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Catalysts, Volume 11, Issue 9

September 2021 - 118 articles

Cover Story: Water oxidation with an electron acceptor, such as Ce4+cations, mimics photosynthesis II. The catalytic reaction involves adsorbed water at the interface of IrO2 clusters between 5 and 10Å in size dispersed on a TiO2 anatase support, and Ce4+ cations were studied. The stability of the system, TON > 56,000, and the absence of an induction period may indicate that catalysts are not reconstructed under reaction conditions. TOF numbers extracted from TPR and XPS(Ir4f) were found to be similar, while those extracted from the particle shape (HR-STEM) were considerably larger. This difference indicates that bulk Ir atoms contribute to this electron transfer reaction. View this paper
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Articles (118)

  • Review
  • Open Access
16 Citations
4,914 Views
30 Pages

21 September 2021

In this paper, the current advantages and disadvantages of using metal-containing nanocatalysts (NCs) for deep chemical oxidative desulfurization (ODS) of liquid fuels are reviewed. A similar analysis is performed for the oxidative biodesulfurization...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,096 Views
17 Pages

Mesoporous Carbon Production by Nanocasting Technique Using Boehmite as a Template

  • María Ortega-Franqueza,
  • Svetlana Ivanova,
  • María Isabel Domínguez and
  • Miguel Ángel Centeno

21 September 2021

A series of mesoporous carbonaceous materials were synthesized by the nanocasting technique using boehmite as a template and glucose as a carbon precursor. After pyrolysis and template removal, the resulting material is a mesoporous carbon that can b...

  • Article
  • Open Access
35 Citations
7,252 Views
16 Pages

Covalent Organic Frameworks for Simultaneous CO2 Capture and Selective Catalytic Transformation

  • Yaling Li,
  • Jianqiang Zhang,
  • Kaiming Zuo,
  • Zhongping Li,
  • Yu Wang,
  • Hui Hu,
  • Chaoyuan Zeng,
  • Huanjun Xu,
  • Baoshan Wang and
  • Yanan Gao

21 September 2021

Combination of capture and simultaneous conversion of CO2 into valuable chemicals is a fascinating strategy for reducing CO2 emissions. Therefore, searching for heterogeneous catalysts for efficient catalytic conversion of CO2 is of great importance...

  • Article
  • Open Access
11 Citations
5,052 Views
14 Pages

21 September 2021

Catalysts based on (R, R)-1,2-diphenylethylenediamine are, as chiral organic catalysts, applied to the asymmetric Michael addition to α, β-unsaturated nitroalkenes under neutral conditions. The role of an aqueous medium for organic catalytic activity...

  • Article
  • Open Access
16 Citations
5,163 Views
12 Pages

Atoms vs. Ions: Intermediates in Reversible Electrochemical Hydrogen Evolution Reaction

  • Jurga Juodkazytė,
  • Kȩstutis Juodkazis and
  • Saulius Juodkazis

21 September 2021

We present a critical analysis of the mechanism of reversible hydrogen evolution reaction based on thermodynamics of hydrogen processes considering atomic and ionic species as intermediates. Clear distinction between molecular hydrogen evolution/oxid...

  • Feature Paper
  • Article
  • Open Access
23 Citations
3,731 Views
16 Pages

20 September 2021

The novel 2D/2D S-scheme heterostructure of BiOCl nanosheets coupled with CaIn2S4 nanosheets (CaIn2S4/BiOCl-SOVs), which contains surface oxygen vacancies (SOVs), has been successfully prepared by high-temperature calcination combined with a solvothe...

  • Feature Paper
  • Review
  • Open Access
29 Citations
13,297 Views
20 Pages

Molecular Dynamics and Machine Learning in Catalysts

  • Wenxiang Liu,
  • Yang Zhu,
  • Yongqiang Wu,
  • Cen Chen,
  • Yang Hong,
  • Yanan Yue,
  • Jingchao Zhang and
  • Bo Hou

19 September 2021

Given the importance of catalysts in the chemical industry, they have been extensively investigated by experimental and numerical methods. With the development of computational algorithms and computer hardware, large-scale simulations have enabled in...

  • Review
  • Open Access
134 Citations
25,698 Views
37 Pages

Current State and Perspectives on Transesterification of Triglycerides for Biodiesel Production

  • Mohammed Salaheldeen,
  • Abdalbasit Adam Mariod,
  • Mohamed Kheireddine Aroua,
  • S. M. Ashrafur Rahman,
  • Manzoore Elahi M. Soudagar and
  • I. M. Rizwanul Fattah

18 September 2021

Triglycerides are the main constituents of lipids, which are the fatty acids of glycerol. Natural organic triglycerides (viz. virgin vegetable oils, recycled cooking oils, and animal fats) are the main sources for biodiesel production. Biodiesel (mon...

  • Feature Paper
  • Article
  • Open Access
13 Citations
3,965 Views
15 Pages

Preparation of Extremely Active Ethylene Tetramerization Catalyst [iPrN(PAr2)2−CrCl2]+[B(C6F5)4] (Ar = −C6H4-p-SiR3)

  • Jung Hyun Lee,
  • Jun Won Baek,
  • Dong Geun Lee,
  • Ji Hyeong Ko,
  • Dong Geun Lee,
  • Kye Sung Cho,
  • Jin Woo Lee and
  • Bun Yeoul Lee

18 September 2021

Numerous efforts have been made to achieve “on-purpose” 1-octene production since Sasol discovered a Cr-based selective ethylene tetramerization catalyst in the early 2000s. By preparing a series of bis(phosphine) ligands iPrN(PAr2)2 where the Ar con...

  • Feature Paper
  • Review
  • Open Access
49 Citations
7,462 Views
15 Pages

Nanoscale Cerium Oxide: Synthesis, Biocatalytic Mechanism, and Applications

  • Guangchun Song,
  • Nan Cheng,
  • Junjie Zhang,
  • Huixian Huang,
  • Yanfang Yuan,
  • Xiaoyun He,
  • Yunbo Luo and
  • Kunlun Huang

18 September 2021

Nanoscale cerium oxide has excellent catalytic performance due to its unique surface properties and has very important applications in various fields. In this paper, the synthesis methods, catalytic mechanism and activity regulation of nanoscale ceri...

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Catalysts - ISSN 2073-4344