Search Results (78)

The growing use of reclaimed asphalt pavement (RAP) in warm-mix asphalt (WMA) presents significant challenges when RAP originates from aged polymer-modified binder (PMB) pavements, where severe oxidation and polymer degradation lead to excessive stiffness and poor cracking resistance. This study presents a multi-scale evaluation of a hybrid modification strategy combining recycled engine oil waste (REOW, 3 wt.%) and styrene–butadiene–styrene (SBS, 1–4 wt.%) to restore aged PMB-containing RAP systems under controlled binder conditions. Three binders (control, REOW-modified, and REOW–SBS hybrid) were prepared using a fixed 70/30 virgin-to-RAP binder blend and characterized through rheological analysis, and multiple stress creep recovery (MSCR). The findings show that REOW softened the binder but reduced elastic recovery, whereas SBS modification restored elastic response. Corresponding WMA mixtures with 30 wt.% RAP and 5.0 wt.% total binder content were evaluated for moisture damage, raveling, rutting, and cracking resistance. At the mixture scale, the hybrid system achieved a TSR of 83%, reduced Hamburg rut depth by ~20%, and increased SCB fracture energy by ~30% compared with the control. These findings demonstrate that combined rejuvenation–reinforcement effectively re-mobilizes aged PMB chemistry and restores polymer elasticity, enabling high-performance WMA production with RAP derived from polymer-modified pavements. Full article

To address the issue of inefficient interfacial diffusion between virgin asphalt and the aged asphalt in Reclaimed Asphalt Pavement (RAP), this study investigates how a rejuvenator improves the interfacial blending behavior and restores the functional properties of aged asphalt. Molecular dynamics (MD) simulations were employed to construct aged asphalt–rejuvenator models with varying rejuvenator contents and to establish a bilayer dynamic model of the virgin-aged asphalt–rejuvenator diffusion system. The kinetic characteristics of the diffusion process were analyzed based on system density and relative concentration profiles, while the mean square displacement (MSD) and diffusion coefficients were calculated to elucidate the diffusion mechanism. The accuracy of the MD simulation results was validated using Fourier Transform Infrared Spectroscopy (FTIR) and Differential Scanning Calorimetry (DSC), and the regulatory mechanism of the rejuvenator on the interfacial diffusion between virgin and aged asphalt was revealed at the microscopic scale. The results demonstrated that the addition of the rejuvenator effectively promotes the blending and diffusion at the virgin-aged asphalt interface. Specifically, a 6% rejuvenator significantly improved the diffusion efficiency at elevated temperatures, optimized system density toward virgin asphalt properties, and achieved the most uniform molecular distribution, thereby facilitating balanced intermolecular interactions. Meanwhile, the regenerant effectively restored the aromatic fraction content, reduced polar functional groups such as sulfoxide, and significantly lowered the glass transition temperature (Tg), thereby enhancing the low-temperature crack resistance and overall mechanical performance of RAP. Full article

Severe asphalt ageing and the difficulty in dispersing agglomerated particles within reclaimed asphalt pavement (RAP) hinder the uniform blending of virgin and aged mineral aggregates during plant-mixed hot recycling, compromising the durability of the recycled asphalt mixture. To accurately quantify the degree of blending between virgin and aged aggregate during thermal recycling and to optimise the mix design and mixing process for thermally recycled asphalt mixtures, a test method has been proposed. This method comprises key steps, including the preparation of asphalt mixtures, separation of virgin and aged materials, separation of the binder from aggregate, and calculation of the blending degree. It analyses the impact of varying mixing conditions on the blending degree of virgin and aged aggregate during the thermal recycling process. The results indicate that complete homogenization of virgin and aged aggregates during mixing is unattainable, with blending efficiency ranging from 40% to 60%. Increasing the amount of RAP has a negligible effect on blending efficiency. Appropriate increases in the amount of rejuvenating agent, mixing temperature, mixing time, and asphalt content enhance blending efficiency by 10% to 30%. The mixing sequence where RAP is first blended with virgin aggregate before incorporating virgin asphalt further enhances the blending efficiency of virgin and aged aggregates by approximately 20%. However, mixing temperatures exceeding 160 °C and mixing times exceeding 270 s caused secondary ageing of the asphalt, adversely affecting the blending degree of virgin and aged aggregates. Full article

To apply molecular dynamics (MD) simulations in the study of virgin asphalt binder, researchers have relied on basis sets of representative model structures from the SARA categories of saturated aliphatics (S), naphthenic aromatics (A), polar aromatics or resins (R), and asphaltenes (A). The evolution of these model compounds for MD of binder is reviewed with emphasis on addition of oxidized species for simulations of recycled aged binders. The level and type of oxygen functional groups in many MD simulations are not consistent with reported findings. Oxidation of primary, secondary, and tertiary benzylic carbons has been used as a rational approach to generate an extended basis set with functional groups reflecting ageing of virgin binder model compounds. Moieties known to be present in aged binder, though not wholly represented in prior work, include carboxylic acids, ketones, alcohols, anhydrides, and sulfoxides. A specific modified basis set for oxidized asphalt binder is proposed along with a methodology for generating other oxygen-consistent basis sets from virgin binder structures. An example illustrates how selection of compounds from the modified basis set and their amounts can be used to match observed functional group compositions. The objective of this approach is more realistic representation of the molecular interactions between aged asphalt binder structures and those in a waste cooking/motor oil, for example, used to rejuvenate the rheological properties of a binder. Full article

Sustainable management of Construction and Demolition Waste (CDW) is key to the Circular Economy. Reusing crushed concrete as recycled concrete aggregates (RCAs) in hot-mix asphalt (HMA) is a viable CDW solution, although RCA’s high absorption can affect performance. This study evaluates the effect of partially replacing 0%, 10%, and 30% of virgin aggregate with RCA in a dense-graded HMA, assessing its moisture susceptibility and cracking resistance. Specimens were subjected to long-term water-immersion aging (3 and 6 months at 25 °C) and tested for Indirect Tensile Strength (ITS), Tensile Strength Ratio (TSR), and Cracking Tolerance Index (CT-index). RCA incorporation consistently increased ITS at all aging levels. In particular, the 30% RCA mixtures exhibited the highest strength, exceeding the absolute ITS thresholds required by various U.S. transportation agencies to ensure structural capacity. While TSR values remained below the 80% AASHTO T 283 threshold, 10% and 30% RCA mixes had higher TSR than the control, indicating a comparative improvement in moisture resistance. Conversely, the CT-index decreased with more RCA and longer immersion, particularly at 30% RCA, revealing a trade-off between strength gain and cracking tolerance under prolonged wet exposure. Overall, a 10% RCA replacement level provided the most balanced performance, supporting its technical feasibility for sustainable, performance-based mixture design. Full article

The miscible process of virgin and aged asphalt in rejuvenated asphalt was studied by molecular dynamics (MD) simulation. In this paper, we used MD software to establish a molecular model of asphalt, and the model of aged asphalt was established by adding ketone and sulfoxide functional groups to the original asphalt. Wood tar rejuvenator (WTR) was selected for rejuvenation of aged asphalt, and parameters such as density, surface free energy, cohesion energy density, and Young’s modulus were used to verify the molecular model. The density, relative concentration, interaction energy, mean square displacement of molecules, diffusion coefficient, mixing free energy, and radial distribution function were used to analyze the action mechanism of the rejuvenator in the rejuvenation process and the suitable service temperature and optimal amount of WTR. The results demonstrated that the WTR with 373 K and 15% mass ratio has the best rejuvenation effect on aged asphalt. The addition of WTR can increase the interaction energy between original and aged asphalt by 12.9%, reduce the Van der Waals potential energy of aged asphalt by 13.85%, and thus ensure the uniform distribution of internal molecules in rejuvenated asphalt. A 15 wt% WTR can reduce the intermolecular distance of asphaltenes from 9.4 Å to 5.2 Å, thereby alleviating the displacement effect during the asphalt aging process. The diffusion coefficients of WT-rejuvenated asphalt at 298 K and 373 K are 28.6% and 44.6% higher than those of extracted oil-rejuvenated asphalt, respectively; thus, WT-rejuvenated asphalt has better crack resistance. Full article

The use of Reclaimed Asphalt Pavement (RAP) in asphalt mixtures offers environmental and economic advantages by reducing reliance on virgin aggregates and minimizing construction waste. However, the aged binder in RAP increases mixture stiffness, which can compromise fatigue resistance. This systematic review evaluates the influence of RAP content on fatigue performance compared to conventional mixtures, with a focus on the Indirect Tensile Test (IDT) as the primary assessment method. Following the parameters of Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines, five studies published between 2014 and 2024 were identified through searches in Web of Science, ScienceDirect, ASCE, and Scopus. Study quality was assessed using the Cochrane Risk of Bias tool. The results indicate that although RAP enhances rutting resistance, higher contents (>30%) often lead to reduced fatigue performance due to binder hardening and reduced mixture flexibility. The incorporation of rejuvenators—such as heavy paraffinic extracts—and modifiers, including high-modulus agents, polymers, and epoxy binders, can partially restore aged binder properties and improve performance. Sustainable innovations, such as lignin-based industrial by-products and warm-mix asphalt technologies, show promise in balancing mechanical performance with reduced environmental impact. Variability in material sources, modification strategies, and test protocols limits direct comparability among studies, underscoring the need for standardized evaluation frameworks. Overall, this review highlights that optimizing RAP content and selecting effective rejuvenation or modification strategies are essential for achieving durable, cost-effective, and environmentally responsible asphalt pavements. Future research should integrate advanced laboratory methods with performance-based design to enable high RAP utilization without compromising fatigue resistance. Full article

To meet the demand for sustainable pavement infrastructure, reclaimed asphalt pavement (RAP) has become a key strategy to enhance material circularity. This study investigates the coupled mobilization and blending behaviors between virgin and aged asphalt mastic in RAP systems. Fourier-Transform Infrared Spectroscopy (FTIR) was utilized to quantify the mobilization rate (MR) of aged mastic on RAP aggregate surfaces using the Composite Aging Index (CAI). Scanning Electron Microscopy (SEM) and Fluorescence Microscopy (FM), combined with digital image analysis, were employed to assess the blending interface and quantify the degree of blending (DoB). A 3D model was developed to describe the nonlinear relationship between MR and DoB. The results show that regeneration is dominated by physical diffusion, while mixing temperature has a stronger effect on MR than time. The binder interface displays a smooth transition, whereas the mastic interface exhibits a gear-like structure. DoB in the binder system is higher than that in the mastic system under the same condition, with early-stage temperature elevation playing a key role. Even near 100%, MR does not lead to full blending due to interfacial saturation. These insights are valuable for guiding the design of RAP and optimizing mixing conditions to enhance recycling efficiency in practical applications. Full article

The increasing demand for sustainable practices in road construction has prompted the search for environmentally friendly and cost-effective materials. This study explores the incorporation of reclaimed asphalt pavement (RAP) and Panasqueira mine waste (greywacke aggregates) as full replacements for virgin aggregates in hot mix asphalt (HMA), aligning with the objectives of UN Sustainable Development Goal 9. Three asphalt mixtures were prepared: a reference mixture (MR) with granite aggregates, and two modified mixtures (M15 and M20) with 15% and 20% RAP, respectively. All mixtures were evaluated through Marshall stability, stiffness modulus, water sensitivity, and wheel tracking tests. The results demonstrated that mixtures containing RAP and mine waste met Portuguese specifications for surface courses. Specifically, the M20 mixture showed the highest stiffness modulus, improved moisture resistance, and the best performance against permanent deformation. These improvements are attributed to the presence of stiff aged binder in RAP and the mechanical characteristics of the greywacke aggregates. Overall, the findings confirm that the combined use of RAP and mining waste provides a technically viable and sustainable alternative for asphalt pavement construction, contributing to resource efficiency and circular economy goals. Full article

Mining by-products present both an environmental challenge and a resource opportunity. This review investigates their potential application in road pavement construction, focusing on materials such as fly ash, slag, sulphur, red mud, tailings, and silica fume. Drawing from laboratory and field studies, the review examines their roles across pavement layers—subgrade, base, subbase, asphalt mixtures, and rigid pavements—emphasising mechanical properties, durability, moisture resistance, and ageing performance. When properly processed or stabilised, many of these wastes meet or exceed conventional performance standards, contributing to reduced use of virgin materials and greenhouse gas emissions. However, issues such as variability in composition, leaching risks, and a lack of standardised design protocols remain barriers to adoption. This review aims to consolidate current research, evaluate practical feasibility, and identify directions for future studies that would enable the responsible and effective reuse of mining waste in transportation infrastructure. Full article

The use of reclaimed asphalt pavement (RAP) in asphalt mixtures has increased due to its economic and environmental benefits. However, RAP integration can negatively impact the durability and performance of asphalt binders, particularly at low temperatures. This study evaluates the effects of RAP modification on the $\Delta T_C$ parameter, a key indicator of binder brittleness and resistance to non-load-related cracking, focusing on PG XX-34 and PG XX-28 grades commonly used in Kansas. Laboratory testing was conducted on virgin and RAP binders subjected to Rolling Thin-Film Oven (RTFO) and Pressure Aging Vessel (PAV) aging. Blended binders were prepared with RAP replacement levels of 15%, 25%, and 40%. The critical temperatures $T_{C,m}$, $T_{C,S}$, and $\Delta T_C$ values were calculated using data from Bending Beam Rheometer (BBR) testing. The results showed that increasing RAP content generally led to more negative $\Delta T_C$ values, indicating reduced relaxation capacity and higher susceptibility to thermal cracking. RAP source variability also affected performance, with some sources causing more severe deterioration than others. These findings highlight the limitations of conventional linear blending assumptions and underscore the need for improved RAP characterization in binder selection. The study recommends limiting RAP replacement to 25% unless the RAP source demonstrates favorable properties, incorporating $\Delta T_C$ thresholds (−2.5 °C and −5.0 °C) into binder specifications, and further investigating RAP–virgin binder interactions to enhance long-term pavement performance. The findings support the potential adoption of $\Delta T_C$ as a specification criterion for binder evaluation, helping agencies like the Kansas Department of Transportation (KDOT) balance binder durability and RAP use. Full article

In recent years, the employment of rejuvenators and warm mix asphalt (WMA) additives for reclaimed asphalt pavement (RAP) has been recognized as a popular approach to increase the recycling rate of waste materials and promote the sustainable development of pavement engineering. However, the composition of warm mix recycled asphalt binder is complicated, and the microstructural changes brought about by the rejuvenators and WMA additives are critical in determining its macroscopic mechanical properties. This research focuses on the atomic modeling of the rejuvenators and WMA additives diffusion behavior of the warm mix recycled asphalt binder. The objective is to reveal the thermodynamic performance and diffusion mechanism of the WMA binder under the dual presence of rejuvenators and WMA additives. Three types of mutual diffusion systems (Aged and oil + virgin + wax, Aged + virgin + wax, and Aged and oil + virgin) were established, respectively, for a comparative investigation of the glass transition temperature, viscosity, thermodynamics, free volume, and diffusion behavior. The results indicate a 44.27% and 31.33% decrease in the glass transition temperature and apparent viscosity, respectively, after the incorporation of 5% oil rejuvenators in the Aged + virgin + wax asphalt binder, demonstrating the improved cracking resistance and construction workability. The presence of the RAP binder and organic WMA additives raised the cohesion of the asphalt binder and decreased self-healing ability and free volume, and these detrimental influences can be offset by the introduction of rejuvenators. The combined use of rejuvenators and organic WMA additives remarkably enhanced the de-agglomeration to asphaltenes, stimulated the activity of aged RAP macromolecular components, and ultimately improved the blending efficiency of virgin binders with the overall structure of RAP binders. Full article

Currently, there is limited research on the utilization of spent coffee grounds (SCG) in asphalt pavement. This study explores using SCG as a novel rejuvenator together with waste cooking oil (WCO) to enhance the performance of aged asphalt (AA). The high-temperature performance of recycled asphalt was preserved using SCG containing oily components. However, the low-temperature performance of long-term aged asphalt could not be completely restored to the level of virgin asphalt. Therefore, various dosages of SCG and WCO were utilized to optimize the recovery of low-temperature properties while maintaining high-temperature performance. The recycled asphalt (RA) was analyzed through conventional indexes, microscopic characteristics, and rheological properties using penetration and softening point tests, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and a dynamic shear rheometer (DSR). The results showed that the G* of W₇S₁₂ increased by 90% relative to virgin asphalt. Additionally, at strain levels of 2.5% and 5%, the fatigue life of W₈S₁₈ was approximately 3.39 times and 2.34 times greater, respectively, than that of the virgin asphalt. The addition of a rejuvenator can enhance the low-temperature cracking resistance of aged asphalt. Moreover, the FTIR results indicated that the regeneration mechanism of recycled asphalt consisted of physical blending. In summary, W₇S₁₂ exhibited the highest high-temperature performance, while W₈S₁₈ demonstrated superior fatigue life. This study may promote the sustainable development of asphalt pavements by utilizing organic waste as a rejuvenator through resource recovery. Full article

Reclaimed asphalt pavement (RAP) reduces energy consumption and enhances economic benefits by recycling road materials, making it an effective approach for the sustainable use of solid waste resources. The performance of reclaimed asphalt pavement is significantly affected not only by the degradation of asphalt binders due to aging but also by the dosage of the rejuvenator used. The master curve of the complex shear modulus is widely recognized as a valuable tool for characterizing the rheological properties of asphalt binders. First, a virgin asphalt binder with a grade of SK70 was subjected to varying degrees of aging, followed by the rejuvenation of the aged asphalt using different dosages of the rejuvenator. Second, frequency sweeps were conducted on the aged and rejuvenated asphalt binders at various temperatures. Complex modulus master curves were constructed, and the CAM model was applied to fit these curves. The viscoelastic properties of asphalt at different aging levels and rejuvenator dosages were then analyzed based on the CAM parameters. Next, by applying a curve-shifting technique based on the least squares method to a reference state, both the time–temperature–aging (TTA) and time–temperature–regenerator (TTR) master curves of the complex modulus were constructed. The relationships between aging shift factors and aging times, as well as between regenerator shift factors and dosages, were established to predict the complex moduli of both aged and rejuvenated asphalt. Finally, the shear stress–strain relationships and material integrity of aged and rejuvenated asphalt were evaluated to assess their fatigue performance. The results indicated that aging significantly increases the complex modulus of asphalt, with TFOT (Thin Film Oven Test) aging having a more pronounced impact than PAV (Pressurized Aging Vessel) aging, resulting in reduced viscous deformation and an increased risk of cracking. Rejuvenator dosage reduces the complex modulus, with a 6% dosage effectively restoring mechanical properties and enhancing low-temperature performance. The TTA master curve demonstrates a strong linear correlation between aging shift factors and time, allowing for accurate predictions of the complex modulus of aged asphalt. Similarly, the TTR master curve reveals a linear relationship between regenerator dosage and shift factor, offering high predictive accuracy for optimizing regenerator dosages in engineering applications. The study further explores how varying levels of aging and rejuvenator dosage affect fatigue life under different strain conditions, uncovering complex behaviors influenced by these aging and regeneration processes. Full article

This study focuses on exploring tensile properties and nanoscale phase structures of different modified asphalts, and their aging behavior. For this, one virgin asphalt and three modified asphalts, namely, 4% SBS-modified asphalt, 2% SBS and 20% crumb rubber (CR) composite asphalt, and 4% SBS and 2%TiO₂ composite asphalt, were prepared and investigated using the force-ductility test and atomic force microscopy (AFM). Also, detailed experiments of short-term (STA) and long-term (LTA) aging were conducted to obtain aged asphalt specimens. The results showed that a ductile fracture was found for the three modified asphalts. However, for the activation energy, SBS asphalt and SBS&TiO₂ asphalt were 2.87 times and 3.31 times that of SBS&CR asphalt, respectively. This demonstrates that the activation of the SBS polymer phase requires more energy during the stretching process when the rubber powder is not present. SBS&CR asphalt and SBS&TiO₂ asphalt showed better tensile properties and aging resistance in terms of the quantitative results of tensile property indicators, indicated by a larger value of fracture ductility, tensile compliance, and the toughness ratio under the same aging condition. According to the AFM results, SBS modifier had little effect on the phase structure of virgin asphalt, while TiO₂ modifier increased the number of bee phases and made their distribution more uniform, indicating the formation of a more stable phase structure system. This may contribute to its better tensile properties and aging resistance. Moreover, TiO₂ molecules inhibited the aggregation behavior of polar molecules during the aging process, which led to a reduction in surface roughness. By comparison, the effect of aging on the phase structure of SBS&CR asphalt was more significant among the three modified asphalts. This result can be attributed to the interaction between rubber powder particles and asphalt. Full article