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16 pages, 5284 KiB  
Article
Hydration, Soundness, and Strength of Low Carbon LC3 Mortar Using Waste Brick Powder as a Source of Calcined Clay
by Saugat Humagain, Gaurab Shrestha, Mini K. Madhavan and Prabir Kumar Sarker
Materials 2025, 18(15), 3697; https://doi.org/10.3390/ma18153697 - 6 Aug 2025
Abstract
The construction industry is responsible for 39% of global CO2 emissions related to energy use, with cement responsible for 5–8% of it. Limestone calcined clay cement (LC3), a ternary blended binder system, offers a low-carbon alternative by partially substituting clinker [...] Read more.
The construction industry is responsible for 39% of global CO2 emissions related to energy use, with cement responsible for 5–8% of it. Limestone calcined clay cement (LC3), a ternary blended binder system, offers a low-carbon alternative by partially substituting clinker with calcined clay and limestone. This study investigated the use of waste clay brick powder (WBP), a waste material, as a source of calcined clay in LC3 formulations, addressing both environmental concerns and SCM scarcity. Two LC3 mixtures containing 15% limestone, 5% gypsum, and either 15% or 30% WBP, corresponding to clinker contents of 65% (LC3-65) or 50% (LC3-50), were evaluated against general purpose (GP) cement mortar. Tests included setting time, flowability, soundness, compressive and flexural strengths, drying shrinkage, isothermal calorimetry, and scanning electron microscopy (SEM). Isothermal calorimetry showed peak heat flow reductions of 26% and 49% for LC3-65 and LC3-50, respectively, indicating a slower reactivity of LC3. The initial and final setting times of the LC3 mixtures were 10–30 min and 30–60 min longer, respectively, due to the slower hydration kinetics caused by the reduced clinker content. Flowability increased in LC3-50, which is attributed to the lower clinker content and higher water availability. At 7 days, LC3-65 retained 98% of the control’s compressive strength, while LC3-50 showed a 47% reduction. At 28 days, the compressive strengths of mixtures LC3-65 and LC3-50 were 7% and 46% lower than the control, with flexural strength reductions being 8% and 40%, respectively. The porosity calculated from the SEM images was found to be 7%, 11%, and 15% in the control, LC3-65, and LC3-50, respectively. Thus, the reduction in strength is attributed to the slower reaction rate and increased porosity associated with the reduced clinker content in LC3 mixtures. However, the results indicate that the performance of LC3-65 was close to that of the control mix, supporting the viability of WBP as a low-carbon partial replacement of clinker in LC3. Full article
(This article belongs to the Special Issue Towards Sustainable Low-Carbon Concrete—Second Edition)
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16 pages, 1572 KiB  
Article
Application of ANN in the Performance Evaluation of Composite Recycled Mortar
by Shichao Zhao, Yaohua Liu, Geng Xu, Hao Zhang, Feng Liu and Binglei Wang
Buildings 2025, 15(15), 2752; https://doi.org/10.3390/buildings15152752 - 4 Aug 2025
Viewed by 131
Abstract
To promote the large-scale utilization of construction and industrial solid waste in engineering, this study focuses on developing accurate prediction and optimization methods for the unconfined compressive strength (UCS) of composite recycled mortar. Innovatively incorporating three types of recycled powder (RP)—recycled clay brick [...] Read more.
To promote the large-scale utilization of construction and industrial solid waste in engineering, this study focuses on developing accurate prediction and optimization methods for the unconfined compressive strength (UCS) of composite recycled mortar. Innovatively incorporating three types of recycled powder (RP)—recycled clay brick powder (RCBS), recycled concrete powder (RCBP), and recycled gypsum powder (RCGP)—we systematically investigated the effects of RP type, replacement rate, and curing period on mortar UCS. The core objective and novelty lie in establishing and comparing three artificial intelligence models for high-precision UCS prediction. Furthermore, leveraging GA-BP’s functional extremum optimization theory, we determined the optimal UCS alongside its corresponding mix proportion and curing scheme, with experimental validation of the solution reliability. Key findings include the following: (1) Increasing total RP content significantly reduces mortar UCS; the maximum UCS is achieved with a 1:1 blend ratio of RCBP:RCGP, while a 20% RCBS replacement rate and extended curing periods markedly enhance strength. (2) Among the prediction models, GA-BP demonstrates superior performance, significantly outperforming BP models with both single and double hidden layer. (3) The functional extremum optimization results exhibit high consistency with experimental validation, showing a relative error below 10%, confirming the method’s effectiveness and engineering applicability. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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38 pages, 15791 KiB  
Article
Experimental and Statistical Evaluations of Recycled Waste Materials and Polyester Fibers in Enhancing Asphalt Concrete Performance
by Sara Laib, Zahreddine Nafa, Abdelghani Merdas, Yazid Chetbani, Bassam A. Tayeh and Yunchao Tang
Buildings 2025, 15(15), 2747; https://doi.org/10.3390/buildings15152747 - 4 Aug 2025
Viewed by 209
Abstract
This research aimed to evaluate the impact of using brick waste powder (BWP) and varying lengths of polyester fibers (PFs) on the performance properties of asphalt concrete (AC) mixtures. BWP was utilized as a replacement for traditional limestone powder (LS) filler, while PFs [...] Read more.
This research aimed to evaluate the impact of using brick waste powder (BWP) and varying lengths of polyester fibers (PFs) on the performance properties of asphalt concrete (AC) mixtures. BWP was utilized as a replacement for traditional limestone powder (LS) filler, while PFs of three lengths (3 mm, 8 mm, and 15 mm) were introduced. The study employed the response surface methodology (RSM) for experimental design and analysis of variance (ANOVA) to identify the influence of BWP and PF on the selected performance indicators. These indicators included bulk density, air voids, voids in the mineral aggregate, voids filled with asphalt, Marshall stability, Marshall flow, Marshall quotient, indirect tensile strength, wet tensile strength, and the tensile strength ratio. The findings demonstrated that BWP improved moisture resistance and the mechanical performance of AC mixes. Moreover, incorporating PF alongside BWP further enhanced these properties, resulting in superior overall performance. Using multi-objective optimization through RSM-based empirical models, the study identified the optimal PF length of 5 mm in combination with BWP for achieving the best AC properties. Validation experiments confirmed the accuracy of the predicted results, with an error margin of less than 8%. The study emphasizes the intriguing prospect of BWP and PF as sustainable alternatives for improving the durability, mechanical characteristics, and cost-efficiency of asphalt pavements. Full article
(This article belongs to the Special Issue Advanced Studies in Asphalt Mixtures)
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17 pages, 4072 KiB  
Article
Experimental Investigation of Mechanical Properties and Microstructure in Cement–Soil Modified with Waste Brick Powder and Polyvinyl Alcohol Fibers
by Xiaosan Yin, Md. Mashiur Rahman, Hongke Pan, Yongchun Ma, Yuzhou Sun and Jian Wang
Materials 2025, 18(15), 3586; https://doi.org/10.3390/ma18153586 - 30 Jul 2025
Viewed by 356
Abstract
This study investigates the synergistic modification of cement–soil using waste brick powder (WBP) and polyvinyl alcohol (PVA) fibers to address the growing demand for sustainable construction materials and recycling of demolition waste. An orthogonal experimental design was employed with 5% WBP (by mass) [...] Read more.
This study investigates the synergistic modification of cement–soil using waste brick powder (WBP) and polyvinyl alcohol (PVA) fibers to address the growing demand for sustainable construction materials and recycling of demolition waste. An orthogonal experimental design was employed with 5% WBP (by mass) and PVA fiber content (0–1%), evaluating mechanical properties based on unconfined compressive strength (UCS) and splitting tensile strength (STS) and microstructure via scanning electron microscopy (SEM) across 3–28 days of curing. The results demonstrate that 0.75% PVA optimizes performance, enhancing UCS by 28.3% (6.87 MPa) and STS by 34.6% (0.93 MPa) at 28 days compared to unmodified cement–soil. SEM analysis revealed that PVA fibers bridged microcracks, suppressing propagation, while WBP triggered pozzolanic reactions to densify the matrix. This dual mechanism concurrently improves mechanical durability and valorizes construction waste, offering a pathway to reduce reliance on virgin materials. This study establishes empirically validated mix ratios for eco-efficient cement–soil composites, advancing scalable solutions for low-carbon geotechnical applications. By aligning material innovation with circular economy principles, this work directly supports global de-carbonization targets in the construction sector. Full article
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16 pages, 3362 KiB  
Article
The Physico-Mechanical, Mineralogical, and Thermal Characterization of Geopolymeric Laterite Bricks Containing Polyethylene Terephthalate Bottle Powder
by Marcel Bertrand Hagbe Ntod, Michel Bertrand Mbog, Lionelle Bitom-Mamdem, Elie Constantin Bayiga, Rolande Aurelie Tchouateu Kamwa, Emmanuel Wantou Ngueko, Gilbert François NgonNgon, Dieudonné Bitom and Jacques Etame
J. Compos. Sci. 2025, 9(7), 320; https://doi.org/10.3390/jcs9070320 - 23 Jun 2025
Viewed by 349
Abstract
Compressed earth blocks (CEBs) obtained by laterite material geopolymerization have great potential as building materials; however, plastic waste recycling remains an important challenge for the 21st century. Samples of lateritic materials (LAT) from the locality of Kompina and its surroundings (Littoral-Cameroon) were collected, [...] Read more.
Compressed earth blocks (CEBs) obtained by laterite material geopolymerization have great potential as building materials; however, plastic waste recycling remains an important challenge for the 21st century. Samples of lateritic materials (LAT) from the locality of Kompina and its surroundings (Littoral-Cameroon) were collected, given the region’s association with polyethylene terephthalate powder (P). They were used to make geopolymeric laterite bricks using a phosphoric acid solution (A) concentrated at 10 mol/L, at a fixed value of 20% phosphoric acid, and values of 0, 5, 10, 15, and 20% polyethylene terephthalate (PET) powder. To assess the suitability of these formulations for construction, the CEBs were tested and their physico-mechanical and thermal characteristics determined, including water absorption rate, compressive strength (CS), thermal conductivity, and effusivity. It was revealed that water absorption decreased for the LAT1 and LAT6 formulas, at 6.73% and 5.01%, respectively, with the lowest value being recorded when 10% of the PET powder was used. The water absorption increased beyond this percentage; the CS values did too, with a peak at 10% PET powder, reaching 6.92 MPa and 6.96 MPa for LAT1 and LAT6, respectively, and values decreasing beyond this point. The thermal conductivity and effusivity decreased, with the lowest values at 20% of the PET powder being 0.289 W·m−1·K−1 and 1078.46 J·K−1·m−2·s−1/2, and 0.289 W·m−1·K−1 and 1078.2 J·K−1·m−2·s−1/2 for LAT1 and LAT6, respectively. Based on the results obtained, we conclude that the formulation LAT-P10A20 is the most recommendable. Full article
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22 pages, 4653 KiB  
Article
Recycled Clay Brick Powder as a Dual-Function Additive: Mitigating the Alkali–Silica Reaction (ASR) and Enhancing Strength in Eco-Friendly Mortar with Hybrid Waste Glass and Clay Brick Aggregates
by Xue-Fei Chen, Xiu-Cheng Zhang and Ying Peng
Materials 2025, 18(12), 2838; https://doi.org/10.3390/ma18122838 - 16 Jun 2025
Viewed by 467
Abstract
The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica [...] Read more.
The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica reaction (ASR) inhibitor in hybrid mortar systems incorporating recycled glass (RG) and recycled clay brick (RCB) aggregates. Leveraging the pozzolanic activity of RCBP’s residual aluminosilicate phases, the research quantifies its influence on mortar durability and mechanical performance under varying substitution scenarios. Experimental findings reveal a nonlinear relationship between RCBP dosage and mortar properties. A 30% cement replacement with RCBP yields a 28-day activity index of 96.95%, confirming significant pozzolanic contributions. Critically, RCBP substitution ≥20% effectively mitigates ASRs induced by RG aggregates, with optimal suppression observed at 25% replacement. This threshold aligns with microstructural analyses showing RCBP’s Al3+ ions preferentially reacting with alkali hydroxides to form non-expansive gels, reducing pore solution pH and silica dissolution rates. Mechanical characterization reveals trade-offs between workability and strength development. Increasing RCBP substitution decreases mortar consistency and fluidity, which is more pronounced in RG-RCBS blends due to glass aggregates’ smooth texture. Compressively, both SS-RCBS and RG-RCBS mortars exhibit strength reduction with higher RCBP content, yet all specimens show accelerated compressive strength gain relative to flexural strength over curing time. Notably, 28-day water absorption increases with RCBP substitution, correlating with microstructural porosity modifications. These findings position recycled construction wastes and glass as valuable resources in circular economy frameworks, offering municipalities a pathway to meet recycled content mandates without sacrificing structural integrity. The study underscores the importance of waste synergy in advancing sustainable mortar technology, with implications for net-zero building practices and industrial waste valorization. Full article
(This article belongs to the Section Construction and Building Materials)
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29 pages, 6425 KiB  
Article
Experimental and Explicit FE Studies on Flexural Behavior of Superposed Slabs
by Qi Ye, Ping Zhang, Ke Ye, Wei Wang, Zeshen Li, Yueqing Gao, Tianyu Xie and Chaofeng Liang
Buildings 2025, 15(10), 1758; https://doi.org/10.3390/buildings15101758 - 21 May 2025
Viewed by 461
Abstract
This study explores the use of recycled brick powder (PRB), derived from waste bricks, and calcined recycled slurry powder (PCRS), sourced from waste cement blocks, as partial replacements for cement and fly ash in concrete. These materials can be [...] Read more.
This study explores the use of recycled brick powder (PRB), derived from waste bricks, and calcined recycled slurry powder (PCRS), sourced from waste cement blocks, as partial replacements for cement and fly ash in concrete. These materials can be utilized to produce concrete with favorable engineering properties. Five concrete mixtures with varying PRB/PCRS proportions were prepared. Uniaxial monotonic compression tests were conducted to generate stress-strain curves for each mixture. Corresponding physical superposed slabs were fabricated, and finite element (FE) models were developed for each slab. Both physical testing and explicit FE simulations were performed to evaluate the flexural performance of the slabs. The results demonstrated that the flexural performance of the PRB/PCRS recycled micro-powder concrete slabs was comparable to that of conventional concrete slabs. Notably, the slab incorporating a 1:1 mixture of PRB and PCRS instead of fly ash exhibited the highest yield and ultimate bearing capacities, reaching 99.3% and 98.4% of those of the conventional concrete slab, respectively. The FE simulations accurately predicted the flexural performance, with maximum deviations of 8.9% for the yield load and 6.5% for the ultimate load. Additionally, the simulation-based energy time-history curve provides valuable insights into the progression of slab cracking. This study contributes to the advancement of research on the engineering and mechanical performance of concrete members incorporated with PRB/PCRS. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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16 pages, 7577 KiB  
Article
Eco-Fired Bricks from Phosphate Mine Waste Rocks: The Effects of Marble Waste Powder on the Physical and Microstructural Properties
by Ayoub Bayoussef, Samira Moukannaa, Mohamed Loutou, Yassine Taha, Mostafa Benzaazoua and Rachid Hakkou
Ceramics 2025, 8(2), 48; https://doi.org/10.3390/ceramics8020048 - 1 May 2025
Viewed by 832
Abstract
Nowadays, the global brick industry utilizes billions of cubic meters of clay soil annually, resulting in the massive consumption of non-renewable resources. This study explores the viability of utilizing red marl from phosphate mining waste rocks for fired brick production. Ecofriendly fired bricks [...] Read more.
Nowadays, the global brick industry utilizes billions of cubic meters of clay soil annually, resulting in the massive consumption of non-renewable resources. This study explores the viability of utilizing red marl from phosphate mining waste rocks for fired brick production. Ecofriendly fired bricks produced from 100% side streams (red marly clays (RM) and marble waste powder (MWP)) were prepared, pressed, dried at 105 °C, and then fired at 1100 °C for 1 h. The effects of marble waste powder addition (up to 30 wt%) on the physical, mechanical, mineralogical, and microstructural properties of the fired bricks were explored. The main results show that fired bricks with high compressive strength of a maximum of 39 MPa could be prepared with a mixture of red marl and 10 wt% of marble waste powder. The thermal conductivity was decreased by marble waste addition (from 0 to 30%) and was reduced from 0.93 W/m.k to 0.53 W/m.k; however, the compressive strength was also decreased to reach a minimum of 17 MPa. The firing shrinkage and density were also reduced with 30% marble waste by 41% and 18%, respectively. Therefore, red marly clays and marble waste could be promising raw materials for eco-fired brick production. Full article
(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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12 pages, 1469 KiB  
Article
Thermal Optimization of Earth Bricks Using Néré Husk (Parkia biglobosa)
by Magnouréwa Josiane Tossim, Elhadji Dieng, Kpatchaa Lidawou Bafei, Cyprien Coffi Aholou and Yawovi Mawuénya Xolali Dany Ayité
Constr. Mater. 2025, 5(2), 18; https://doi.org/10.3390/constrmater5020018 - 28 Mar 2025
Viewed by 447
Abstract
Integrating local, bio-sourced materials, such as earth and agricultural waste like dwarf hulls, is a sustainable solution to the challenges of climate change and increasing urbanization. The use of bio-based materials such as néré husk (Parkia biglobosa) in the manufacture of [...] Read more.
Integrating local, bio-sourced materials, such as earth and agricultural waste like dwarf hulls, is a sustainable solution to the challenges of climate change and increasing urbanization. The use of bio-based materials such as néré husk (Parkia biglobosa) in the manufacture of compressed earth bricks is a sustainable alternative for improving their thermal performance. This study assesses the impact of adding hulls in different forms (fine powder < 0.08 mm, aggregates from 2 mm to 5 mm, and aqueous maceration) on the thermal conductivity and effusivity of bricks. The tests were carried out using the asymmetric hot plane method, applying a constant heat flux and measuring the temperature variation via a thermocouple. Three samples of each formulation were analyzed to ensure the reliability of the results. The results show that the addition of fine powdered husk reduces the thermal conductivity of the bricks to 0.404 W/m.K and their effusivity to 922.2 W/(Km2) s1/2, compared with 0.557 W/m.K and 1000.32 W/(Km2) s1/2 for the control bricks. The addition of coarser aggregates (2 mm–5 mm) gives intermediate values (0.467 W/m.K and 907.99 W/(Km2) s1/2). Aqueous maceration, on the other hand, results in an increase in thermal conductivity to 0.614 W/m.K. These results confirm that the shape and method of incorporation of the husk influence the thermal performance of the bricks, with fine powder offering the best thermal insulation. This approach highlights the potential of bio-based materials for eco-responsible construction. Full article
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12 pages, 9168 KiB  
Article
A Study on the Uniaxial Compressive Constitutive Characteristics of Phosphogypsum-Based Irregular-Shaped Bricks (PG-ISBs) for Underground Filling Retaining Walls
by Jixiang Jiang, Guihong Xu, Zhenhua Zhao, Hejun Li, Mingwei He, Wenqi Wu and Ziwei Chen
J. Compos. Sci. 2025, 9(4), 157; https://doi.org/10.3390/jcs9040157 - 25 Mar 2025
Viewed by 358
Abstract
This study investigated the mechanical properties of a cementitious material used to prepare irregular-shaped brick masonry structures (PG-ISBs) from industrial solid wastes, including phosphogypsum, calcium powder, cementitious agents, and construction brick debris. The hydration products, microstructure, and elemental composition of the system were [...] Read more.
This study investigated the mechanical properties of a cementitious material used to prepare irregular-shaped brick masonry structures (PG-ISBs) from industrial solid wastes, including phosphogypsum, calcium powder, cementitious agents, and construction brick debris. The hydration products, microstructure, and elemental composition of the system were analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Based on the experimental stress–strain relationship curves, a constitutive model for the cementitious material was established. The results show that the compressive strength of the PG-ISB cementitious material meets the requirements for filling retaining walls. SEM observations reveal a significant number of micro-pores within the PG-ISB cementitious material, which are important factors affecting its strength. An empirical constitutive model for the uniaxial compression of the specimen was established based on the experimental stress–strain full curves, and the fitting curves showed good agreement with the experimental data. Full article
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23 pages, 9572 KiB  
Article
Investigation on Mix Proportions of Ultra-High Performance Concrete with Recycled Powder and Recycled Sand
by Peng Zhu, Shijie Du, Phirun Heng, Lianzhen Zhang, Shengdong Zhang and Yuching Wu
Buildings 2025, 15(7), 1048; https://doi.org/10.3390/buildings15071048 - 25 Mar 2025
Viewed by 567
Abstract
The construction waste of brick and concrete can be used to produce recycled powder and recycled sand, which can replace cement and natural sand, respectively, in concrete. This can reduce the cost of concrete, reutilize construction waste and decrease environmental pollution. The idea [...] Read more.
The construction waste of brick and concrete can be used to produce recycled powder and recycled sand, which can replace cement and natural sand, respectively, in concrete. This can reduce the cost of concrete, reutilize construction waste and decrease environmental pollution. The idea of producing UHPC incorporating both RP and RS by standard curing instead of steam curing is proposed in this study. The optimal mixture design of ultra-high-performance concrete (UHPC) with both recycled powder and recycled sand is investigated. Based on the revised Dinger–Funk model, the optimal mix proportions of green UHPC (GUHPC) with recycled powder and recycled sand were calculated on this basis, and the effects of the superplasticizer content, water–binder ratio, recycled powder and recycled sand replacement ratio on the workability and mechanical properties of GUHPC at different ages were investigated through the designed experimental program. The test results show that when the superplasticizer to cementitious material ratio was 0.8%, the flowability and the 28 d compressive strength were highest. When the water–binder ratio was 0.16, the flexural strength and compressive strength of the GUHPC at different ages were the largest. As the replacement ratio of the recycled powder increased, the workability of the GUHPC decreased. However, even when replacement ratio of recycled powder was 30%, the flowability was still higher than 180 mm. The flexural strength and the 28 d compressive strength increased first and then decreased. Compared with mixtures without RP, the 28 d compressive strength increased by 6.4% and reached the maximum value when the replacement ratio of the RP was 30%. The comprehensive contribution of recycled powder to the strength was analyzed. Recycled powder can enhance the contribution of cement to GUHPC strength, and the enhancement effect increases with increases in the recycled powder content and age. The optimal replacement ratio of recycled powder is 30%. As the replacement ratio of the recycled sand increased, the flowability of the GUHPC first increased and then decreased, and the flexural and compressive strength decreased. The toughness was analyzed by the flexural strength to compressive strength ratio (f:c). With increases in the recycled sand, the f:c at 3 d of age increased, the f:c at 7 d of age showed no significant change, and the f:c at 28 d of age first increased and then decreased. The f:c at 28 d of age reached a maximum value of 0.316 when the replacement ratio of recycled sand was 50%. Therefore, the replacement ratio of the recycled sand was selected to be 50%. The optimum mix proportions of GUHPC were obtained by considering the workability, mechanical properties and amount of recycled material. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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18 pages, 9061 KiB  
Article
Preparation and Performance Optimization of Lead–Zinc Tailing Sintered Bricks
by Dongliang He, Yanhui Cheng, Rui Li and Hang Lin
Materials 2025, 18(6), 1381; https://doi.org/10.3390/ma18061381 - 20 Mar 2025
Cited by 1 | Viewed by 506
Abstract
Lead–zinc tailings are waste materials generated from mineral processing and smelting, and their long-term accumulation poses potential threats to the environment and soil. To achieve resource recycling and sustainable development, this study used lead–zinc tailings and clay as raw materials and glass powder [...] Read more.
Lead–zinc tailings are waste materials generated from mineral processing and smelting, and their long-term accumulation poses potential threats to the environment and soil. To achieve resource recycling and sustainable development, this study used lead–zinc tailings and clay as raw materials and glass powder as a modifier to prepare modified lead–zinc tailing sintered bricks. Through full-factor experiments and single-factor experiments, the effects of the material proportions, the sintering temperature, and the holding time on the properties of the sintered bricks were investigated. The results show that the addition of glass powder significantly enhanced the compressive strength of the sintered bricks, reduced their water absorption rate, and improved their volume shrinkage rate. The optimal preparation conditions were as follows: 9% glass powder content, 90% lead–zinc tailings content, a sintering temperature of 1060 °C, and a holding time of 60 min. The resulting sintered bricks met the MU30-strength-grade requirements of the national standard for ordinary sintered bricks (GB/T5101-2017). The sintering temperature has a significant impact on brick performance; the compressive strength first increases, and then decreases, the water absorption rate continues to decrease, and volume change shifts from expansion to contraction. The influence of holding time was relatively weaker, but as the holding time increased, the compressive strength and the water absorption rate of the sintered bricks gradually stabilized. XRD and SEM analyses indicated that the minerals in the lead–zinc tailings decomposed and recrystallized during the sintering process. The liquid phase melt from the glass powder filled the pores and enhanced skeletal strength, thereby improving the microstructure and properties of the sintered bricks. The research findings provide a theoretical basis and practical guidance for the efficient utilization and building material application of lead–zinc tailings. Full article
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19 pages, 7976 KiB  
Article
La/Fe-Bimetallic-Modified Red Brick Powder for Phosphate Removal from Wastewater: Characterization, Adsorption, and Mechanism
by Yunrui Zhao, Hui Luo, Rubin Han, Shiheng Tao, Meng Liu, Ming Tang, Jiayao Xing, Limin Chen and Bao-Jie He
Materials 2025, 18(6), 1326; https://doi.org/10.3390/ma18061326 - 17 Mar 2025
Viewed by 439
Abstract
The use of construction waste red brick powder (RBP) to prepare adsorbents for phosphate removal from wastewater represents a promising technology with substantial research potential. This study investigates the preparation of La-based magnetic red brick powder (La-Fe-RBP) via bimetallic modification to enhance its [...] Read more.
The use of construction waste red brick powder (RBP) to prepare adsorbents for phosphate removal from wastewater represents a promising technology with substantial research potential. This study investigates the preparation of La-based magnetic red brick powder (La-Fe-RBP) via bimetallic modification to enhance its adsorption performance. The key characteristics, adsorption process, adsorption mechanism, and practical applications of the modified adsorbent were analyzed. The obtained results suggested that the underlying adsorption mechanism of La-Fe-RBP was best described by the Langmuir and pseudo-second-order kinetic models, which suggested that the adsorption mechanism was monolayer chemical adsorption. La-Fe-RBP exhibited rapid kinetics, achieving adsorption saturation in just 40 min, significantly faster than RBP (360 min). Additionally, isotherm experiments determined the highest theoretical adsorption capacity as 42.835 mg/g. More importantly, La-Fe-RBP exhibited efficient phosphate adsorption within a pH ranging from 3 to 8. Furthermore, La-Fe-RBP exhibited high selectivity for phosphate ions in the presence of coexisting ions (SO42, NO3, Cl, HCO3, Mg2+, and Ca2+), demonstrating its robustness and effectiveness in complex water conditions. FTIR and XPS analyses demonstrated that ligand exchange and electrostatic attraction were the primary mechanisms underlying phosphate adsorption by La-Fe-RBP. Domestic sewage treated with La-Fe-RBP met the Class IV surface water environmental quality standards in China. The findings of this study prove that the La-Fe-RBP composite material, characterized by high adsorption efficiency and strong selectivity, holds significant potential for removing phosphates from real wastewater. Full article
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31 pages, 10329 KiB  
Article
Sustainable Utilization of Waste Glass Powder and Brick Dust as Cement Replacements: Effects on Mortar Performance and Environmental Benefits
by Balikis Omotola Rabiu and Mohammad Ali Mosaberpanah
Sustainability 2025, 17(3), 1298; https://doi.org/10.3390/su17031298 - 5 Feb 2025
Viewed by 1611
Abstract
With respect to sustainability, the material must maintain the quality and properties of concrete and be safe for human health, the environment, and long-time use. In recent times, the emission of CO2 from cement production processes has lessened with the passage of [...] Read more.
With respect to sustainability, the material must maintain the quality and properties of concrete and be safe for human health, the environment, and long-time use. In recent times, the emission of CO2 from cement production processes has lessened with the passage of time due to its effect on the environment. In order to lessen the emissions and reduce environmental waste, available by-products with pozzolanic properties are applied. With respect to Portland limestone cement (CEMI II-BL), i.e., cement with lower carbon dioxide emissions and better workability than CEM I, the two main materials applied in the study as substitutes are brick dust (BD) and waste glass powder (WGP) bottles. Waste glass powder and brick dust, in quantities varying from 5% to 10%, 15%, and 20%, with a water/cement ratio of 0.35 and a 1.5% superplasticizer, were utilized to observe the effectiveness of BD and WGP on the flowability, compressive strength, flexural strength, water absorption, density, drying shrinkage, and fire resistance of the specimen mortar. The output shows that a WGP of 20% increased flowability compared to the control, whereas the inclusion of brick dust decreased it. At the age of 28, glass powder of 20% increased the compressive strength, while 20% brick dust exhibited a reduction; 15% WGP with 5% BD displayed the lowest absorption of water; and the density of all the samples proved to be much lower than the traditional mix, with 20% BD being the lowest (hereby labeled as light mortar). The 10% WGP with 10% BD displayed better resistance to fire, and the drying shrinkage of the sample was relatively low after several days of air curing. The impact on the environment and cost were considered without accounting for the transportation and manufacturing energy. As to the outcome of this experiment, we concluded that the use of both brick dust and glass powder with CEM II for producing mortar has proven very promising in a variety of different respects, including the mechanical and fresh features of mortar, with the combination of 5% WGP and 15% BD exhibiting the most potential in all of the acquired parameters. Full article
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23 pages, 15546 KiB  
Article
Sustainable Alkali-Activated Self-Compacting Concrete for Precast Textile-Reinforced Concrete: Experimental–Statistical Modeling Approach
by Vitalii Kryzhanovskyi and Jeanette Orlowsky
Materials 2024, 17(24), 6280; https://doi.org/10.3390/ma17246280 - 22 Dec 2024
Cited by 1 | Viewed by 1167
Abstract
Industrial and construction wastes make up about half of all world wastes. In order to reduce their negative impact on the environment, it is possible to use part of them for concrete production. Using experimental–statistical modeling techniques, the combined effect of brick powder, [...] Read more.
Industrial and construction wastes make up about half of all world wastes. In order to reduce their negative impact on the environment, it is possible to use part of them for concrete production. Using experimental–statistical modeling techniques, the combined effect of brick powder, recycling sand, and alkaline activator on fresh and hardened properties of self-compacting concrete for the production of textile-reinforced concrete was investigated. Experimental data on flowability, passing ability, spreading speed, segregation resistance, air content, and density of fresh mixtures were obtained. The standard passing ability tests were modified using a textile mesh to maximize the approximation to the real conditions of textile concrete production. To determine the dynamics of concrete strength development, compression and flexural tests at the ages of 1, 3, 7, and 28 days and splitting tensile strength tests of 28 days were conducted. The preparation technology of the investigated modified mixtures depending on the composition is presented. The resulting mathematical models allow for the optimization of concrete compositions for partial replacement of slag cement with brick powder (up to 30%), and natural sand with recycled sand (up to 100%) with the addition of an alkaline activator in the range of 0.5–1% of the cement content. This allows us to obtain sustainable, alkali-activated high-strength self-compacting recycling concrete, which significantly reduces the negative impact on the environment and promotes the development of a circular economy in the construction industry. Full article
(This article belongs to the Special Issue Artificial Intelligence in Materials Science and Engineering)
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