Search Results (129)

In a bid to investigate the optimum transportation method for offshore wind-produced hydrogen (H₂) and assess the feasibility of repurposing the existing oil and gas infrastructure for H₂ transmission, this paper assesses the existing H₂ transportation methods with a comprehensive review of the H₂ impact on the existing natural gas pipeline infrastructure. To establish the possibility of repurposing the existing natural gas (NG) pipelines for H₂ gas transport, this paper reviews the influential technical measures—composition, pressure, temperature, volumetric energy density, density, and pressure drop—to assess whether the characteristics of hydrogen gas are compatible with the natural gas pipeline infrastructure. Based on these reviews, it was found that the current NG pipeline pressure exacerbates the H₂ embrittlement; for the existing NG pipelines to be repurposed, the operating pressure should be reduced, and the pipeline material should be revised. It was found that higher strength steels can be re-used with major modifications, or the pipeline should be constructed from material grade X52 or below. Nevertheless, the fitness of the existing NG pipelines for H₂ transmission should be assessed on a case-by-case basis and other factors such as erosion, leakage, pressure cycling, monitoring (e.g., distributed fiber-optic sensing technology) and a rigorous assessment of welds and joints should also be considered. Full article

Bamboo is widely available and renewable. Using bamboo blocks to partially replace coarse aggregates in the production of concrete solid bricks shows promising application prospects in areas such as nonload-bearing wall materials. However, as a natural biomass material, bamboo squares have disadvantages such as susceptibility to decay, water absorption, swelling, and drying shrinkage, necessitating modification when used as concrete coarse aggregate. This study subjected raw bamboo squares to high-temperature carbonization. The compressive performance of concrete made with these carbonized bamboo squares was first tested and compared with concrete containing raw bamboo squares. Subsequently, both raw and carbonized bamboo squares were modified using conventional methods: polyvinyl alcohol (PVA) treatment, epoxy mortar (EM) treatment, epoxy resin (EPR) treatment, water glass (WG) treatment, and glutinous rice glue treatment. Modified bamboo block concrete specimens were prepared, and their compressive strengths were tested and compared. The results indicated that the compressive mechanical performance of carbonized bamboo block concrete consistently outperformed that of raw bamboo block concrete across all substitution rates. Specifically, the optimal modification method—using epoxy mortar (EM) encapsulation—significantly enhanced the mechanical properties. At a high volumetric replacement rate of 30%, the EM-modified carbonized bamboo concrete achieved a compressive strength of 27.79 MPa, which is 15.1% higher than that of identically treated raw bamboo concrete and far exceeds the standard MU7.5 grade requirements. These quantitative findings provide a solid experimental and theoretical basis for the high-value application of bamboo squares in sustainable concrete solid bricks. Full article

The decarbonization of marine transport requires the wider use of alternative low-carbon fuels that can be applied in existing compression ignition (CI) engines without major modifications. Hydrotreated vegetable oil (HVO) is considered a promising renewable drop-in fuel due to its favorable physicochemical properties and high cetane number. This study investigates the influence of neat HVO and its blends with conventional diesel fuel on the combustion characteristics, energy, and emission indicators of a CI engine operating under different load conditions and exhaust gas recirculation (EGR) ratios. Experimental tests were carried out on a four-cylinder CI engine at constant speed and variable load using diesel fuel (D100), HVO100, and their blends (D80_HVO20 and D50_HVO50). In-cylinder pressure measurements and combustion analysis were performed using AVL instrumentation and AVL BOOST software. The results show that increasing the HVO fraction slightly advances combustion phasing and increases maximum in-cylinder pressure by approximately 4–5%. The use of HVO was found to reduce brake-specific fuel consumption by up to 3.4% and increase brake thermal efficiency by about 1.9%, although volumetric fuel consumption increases due to the lower fuel density. In addition, higher HVO content significantly reduces smoke opacity by up to 42% and decreases CO₂ emissions by 4.7–6.3%, while the influence on NO_x emissions depends on the applied EGR strategy. The results indicate that HVO and its blends can be effectively applied in CI engines; however, optimal performance and emission characteristics require appropriate calibration of EGR rate and fuel injection timing. Full article

Amidst the high global reliance on petroleum, this study addresses energy inefficiency in beam-pumping units used for oil extraction. We developed a tubular solid–liquid triboelectric nanogenerator (TENG) based on fluorinated polydimethylsiloxane (PDMS) films. Self-assembled surface modification with fluorosilane molecular chains enhanced charge transfer, achieving a 2.7-fold increase with 13F-PDMS. The enclosed tubular design utilizes periodic liquid-electrode contact to generate a volumetric effect. Experiments investigated the influence of liquid composition and device configuration on performance. Using a 1.69 mol/L FeCl₃ solution with four series-connected units, the TENG reached 29 V and 263 nA, powering 150 LEDs. This demonstrates its potential for harvesting reciprocating mechanical energy from pumping units to reduce operational energy consumption. Full article

Objectives: To evaluate the effectiveness of different optimization parameters on radiotherapy plan quality for seventeen head and neck cancer patients. Methods: Volumetric Modulated Arc Therapy with Simultaneous Integrated Boost (VMAT-SIB) plans, involving up to three tumors, were generated. For each participant, a reference plan (Plan_Ref) was created using dual-arc with 180 control points, 20° gantry-angle increment and 1 cm minimum segment width. Modified plans were developed with dose constraints and optimization settings constant by changing to single-arc, 150 and 200 control points, 0.5 cm minimum segment width, and 30° and 40° gantry-angle increments. These plans were referred to as Plan_Arc1, Plan_CP150, Plan_CP200, Plan_SW0.5, Plan_Inc30, and Plan_Inc40, respectively. D_95% of planning target volumes (PTVs), homogeneity index (HI), monitor units (MUs), maximum dose (D_max) of spinal cord, mandible, and brainstem were recorded. Statistical and Bland–Altman analysis was performed comparing the modified plans to Plan_Ref. Results: Average D_95% values for PTV1, PTV2, and PTV3 ranged from 93.13 to 98.82%. Plan_SW0.5 provided superior target coverage and homogeneity with higher MUs than Plan_Ref. Plan_Arc1 significantly reduced PTV coverage and dose homogeneity, while increasing MUs compared with Plan_Ref (p < 0.05). The average D_max as derived from all planning approaches was up to 43.86 Gy, 65.86 Gy, and 48.85 Gy for spinal cord, mandible and brainstem, respectively. For spinal cord, Plan_Ref led to significantly lower doses compared to Plan_Arc1 and Plan_Inc30, while the brainstem recorded statistically higher D_max doses than Plan_Arc1. Significantly higher D_max was observed for the mandible using Plan_SW0.5 (p < 0.05). However, for D_max, the comparison plans showed good agreement with Plan_Ref based on Bland–Altman analysis. Conclusions: The VMAT plan quality is strongly affected by the minimum segment width whereas no differences were observed with the modification of the number of control points. Full article

Laser powder bed fusion (LPBF) of AA7075 is severely constrained by a narrow process window and susceptibility to defect formation (hot cracking and porosity), which often dominates performance. In this study, 5 wt.% AlCoCrFeNi_2.1 high-entropy alloy (HEA) particles, volumetric energy density (VED = 74–222 J·mm⁻³), and subsequent T6 heat treatment were systematically investigated to reveal their combined effects on defect structure, crystallographic texture/substructure, and tensile behaviour. Quantitative EBSD shows a measurable grain refinement in the as-built state (average grain size 13.44 → 11.80 µm, ~12%) accompanied by a pronounced weakening of the <001> fibre texture (maximum MRD 4.94 → 2.38), indicating disrupted epitaxial growth and a more dispersed orientation distribution. After T6, the reinforced alloy retains a higher low-angle boundary fraction (31.62% vs. 24.17% in unreinforced AA7075) and a higher kernel average misorientation (0.80° vs. 0.60°), consistent with particle-stabilised substructure retention and retarded recovery. Across all VEDs, AA7075-HEA exhibits higher microhardness (compared with AA7075, the addition of HEA increases the hardness by roughly 20–50 HV) and tensile strength, with the intermediate VED (140.74 J·mm⁻³, T6 states) yielding the best performance. While macroscopic cracking is not fully eliminated, the results clarify that HEA-enabled texture/substructure modifications can contribute to enhanced defect tolerance and are more effectively translated into tensile performance when the as-built defect severity is controlled. These findings provide quantitative insights into defect–microstructure–property coupling in LPBF AA7075-HEA composites from as-built to T6 states. Full article

Metal hydride-based hydrogen storage reactors combine high volumetric hydrogen density with intrinsic safety, yet their performance is fundamentally limited by inefficient thermal management arising from the strong coupling among heat transfer, thermodynamics, and reaction kinetics. The highly exothermic and endothermic nature of hydrogen absorption and desorption requires rapid and spatially uniform heat removal or supply, which is difficult to achieve due to the low thermal conductivity and complex internal structure of hydride beds. This review presents a mechanistic and architectural overview of thermal management in metal hydride hydrogen storage reactors. Key heat transfer limitations within hydride beds are first analyzed, followed by a systematic classification and critical comparison of major thermal management architectures, including bed-level modifications, structural reactor designs, and heat-exchanger intensification strategies such as embedded tubes, fins, and phase-change materials. The advantages and limitations of these approaches are discussed in terms of heat transfer efficiency, hydrogen storage capacity, structural complexity, and scalability. Finally, the review highlights the central design trade-offs governing compactness, efficiency, and manufacturability, and outlines future directions toward application-oriented and scalable reactor design through integrated thermal and structural optimization. Full article

Acoustic precipitation enhancement (APE) is an emerging non-chemical weather-modification technique, yet quantitative three-dimensional evidence of its impact on rainy clouds remains scarce. This study investigates a stratiform precipitation event over the Bayinbuluke Basin in the central Tianshan Mountains of northwestern China, 29–30 August 2024, using an X-band phased-array weather radar (X-PAR) coordinated with an upward-directed acoustic source. Rapid volumetric scans and sector-aligned range-height indicators were combined to reconstruct the three-dimensional cloud structure before, during, and after acoustic operation. During acoustic operation, the results were stronger and more persistent than during the non-operation period, with localized values exceeding 40 dBZ. Within the 3 km influence zone, low-level reflectivity increased across all azimuthal sectors with clear directional dependence. Dual-ratio analysis showed statistically significant enhancement in the windward sector (247°, $DR$ = 1.91, $p$ = 0.0004) and the leeward sector (137°, $DR$ = 1.51, $p$ = 0.008), indicating that acoustic-induced responses extended beyond the primary radiation sector and propagated downstream with cloud advection. These results, based on a single stratiform precipitation case, demonstrate that volumetric X-PAR observations can detect localized cloud-structure responses during acoustic operation. Full article

Anthropogenic CO₂ emissions have accelerated climate change, prompting the need for effective capture technologies. Adsorption using clay-based sorbents offers an eco-friendly alternative, although performance often requires enhancement. This study explored mechanochemical modification of two halloysite-rich kaolin clay samples—iron-poor (Hal) and iron-rich (HalFe)—using locust bean gum and quillaja saponin and compared their CO₂ uptake with the calcined counterparts (CHal, CHalFe). All samples were characterized using standard techniques, and their CO₂ uptake was measured volumetrically across 0.1–20 bar and 15–35 °C. Modified sorbents showed enhanced mesoporosity and binding sites, increasing CO₂ uptake by up to 26% at 20 bar (11.85 mg/g) and 125% at 1 bar (2.25 mg/g). Calcination, however, reduced surface area and sorption capacity. Isosteric heat values remained within the physisorption range, as supported by FTIR, XRF, and XPS, which showed no bulk carbonate formation. These sorbents show lower CO₂ uptakes than conventional ones. Yet their low costs, abundance, biocompatibility, and solvent-free synthesis indicate strong potential for large-scale applications, especially for low-pressure implementations such as landfills. Further detailed studies on kinetics, thermodynamics, and sorbent regeneration are needed. Spent sorbents can potentially be repurposed for subsequent use in other applications, e.g., water treatment, construction materials, thereby minimizing waste production and supporting circular economy principles. Full article

The goal of brain metastasis therapy is to reduce the risk of intracranial disease progression and to minimize treatment-related adverse effects and loss of neurologic function without compromising extracranial disease control. A response assessment system plays a critical role in the comparative evaluation of therapeutic strategies in clinical trials and in routine patient care. Since 2015, the RANO-BM criteria have become a standard schema for evaluating brain metastases treatment response, providing uniform definitions and methodology particularly practical in prospective clinical trials of systemic therapy. There have been a variety of modifications and additions to the original guidelines proposed to improve their utility for brain metastases response assessment, including lowering the measurable disease size threshold, optimizing disease progression metrics, and employing tumor volumetric analysis using automated measurement tools. However, despite these enhancements, the criteria display limitations in selected clinical scenarios. This article provides a detailed overview of these limitations and their corresponding clinical contexts and concludes with a discussion of approaches which may aid in the development of a more comprehensive brain metastases response assessment system. Full article

18CrNiMo7-6 steel is widely used in high-load mechanical components, but its poor surface hardness and corrosion resistance limit its service life. This study performed vacuum solid boriding treatment on 18CrNiMo7-6 steel at 1000 °C for different times and investigated the phase composition, microstructure, hardness, surface morphology, and corrosion resistance of the resulting boride layers. The experimental results showed that the boriding treatment formed a dual-phase boride layer on the steel surface, consisting of an outer FeB layer and an inner Fe₂B layer, both of which increased in thickness with increasing boriding time. The surface hardness was significantly enhanced due to the formation of hard boride phases, exhibiting a gradient distribution that correlates with the microstructural transition from the surface to the substrate. The surface roughness exhibited a progressive increase with boriding time, which was attributed to the volumetric expansion and nodular growth associated with boride formation. Furthermore, the corrosion resistance was remarkably improved after boriding and was further enhanced with longer processing times. This improvement is attributed to the thickening and enhanced continuity of the boride layer over time, which mitigated the potential adverse effects of surface roughness. This study demonstrates that vacuum high-temperature boriding effectively co-enhances the surface hardness and corrosion resistance of alloy steel, providing a viable surface modification strategy for high-load components. Full article

This paper addresses critical issues related to the structural design of a micro-factory housing a mobile 3D printing system for plastic recycling. Rather than a simple comparison, it quantifies the “modification penalty”, the structural and economic cost of retrofitting a repurposed ISO shipping container (ISCC) versus deploying a purpose-built cold-formed steel (CFS) volumetric structure. Finite Element Analysis of a standard 20-foot shipping container revealed a serviceability failure in its roof under standard imposed loads. Concurrently, an initial analysis of an equivalent CFS structure also indicated non-compliance, with significant floor and roof deflections. Both platforms were subsequently redesigned with structural reinforcements to achieve full compliance with Australian Standards. The comparative evaluation moves beyond static analysis to incorporate critical performance metrics. While the CFS structure proved to be 575 kg lighter with a lifespan 300–400% longer, the modified ISCC was 47% cheaper in initial capital outlay ($7161 vs. $13,549). However, when considering the totality of performance factors, specifically the ISCC’s inherent vulnerability to resonance (8–18 Hz), which overlaps with transport frequencies, and the logistical burden of losing CSC certification upon modification, the CFS platform is conclusively identified as the superior engineering solution. Its design flexibility, predictable performance, and amenability to purpose-built optimization make it a more reliable and operationally secure platform for this specialized application. Full article

Background: Artificial intelligence (AI) integrated with cone-beam computed tomography (CBCT) has rapidly advanced the diagnostic capability of orthodontics, particularly for quantifying external root resorption (ERR). High-risk scenarios such as bilateral maxillary canine impaction require objective tools to guide treatment decisions and prevent irreversible damage. Objectives: To evaluate the diagnostic accuracy and clinical applicability of AI-assisted CBCT for orthodontically induced ERR, and to demonstrate its value in a complex clinical case where decision-making regarding canine traction versus extraction required precise risk quantification and definition of biological limits. Methods: A systematic review following PRISMA 2020 guidelines was conducted in PubMed, ScienceDirect, and Cochrane Library (2015–September 2025). Eligible studies applied AI-enhanced CBCT to assess ERR in orthodontic patients. Additionally, a clinical case with bilaterally impacted maxillary canines was evaluated using CBCT with automated AI segmentation and manual refinement to quantify root volume changes and determine prognostic thresholds for treatment modification. Results: Nine studies met the inclusion criteria. AI-based imaging, predominantly convolutional neural networks, showed high diagnostic accuracy (up to 94%), improving reproducibility and reducing operator dependency. In the clinical case, volumetric monitoring showed rapid progression of ERR in the lateral incisors (LI) associated with a persistent unfavorable 3D spatial relationship between the canines and incisor roots, despite controlled distal traction with skeletal anchorage, leading to a timely change in the treatment plan and extraction of the severely compromised incisors with substitution by the canines. AI-generated data provided objective evidence supporting safer decision-making and prevented further structural deterioration. Conclusions: AI-enhanced CBCT enables early, objective, and quantifiable ERR assessment, strengthening prognosis-based decisions in orthodontics. Findings of this review and the clinical case highlight the translational relevance of AI for managing high-risk cases, such as maxillary canine impaction with extensive LI resorption, supporting future predictive AI models for safer canine traction. Full article

Direct ink writing (DIW) deposits viscous, shear-responsive inks at low temperature, enabling hydrogels and cell-laden bioinks for biomedical fabrication. Access to DIW remains limited by the cost of dedicated systems and the complexity of custom motion control. Repurposing fused deposition modeling (FDM) printers lowers these barriers by using accurate motion stages, open firmware, and familiar workflows while preserving build volume. In this study, three DIW actuator designs were implemented on an FDM frame. The first used a gear-and-rail transmission that converted stepper rotation to plunger travel. The second used a direct trapezoidal-screw pusher that increased force but reduced build-space clearance. The third relocated actuation to a remote piston-driven module that decoupled force generation from the printhead. The final architecture integrates the remote piston with partitioned control, where the printer executes motion and a programmable logic controller (PLC) manages extrusion. This arrangement reduces carried mass, preserves build space, and enables precise volumetric dosing with fast response. On a standard desktop frame, the system achieved controllable deposition of an agar/alginate ink using off-the-shelf electronics and modest modifications. This approach promotes sustainable and accessible innovation by repurposing existing FDM printers with open-source hardware and modular components. The resulting platform supports biomimetic biofabrication by combining mechanical efficiency, environmental responsibility, and cost-effective design. Full article

The development of metal nanostructures on large-area Gallium Nitride (GaN) surfaces has the potential to enable new, low-cost technologies for III-N semiconductor layer nanostructuring. Self-assembled nanostructures are typically formed through the thermal activation of solid-state dewetting (SSD) in thin metal layers. However, such thermal processing can induce degradation of the metal-GaN material system. This comprehensive study investigated the thermal stability of thin metal films on GaN surfaces, focusing on their morphology and nanostructuring for high-temperature processing. The research expands and systematizes the understanding of the thin metal layers on GaN surface interactions at high temperatures by categorizing metals based on their behaviour: those that exhibit self-assembly, those that catalyze GaN decomposition, and those that remain thermally stable. Depending on the annealing temperature and metal type, varying degrees of GaN layer decomposition were observed, ranging from partial surface modification to significant volumetric degradation of the material. A wide range of metals was investigated: Au, Ag, Pt, Ni, Ru, Mo, Ti, Cr, V, Nb. These materials were selected based on criteria such as high work function and chemical resistance. In this studies metal layers with a target thickness of 10 nm deposited by vacuum evaporation on 2.2 $\mathsf{\mu }$m thick GaN layers grown by metal organic vapor phase epitaxy were applied. The surface morphology and composition were analyzed using AFM, SEM, EDS, and Raman spectroscopy measurement techniques. Full article