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Catalysts, Volume 11, Issue 6

June 2021 - 106 articles

Cover Story: The prevalence of ether and amine motifs in various areas of chemistry has driven the development of original and innovative methods for their efficient synthesis. The most attractive and atom-economical approach towards these prevalent motifs is undoubtedly the addition of N–H or O-H -bond onto unactivated alkenes—referred to as alkene hydroamination or hydroalkoxylation. The current booming trend for the use of earth-abundant, first-row late transition metals in catalysis has reshaped the field of alkene hydrofunctionalization and given birth to efficient strategies that not only rely on classical activation modes but also on novel radical-type reactivities. This review will survey the most relevant achievements in the field of the intra- and intermolecular hydroalkoxylation and hydroamination of unactivated alkenes promoted by earth-abundant 3D transition metal catalysts from manganese to zinc. View this paper
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Articles (106)

  • Feature Paper
  • Article
  • Open Access
17 Citations
3,881 Views
17 Pages

Shape Effects of Ceria Nanoparticles on the Water‒Gas Shift Performance of CuOx/CeO2 Catalysts

  • Maria Lykaki,
  • Sofia Stefa,
  • Sónia A. C. Carabineiro,
  • Miguel A. Soria,
  • Luís M. Madeira and
  • Michalis Konsolakis

21 June 2021

The copper–ceria (CuOx/CeO2) system has been extensively investigated in several catalytic processes, given its distinctive properties and considerable low cost compared to noble metal-based catalysts. The fine-tuning of key parameters, e.g., the par...

  • Feature Paper
  • Review
  • Open Access
24 Citations
5,850 Views
17 Pages

Light-Driven Hydrogen Evolution Assisted by Covalent Organic Frameworks

  • Nuria Romero,
  • Roger Bofill,
  • Laia Francàs,
  • Jordi García-Antón and
  • Xavier Sala

21 June 2021

Covalent organic frameworks (COFs) are crystalline porous organic polymers built from covalent organic blocks that can be photochemically active when incorporating organic semiconducting units, such as triazine rings or diacetylene bridges. The bandg...

  • Feature Paper
  • Article
  • Open Access
18 Citations
5,824 Views
15 Pages

Aqueous Extraction of Seed Oil from Mamey Sapote (Pouteria sapota) after Viscozyme L Treatment

  • Veymar G. Tacias-Pascacio,
  • Arnulfo Rosales-Quintero,
  • Rafael C. Rodrigues,
  • Daniel Castañeda-Valbuena,
  • Pablo F. Díaz-Suarez,
  • Beatriz Torrestiana-Sánchez,
  • Erik F. Jiménez-Gómez and
  • Roberto Fernandez-Lafuente

19 June 2021

In this study, aqueous enzymatic extraction (AEE) was evaluated during the process of obtaining oil from mamey sapote seed (OMSS). Viscozyme L enzyme complex was used at pH 4 and 50 °C during the optimization of the extraction process by central comp...

  • Article
  • Open Access
13 Citations
3,871 Views
19 Pages

Development of a Novel Bi-Enzymatic Nanobiocatalyst for the Efficient Bioconversion of Oleuropein to Hydroxytyrosol

  • Archontoula Giannakopoulou,
  • Alexandra V. Chatzikonstantinou,
  • Nikolaos Chalmpes,
  • Georgia Tsapara,
  • Dimitrios Gournis,
  • Angeliki C. Polydera and
  • Haralambos Stamatis

19 June 2021

Lipase A from Candida antarctica (CalA) and β-glucosidase from Thermotoga maritima (bgl) were covalently co-immobilized onto the surface of chitosan-coated magnetic nanoparticles (CS-MNPs). Several parameters regarding the co-immobilization procedure...

  • Feature Paper
  • Article
  • Open Access
15 Citations
4,779 Views
17 Pages

The Impact of Biomass and Acid Loading on Methanolysis during Two-Step Lignin-First Processing of Birchwood

  • Panos D. Kouris,
  • Xiaoming Huang,
  • Xianhong Ouyang,
  • Dannie J. G. P. van Osch,
  • Geert J. W. Cremers,
  • Michael D. Boot and
  • Emiel J. M. Hensen

19 June 2021

We optimized the solvolysis step in methanol for two-step lignin-first upgrading of woody biomass. Birchwood was first converted via sulfuric acid methanolysis to cellulose pulp and a lignin oil intermediate, which comprises a mixture of lignin oligo...

  • Article
  • Open Access
8 Citations
4,171 Views
13 Pages

Critical Role of Al Pair Sites in Methane Oxidation to Methanol on Cu-Exchanged Mordenite Zeolites

  • Peijie Han,
  • Zhaoxia Zhang,
  • Zheng Chen,
  • Jingdong Lin,
  • Shaolong Wan,
  • Yong Wang and
  • Shuai Wang

19 June 2021

Cu-exchanged aluminosilicate zeolites have been intensively studied for the selective oxidation of methane to methanol via a chemical looping manner, while the nature of active Cu-oxo species for these catalysts is still under debate. This study inqu...

  • Feature Paper
  • Article
  • Open Access
20 Citations
3,302 Views
16 Pages

Transformation of Resinous Components of the Ashalcha Field Oil during Catalytic Aquathermolysis in the Presence of a Cobalt-Containing Catalyst Precursor

  • Irek I. Mukhamatdinov,
  • Indad Sh.S. Salih,
  • Ilfat Z. Rakhmatullin,
  • Nikita N. Sviridenko,
  • Galina S. Pevneva,
  • Rakesh K. Sharma and
  • Alexey V. Vakhin

18 June 2021

The aim of this work was to study the fractional composition of super-viscous oil resins from the Ashalcha field, as well as the catalytic aquathermolysis product in the presence of a cobalt-containing catalyst precursor and a hydrogen donor. The stu...

  • Feature Paper
  • Article
  • Open Access
8 Citations
3,570 Views
13 Pages

18 June 2021

Ceria-supported vanadium catalysts were studied for H2S removal via partial and selective oxidation reactions at low temperature. The catalysts were characterized by N2 adsorption at 77 K, Raman spectroscopy, X-ray diffraction techniques, and X-ray f...

  • Feature Paper
  • Article
  • Open Access
12 Citations
4,054 Views
12 Pages

Theoretical Investigation of the Deactivation of Ni Supported Catalysts for the Catalytic Deoxygenation of Palm Oil for Green Diesel Production

  • Sanaa Hafeez,
  • Sultan M Al-Salem,
  • Kyriakos N Papageridis,
  • Nikolaos D Charisiou,
  • Maria A Goula,
  • George Manos and
  • Achilleas Constantinou

18 June 2021

For the first time, a fully comprehensive heterogeneous computational fluid dynamic (CFD) model has been developed to predict the selective catalytic deoxygenation of palm oil to produce green diesel over an Ni/ZrO2 catalyst. The modelling results we...

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Catalysts - ISSN 2073-4344