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20 pages, 3578 KiB  
Article
Performance Improvement of Proton Exchange Membrane Fuel Cell by a New Coupling Channel in Bipolar Plate
by Qingsong Song, Shuochen Yang, Hongtao Li, Yunguang Ji, Dajun Cai, Guangyu Wang and Yuan Liufu
Energies 2025, 18(15), 4068; https://doi.org/10.3390/en18154068 - 31 Jul 2025
Viewed by 148
Abstract
The geometric design of flow channels in bipolar plates is one of the critical features of proton exchange membrane fuel cells (PEMFCs), as it determines the power output of the fuel cell and has a significant impact on its performance and durability. The [...] Read more.
The geometric design of flow channels in bipolar plates is one of the critical features of proton exchange membrane fuel cells (PEMFCs), as it determines the power output of the fuel cell and has a significant impact on its performance and durability. The function of the bipolar plate is to guide the transfer of reactant gases to the gas diffusion layer and catalytic layer inside the PEMFC, while removing unreacted gases and gas–liquid byproducts. Therefore, the design of the bipolar plate flow channel is directly related to the water and thermal management of the PEMFC. In order to improve the comprehensive performance of PEMFCs and ensure their safe and stable operation, it is necessary to design the flow channels in bipolar plates rationally and effectively. This study addresses the limitations of existing bipolar plate flow channels by proposing a new coupling of serpentine and radial channels. The distribution of oxygen, water concentrations, and temperature inside the channel is simulated using the multi-physics simulation software COMSOL Multiphysics 6.0. The performance of this novel design is compared with conventional flow channels, with a particular focus on the pressure drop and current density to evaluate changes in the output performance of the PEMFC. The results show that the maximum current density of this novel design is increased by 67.36% and 10.43% compared to straight channel and single serpentine channels, respectively. The main contribution of this research is the innovative design of a new coupling of serpentine and radial channels in bipolar plates, which improves the overall performance of the PEMFC. This study provides theoretical support for the design of bipolar plate flow channels in PEMFCs and holds significant importance for the green development of energy. Full article
(This article belongs to the Special Issue Advanced Energy Storage Technologies)
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21 pages, 932 KiB  
Article
Investigating Roasted Açaí (Euterpe oleracea) Seed Powder as a Coffee Substitute: Effects of Water Temperature, Milk Addition, and In Vitro Digestion on Phenolic Content and Antioxidant Capacity
by Rayssa Cruz Lima, Carini Aparecida Lelis, Jelmir Craveiro de Andrade and Carlos Adam Conte-Junior
Foods 2025, 14(15), 2696; https://doi.org/10.3390/foods14152696 - 31 Jul 2025
Viewed by 250
Abstract
Açaí (Euterpe oleracea) seeds account for up to 95% of the fruit’s weight and are commonly discarded during pulp processing. Roasted açaí seed extract (RASE) has recently emerged as a caffeine-free coffee substitute, although its composition and functionality remain underexplored. This [...] Read more.
Açaí (Euterpe oleracea) seeds account for up to 95% of the fruit’s weight and are commonly discarded during pulp processing. Roasted açaí seed extract (RASE) has recently emerged as a caffeine-free coffee substitute, although its composition and functionality remain underexplored. This study characterized commercial açaí seed powder and evaluated the effect of temperature on the recovery of total phenolic content (TPC) in the aqueous extract using a Central Composite Rotatable Design (CCRD). An intermediate extraction condition (6.0 ± 0.5 g 100 mL−1 at 100 °C) was selected, resulting in 21.78 mg GAE/g TPC, 36.23 mg QE/g total flavonoids, and notable antioxidant capacity (FRAP: 183.33 µmol TE/g; DPPH: 23.06 mg TE/g; ABTS: 51.63 mg TE/g; ORAC: 31.46 µmol TE/g). Proton Nuclear Magnetic Resonance (1H NMR) analysis suggested the presence of amino acids, carbohydrates, and organic acids. During in vitro digestion, TPC decreased from 54.31 to 17.48 mg GAE 100 mL−1 when RASE was combined with goat milk. However, higher bioaccessibility was observed with skimmed (33%) and semi-skimmed (35%) cow milk. These findings highlight RASE as a phenolic-rich, antioxidant beverage with functional stability when prepared with boiling water. This is the first study to report the phytochemical profile of RASE and its interactions with different milk types, supporting its potential as a coffee alternative. Full article
(This article belongs to the Special Issue Fruit By-Products and Their Applications in Food Industry)
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16 pages, 2207 KiB  
Article
Mitogenomic Insights into Adaptive Evolution of African Ground Squirrels in Arid Environments
by Yamin Xing, Xibao Wang, Yao Chen, Yongquan Shang, Haotian Cai, Liangkai Wang and Xiaoyang Wu
Diversity 2025, 17(8), 538; https://doi.org/10.3390/d17080538 - 31 Jul 2025
Viewed by 222
Abstract
African ground squirrels (Xerus spp.), the inhabitants of African arid zones, face extreme heat and water scarcity driving selection for metabolic optimization. We assembled and annotated the first mitogenomes of Xerus inauris and Xerus rutilus (16,525–16,517 bp), revealing conserved vertebrate architecture with [...] Read more.
African ground squirrels (Xerus spp.), the inhabitants of African arid zones, face extreme heat and water scarcity driving selection for metabolic optimization. We assembled and annotated the first mitogenomes of Xerus inauris and Xerus rutilus (16,525–16,517 bp), revealing conserved vertebrate architecture with genus-specific traits. Key features include Xerus rutilus’s elongated ATP6 (680 vs. 605 bp), truncated ATP8ATP6 spacers (4 vs. 43 bp), and tRNA-Pro control regions with 78.1–78.3% AT content. Their nucleotide composition diverged from that of related sciurids, marked by reduced T (25.78–26.9%) and extreme GC skew (−0.361 to −0.376). Codon usage showed strong Arg-CGA bias (RSCU = 3.78–3.88) and species-specific elevations in Xerus rutilus’s UGC-Cys (RSCU = 1.83 vs. 1.17). Phylogenetics positioned Xerus as sister to Ratufa bicolor (Bayesian PP = 0.928; ML = 1.0), aligning with African biogeographic isolation. Critically, we identified significant signatures of positive selection in key mitochondrial genes linked to arid adaptation. Positive selection signals in ND4 (ω = 1.8 × background), ND1, and ATP6 (p < 0.0033) correspond to enhanced proton gradient efficiency and ATP synthesis–molecular adaptations likely crucial for optimizing energy metabolism under chronic water scarcity and thermoregulatory stress in desert environments. Distinct evolutionary rates were observed across mitochondrial genes and complexes: Genes encoding Complex I subunits (ND2, ND6) and Complex III (Cytb) exhibited accelerated evolution in arid-adapted lineages, while genes encoding Complex IV subunits (COXI) and Complex V (ATP8) remained highly conserved. These findings resolve the Xerus mitogenomic diversity, demonstrating adaptive plasticity balancing arid-energy optimization and historical diversification while filling critical genomic gaps for this xeric-adapted lineage. Full article
(This article belongs to the Section Animal Diversity)
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24 pages, 1538 KiB  
Review
H+ and Confined Water in Gating in Many Voltage-Gated Potassium Channels: Ion/Water/Counterion/Protein Networks and Protons Added to Gate the Channel
by Alisher M. Kariev and Michael E. Green
Int. J. Mol. Sci. 2025, 26(15), 7325; https://doi.org/10.3390/ijms26157325 - 29 Jul 2025
Viewed by 303
Abstract
The mechanism by which voltage-gated ion channels open and close has been the subject of intensive investigation for decades. For a large class of potassium channels and related sodium channels, the consensus has been that the gating current preceding the main ionic current [...] Read more.
The mechanism by which voltage-gated ion channels open and close has been the subject of intensive investigation for decades. For a large class of potassium channels and related sodium channels, the consensus has been that the gating current preceding the main ionic current is a large movement of positively charged segments of protein from voltage-sensing domains that are mechanically connected to the gate through linker sections of the protein, thus opening and closing the gate. We have pointed out that this mechanism is based on evidence that has alternate interpretations in which protons move. Very little literature considers the role of water and protons in gating, although water must be present, and there is evidence that protons can move in related channels. It is known that water has properties in confined spaces and at the surface of proteins different from those in bulk water. In addition, there is the possibility of quantum properties that are associated with mobile protons and the hydrogen bonds that must be present in the pore; these are likely to be of major importance in gating. In this review, we consider the evidence that indicates a central role for water and the mobility of protons, as well as alternate ways to interpret the evidence of the standard model in which a segment of protein moves. We discuss evidence that includes the importance of quantum effects and hydrogen bonding in confined spaces. K+ must be partially dehydrated as it passes the gate, and a possible mechanism for this is considered; added protons could prevent this mechanism from operating, thus closing the channel. The implications of certain mutations have been unclear, and we offer consistent interpretations for some that are of particular interest. Evidence for proton transport in response to voltage change includes a similarity in sequence to the Hv1 channel; this appears to be conserved in a number of K+ channels. We also consider evidence for a switch in -OH side chain orientation in certain key serines and threonines. Full article
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22 pages, 1438 KiB  
Article
The Transcription Machinery and the Driving Force of the Transcriptional Molecular Condensate: The Role of Phosphates
by Raúl Riera Aroche, Esli C. Sánchez Moreno, Yveth M. Ortiz García, Andrea C. Machado Sulbarán, Lizbeth Riera Leal, Luis R. Olivas Román and Annie Riera Leal
Curr. Issues Mol. Biol. 2025, 47(7), 571; https://doi.org/10.3390/cimb47070571 - 20 Jul 2025
Viewed by 366
Abstract
The dynamic phosphorylation of the human RNA Pol II CTD establishes a code applicable to all eukaryotic transcription processes. However, the ability of these specific post-translational modifications to convey molecular signals through structural changes remains unclear. We previously explained that each gene can [...] Read more.
The dynamic phosphorylation of the human RNA Pol II CTD establishes a code applicable to all eukaryotic transcription processes. However, the ability of these specific post-translational modifications to convey molecular signals through structural changes remains unclear. We previously explained that each gene can be modeled as a combination of n circuits connected in parallel. RNA Pol II accesses these circuits and, through a series of pulses, matches the resonance frequency of the DNA qubits, enabling it to extract genetic information and quantum teleport it. Negatively charged phosphates react under RNA Pol II catalysis, which increases the electron density on the deoxyribose acceptor carbon (2’C in the DNA sugar backbone). The phosphorylation effect on the stability of a carbon radical connects tyrosine to the nitrogenous base, while the subsequent pulses link the protein to molecular water through hydrogen bonds. The selective activation of inert C(sp3)–H bonds begins by reading the quantum information stored in the nitrogenous bases. The coupling of hydrogen proton transfer with electron transfer in water generates a supercurrent, which is explained by the correlation of pairs of the same type of fermions exchanging a boson. All these changes lead to the formation of a molecular protein–DNA–water transcriptional condensate. Full article
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20 pages, 2939 KiB  
Article
Investigations of Dongyue Series Perfluorosulfonic Acid Membranes for Applications in Proton Exchange Membrane Fuel Cells (PEMFCs)
by Ge Meng, Xiang Li, Mengjie Liu, Sergey A. Grigoriev, Ivan Tolj, Jiaqi Shen, Chaonan Yue and Chuanyu Sun
Batteries 2025, 11(7), 277; https://doi.org/10.3390/batteries11070277 - 20 Jul 2025
Viewed by 404
Abstract
This study systematically investigated the physicochemical properties and proton exchange membrane fuel cell (PEMFC) performance of perfluorosulfonic acid (PFSA) membranes with different thicknesses, which were prepared based on the resins produced by Dongyue (China) in comparison with commercial Nafion membranes. It was found [...] Read more.
This study systematically investigated the physicochemical properties and proton exchange membrane fuel cell (PEMFC) performance of perfluorosulfonic acid (PFSA) membranes with different thicknesses, which were prepared based on the resins produced by Dongyue (China) in comparison with commercial Nafion membranes. It was found that the water uptake of Dongyue membranes is significantly higher than that of Nafion, showing a significant upward trend with the thickness increase. The ion exchange capacity (IEC) of these membranes is ca. 1 mmol·g−1. Moreover, the tensile strength of the Dongyue membrane was positively correlated with the thickness and was significantly higher than that of recast Nafion. Under 80 °C, all Dongyue membranes with various thicknesses (15~45 μm) exhibited PEMFC single-cell performance superior to that of Nafion. The maximum power density is observed with a thickness of 25 μm, reaching 851.76 mW·cm−2, which is higher than that of Nafion (635.99 mW·cm−2). However, the oxidative stability of the prepared Dongyue PFSA series membranes exhibits a slight deficit compared to commercial Nafion membranes. Subsequently, the modification and optimization of preparation processes can be employed to improve the mechanical and chemical stability of Dongyue PFSA membranes. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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32 pages, 8548 KiB  
Article
A Comprehensive Study of the Macro-Scale Performance of Graphene Oxide Enhanced Low Carbon Concrete
by Thusitha Ginigaddara, Pasadi Devapura, Vanissorn Vimonsatit, Michael Booy, Priyan Mendis and Rish Satsangi
Constr. Mater. 2025, 5(3), 47; https://doi.org/10.3390/constrmater5030047 - 18 Jul 2025
Viewed by 365
Abstract
This study presents a detailed and comprehensive investigation into the macro-scale performance, strength gain mechanisms, environment and economic performance of graphene oxide (GO)-enhanced low-emission concrete. A comprehensive experimental program evaluated fresh and hardened properties, including slump retention, bleeding, air content, compressive, flexural, and [...] Read more.
This study presents a detailed and comprehensive investigation into the macro-scale performance, strength gain mechanisms, environment and economic performance of graphene oxide (GO)-enhanced low-emission concrete. A comprehensive experimental program evaluated fresh and hardened properties, including slump retention, bleeding, air content, compressive, flexural, and tensile strength, drying shrinkage, and elastic modulus. Scanning Electron Microscopy (SEM), energy-dispersive spectroscopy (EDS), Thermogravimetric analysis (TGA) and proton nuclear magnetic resonance (1H-NMR) was employed to examine microstructural evolution and early age water retention, confirming GO’s role in accelerating cement hydration and promoting C-S-H formation. Optimal performance was achieved at 0.05% GO (by binder weight), resulting in a 25% increase in 28-day compressive strength without compromising workability. This outcome is attributed to a tailored, non-invasive mixing strategy, wherein GO was pre-dispersed during synthesis and subsequently blended without the use of invasive mixing methods such as high shear mixing or ultrasonication. Fourier-transform infrared (FTIR) spectroscopy further validated the chemical compatibility of GO and PCE and confirmed the compatibility and efficiency of the admixture. Sustainability metrics, including embodied carbon and strength-normalized cost indices (USD/MPa), indicated that, although GO increased material cost, the overall cost-performance ratio remained competitive at breakeven GO prices. Enhanced efficiency also led to lower net embodied CO2 emissions. By integrating mechanical, microstructural, and environmental analyses, this study demonstrates GO’s multifunctional benefits and provides a robust basis for its industrial implementation in sustainable infrastructure. Full article
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22 pages, 1725 KiB  
Article
Capacity Optimization for Coordinated Operation of Hybrid Electrolytic Cells Based on Wavelet Packet
by Yi Yang, Bowen Zhou, Yang Xu, Juan Zhang, Bo Yang, Guiping Zhou and Shunjiang Wang
Sustainability 2025, 17(14), 6412; https://doi.org/10.3390/su17146412 - 13 Jul 2025
Viewed by 332
Abstract
Hydrogen production through electrolysis of water can achieve efficient, stable and diversified utilization of renewable energy. To this end, a hybrid electrolyzer system for hydrogen production based on bi-layer optimization is constructed. Firstly, the wind and photovoltaic power is decomposed into high-frequency and [...] Read more.
Hydrogen production through electrolysis of water can achieve efficient, stable and diversified utilization of renewable energy. To this end, a hybrid electrolyzer system for hydrogen production based on bi-layer optimization is constructed. Firstly, the wind and photovoltaic power is decomposed into high-frequency and low-frequency components by an adaptive wavelet packet. The low-frequency power is allocated to the alkaline electrolyzers (AWE) to ensure its stability, and the high-frequency power is allocated to the proton exchange membrane electrolyzers (PEM) with a faster response characteristic, thereby improving the energy utilization rate. This paper proposes a bi-layer optimization model, in which the upper-layer objective is to minimize the cost of mixed hydrogen production, and the lower-layer optimization objective is to maximize the utilization rate of renewable energy. The differential evolution algorithm optimizes the upper-layer objective, with results sent to the lower layer. Then, the YALMIP toolbox is used to solve the lower-layer objective. Through case analysis, the optimal proportion of AWE and PEM hydrogen electrolyzers obtained by this optimization method is 89.5 and 10.5, respectively. Compared with a single type of electrolyzer, the method proposed in this paper effectively improves the energy utilization efficiency and reduces the cost of hydrogen production. Full article
(This article belongs to the Topic Clean Energy Technologies and Assessment, 2nd Edition)
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10 pages, 3200 KiB  
Article
Enhancing Fuel Cell Performance by Constructing a Gas Diffusion Layer with Gradient Microstructure
by Rui-Xin Wang, Bai-He Chen, Ye-Fan-Hao Wang, Cheng Guo, Bo-Wen Deng, Zhou-Long Song, Yi You and Hai-Bo Jiang
Materials 2025, 18(14), 3271; https://doi.org/10.3390/ma18143271 - 11 Jul 2025
Viewed by 355
Abstract
This study focuses on addressing the issues of water flooding and mass transfer limitations in proton exchange membrane fuel cells (PEMFCs) under high current density conditions. A multi-scale gradient pore gas diffusion layer (GDL) is designed to enhance fuel cell performance. The pore [...] Read more.
This study focuses on addressing the issues of water flooding and mass transfer limitations in proton exchange membrane fuel cells (PEMFCs) under high current density conditions. A multi-scale gradient pore gas diffusion layer (GDL) is designed to enhance fuel cell performance. The pore structure is precisely controlled using a self-assembled mold, resulting in the fabrication of a GDL with a gradient distribution of pore diameters ranging from 80 to 170 μm. Experimental results indicate that, with the optimized gradient pore GDL, the peak power density of the fuel cell reaches 1.18 W·cm−2, representing a 20% improvement compared to the traditional structure. A mechanism analysis reveals that this structure establishes a concentrated water transport pathway through channels while enabling gas diffusion and transport driven by concentration gradients, thereby achieving the collaborative optimization of gas–liquid transport. This approach offers a novel solution for managing water in PEMFCs operating under high current density conditions, and holds significant implications for advancing the commercialization of PEMFC technology. Full article
(This article belongs to the Section Energy Materials)
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16 pages, 2672 KiB  
Article
Chemical Stability and Leaching Behavior of ECO EPDM in Acidic Fuel Cell-like Conditions
by Daniel Foltuț, Georgiana-Iulia Șoșoi and Viorel-Aurel Șerban
Materials 2025, 18(14), 3260; https://doi.org/10.3390/ma18143260 - 10 Jul 2025
Viewed by 297
Abstract
This study investigates the chemical stability and leaching behavior of two environmentally sustainable EPDM elastomers filled with circular carbon black (CCB) and recycled carbon black (RCB) when exposed to acidic, fuel cell-like environments. Accelerated aging tests were conducted in sulfuric acid solutions of [...] Read more.
This study investigates the chemical stability and leaching behavior of two environmentally sustainable EPDM elastomers filled with circular carbon black (CCB) and recycled carbon black (RCB) when exposed to acidic, fuel cell-like environments. Accelerated aging tests were conducted in sulfuric acid solutions of varying concentrations (1 M, 0.1 M, and 0.001 M) at 90 °C for 1000 h to simulate long-term degradation in proton exchange membrane fuel cell (PEMFC) sealing applications. Complementary hot water extraction tests (HWET) were performed at 80 °C for up to 168 h to evaluate ionic leaching via conductivity measurements. HPLC-DAD analysis was used to assess organic leachates, while surface changes were examined by SEM and thermal transitions by DSC. Results revealed lower leaching and improved surface preservation in the CCB-filled EPDM, which remained below the critical 5 µS/cm ionic conductivity threshold for longer durations than its RCB counterpart. HPLC results showed filler-dependent trends in organic compound release, with CCB EPDM exhibiting higher leaching only under strong acid exposure. SEM confirmed greater surface damage and porosity in RCB EPDM. Overall, both materials demonstrated adequate chemical resistance, but the CCB formulation exhibited superior long-term stability, supporting its use in sustainable PEMFC sealing applications. Full article
(This article belongs to the Collection Materials and Technologies for Hydrogen and Fuel Cells)
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16 pages, 2609 KiB  
Article
Comparative Life Cycle and Techno-Economic Assessment of Constructed Wetland, Microbial Fuel Cell, and Their Integration for Wastewater Treatment
by Nicholas Miwornunyuie, Samuel O. Alamu, Guozhu Mao, Nihed Benani, James Hunter and Gbekeloluwa Oguntimein
Clean Technol. 2025, 7(3), 57; https://doi.org/10.3390/cleantechnol7030057 - 10 Jul 2025
Viewed by 438
Abstract
This study systematically compares the environmental and economic performance of three wastewater treatment systems: constructed wetlands (CWs), microbial fuel cells (MFCs), and their integration (CW–MFC). Lab-scale units of each system were constructed using a multi-media matrix (gravel, zeolite, and granular activated carbon), composite [...] Read more.
This study systematically compares the environmental and economic performance of three wastewater treatment systems: constructed wetlands (CWs), microbial fuel cells (MFCs), and their integration (CW–MFC). Lab-scale units of each system were constructed using a multi-media matrix (gravel, zeolite, and granular activated carbon), composite native wetland species (Juncus effusus, Iris sp., and Typha angustifolia), carbon-based electrodes (graphite), and standard inoculum for CW and CW–MFC. The MFC system employed carbon-based electrodes and proton-exchange membrane. The experimental design included a parallel operation of all systems treating domestic wastewater under identical hydraulic and organic loading rates. Environmental impacts were quantified across construction and operational phases using life cycle assessment (LCA) with GaBi software 9.2, employing TRACI 2021 and ReCiPe 2016 methods, while techno-economic analysis (TEA) evaluated capital and operational costs. The key results indicate that CW demonstrates the lowest global warming potential (142.26 kg CO2-eq) due to its reliance on natural biological processes. The integrated CW–MFC system achieved enhanced pollutant removal (82.8%, 87.13%, 78.13%, and 90.3% for COD, NO3, TN, and TP) and bioenergy generation of 2.68 kWh, balancing environmental benefits with superior treatment efficiency. In contrast, the stand-alone MFC shows higher environmental burdens, primarily due to energy-intensive material requirements and fabrication processes. TEA results highlight CW as the most cost-effective solution (USD 627/m3), with CW–MFC emerging as a competitive alternative when considering environmental benefits and operational efficiencies (USD 718/m3). This study highlights the potential of hybrid systems, such as CW–MFC, to advance sustainable wastewater treatment technologies by minimizing environmental impacts and enhancing resource recovery, supporting their broader adoption in future water management strategies. Future research should focus on optimizing materials and energy use to improve scalability and feasibility. Full article
(This article belongs to the Collection Water and Wastewater Treatment Technologies)
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23 pages, 8106 KiB  
Article
Study on the Flexible Scheduling Strategy of Water–Electricity–Hydrogen Systems in Oceanic Island Groups Enabled by Hydrogen-Powered Ships
by Qiang Wang, Binbin Long and An Zhang
Energies 2025, 18(14), 3627; https://doi.org/10.3390/en18143627 - 9 Jul 2025
Viewed by 341
Abstract
In order to improve energy utilization efficiency and the flexibility of resource transfer in oceanic-island-group microgrids, a water–electricity–hydrogen flexible scheduling strategy based on a multi-rate hydrogen-powered ship is proposed. First, the characteristics of the seawater desalination unit (SDU), proton exchange membrane electrolyzer (PEMEL), [...] Read more.
In order to improve energy utilization efficiency and the flexibility of resource transfer in oceanic-island-group microgrids, a water–electricity–hydrogen flexible scheduling strategy based on a multi-rate hydrogen-powered ship is proposed. First, the characteristics of the seawater desalination unit (SDU), proton exchange membrane electrolyzer (PEMEL), and battery system (BS) in consuming surplus renewable energy on resource islands are analyzed. The variable-efficiency operation characteristics of the SDU and PEMEL are established, and the effect of battery life loss is also taken into account. Second, a spatio-temporal model for the multi-rate hydrogen-powered ship is proposed to incorporate speed adjustment into the system optimization framework for flexible resource transfer among islands. Finally, with the goal of minimizing the total cost of the system, a flexible water–electricity–hydrogen hybrid resource transfer model is constructed, and a certain island group in the South China Sea is used as an example for simulation and analysis. The results show that the proposed scheduling strategy can effectively reduce energy loss, promote renewable energy absorption, and improve the flexibility of resource transfer. Full article
(This article belongs to the Special Issue Hybrid-Renewable Energy Systems in Microgrids)
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16 pages, 3764 KiB  
Article
Luminescence of Carbon Dots Induced by MeV Protons
by Mariapompea Cutroneo, Vladimir Havranek, Vaclav Holy, Petr Malinsky, Petr Slepicka, Selena Cutroneo and Lorenzo Torrisi
Chemosensors 2025, 13(7), 245; https://doi.org/10.3390/chemosensors13070245 - 9 Jul 2025
Viewed by 361
Abstract
In this study, we describe the preparation of carbon dots (CDs) from natural charcoal by laser ablation in a liquid. A continuum wave (CW) laser diode operating at a wavelength of 450 nm, hitting a solid carbon target placed into a biocompatible liquid, [...] Read more.
In this study, we describe the preparation of carbon dots (CDs) from natural charcoal by laser ablation in a liquid. A continuum wave (CW) laser diode operating at a wavelength of 450 nm, hitting a solid carbon target placed into a biocompatible liquid, constituted of a phosphate-buffered saline (PBS) solution and distilled water, was used for the generation of the CDs suspension. Exploring the practical applications of carbon dots, it was observed that the luminescence of the produced CDs can be used as bioimaging in living organisms, environmental monitoring, chemical analysis, targeted drug delivery, disease diagnosis, therapy, and others. The CDs’ luminescence can be induced by UV irradiation and, as demonstrated in this study, by energetic MeV proton beams. The fluorescence was revealed mainly at 480 nm when UV illuminated the CDs, and also in the region at 514–642 nm when the CDs were irradiated by energetic proton ions. Atomic force microscopy (AFM) of the CD films revealed their spherical shape with a size of about 10 nm. The significance of the manuscript lies in the use of CDs produced by laser ablation exhibiting luminescence under irradiation of an energetic proton beam. Full article
(This article belongs to the Section Materials for Chemical Sensing)
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20 pages, 2317 KiB  
Article
Multifunctional Amphiphilic Biocidal Copolymers Based on N-(3-(Dimethylamino)propyl)methacrylamide Exhibiting pH-, Thermo-, and CO2-Sensitivity
by Maria Filomeni Koutsougera, Spyridoula Adamopoulou, Denisa Druvari, Alexios Vlamis-Gardikas, Zacharoula Iatridi and Georgios Bokias
Polymers 2025, 17(14), 1896; https://doi.org/10.3390/polym17141896 - 9 Jul 2025
Viewed by 456
Abstract
Because of their potential “smart” applications, multifunctional stimuli-responsive polymers are gaining increasing scientific interest. The present work explores the possibility of developing such materials based on the hydrolytically stable N-3-dimethylamino propyl methacrylamide), DMAPMA. To this end, the properties in aqueous solution of the [...] Read more.
Because of their potential “smart” applications, multifunctional stimuli-responsive polymers are gaining increasing scientific interest. The present work explores the possibility of developing such materials based on the hydrolytically stable N-3-dimethylamino propyl methacrylamide), DMAPMA. To this end, the properties in aqueous solution of the homopolymer PDMAPMA and copolymers P(DMAPMA-co-MMAx) of DMAPMA with the hydrophobic monomer methyl methacrylate, MMA, were explored. Two copolymers were prepared with a molar content x = 20% and 35%, as determined by Proton Nuclear Magnetic Resonance (1H NMR). Turbidimetry studies revealed that, in contrast to the homopolymer exhibiting a lower critical solution temperature (LCST) behavior only at pH 14 in the absence of salt, the LCST of the copolymers covers a wider pH range (pH > 8.5) and can be tuned within the whole temperature range studied (from room temperature up to ~70 °C) through the use of salt. The copolymers self-assemble in water above a critical aggregation Concentration (CAC), as determined by Nile Red probing, and form nanostructures with a size of ~15 nm (for P(DMAPMA-co-MMA35)), as revealed by transmission electron microscopy (TEM) and dynamic light scattering (DLS). The combination of turbidimetry with 1H NMR and automatic total organic carbon/total nitrogen (TOC/TN) results revealed the potential of the copolymers as visual CO2 sensors. Finally, the alkylation of the copolymers with dodecyl groups lead to cationic amphiphilic materials with an order of magnitude lower CAC (as compared to the unmodified precursor), effectively stabilized in water as larger aggregates (~200 nm) over a wide temperature range, due to their increased ζ potential (+15 mV). Such alkylated products show promising biocidal properties against microorganisms such as Escherichia coli and Staphylococcus aureus. Full article
(This article belongs to the Special Issue Development and Innovation of Stimuli-Responsive Polymers)
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31 pages, 3723 KiB  
Review
Chemical Profiling and Quality Assessment of Food Products Employing Magnetic Resonance Technologies
by Chandra Prakash and Rohit Mahar
Foods 2025, 14(14), 2417; https://doi.org/10.3390/foods14142417 - 9 Jul 2025
Viewed by 638
Abstract
Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI) are powerful techniques that have been employed to analyze foodstuffs comprehensively. These techniques offer in-depth information about the chemical composition, structure, and spatial distribution of components in a variety of food products. Quantitative NMR [...] Read more.
Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI) are powerful techniques that have been employed to analyze foodstuffs comprehensively. These techniques offer in-depth information about the chemical composition, structure, and spatial distribution of components in a variety of food products. Quantitative NMR is widely applied for precise quantification of metabolites, authentication of food products, and monitoring of food quality. Low-field 1H-NMR relaxometry is an important technique for investigating the most abundant components of intact foodstuffs based on relaxation times and amplitude of the NMR signals. In particular, information on water compartments, diffusion, and movement can be obtained by detecting proton signals because of H2O in foodstuffs. Saffron adulterations with calendula, safflower, turmeric, sandalwood, and tartrazine have been analyzed using benchtop NMR, an alternative to the high-field NMR approach. The fraudulent addition of Robusta to Arabica coffee was investigated by 1H-NMR Spectroscopy and the marker of Robusta coffee can be detected in the 1H-NMR spectrum. MRI images can be a reliable tool for appreciating morphological differences in vegetables and fruits. In kiwifruit, the effects of water loss and the states of water were investigated using MRI. It provides informative images regarding the spin density distribution of water molecules and the relationship between water and cellular tissues. 1H-NMR spectra of aqueous extract of kiwifruits affected by elephantiasis show a higher number of small oligosaccharides than healthy fruits do. One of the frauds that has been detected in the olive oil sector reflects the addition of hazelnut oils to olive oils. However, using the NMR methodology, it is possible to distinguish the two types of oils, since, in hazelnut oils, linolenic fatty chains and squalene are absent, which is also indicated by the 1H-NMR spectrum. NMR has been applied to detect milk adulterations, such as bovine milk being spiked with known levels of whey, urea, synthetic urine, and synthetic milk. In particular, T2 relaxation time has been found to be significantly affected by adulteration as it increases with adulterant percentage. The 1H spectrum of honey samples from two botanical species shows the presence of signals due to the specific markers of two botanical species. NMR generates large datasets due to the complexity of food matrices and, to deal with this, chemometrics (multivariate analysis) can be applied to monitor the changes in the constituents of foodstuffs, assess the self-life, and determine the effects of storage conditions. Multivariate analysis could help in managing and interpreting complex NMR data by reducing dimensionality and identifying patterns. NMR spectroscopy followed by multivariate analysis can be channelized for evaluating the nutritional profile of food products by quantifying vitamins, sugars, fatty acids, amino acids, and other nutrients. In this review, we summarize the importance of NMR spectroscopy in chemical profiling and quality assessment of food products employing magnetic resonance technologies and multivariate statistical analysis. Full article
(This article belongs to the Special Issue Quantitative NMR and MRI Methods Applied for Foodstuffs)
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