Search Results (1,063)

This study developed a new magnetic adsorbent from waste coconut shells using high-temperature carbonization, EDTA-2Na chelation, and Fe₃O₄ magnetic loading. Response surface methodology optimized the preparation conditions to a mass ratio of activated carbon: EDTA-2Na:Fe₃O₄ = 2:0.6:0.2. Characterization (SEM, XRD, FT-IR, and EDS) showed that EDTA-2Na increased the surface carboxyl and amino group density, while Fe₃O₄ loading (Fe concentration 6.83%) provided superior magnetic separation performance. The optimal adsorption conditions of Cu²⁺ by EDTA-2Na-Fe₃O₄-activated carbon composite material are as follows: when pH = 5.0 and the initial concentration is 180 mg/L, the equilibrium adsorption capacity reaches 174.96 mg/g, and the removal rate reaches 97.2%. The optimal adsorption conditions for Pb²⁺ are as follows: when pH = 6.0 and the initial concentration is 160 mg/L, the equilibrium adsorption capacity reaches 157.60 mg/g, and the removal rate reaches 98.5%. The optimal adsorption conditions for Cd²⁺ are pH = 8.0 and an initial concentration of 20 mg/L. The equilibrium adsorption capacity reaches 18.76 mg/g, and the removal rate reaches 93.8%. The adsorption followed the pseudo-second-order kinetics (R² > 0.95) and Langmuir/Freundlich isotherm models, indicating chemisorption dominance. Desorption experiments using 0.1 mol/L HCl and EDTA-2Na achieved efficient desorption (>85%), and the material retained over 80% of its adsorption capacity after five cycles. This cost-effective and sustainable adsorbent offers a promising solution for heavy metal wastewater treatment. Full article

Typhoon Yagi (2024) was a rapidly moving storm that lasted for eight days and made landfall in three locations, producing heavy rainfall over Hainan and Vietnam. This study aims to investigate the dynamical processes contributing to the heavy rainfall, concentrating on enthalpy flux (EF) and moisture flux (MF). The results indicate that both EF and MF increased significantly during the typhoon’s intensification stage and were high at the time of landfall. Before landfalling at Hainan, latent heat flux (LHF) reached 600 W/m², while sensible heat flux (SHF) was recorded as 80 W/m². Landfall at Hainan resulted in a decrease in LHF and SHF. LHF and SHF subsequently increased to 700 W/m² and 100 W/m², respectively, as noted prior to the landfall in Vietnam. The increased LHF led to higher evaporation, which subsequently elevated moisture flux (MF) following the landfall in Vietnam, while the region’s topography further intensified the rainfall. The mean daily rainfall observed over Philippines is 75 mm on 2 September (landfall and passing through), 100 mm over Hainan (landfall and passing through) on 6 September, and 95 mm at over Vietnam on 7 September (landfall and after), respectively. Heavy rainfall was observed over the land while the typhoon was passing and during the landfall. This research reveals that Typhoon Yagi’s intensity was maintained by a well-organized and extensive circulation system, supported by favorable weather conditions, including high sea surface temperatures (SST) exceeding 30.5 °C, substantial low-level moisture convergence, and elevated EF during the landfall in Vietnam. Full article

Extreme surface winds and wave heights of tropical cyclones (TCs)—pose serious threats to coastal community, infrastructure and environments. In recent decades, progress in numerical wave modeling has significantly enhanced the ability to reconstruct and predict wave behavior. This review offers an in-depth overview of TC-related wave modeling utilizing different computational schemes, with a special attention to WAVEWATCH III (WW3) and Simulating Waves Nearshore (SWAN). Due to the complex air–sea interactions during TCs, it is challenging to obtain accurate wind input data and optimize the parameterizations. Substantial spatial and temporal variations in water levels and current patterns occurs when coastal circulation is modulated by varying underwater topography. To explore their influence on waves, this study employs a coupled SWAN and Finite-Volume Community Ocean Model (FVCOM) modeling approach. Additionally, the interplay between wave and sea surface temperature (SST) is investigated by incorporating four key wave-induced forcing through breaking and non-breaking waves, radiation stress, and Stokes drift from WW3 into the Stony Brook Parallel Ocean Model (sbPOM). 20 TC events were analyzed to evaluate the performance of the selected parameterizations of external forcings in WW3 and SWAN. Among different nonlinear wave interaction schemes, Generalized Multiple Discrete Interaction Approximation (GMD) Discrete Interaction Approximation (DIA) and the computationally expensive Wave-Ray Tracing (WRT) A refined drag coefficient (C_d) equation, applied within an upgraded ST6 configuration, reduce significant wave height (SWH) prediction errors and the root mean square error (RMSE) for both SWAN and WW3 wave models. Surface currents and sea level variations notably altered the wave energy and wave height distributions, especially in the area with strong TC-induced oceanic current. Finally, coupling four wave-induced forcings into sbPOM enhanced SST simulation by refining heat flux estimates and promoting vertical mixing. Validation against Argo data showed that the updated sbPOM model achieved an RMSE as low as 1.39 m, with correlation coefficients nearing 0.9881. Full article

Change in sea level (SL) is an important indicator of global warming, since it reflects alterations in several components of the climate system at once. The main factors behind this phenomenon are the melting of glaciers and thermal expansion of ocean water, with the latter contributing about 40% to the overall rise in SL. Rising SL indirectly indicates an increase in ocean heat content and, consequently, its surface temperature. Previous studies have found that tropical sea surface temperature (SST) is critical to regulating the Earth’s climate and weather patterns in high and mid-latitudes. For this reason, SST and SL in the tropics can be considered as precursors of both global climate change and the emergence of climate anomalies in extratropical latitudes. Although SST has been used in this capacity in a number of studies, similar research regarding SL had not been conducted until recently. In this paper, we examine the links between SL in the tropical North Atlantic and North Pacific Oceans and surface air temperature (SAT) at mid- and high latitudes, with the aim of assessing the potential of SL as a predictor in forecasting SAT anomalies. To identify similarities between the variability of tropical SL and SST and that of SAT in high- and mid-latitude regions, as well as to estimate possible time lags, we applied factor analysis, clustering, cross-correlation and cross-spectral analyses. The results reveal a structural similarity in the internal variability of tropical SL and extratropical SAT, along with a significant lagged relationship between them, with a time lag of several years. Full article

High-resolution mooring observations captured diverse upper-ocean responses during typhoon passage, showing strong agreement with satellite-derived sea surface temperature and salinity. Analysis indicates that significant wind-induced mixing drove pronounced near-surface cooling and salinity increases at the mooring site. This mixing enhancement was predominantly governed by rapid intensification of near-inertial shear in the surface layer, revealed by mooring observations. Unlike shear instability, near-inertial horizontal kinetic energy displays a unique vertical distribution, decreasing with depth before rising again. Interestingly, the subsurface peak in diurnal tidal energy coincides vertically with the minimum in near-inertial energy. While both barotropic tidal forcing and stratification changes negligibly influence diurnal tidal energy emergence, significant energy transfer occurs from near-inertial internal waves to the diurnal tide. This finding highlights a critical tide–wave interaction process and demonstrates energy cascading within the oceanic internal wave spectrum. Full article

Under global warming, persistent extreme heat events (PHEs) in China have increased significantly in both frequency and intensity, posing severe threats to agriculture and socioeconomic development. Combining observational analysis (1961–2019) and numerical simulations, this study investigates the distinct impacts of Northwest Pacific (NWP) and North Atlantic (NA) sea surface temperature (SST) anomalies on PHEs over China. Key findings include the following: (1) PHEs exhibit heterogeneous spatial distribution, with the Yangtze-Huai River Valley as the hotspot showing the highest frequency and intensity. A regime shift occurred post-2000, marked by a threefold increase in extreme indices (+3σ to +4σ). (2) Observational analyses reveal significant but independent correlations between PHEs and SST anomalies in the tropical NWP and mid-high latitude NA. (3) Numerical experiments demonstrate that NWP warming triggers a meridional dipole response (warming in southern China vs. cooling in the north) via the Pacific–Japan teleconnection pattern, characterized by an eastward-retreated and southward-shifted sub-tropical high (WPSH) coupled with an intensified South Asian High (SAH). In contrast, NA warming induces uniform warming across eastern China through a Eurasian Rossby wave train that modulates the WPSH northward. (4) Thermodynamically, NWP forcing dominates via asymmetric vertical motion and advection processes, while NA forcing primarily enhances large-scale subsidence and shortwave radiation. This study elucidates region-specific oceanic drivers of extreme heat, advancing mechanistic understanding for improved heatwave predictability. Full article

In this paper, nanoscale graphene film electrodes were prepared using laser-induced technology, and an in situ electrochemical cell was constructed. The normalized peak areas at 2.82 ppm for the samples without the in situ electrochemical cell and with an in situ electrochemical cell are 4.02 and 4.41, respectively. Tests showed that this in situ electrochemical cell has minimal interference from the nuclear magnetic resonance (NMR) magnetic field, allowing for high-resolution in situ spectra. Using this in situ electrochemical cell and employing in situ electrochemistry combined with NMR techniques, we investigated the oxidation reaction of 0.01 M procarbazine (PCZ) in real-time. We elucidated the following oxidation mechanism for procarbazine: the oxidation of PCZ first generates azo-procarbazine, which then undergoes a double bond shift to hydrazo-procarbazine. hydrazo-procarbazine undergoes hydrolysis to yield benzaldehyde-procarbazine, and then finally oxidizes to produce N-isopropylterephthalic acid. This confirms that the combination of in situ electrochemistry and nuclear magnetic resonance technology provides chemists with an effective tool for in situ studying the reaction mechanisms of drug molecules. Full article

Part I of this two-part documentation of the ECMWF ensemble (ECEPS) new tropical cyclone track and intensity forecasting challenges during the 2024 western North Pacific season described four typhoons that started well to the south of an unfavorable external environment north of 20° N. In this Part II, five other 2024 season typhoons that formed and intensified near and north of 20° N are documented. One change is that the Cooperative Institute for Meteorological Satellite Studies ADT + AIDT intensities derived from the Himawari-9 satellite were utilized for initialization and validation of the ECEPS intensity forecasts. Our first objective of providing earlier track and intensity forecast guidance than the Joint Typhoon Warning Center (JTWC) five-day forecasts was achieved for all five typhoons, although the track forecast spread was large for the early forecasts. For Marie (06 W) and Ampil (08 W) that formed near 25° N, 140° E in the middle of the unfavorable external environment, the ECEPS intensity forecasts accurately predicted the ADT + AIDT intensities with the exception that the rapid intensification of Ampil over the Kuroshio ocean current was underpredicted. Shanshan (11 W) was a challenging forecast as it intensified to a typhoon while being quasi-stationary near 17° N, 142° E before turning to the north to cross 20° N into the unfavorable external environment. While the ECEPS provided accurate guidance as to the timing and the longitude of the 20° N crossing, the later recurvature near Japan timing was a day early and 4 degrees longitude to the east. The ECEPS provided early, accurate track forecasts of Jebi’s (19 W) threat to mainland Japan. However, the ECEPS was predicting extratropical transition with V_max ~35 kt when the JTWC was interpreting Jebi’s remnants as a tropical cyclone. The ECEPS predicted well the unusual southward track of Krathon (20 W) out of the unfavorable environment to intensify while quasi-stationary near 18.5° N, 125.6° E. However, the rapid intensification as Krathon moved westward along 20° N was underpredicted. Full article

Typhoons are major climate disturbances that significantly impact coastal ecosystems, particularly mangrove forests. This study examines the effects of typhoons on mangrove communities at different stages of recovery, focusing on how environmental factors influence carbon storage and net ecosystem exchange (NEE). Three mangrove sites were selected based on their recovery age: young, moderately restored, and mature. The results revealed that typhoons had the most pronounced effect on young mangroves, resulting in significant reductions in both above-ground and soil carbon storage. In contrast, mid-aged and mature mangroves demonstrated greater resilience, with mature mangroves recovering most rapidly in terms of community structure and carbon storage. Key factors such as wind speed, heavy rainfall, and changes in photosynthetically active radiation (PAR) contributed to carbon storage losses, particularly in young mangrove forests. This study underscores the importance of recovery age in determining mangrove resilience to extreme weather events and offers insights for enhancing restoration and conservation strategies to mitigate the impacts of climate change on coastal carbon sequestration. Full article

The Wyrtki Jet (WJ), a pivotal surface circulation system in the equatorial Indian Ocean, exerts significant regulatory control over regional climate dynamics through its intense eastward transport characteristics, which modulate water mass exchange, thermohaline balance, and cross-basin energy transfer. To address the scarcity of in situ observational data, this study developed a satellite remote sensing-driven multi-parameter coupled model and reconstructed the WJ’s seasonal variations using the XGBoost machine learning algorithm. The results revealed that wind stress components, sea surface temperature, and wind stress curl serve as the primary drivers of its seasonal dynamics. The XGBoost model demonstrated superior performance in reconstructing WJ’s seasonal variations, achieving coefficients of determination (R²) exceeding 0.97 across all seasons and maintaining root mean square errors (RMSE) below 0.2 m/s across all seasons. The reconstructed currents exhibited strong consistency with the Ocean Surface Current Analysis Real-time (OSCAR) dataset, showing errors below 0.05 m/s in spring and autumn and under 0.1 m/s in summer and winter. The proposed multi-feature integrated modeling framework delivers a high spatiotemporal resolution analytical tool for tropical Indian Ocean circulation dynamics research, while simultaneously establishing critical data infrastructure to decode monsoon current coupling mechanisms, advancing early warning systems for extreme climatic events, and optimizing regional marine resource governance. Full article

Background: Aquaculture increasingly seeks sustainable alternatives to fishmeal, a key protein source in fish diets. Black Soldier Fly Larvae (BSFL) meal is a promising substitute, but its effects on fish growth, immunity, and gut health need further investigation. This study aimed to evaluate the impact of varying BSFL inclusion levels on juvenile hybrid grouper (Epinephelus fuscoguttatus ♀ × Epinephelus lanceolatus ♂), a widely farmed species in tropical aquaculture. Methods: Juvenile hybrid grouper were fed diets with four levels of BSFL substitution (0%, 10%, 30%, and 50%) over 56 days. Key metrics such as growth performance, immune function, antioxidant capacity, and gut transcriptome were analyzed. Results: Replacing fish meal with BSFL meal had no significant effect on the survival rate of hybrid grouper (p > 0.05) but significantly affected growth performance, immune function, and antioxidant capacity (p < 0.05). BSFL10 and BSFL30 groups showed good growth and elevated immune enzyme activity, with significantly higher HIS levels (p < 0.05); the Wf of the BSFL10 group was comparable to the control. However, excessive replacement (BSFL50) led to reduced growth (Wf significantly lower, p < 0.05) and increased oxidative stress, as indicated by higher CAT activity (p < 0.05). Transcriptomic analysis revealed upregulation of immune- and metabolism-related genes with increasing BSFL levels, with immune pathways notably activated in the BSFL50 group. Conclusions: BSFL meal is a promising alternative to fishmeal in juvenile hybrid grouper diets, with moderate inclusion (10–30%) being most beneficial. Excessive BSFL substitution (50%) may impair fish health, highlighting the need for careful formulation in aquaculture diets. Full article

The population of southern fin whales (Balaenoptera physalus quoyi) was severely depleted by 19th and 20th century whaling. Its conservation status remains ‘vulnerable’, as recovery has been slow. Over 19 years of underwater acoustic recordings from the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO)’s hydrophones off Cape Leeuwin, Western Australia, were analyzed to monitor fin whales’ annual migration from their Southern Ocean feeding grounds (where they spend the austral summer) to their tropical breeding grounds (where they spend the austral winter) and back. Northward migrants arrived ~2 d/y earlier (2002–2020). The number of hours with fin whale acoustic presence increased by ~49 h/y and the number of days with fin whale acoustic presence by ~3 d/y. Thus, by the end of the 19-year recording period, fin whales were acoustically present on 74 more days than at the beginning of recording. While changes in habitat function, climate, and ambient noise may affect migratory behavior, the most likely explanation is a post-whaling increase in the number of animals of this Southern Hemisphere subspecies. Full article

As major bleaching continues to ravage reefs worldwide, there is an urgent need for active coral restoration. However, the high cost of such a project is inhibitive for many countries. Here, we introduce a cost-effective design for Acropora robusta and Acroporavalenciennesi coral gardening through fragmentation and direct transplantation. Implemented off Boundary Island, Hainan Province, China, the project demonstrated high coral survival rates (>94%) at a reduced cost of USD 2.50 per coral after 246 days, besides exhibiting an efficient outplanting rate at 30 coral h⁻¹ person⁻¹. Growth monitoring suggested that the transplanted Acropora spp. follow an exponential growth model over time. Initial fragment size did not seem to affect the growth rate of outplanted Acropora spp., although a weak negative correlation was found at day 246 for A. robusta. Finally, the design used in this study employs detachable steel grid nurseries and is plastics-free, ensuring sustainability and adaptability to different reef conditions, and thus providing a promising strategy for affordable coral reef restoration. Full article

The Upper Carboniferous strata in the eastern Qaidam Basin, comprising several hundred meters of thick, mixed clastic–carbonate successions that have been little reported or explained, provide an excellent geological record of paleoenvironmental and paleo-sea level changes during the Late Carboniferous icehouse period. This tropical carbonate–clastic system offers critical constraints for correlating equatorial sea level responses with high-latitude glacial cycles during the Late Paleozoic Ice Age. Based on detailed outcrop observations and interpretations, five facies assemblages, including fluvial channel, tide-dominated estuary, wave-dominated shoreface, tide-influenced delta, and carbonate-dominated marine, have been identified and organized into cyclical stacking patterns. Correspondingly, four third-order sequences were recognized, each composed of lowstand, transgressive, and highstand system tracts (LST, TST, and HST). LST is generally dominated by fluvial channels as a result of river juvenation when the sea level falls. The TST is characterized by tide-dominated estuaries, followed by retrogradational, carbonated-dominated marine deposits formed during a period of sea level rise. The HST is dominated by aggradational marine deposits, wave-dominated shoreface environments, or tide-influenced deltas, caused by subsequent sea level falls and increased debris supply. The sequence stratigraphic evolution and geochemical records, based on carbon and oxygen isotopes and trace elements, suggest that during the Late Carboniferous period, the eastern Qaidam Basin experienced at least four significant sea level fluctuation events, and an overall long-term sea level rise. These were primarily driven by the Gondwana glacio-eustasy and regionally ascribed to the Paleo-Tethys Ocean expansion induced by the late Hercynian movement. Assessing the history of glacio-eustasy-driven sea level changes in the eastern Qaidam Basin is useful for predicting the distribution and evolution of mixed cyclic succession in and around the Tibetan Plateau. Full article

This study presents a global aerosol climatology derived from six years (October 2018–October 2024) of the Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) observations, using a U-Net Convolutional Neural Network (CNN) machine learning algorithm for Cloud–Aerosol Discrimination (CAD). Despite ICESat-2’s design primarily as an altimetry mission with a single-wavelength, low-power, high-repetition-rate laser, ICESat-2 effectively captures global aerosol distribution patterns and can provide valuable insights to bridge the observational gap between the Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) and Earth Cloud, Aerosol and Radiation Explorer (EarthCARE) missions to support future spaceborne lidar mission design. The machine learning approach outperforms traditional thresholding methods, particularly in complex conditions of cloud embedded in aerosol, owing to a finer spatiotemporal resolution. Our results show that annually, between 60°S and 60°N, 78.4%, 17.0%, and 4.5% of aerosols are located within the 0–2 km, 2–4 km, and 4–6 km altitude ranges, respectively. Regional analyses cover the Arabian Sea (ARS), Arabian Peninsula (ARP), South Asia (SAS), East Asia (EAS), Southeast Asia (SEA), the Americas, and tropical oceans. Vertical aerosol structures reveal strong trans-Atlantic dust transport from the Sahara in summer and biomass burning smoke transport from the Savanna during dry seasons. Marine aerosol belts are most prominent in the tropics, contrasting with earlier reports of the Southern Ocean maxima. This work highlights the importance of vertical aerosol distributions needed for more accurate quantification of the aerosol–cloud interaction influence on radiative forcing for improving global climate models. Full article