Search Results (130)

Thin-walled composite beams with unsymmetric laminates are attracting increasing attention in lightweight aerospace and mechanical structures because they enable enhanced stiffness tailoring and weight reduction beyond the limitations of conventional symmetric stacking sequences. However, despite their practical relevance, unsymmetric thin-walled laminates have received comparatively limited attention in the available buckling literature due to the additional complexity introduced by membrane–bending coupling effects. This study presents an efficient and physically transparent formulation for the buckling analysis of thin-walled composite beams with both symmetric and unsymmetric layups by combining Generalized Beam Theory (GBT) with the Ritz method. The proposed GBT-Ritz framework captures global, local, distortional, torsional, and shear-related deformation modes while consistently incorporating laminate coupling effects associated with unsymmetric configurations. The formulation is applicable to open, closed, branched, and unbranched cross-sections commonly encountered in aerospace structures. Validation against ABAQUS V2017 shell finite element models demonstrates excellent agreement (with discrepancies generally below 6%) in predicting critical buckling loads and mode shapes for various geometries and boundary conditions. The results show that unsymmetric laminates can significantly influence buckling behavior, particularly in open sections and intermediate beam lengths where coupling effects become dominant. Compared with conventional finite element approaches, the proposed method achieves substantially lower computational cost (providing speed-up factors of 1.5 to 2.5) while preserving clear physical insight into interacting instability mechanisms. Overall, the developed framework provides an efficient and practically relevant tool for the analysis and design of advanced thin-walled composite structures with tailored unsymmetric laminates. Full article

Delamination is a critical failure mode in composite laminates that degrades the structural performance and load-carrying capacity. This study investigates the improvement of Mode I and Mode II interlaminar fracture toughness of carbon fiber-reinforced polymer (CFRP) laminates through the interleaving of electrospun thermoplastic nanofiber mats. Nanofiber veils were inserted between carbon fiber plies to enhance resistance to delamination under tensile opening (Mode I) and in-plane shear (Mode II) loading. The effects of nanofiber interleaving were evaluated using double cantilever beam (DCB) tests for Mode I and end notch flexure (ENF) tests for Mode II. Both tests were conducted on a symmetric quasi-isotropic laminate [-45/45/90/0₅]_s containing a thick unidirectional 0° ply at the mid-plane. Thermally induced residual stresses resulting from mismatches in ply coefficients of thermal expansion and unsymmetric arm lay-ups were accounted for in the experimental determination of fracture toughness. These stresses, generated during cooling from the cure temperature, influence the effective strain energy release rate and were included in the fracture toughness calculations to ensure accurate toughness evaluation and consistency with numerical predictions. The results demonstrate improved delamination fracture toughness, highlighting the potential of nanofiber interleaving for aerospace and wind energy applications. Full article

A novel unsymmetrical azine, 6-((2-oxoindolin-3-ylidene)hydrazineylidene)indolo[2,1-b]quinazolin-12(6H)-one, was synthesized through a condensation reaction between tryptanthrin-6-hydrazone and isatin in chloroform under reflux conditions. Structural characterization revealed the compound exists as a mixture of geometric isomers with one predominant form. Density functional theory (DFT) calculations identified the E,E configuration as the most stable isomer. The isomerization barriers for both C=N bonds were calculated at approximately 18.5 kcal/mol via nitrogen inversion. Given the established biological activities of tryptanthrin and isatin derivatives, this hybrid azine represents a promising lead compound for developing bifunctional drug candidates. Full article

Safety is the most important requirement in flight operations. This also affects the application for an extreme lightweight glider in this paper. Essential properties are the target weight below 120 $\mathrm{k}\mathrm{g}$ and the electric propulsion. The unsymmetric inertia from the two-blade propeller at the rear in combination with the light and flexible aluminium tube support makes it necessary to investigate the risk of mechanical instability. Starting from the equations of motion, the time-variant system matrices are set up. The simulation of Floquet multiplier and Hill’s hyper-eigenvalue problem provide the necessary information about the system stability. The conclusion is that the potential instability due to structural damping in the observed system can be avoided in the range of operation. The damping, experimentally determined by approximately 2%, is sufficient. Full article

In this study, two γ-carbon-substituted dialkylphosphinic acids—symmetrical di-(3,5,5-trimethylhexyl)phosphinic acid (P355) and unsymmetrical (2-ethylhexyl)(3,5,5-trimethylhexyl)phosphinic acid (P227-355)—were synthesized via a precise free radical addition method. Their chemical structures were fully characterized using ESI-HRMS, ¹H NMR, ³¹P NMR, and FT-IR. Their middle REE extraction/separation performance, anti-emulsification behavior, and underlying mechanisms were investigated. Key results showed that P355 had better Dy saturation capacity (357.51 mg/L) and good selectivity for middle REEs (their average value of β_{N + 1/N} = 3.18), while P227-355 showed higher back-extraction efficiency (≈90% Dy stripping at ≥0.02 mol/L H₂SO₄). Methyl n-pentyl ketone (MNPK) eliminated emulsification and boosted saturation capacity (324.18 mg/L Sm and 357.51 mg/L Dy for P355). Mechanistically, the extraction followed cation exchange (Sm³⁺ + 2(HL)₂ ↔ Sm·L₃·(HL) + 3H⁺); MNPK formed hydrogen-bonded associates (HL·MNPK) with free extractants, slightly reducing the effective concentration of (HL)₂ but not altering the core cation exchange mechanism. Full article

Two phenanthroline derivatives, 2-(2,6-diisopropylphenoxy)-9-phenyl-1,10-phenanthroline and 2,9-bis(2,6-diisopropylphenoxy)-1,10-phenanthroline, were synthesized. The unsymmetrical derivative was obtained in high yield through a sequence combining Suzuki coupling and nucleophilic substitution. The crystal structures of both compounds were determined by single-crystal X-ray diffraction and examined by Hirshfeld surface analysis, which outlined the main intermolecular interactions responsible for the packing. The optical properties were studied by UV–Vis absorption and fluorescence spectroscopy in different solvents. The unsymmetrical compound showed stronger intramolecular charge transfer and more pronounced solvatochromism, while the symmetrical analog had a higher fluorescence quantum yield and longer excited-state lifetime. These results demonstrate the role of substitution symmetry in controlling molecular organization and photophysical properties of phenanthroline derivatives, with relevance to sensing and optoelectronic applications. Full article

In low-voltage (LV) distribution networks, system operating conditions are always unbalanced due to the unpredictability of the load demand in each phase, coupled with a potentially asymmetrical network structure due to different phase conductors’ sizes and lengths. The widespread diffusion of distributed generators (DGs) among network users has significantly contributed to reducing the overall load of the electrical system, but at the cost of making voltages slightly more unbalanced. In this article, an LV distribution test network equipped with several single-phase DGs has been considered, and all During-Fault Voltages (DFVs) have been studied, according to each possible type of short circuit. To provide a measure of the asymmetry of unsymmetrical voltage dips, three different indices based on the symmetrical components of the voltages have been considered; moreover, the Monte Carlo simulation (MCS) method has allowed for studying faults and asymmetries in a probabilistic manner. Through the probability density functions (pdfs) of the DFVs, it has been possible to assess the impact of single-phase DGs on the asymmetry of bus voltages due to short-circuits. Full article

Predicting buckling in large-scale composite structures is hindered by the need for highly detailed Finite Element (FE) models, which are computationally expensive and impractical for early-stage design iterations. This study introduces a macromodelling buckling framework that reduces those models to plate-level size without sacrificing accuracy. An equivalent bending stiffness matrix is derived from strain–energy equivalence, rigorously retaining orthotropic in-plane terms, bending–extensional coupling, and—crucially—the eccentricity of compressive loads about an unsymmetrically stiffened mid-plane, effects overlooked by conventional Parallel-Axis smearing. These stiffness terms contribute to closed-form analytical solutions for homogeneous orthotropic plates, providing millisecond-level evaluations ideal for gradient-based design optimisation. The method is benchmarked against detailed FE simulations of panels with three to ten stringers under longitudinal and transverse compression, showing less than 5% deviation in critical load prediction. Its utility is demonstrated in the sizing optimisation of the upper cover of a scaled Airbus A330 composite wing-box, where the proposed model explores the design space in minutes on a standard workstation, orders of magnitude faster than full FE analyses. By combining analytical plate theory, enhanced smearing, and rapid optimisation capability, the framework provides an accurate, ultra-fast tool for buckling analysis and the preliminary design of large-scale stiffened composite structures. Full article

A synthesis of substituted 1,4-benzodiazepines has been developed via palladium-catalyzed cyclization of N-tosyl-disubstituted 2-aminobenzylamines with propargylic carbonates. The reaction proceeds through the formation of π-allylpalladium intermediates, which undergo intramolecular nucleophilic attack by the amide nitrogen to afford seven-membered benzodiazepine cores. In reactions involving unsymmetrical diaryl-substituted carbonates, regioselectivity was observed to favor nucleophilic attack at the alkyne terminus substituted with the more electron-rich aryl group, suggesting that electronic effects play a key role in determining product distribution. The versatility of this reaction was further demonstrated by constructing a benzodiazepine framework found in bioactive molecules, indicating its potential utility in medicinal chemistry. Mechanistic insights supported by stereochemical outcomes and X-ray crystallographic analysis of key intermediates reinforce the proposed reaction pathway. This palladium-catalyzed protocol thus offers an efficient and practical approach to access structurally diverse benzodiazepine derivatives. Full article

The purpose of this research was to indicate the importance of an efficient design of steel frame structures, taking into account the fire design situation. In the case of steel frame structures, the typical mechanisms of failure (sway, beam, and mixed) are well known. Using this knowledge, combined with a reliability assessment of single nodes, may let designers reduce both the amount of material used for a structure and the total cost of the structure. In this article, one-story, single-nave frames with different loads were analyzed. Two types of loads were analyzed: symmetrical and unsymmetrical. Both cases resulted in different failure paths. The static analysis of the structure in the following minutes of the fire duration was carried out in the Robot Structural Analysis programme. The temperature load was computed according to the Eurocode recommendation with the assumption that the temperature of fire gases is described by the standard fire curve. Afterward, the system reliability analysis for the selected failure paths was conducted. Additionally, the displacement analysis was performed in the following minutes of the fire. The biggest challenge in the proposed method is that there are many potential failure paths, and checking all of them is very time-consuming, even when using advanced computers. Therefore, only selected collapse modes were analyzed. Full article

The catalytic performance of α-diiminonickel complexes is highly sensitive to structural modifications in their ligand frameworks. In this study, a series of unsymmetrical 2,3-bis(arylimino)butane-nickel complexes featuring ortho-2,6-dibenzhydryl groups as sterically demanding motifs and para-methyl groups as electron-donating enhancers were proposed and synthesized. These nickel complexes were thoroughly characterized using FTIR, elemental analysis, and single-crystal X-ray diffraction (for Ni4 and Ni5), revealing deviations from ideal tetrahedral geometry. Upon activation with Et₂AlCl, these complexes demonstrated exceptional ethylene polymerization activity, achieving a remarkable value of 13.67 × 10⁶ g PE mol⁻¹ (Ni) h⁻¹ at 20 °C. Notably, even at 80 °C, the nickel complexes maintained a high activity of 1.97 × 10⁶ g PE mol⁻¹ (Ni) h⁻¹, showcasing superiority compared to previously reported unsymmetrical 2,3-bis(arylimino)butane-nickel complexes. The resulting polyethylenes exhibited ultra-high molecular weights (M_w: 3.33–19.47 × 10⁵ g mol⁻¹) and tunable branching densities (84–217/1000C), which were effectively controlled by polymerization temperature. Moreover, the mechanical properties of the polyethylenes, including tensile strength (σ_b = 0.74–16.83 MPa), elongation at break (ε_b = 271–475%), and elastic recovery (SR = 42–74%), were finely tailored by optimizing molecular weight, crystallinity, and branching degree. The prepared polyethylenes displayed outstanding elastic recovery, a hallmark of high-performance thermoplastic elastomers, making them promising candidates for advanced material applications. Full article

Cold-formed steel (CFS) unsymmetrical angles are increasingly used in structural applications such as portal frames, roof trusses, and transmission towers. However, research on built-up face-to-face unsymmetrical CFS angle columns (FFUACs) with stiffeners remains limited. This study addresses this gap by presenting the findings from six experimental investigations on intermediate FFUACs connected using intermittent screw fasteners. The results offer insights into failure deformation patterns and load-axial shortening behaviour. A nonlinear finite element (FE) model was developed to account for material and geometric nonlinearity, with experimental results used for validation. This study contributes 166 new data points, including six experimental tests under concentric compression and 160 finite element analysis (FEA) results focused on the compressive strength of FFUACs. Additionally, this study evaluates the performance of existing design guidelines based on the direct strength method (DSM). The DSM strength predictions were found to be less conservative for stub FFUAC specimens that failed due to local buckling and more conservative for short FFUAC specimens that failed due to a combination of local and flexural buckling. A revised DSM methodology is proposed to address these discrepancies. Full article

Unsymmetrical urea derivatives are essential structural motifs in a wide array of biologically significant compounds. Despite the well-established methods for synthesizing symmetrical ureas, efficient strategies for the synthesis of unsymmetrical urea derivatives remain limited. In this study, we present a novel approach for the synthesis of unsymmetrical urea derivatives through the coupling of amides and amines. Utilizing hypervalent iodine reagent PhI(OAc)₂ as a coupling mediator, this method circumvents the need for metal catalysts, high temperatures, and inert atmosphere. The reaction proceeds under mild conditions and demonstrates broad substrate scope, including various primary and secondary amines and primary benzamides. This protocol not only offers a practical and versatile route for synthesizing unsymmetrical ureas but also shows significant potential for the late-stage functionalization of complex molecules in drug development. Full article

Curcuminoids are widely studied due to their well-recognized therapeutic properties. These molecules are often derivatized with metals, producing their corresponding homoleptic metal complexes. Numerous crystal structures of homoleptic symmetric curcuminoids with physiologically essential metals are known, although the literature lacks reports of homoleptic metal complexes of unsymmetric curcuminoids (or hemi-curcuminoids) as ligands. Three unknowns must be solved when an unsymmetric curcuminoid ligand is reacted with a metal ion: (a) the degree of coordination (MLn); (b) the spatial geometry; and (c) the conformational nature (syn or anti) of the complex. Herein, we report the structure of the anti-isomer of the Zn complex of the hemi-curcuminoid 5-hydroxy-1-(4-methoxyphenyl)hexa-1,4-dien-3-one. While the NMR shows only one set of signals for this homoleptic complex, the unambiguous stereochemistry was established through single-crystal X-ray diffractometry, revealing an anti-hexacoordinated octahedral ML₂ structure. Full article

It is widely recognized that certain structures, when subjected to static compression, may exhibit a bifurcation point, leading to the potential occurrence of a secondary equilibrium path. Also, there is a tendency of deflection increment without a bifurcation point to occur for imperfect structures. In this paper, some relatively unknown phenomena are investigated. First, it is demonstrated that in some conditions, the linear buckling mode shape may differ from the result of geometrically nonlinear analysis. Second, a mode jumping phenomenon is described as a transition from a secondary equilibrium path to an obscure one as a tertiary equilibrium path or a second bifurcation point. In this regard, some non-square plates with unsymmetric layer arrangements (in the presence of extension–bending coupling) are subjected to a uniaxial in-plane compression. By considering the geometrically linear and nonlinear problems, the bucking modes and post-buckling behaviors, e.g., the out-of-plane displacement of the plate versus the load, are obtained by ANSYS 2023 R1 software. Through a parametric analysis, the possibility of these phenomena is investigated in detail. Full article