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Catalysts, Volume 7, Issue 6

June 2017 - 26 articles

Cover Story: From molecular recognition and self-organization, novel catalytic supramolecular systems have emerged. Weak interactions proved to be effective to access novel self-assembled catalysts able to adjust their three-dimensional structure to provide good complementarity to the transition state, thus contributing to the chemo-, regio-, and stereoselectivity of the reaction. This short review is focused on cyclodextrin-based, self-assembly-driven catalytic processes taking place in water in the presence of organometallic catalysts. Emphasis is on cyclodextrin-based self-assembled organometallic catalysts, micellar aggregates, and host–guest catalysis developed during the past 10 years. View the paper
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Articles (26)

  • Article
  • Open Access
7 Citations
7,409 Views
11 Pages

l-Amino Acid Production by a Immobilized Double-Racemase Hydantoinase Process: Improvement and Comparison with a Free Protein System

  • María José Rodríguez-Alonso,
  • Felipe Rodríguez-Vico,
  • Francisco Javier Las Heras-Vázquez and
  • Josefa María Clemente-Jiménez

20 June 2017

Protein immobilization is proving to be an environmentally friendly strategy for manufacturing biochemicals at high yields and low production costs. This work describes the optimization of the so-called “double-racemase hydantoinase process,” a syste...

  • Review
  • Open Access
62 Citations
9,853 Views
18 Pages

19 June 2017

An overview on the developments of zirconium phosphate (ZrP) and its organic derivatives in heterogeneous catalysis in recent years is reported in the present review. Two basic aspects have been emphasized: first, the catalytic properties of zirconiu...

  • Article
  • Open Access
6 Citations
5,019 Views
10 Pages

A Theoretical Insight into Enhanced Catalytic Activity of Au by Multiple Twin Nanoparticles

  • Kyoichi Sawabe,
  • Taiki Koketsu,
  • Junya Ohyama and
  • Atsushi Satsuma

19 June 2017

Recently, it has been reported that the morphology of Au nanoparticles (NPs) affects the catalytic activity of CO oxidation; twin crystal NPs show higher activity for CO oxidation than single-crystal NPs. In this study, density functional calculation...

  • Article
  • Open Access
18 Citations
7,247 Views
9 Pages

Co3O4 Nanoparticle-Decorated N-Doped Mesoporous Carbon Nanofibers as an Efficient Catalyst for Oxygen Reduction Reaction

  • Hairong Xue,
  • Tao Wang,
  • Hao Gong,
  • Hu Guo,
  • Xiaoli Fan,
  • Li Song,
  • Wei Xia,
  • Yaya Feng and
  • Jianping He

15 June 2017

A low cost, durable, and efficient electrocatalyst for oxygen reduction reactions (ORR) is essential for high-performance fuel cells. Here, we fabricated Co3O4 nanoparticles (NPs) anchored on N-doped mesoporous carbon nanofibers (Co3O4/NMCF) by elect...

  • Article
  • Open Access
30 Citations
6,458 Views
12 Pages

Using Laccases in the Nanoflower to Synthesize Viniferin

  • Zhuofu Wu,
  • Heng Li,
  • XueJun Zhu,
  • Shuai Li,
  • Zhi Wang,
  • Lei Wang,
  • Zhengqiang Li and
  • Guang Chen

12 June 2017

The laccase-incorporated nanoflower was fabricated and characterized by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR). SEM images indicate that the laccase-incorporated nanoflower has a high surface area, which...

  • Feature Paper
  • Article
  • Open Access
35 Citations
6,249 Views
20 Pages

9 June 2017

Zirconium phosphate glycine diphosphonate nanosheets (ZPGly) have been used as support for the preparation of solid palladium nanoparticles, namely Pd@ZPGly. Thanks to the presence of carboxy-aminophosponate groups on the layer surface, ZPGly-based m...

  • Review
  • Open Access
45 Citations
12,827 Views
29 Pages

9 June 2017

The development of processes based on the integration of new technologies is of growing interest to industrial catalysis. Recently, significant efforts have been focused on the design of catalytic membrane reactors to improve process performance. In...

  • Article
  • Open Access
17 Citations
6,234 Views
12 Pages

8 June 2017

To improve the hydroquinone (HQ) determination limit in wastewater and contribute to the comprehensive utilization of lignin, a zinc oxide-loaded lignin-based carbon fiber (ZCF) was prepared by a combination of electrospinning and thermal treatment p...

  • Article
  • Open Access
22 Citations
5,835 Views
15 Pages

8 June 2017

The effects of SO2 and H2O on the low-temperature selective catalytic reduction (SCR) activity over MnOx/ZrO2/MWCNTs and MnOx/ZrO2/MWCNTs catalysts modified by Ce or Y was studied. MnCeZr and MnYZr catalysts reached nearly 100% and 93.9% NOx conversi...

  • Article
  • Open Access
23 Citations
6,158 Views
10 Pages

8 June 2017

The use of common metal salts as catalysts for 5-ethoxymethylfurfural (EMF) synthesis from carbohydrate transformation was performed. Initial screening suggested AlCl3 as an efficient catalyst for EMF synthesis (45.0%) from fructose at 140 °C. Intere...

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Catalysts - ISSN 2073-4344Creative Common CC BY license