
5,234 Views
11 Pages

Photocatalytic Reduction of CO2 from Simulated Flue Gas with Colored Anatase

  • Yebin Guan,
  • Ming Xia,
  • Alessandro Marchetti,
  • Xiaohong Wang,
  • Weicheng Cao,
  • Hanxi Guan and
  • Xueqian Kong

13 February 2018

Photocatalytic reduction with sunlight is an economical and promising advanced approach for reducing the excessive emissions of CO2 from the combustion of fossil fuels. Aimed at practical applications, a type of inexpensive colored anatase material w...

  • Article
  • Open Access
15 Citations
5,284 Views
14 Pages

Heterogeneous Catalysis by Tetraethylammonium Tetrachloroferrate of the Photooxidation of Toluene by Visible and Near-UV Light

  • Kelsie R. Barnard,
  • Valerie R. Bright,
  • Robert J. Enright,
  • Kira M. Fahy,
  • Adam C. Liu and
  • Patrick E. Hoggard

13 February 2018

Titanium dioxide is the most extensively used heterogeneous catalyst for the photooxidation of toluene and other hydrocarbons, but it has low utility for the synthesis of benzyl alcohol, of which little is produced, or benzaldehyde, due to further ox...

  • Review
  • Open Access
11 Citations
5,801 Views
30 Pages

Oriented Decoration in Metal-Functionalized Ordered Mesoporous Silicas and Their Catalytic Applications in the Oxidation of Aromatic Compounds

  • Shijian Zhou,
  • Fu Yang,
  • Bangbang Wang,
  • Hang Su,
  • Kangchao Lu,
  • Yun Ding,
  • Kai Lei,
  • Man Xu,
  • Bo Shao and
  • Yun Wang
  • + 1 author

13 February 2018

Ordered mesoporous silicas (OMSs) attract considerable attention due to their advanced structural properties. However, for the pristine silica materials, the inert property greatly inhibits their catalytic applications. Thus, to contribute to the ver...

  • Article
  • Open Access
29 Citations
6,498 Views
14 Pages

12 February 2018

A series of Mn-Ce-V-WOx/TiO2 composite oxide catalysts with different molar ratios (active components/TiO2 = 0.1, 0.2, 0.3, 0.6) have been prepared by wet impregnation method and tested in selective catalytic reduction (SCR) of NO by NH3 in a wide te...

  • Article
  • Open Access
19 Citations
5,592 Views
17 Pages

12 February 2018

The effect of support material pretreatment temperature, prior to adding the active phase and promoters, on Fischer–Tropsch activity and selectivity was explored. Four iron catalysts were prepared on silica-stabilized alumina (AlSi) supports pretreat...

  • Feature Paper
  • Review
  • Open Access
54 Citations
9,424 Views
28 Pages

One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules

  • Nicolás Ríos-Lombardía,
  • Joaquín García-Álvarez and
  • Javier González-Sabín

10 February 2018

During the last decade, the combination of different metal- and bio-catalyzed organic reactions in aqueous media has permitted the flourishing of a variety of one-pot asymmetric multi-catalytic reactions devoted to the construction of enantiopure and...

  • Article
  • Open Access
28 Citations
5,220 Views
11 Pages

Effect of Dopant Loading on the Structural and Catalytic Properties of Mn-Doped SrTiO3 Catalysts for Catalytic Soot Combustion

  • Santiago Iván Suárez-Vázquez,
  • Arquímedes Cruz-López,
  • Carlos Eduardo Molina-Guerrero,
  • Astrid Iriana Sánchez-Vázquez and
  • Carlos Macías-Sotelo

9 February 2018

Soot particles have been associated with respiratory diseases and cancer. To decrease these emissions, perovskite-mixed oxides have been proposed due to their thermal stability and redox surface properties. In this work, SrTiO3 doped with different a...

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Catalysts - ISSN 2073-4344