Anisotropic Behavior of 3D-Printed Concrete: Interlayer Bonding, Pore Architecture, Reinforcement Limitations, and Durability Mechanisms
Abstract
1. Introduction
2. Printed Architecture and Structural Anisotropy
2.1. Hierarchical Anisotropy
2.2. Pore Architecture
2.3. Anatomy of a Cold Joint in 3D Printing
2.4. Preferential Orientation of Constituents
3. Chemical Reasons for Anisotropic Weakness
3.1. Disrupted Hydration
3.2. Direction-Dependent Durability
3.3. Surface Carbonation and Sulfate Attack
3.4. Porosity-Controlled Transport and Durability
4. Physical Reasons for Anisotropic Weakness
4.1. Lack of Mechanical Interlocking
4.2. Lack of Reinforcement in 3DPC
4.3. Fiber Reinforcement
4.4. SEM Observations of 3DPC
5. Discussion
6. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| Review | Primary Scope | Interlayer Bonding | Pore Architecture & Durability | Reinforcement & Numerical Modeling |
|---|---|---|---|---|
| Ding, Xiao & Mechtcherine (2023) [33] | Critical synthesis of interlayer region microstructure and mechanical properties | Central focus of the review | Discussed only in relation to interlayer microstructure; durability mechanisms not addressed | Not addressed |
| Baktheer & Classen (2024) [34] | Numerical modeling strategies for the anisotropic behavior of hardened 3DPC | Addressed indirectly through interface-based constitutive models | Not addressed | Central focus: phenomenological, interface-based, and discrete modeling categories |
| Present study | Unified architectural, physical, and chemical basis of anisotropic behavior | Addressed as part of the physical mechanism category, linked to cold-joint formation and mechanical interlocking | Addressed in detail, including pore location, morphology, and durability-related transport mechanisms | Reinforcement addressed (fiber, textile, FRP, discrete systems); numerical modeling referenced but not synthesized in depth |
| Framework Stage | Governing Mechanism | Key Factors | Covered In |
|---|---|---|---|
| Process | Extrusion and layer-by-layer deposition | Nozzle geometry, deposition pressure, interlayer time, rheology | Section 2.1 and Section 4.1 |
| Architecture | Interlayer interface and pore architecture | Bond quality, cold-joint formation, pore morphology and connectivity | Section 2.2 and Section 2.3 |
| Mechanical response | Direction-dependent strength and failure mode | Loading direction relative to interlayer plane, mechanical interlocking | Section 2.1, Section 4.1 and Section 5 |
| Durability response | Direction-dependent transport and degradation | Carbonation, chloride ingress, sulfate attack, freeze–thaw, hydration continuity | Section 3 |
| Mitigation | Reinforcement strategies | Fiber, textile, FRP, discrete reinforcement; bridging weak planes vs. reinforcing filament direction | Section 4.2, Section 4.3 and Section 4.4 |
| Synthesis | Integration of all mechanisms | Combined design approach across mixture, process, and reinforcement | Section 5 (Figure 11) |
| Source | Mixture/Material | Layer Height | Nozzle/Deposition Speed | Interlayer Time Gap/Test Configuration | Reported Result | Anisotropy Ratio (Quantitative) |
|---|---|---|---|---|---|---|
| Xiao, Liu & Ding [21] | Cement mortar, fc = 31 MPa | Not stated as “layer height”; filament (specimen) height was 10 mm for compression and 15 mm for flexural specimens | Not reported | Filament 20 × 10 mm (compression), 30 × 15 mm (flexure); no interlayer time gap | Compression: Fc > Fx > Fz > Fy. Flexure: Fz ≈ Fc ≈ Fy > Fx (source reports these as bar-chart results only; no numerical strength table is given for its own specimens) | Not quantifiable—the source does not tabulate absolute strength values for its own specimens (bar charts only), so a precise ratio cannot be computed |
| Liu et al. [43] | Sand:cement = 1.5; 0.6% polypropylene fiber (confirmed in source) | 12–14 mm (reported directly in the source as the printing-belt/filament height) | Not reported | Filament width 23–26 mm; no interlayer time gap | Compression: DX = 35.66 MPa (highest); DY = 87.07% of DX; DZ = 82.56% of DX | DY/DX ≈ 0.87; DZ/DX ≈ 0.83 |
| Aminpour & Memari [20] | Normal-weight and lightweight (40% EPS) printable concrete | Not reported | Not reported | 30–35 s (minimal) vs. 5 min interlayer time gap | Compressive strength reduced 4.5–53% (NWC) and 11–49% (LWC) by printing and delay | Anisotropic coefficient (source’s own term/metric) multiplied by delay ×6.98 (compressive), ×7.81 (flexural), ×10.81 (shear) for NWC; ×3.95, ×5.0, ×4.2 respectively for LWC |
| Maroszek et al. [44] | Portland cement-based mineral composite | Not stated directly; inferable from specimen preparation—flexural specimens (40 × 40 × 160 mm) were cut to include four printed layers, implying a layer height of ≈10 mm | Not given for the tested specimens; the source separately reports maximum achievable printing speeds of 100 mm/s (20 mm nozzle) and 50 mm/s (40 mm nozzle) in the context of justifying its time-gap values, not as the speed actually used for these specimens | 0, 25, and 50 min interlayer time gap | Flexural strength (perpendicular) fell from ≈4.8 MPa (0 min) to ≈3.5 MPa (50 min), a ≈27% reduction; flexural strength parallel to the layers was ≈60% lower than perpendicular, regardless of gap; compressive strength fell by ≈17% (perpendicular) and ≈10% (parallel) at 50 min | Flexural, parallel/perpendicular ≈ 0.40 (confirmed: source states parallel values are ~60% lower). Flexural, 50 min/0 min (perpendicular) ≈ 3.5/4.8 ≈ 0.73 |
| Source | Material/CT Method | Region Investigated | Reported Porosity | Remarks |
|---|---|---|---|---|
| Kruger et al. [64] | 3DPC mortar; X-ray µCT, 15 µm voxel resolution | Cast reference (no pumping or vibration) | 6.8% (COV 8.9%) | Baseline for comparison with printed specimens |
| Kruger et al. [64] | 3DPC mortar; X-ray µCT, 15 µm voxel resolution | Filament core, single printed layer | 7.9% (COV 7.9%) | Printed filament core porosity slightly higher than the cast reference |
| Kruger et al. [64] | Full filament segment (40 × 40 × 10 mm); X-ray µCT, 22.5 µm voxel resolution | Filament core (larger sampling volume) | 4.2% (COV 30.9%) | Larger voxel size cannot resolve the smallest pores detected in the molded specimens; voids elongated and tri-axial ellipsoidal, oriented along the print direction |
| Kruger et al. [64] | 3DPC mortar; X-ray µCT, 15 µm voxel resolution | Vertical interlayer (0 min pass time) | 8.0% | Comparable to the horizontal interlayer porosity below |
| Kruger et al. [64] | 3DPC mortar; X-ray µCT, 15 µm voxel resolution | Horizontal interlayer, pass time 0–60 min | 7.7% (0 min), rising to a local peak of ≈14% (60 min) | At short pass times, interlayer porosity did not differ significantly from the filament core (≈8%); longer pass times produced larger, elongated interlayer voids |
| Van Der Putten et al. [61] | 3DPC mortar; BSE-SEM phase analysis | Bottom/top layer, 0 min interlayer time | Bottom 7.6%; top 8.4% | Comparable unhydrated cement (UH) content in both layers, confirming negligible moisture exchange at the interface |
| Van Der Putten et al. [61] | 3DPC mortar; BSE-SEM phase analysis | Bottom/top layer, 10 min interlayer time | Bottom 10.8%; top 11.4% | Highest capillary porosity and air-void content (3.4%, RapidAir) recorded at this interval, attributed to peak moisture exchange between layers |
| Van Der Putten et al. [61] | 3DPC mortar; BSE-SEM phase analysis | Bottom/top layer, 30 min interlayer time | Bottom 4.9%; top 8.4% | Porosity and unhydrated cement content decreasing relative to the 10 min interval |
| Van Der Putten et al. [61] | 3DPC mortar; BSE-SEM phase analysis | Bottom/top layer, 60 min interlayer time | Bottom 1.2%; top 8.5% | Air-void content (2.8%) remained above the 0 min baseline despite lower bottom-layer capillary porosity |
| Source | Material/Test Method | Interlayer Time Gaps Investigated | Reported Result | Measurement Type |
|---|---|---|---|---|
| Tay et al. [66] | Cement paste, direct tensile bond test (ASTM C1583) | 1, 5, 10, and 20 min | Bond strength decreased logarithmically from ≈0.82 MPa (1 min) to ≈0.16 MPa (20 min); the reduction was most pronounced between 1 and 5 min and became insignificant beyond 10 min | Direct interlayer bond strength |
| Xu et al. [67] | 3DPC mortar, oblique shear bond test, 28-day curing | 0 (T0), 1, 2, 3, 5, 10, 20, 30, and 60 min | Shear bond strength dropped from 14.41 MPa (T1) to 8.04 MPa (T10, −44.2%) and to 7.11 MPa (T60, ≈half of T1); the first 10 min were most critical, with a comparatively stable trend thereafter | Direct interlayer bond strength (shear) |
| Van Der Putten et al. [68] | Four-layered printed mortar, chloride diffusion and colorimetric penetration analysis | 0 min (T0) vs. 30 min (T30) | Bond strength not measured directly; T30 showed markedly higher interlayer porosity and a shift from equidistant to interlayer-dominated chloride and CO2 penetration, indicating progressive weakening of the interface with increasing time gap | Indirect—porosity and transport (durability) consequence of the time gap, not a direct bond-strength measurement |
| Maroszek et al. [44] | Portland cement-based mineral composite; flexural, compressive, direct tensile, and splitting tensile tests | 0, 25, and 50 min | Flexural strength (perpendicular) fell from ≈4.8 to ≈3.5 MPa (−27%) at 50 min; compressive strength (perpendicular) fell by ≈17% at 50 min, ≈10% parallel; the direction parallel to the layers was consistently less sensitive to the time gap | Indirect—bulk flexural/tensile/compressive strength of printed specimens, not a dedicated interlayer bond test |
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Mardani, A.; Hematibahar, M.; Özteber, S.; Qais, Q.A.A.; Khalil, I.; Gebre, T.H.; Elsheikh, A. Anisotropic Behavior of 3D-Printed Concrete: Interlayer Bonding, Pore Architecture, Reinforcement Limitations, and Durability Mechanisms. Materials 2026, 19, 3698. https://doi.org/10.3390/ma19173698
Mardani A, Hematibahar M, Özteber S, Qais QAA, Khalil I, Gebre TH, Elsheikh A. Anisotropic Behavior of 3D-Printed Concrete: Interlayer Bonding, Pore Architecture, Reinforcement Limitations, and Durability Mechanisms. Materials. 2026; 19(17):3698. https://doi.org/10.3390/ma19173698
Chicago/Turabian StyleMardani, Ali, Mohammad Hematibahar, Selin Özteber, Qais Abdulrahman Ali Qais, Ivan Khalil, Tesfaldet Hadgembes Gebre, and Ahmed Elsheikh. 2026. "Anisotropic Behavior of 3D-Printed Concrete: Interlayer Bonding, Pore Architecture, Reinforcement Limitations, and Durability Mechanisms" Materials 19, no. 17: 3698. https://doi.org/10.3390/ma19173698
APA StyleMardani, A., Hematibahar, M., Özteber, S., Qais, Q. A. A., Khalil, I., Gebre, T. H., & Elsheikh, A. (2026). Anisotropic Behavior of 3D-Printed Concrete: Interlayer Bonding, Pore Architecture, Reinforcement Limitations, and Durability Mechanisms. Materials, 19(17), 3698. https://doi.org/10.3390/ma19173698

